ライフサイエンスコーパス: energetically

1 nd these are related, both geometrically and energetically.

2 addition-elimination (AE) pathway is favored energetically.

3 while the associated valence band holes are energetically able to oxidize water to O2.

4 Extensive computer analyses of energetically accessible analogue conformations suggeste

5 se calculations revealed the existence of an energetically accessible and more basic Fe(0)Ni(II) isom

6 glycosidic linkage fundamentally alters the energetically accessible conformational space of a thiom

7 omputational methodology to predict multiple energetically accessible conformations for G protein-cou

8 ercury 6p1/2 and 6p3/2 orbitals, making them energetically accessible for chemical bonding.

9 hodium congener highlights the impact of the energetically accessible one-electron redox couple of th

10 omerization of {[LCu(III)]2-(mu-O)2}(2+) are energetically accessible pathways for O-O bond formation

11 pi* orbitals of b1 and a2 symmetry that are energetically accessible.

12 xit channel to produce C + O2 should also be energetically accessible.

13 where one or more repeats are unfolded to be energetically accessible.

14 This response involves redistribution of energetically active mitochondria to the cortical cytosk

15 enefits from orographic lift, is shown to be energetically advantageous for flights over the Himalaya

16 ally expensive brains of Homo sapiens can be energetically afforded.

17 upied molecular orbital (LUMO) are generally energetically and chemically stable.

18 these inter-Landau-level states, being both energetically and spatially isolated quantum states, are

19 Despite residing in an energetically and structurally disordered landscape, the

20 urprisingly compact structure, featuring two energetically and structurally equivalent binding modes

21 hepatic anaplerotic/cataplerotic pathways is energetically backed by elevated oxidative metabolism an

22 oth inner and outer membranes and are driven energetically by a primary or secondary transporter comp

23 ects of palmitate and glucose on resting and energetically challenged mitochondria in DRG neurons.

24 ation and may adopt a diurnal phenotype when energetically challenged.

25 o ammonia (NH3) is a kinetically complex and energetically challenging multistep reaction.

26 While the latter is energetically close to the unfolded state, its volumetri

27 ciples calculations, showing these polytypes energetically comparable to the A7 structure under ambie

28 -image and native conformations are at least energetically compatible.

29 Furthermore, energetically competing C- and G-type magnetic orderings

30 ng different crystallographic directions are energetically competing.

31 itio random structure search reveals all the energetically competitive monolayer configurations to be

32 b initio random structure search reveals six energetically competitive potential phases, four tetrago

33 Such a surface is energetically competitive with the known dimer structure

34 , the Fe(III)-vacancy mechanism becomes more energetically competitive.

35 g a binding mode that is both temporally and energetically complementary with a system requiring posi

36 We report the experimental observation of energetically confined self-accelerating optical beams p

37 quantitatively reconcile this contrast in an energetically consistent manner.

38 Therefore, not all mesopredators are energetically constrained by direct competition.

39 Here, we examine these interactions in a bio-energetically constrained, spatially and temporally reso

40 s) have led some to suggest that richness is energetically constrained.

41 The production of offspring is energetically costly and relies on incompletely understo

42 Brain activity is energetically costly and requires a steady and highly re

43 (c) cause triggered arrhythmias; and (d) be energetically costly because of extra ATP used to repump

44 ed response appears to divert resources from energetically costly biomass production to improve resil

45 remains poorly understood which tasks are so energetically costly for the brain.

46 rsity and abundance of milk glycans that are energetically costly for the mammary gland to produce ye

47 gs (Lycaon pictus) are reported to hunt with energetically costly long chase distances.

48 reduced foraging time, especially during the energetically costly pup-rearing period.

49 Although restoring ionic gradients is energetically costly, a rise in intracellular Ca(2+) act

50 ally encoded alphabet are extremely rare and energetically costly.

51 , these performance gains are submaximal and energetically costly.

52 Defense of core body temperature (Tc) can be energetically costly; thus, it is critical that thermore

53 series of large conformational changes that energetically couple refolding to membrane fusion.

54 ences, we built a model of residues that are energetically coupled and that define molecular routes f

55 han 25 mutants demonstrate that residues are energetically coupled in the DSE.

56 steps in AChR activation comprise a single, energetically coupled process.

57 rwise mutations reveals that alphaAsp-138 is energetically coupled to alphaArg-209 in the neighboring

58 tructurally and functionally conserved while energetically coupled to each other.

59 ociated with the supercomplex appeared to be energetically coupled to PS I based on 77 K fluorescence

60 e arm contains four antiporter-like domains, energetically coupled to the quinone site and involved i

61 cell function because membrane proteins are energetically coupled to their host lipid bilayer.

62 ole hopping can equilibrate the six possible energetically degenerate ion-pair states, as suggested b

63 Leveraging competition between energetically degenerate states to achieve large field-d

64 n in superhard WB3 and MoB3 with a series of energetically degenerate structures due to the random st

65 artitioning of PbTiO3 thin films into nearly energetically degenerate, hierarchical domain architectu

66 populations, even though the two valleys are energetically degenerate, locked by time-reversal symmet

67 tion pathways corresponding to distinct, but energetically degenerate, random hexagonal close-packed

68 the Wheland intermediate, thus avoiding more energetically demanding [1,3]- or [1,2]/[1,2]-H shifts.

69 rt inter-birth intervals that make offspring energetically demanding [9] and have moved to a dietary

70 This energetically demanding activity is crucial for precise

71 TIM is activated through an energetically demanding conformational change, which hel

72 r cooperative helix formation in terms of an energetically demanding nucleation event (described by t

73 le in increased fat metabolism during highly energetically demanding periods, and that blubber concen

74 This energetically demanding process depends upon the ability

75 thesis of eukaryotic ribosomes is a complex, energetically demanding process requiring the aid of num

76 strocytes ensure local metabolic support for energetically demanding processes and enable coupling be

77 nse and reproduction are physiologically and energetically demanding processes and have been observed

78 daptive response featuring the inhibition of energetically demanding processes, including gluconeogen

79 s of the ATP synthase and is suspected to be energetically dependent on its host, Ignicoccus hospital

80 trostatic interactions that could be used to energetically differentiate transition states.

81 , carbon, but the mechanistic basis for this energetically disfavored regiostereochemistry has been l

82 chain of p-biphenylalanine is trapped in the energetically disfavored, coplanar conformation of the T

83 and an unexpected approximately 300-nm wide, energetically disordered edge region.

84 t c intermediates and pathways during normal energetically downhill kinetic folding, the present work

85 brium geometry for the protonated species is energetically downhill.

86 Fibril growth is disfavored energetically due to cancellation of direct peptide-pept

87 r sense, we have discovered a temporally and energetically efficient mechanism in which the innate im

88 s leakage, making the CCM significantly more energetically efficient.

89 O2 but is able to pump protons and hence is energetically efficient; Cyd has a high affinity for O2

90 f the core states by a transiting carrier is energetically enabled, resulting in a sequential tunnell

91 reference for one particular state from many energetically equivalent available minima.

92 surface and that it can transit between two energetically equivalent extended and contracted conform

93 phenomenon of frustration leads to numerous energetically equivalent ground states, and results in e

94 res undergo hysteretic behaviour between two energetically equivalent skyrmionic states with differen

95 ole does not provide catalysis by forming an energetically exceptional pKa-matched hydrogen bond.

96 However, since protein translation is energetically expensive and tightly controlled, it is un

97 Exposure did not elicit energetically expensive behaviors, but scallops showed s

98 e their utility for prey capture, venoms are energetically expensive commodities, and consequently it

99 conserved mechanism well-suited to suppress energetically expensive correlated network events under

100 compound II state and reducing the need for energetically expensive electron donor molecules.

101 ary carbon and energy substrate, whereas the energetically expensive NMG pathway plays a pivotal role

102 s, translation of viral proteins is the most energetically expensive process.

103 rnative to modulating mitochondrial mass, an energetically expensive process.

104 apparently vigorous, the infected shoots are energetically expensive structures characterized by the

105 However, producing wings is energetically expensive.

106 synthesis and mitochondrial proton leak are energetically expensive.

107 than for the Ag 4d(10) orbitals, Cu(I) atoms energetically favor 4-fold coordination, forming [CuX4 ]

108 guest content, and so to determine the most energetically favorable adsorption sites.

109 ow that NO-assisted NH3 dissociation is both energetically favorable and accounts for the observed Cu

110 hin film, which inhibits oxidation to a more energetically favorable and stable V2O5 phase.

111 ecular oxidation of the phenol by Ru(III) is energetically favorable by both stepwise and concerted p

112 Energetically favorable cation-pi interactions play impo

113 oxidized to phosphate (PO4(3-)), is the most energetically favorable chemotrophic electron-donating p

114 t in the case of the six-membered lactone an energetically favorable conformer adopts a nearly synper

115 n active site could lead to structurally and energetically favorable coordination ready for the non-t

116 s followed by the rapid delivery of a second energetically favorable electron to fully reduce the T3

117 thyl conformations rather than as their more energetically favorable equatorial analogues.

118 entially layered manner, thereby creating an energetically favorable gradient for charge separation.

119 h aspect ratio, electrically addressable and energetically favorable interfaces, and substantial enha

120 This mutation stabilizes a novel energetically favorable open conformation in which chang

121 The most energetically favorable outcome is the production of met

122 to the tetragonal superlattice that becomes energetically favorable over its hexagonal counterpart.

123 thm is applied to search for the most common energetically favorable packing motifs in crystalline st

124 To achieve energetically favorable packing structures for the cryst

125 rangements, including a rearrangement to the energetically favorable para isomer.

126 eformations along the first mode produced an energetically favorable path, which was interestingly fa

127 This leads to the emergence of a new type of energetically favorable quasiparticle: bielectron vortic

128 Our model shows that despite the more energetically favorable reaction pathways provided by th

129 B3LYP/6-31G* calculations confirm the energetically favorable reactions between HNO and the PY

130 calized states are predominantly composed of energetically favorable Sb pz states, which break off fr

131 of pairs in dinucleotide steps, arising from energetically favorable stacking of the nitro group in w

132 ar concerted cycloaddition mechanism via the energetically favorable syn/endo-transition states.

133 rt against its concentration gradient to the energetically favorable transport of one or several ions

134 -pathway self-polymerization that results in energetically favorable trimers and could serve as a dri

135 onstrates that voltage sensor return is less energetically favorable upon repolarization than pore ga

136 to interrogate the full-length ROMK pore for energetically favorable VU591 binding sites.

137 silico docking models predicted altered yet energetically favorable wild-type mutant dimerization.

138 ce small lattice strain via the formation of energetically favorable {112}beta1/{100}Mg interfaces, a

139 hen the direct transitions between them are 'energetically favorable'.

140 onfirm that twin nucleation at Sr columns is energetically favorable.

141 findings, revealing the reaction cycle to be energetically favorable.

142 e hydrogenation of CO2 by PtH3 (-) is highly energetically favorable.

143 etry revealed that keto-MA binding to TR4 is energetically favorable.

144 (relatively) softer boundary region becomes energetically favorable.

145 tion with the aliphatic tails of lipids more energetically favorable.

146 H2 binding to the Ni-SIa redox state is energetically favored (by 4.0 kcal mol(-1)) only when H2

147 stituents, the concerted mechanism is always energetically favored as compared to a two-step process,

148 in silico modeling of the predicted order of energetically favored binding.

149 the z-AlN is ascribed to the kinetically and energetically favored nitridation of the deposited alumi

150 We find that a 2D bridging network is energetically favored over a 3D network, driving the for

151 thermore, the cubic phase is found to be the energetically favored polytype.

152 a metastable prefusion conformation into an energetically favored postfusion state.

153 tions reveal that the phase transition is an energetically favored process.

154 stepwise-migration processes, which are also energetically favored processes in the ab initio calcula

155 y oxygenate primary C-H bonds over adjacent, energetically favored secondary C-H bonds, but the mecha

156 the alternation of pearls and strings is an energetically favored state of the unsupported plasma me

157 suggesting that C(+)*C mismatches are still energetically favored such that i-motif conformations ar

158 (+) via OH(-) insertion into Co-OAc bonds is energetically favored, followed by outer-sphere oxidatio

159 entrations within hours of incubation and is energetically favored, in contrast to classical domain-s

160 pyridinium and pyridinium adsorption are not energetically favored, thus making very unlikely pyridin

161 Following extension, headpiece opening is energetically favored.

162 a conformational selection mechanism to form energetically-favored cross-beta structures, regardless

163 ted in the system, microbial communities use energetically favourable alternative electron acceptors

164 ion of domain walls in ferroelectrics is not energetically favourable in low-dimensional systems.

165 ory demonstrate that this process follows an energetically favourable path.

166 e, because the cleavage process is much less energetically favourable.

167 ely, DFT predicts a metallic structure to be energetically favoured at a broad range of pressures up

168 Although Cs (II) and (IV) are not energetically favoured, the interplay between two mechan

169 s were channeled with limited barriers in an energetically feasible process.

170 n of a (4 + 3) cycloaddition product was not energetically feasible, but (3 + 2) cycloaddition produc

171 lyses show that most elongation pathways are energetically feasible.

172 etermined by MD for ring configurations with energetically flat pseudorotational itineraries may not

173 substrate is much easier than a correct one energetically from the umbrella sampling simulations.

174 and sequences of quantum states split away, energetically, from the degenerate bulk Landau levels.

175 nstrate that the contact line (CL) motion on energetically heterogeneous solid surfaces occurs in a c

176 l-beta anti(G:C) system, whose open state is energetically higher than the closed state.

177 etween high-energy excited states, producing energetically hot states (>6.0 eV) that lead to molecula

178 in the electron-poor [Tl4Sb6Se10] layer that energetically impedes electron propagation.

179 s along the GammaK directions shift downward energetically in the presence of interlayer interactions

180 nd breaking would produce protonated CO2, an energetically inaccessible species that can be avoided b

181 of common organic functional groups that are energetically inaccessible using traditional HAT-based a

182 assical three-center transition structure is energetically inaccessible.

183 ndence of specific residues identified three energetically independent but structurally interconnecte

184 nal search and compaction electrostatics are energetically independent from the formation of the tert

185 This process is energetically inefficient because >1 V of overpotential

186 However, reward made it worthwhile to be energetically inefficient.

187 the consideration of surface states located energetically inside the band gap.

188 rgetic deficits that conspire to make humans energetically interdependent.

189 s occurs through a zero-energy state that is energetically isolated from a continuum, yielding unifor

190 onding facilitates alkyne slippage, which is energetically less costly for gold than for platinum and

191 ment of this translationally mobile water is energetically less costly than that of more strongly bou

192 enders membrane bending and tubule formation energetically less costly.

193 fibril morphology while omitting competing, energetically less favorable structural states.

194 , with HG base pairs being more abundant for energetically less favourable WC base pairs.

195 cularly serious problem when the E-alkene is energetically less favoured.

196 infrared spectra of all the ground state and energetically low lying structures presented.

197 We present the ground state and energetically low structures of BenH2n nanoclusters as p

198 The presence of energetically low-lying triplet states is a hallmark of

199 single-molecule conductance, a result of an energetically lower-lying LUMO level that extends deeper

200 9 ring type and link type structures are the energetically lowest configurations.

201 Coffinite is energetically metastable with respect to a mixture of UO

202 dly striking the nuts with moderate force is energetically more efficient than forcefully striking th

203 ucture of all forms studied, and it shows an energetically more favorable interaction with membranes

204 ed to be endothermic by 169 kJ/mol, which is energetically more favorable than formation of NUOCl2(-)

205 demonstrate that MOR on smaller PtZn iNPs is energetically more favorable than larger iNPs, due to th

206 nism via an unstable Cu(III) intermediate is energetically more feasible than other possible mechanis

207 bose-protonated repair mechanism is not only energetically more preferable, but also explains the sel

208 d by a reductive elimination) is found to be energetically more preferred over an allylic pathway whe

209 azinylcarbenes, which often rearrange to the energetically more stable arylnitrenes.

210 onal H-bonds with the framework that lead to energetically more stable diastereomeric adducts.

211 planes, leading to a 'weak' polarization, is energetically more stable than parallel arrangements of

212 This is contrasted by the energetically more strained and less favorable lens shap

213 d in REs are exploited by p53 to achieve the energetically most favorable mode of deformation, conseq

214 es from interacting with the residues in the energetically most important hot spot, a ligand moiety t

215 Finding the energetically most important regions, mapping can identi

216 nds can be explained by the formation of the energetically most stable carbenium ion conformation, fo

217 ents reveal that the bcc superlattice is the energetically most stable polymorph, with the bct being

218 let and triplet states of these carbenes are energetically nearly degenerate in the gas phase.

219 articles to reach regions in space which are energetically not accessible according to classical mech

220 climate-driven expectations, resulting in an energetically novel ecosystem.

221 nics of the body dominate in determining the energetically optimal course of action.

222 evidence that intermediate-sized groups have energetically optimal space-use strategies; both large a

223 metries to determine whether symmetry is the energetically optimal strategy for walking on a split-be

224 novel perturbation during locomotion is also energetically optimal.

225 to cyclic b ion (M --> (c)b) pathway is less energetically (or kinetically) favored.

226 trong electronic interlayer coupling, detail energetically possible stacking geometries, and provide

227 s binding to a MOR crystal structure suggest energetically preferred binding modes that differ from c

228 The importance of energetically preferred ionic and tautomeric representat

229 interfaces, a faulted stacking structure is energetically preferred on the Al side of the interface.

230 mmetry stabilized by pressure is found to be energetically preferred over the experimental NaCl-type

231 d by the methylamino group rotating from its energetically preferred syn geometry on the Watson-Crick

232 ate) ligands causes the larger species to be energetically preferred, we are able to freeze the self-

233 r-oxyl-mediated, oxygen-rebound mechanism is energetically preferred.

234 Two cystine knots are energetically preferred; however, all eight disulfide br

235 t cluster consisting of few than three atoms energetically prefers a face-centered-cubic stacking, to

236 In this work, the energetically privileged conformation of a disaccharide

237 LHCIIs do not bind to PSI, but instead form energetically quenched complexes, which were shown to be

238 xation suggesting that the two processes are energetically related.

239 erodimeric state to be substantially favored energetically relative to the CEACAM6 homodimer.

240 ch indicates that African wild dogs are more energetically robust than previously believed.

241 forms a bromosulfonium-ion intermediate that energetically selects for sulfilimine formation.

242 The standard view is that energetically significant coupled interactions involving

243 odel system, we demonstrate that networks of energetically significant, coupled interactions can form

244 We demonstrate the existence of energetically similar but mechanistically distinct possi

245 dation via the Psigma* pathway represents an energetically somewhat higher lying alternative; possibl

246 ized TIPS-tetraazapentacene derivatives with energetically stabilized FMOs.

247 The tilings are energetically stabilized with binding energies up to 250

248 tral MCPA molecule were found to be the most energetically stable adsorbate forms.

249 ds through a triplet intermediate to form an energetically stable four-membered ring in the singlet s

250 te, rendering the B2,5 conformation the most energetically stable on-enzyme.

251 The energetically stable trans form can be completely conver

252 Via 'phosphate steering', basic residues energetically steer an inverted ss 5'-flap through a gat

253 ithin the small protein capsid results in an energetically stressed DNA state exerting tens of atmosp

254 etecting productive fruit patches during the energetically stressful dry season also benefits dichrom

255 tions revealed a distinct transition between energetically sustainable and unsustainable ATP concentr

256 conjugate addition pathway as more favorable energetically than an alternative electrocyclization pat

257 We compare biophysically and energetically the cellular responses to direct electrica

258 llic compounds, of which XeFe3 and XeNi3 are energetically the most stable.

259 Energetically, the lesioned open states are similar in e

260 teractions in the native state are optimized energetically, thereby potentiating slow folding and mis

261 y which liquid water becomes water vapor and energetically this accounts for much of incoming solar r

262 tribution only at alphagamma that is coupled energetically to those contributions of some of the alph

263 ar weight MgxMo3S4, thus rendering full cell energetically uncompetitive.

264 nd structural properties of siloxanes; it is energetically unfavorable and thus highly unlikely.

265 The first binding event requires the energetically unfavorable closing of this loop, reducing

266 stasis by chaperoning mature factors through energetically unfavorable events, thereby maintaining th

267 4.1 kcal mol(-1)), which is a consequence of energetically unfavorable exchange-repulsion interaction

268 on of the interchain excited states that are energetically unfavorable for charge separation.

269 agnetocrystalline hard axis, a configuration energetically unfavorable for formation of strong dipole

270 Vacancy sites that are energetically unfavorable for segregation are found in a

271 ion and allows new, refractory, or otherwise energetically unfavorable materials to form under softer

272 fied Tyr-19-His-132 dyad, which indicated an energetically unfavorable mechanism.

273 a class of oxygenases able to catalyze this energetically unfavorable reaction without any cofactor.

274 etter understand the molecular basis of this energetically unfavorable reaction, the x-ray crystal st

275 that the tryptophan substitutions lower the energetically unfavorable residual hydrophobic mismatch

276 ility for double-stranded DNA viruses is the energetically unfavorable state of the tightly confined

277 hydration of the hydrophobic cavity is more energetically unfavorable than global unfolding.

278 ated or "tetrameric" C-linker, which becomes energetically unfavored.

279 uent ordered lipid domains are thought to be energetically unfavourable for membrane fusion, rafts ha

280 larization under external bias that leads to energetically unfavourable head-to-head domain walls in

281 Charged ferroelectric walls, which are energetically unfavourable in general, were found to be

282 o encourage application of this technique to energetically unfavourable or demanding reactions.

283 enders the efflux of divalent cationic drugs energetically unfavourable, as it requires exchange with

284 with new Ge-O bond formation and decrease in energetically unstable edge sharing GeSe4/2 tetrahedra.

285 elps stabilize conformers that are otherwise energetically unstable ultimately leading to the assembl

286 show that the guest-free CMOF-5 structure is energetically unstable, with either the achiral conventi

287 cleotide-binding domains (NBDs) to power the energetically uphill efflux of substrates by a dedicated

288 foldon-dependent pathway intermediates as in energetically uphill equilibrium unfolding.

289 ter from Escherichia coli, EmrE, couples the energetically uphill extrusion of hydrophobic cations ou

290 e direction relative to a dumbbell toward an energetically uphill state.

291 l importance, the transporters mediating the energetically uphill transport of K(+) into the vacuole

292 s engaged with natural logs, which contained energetically valuable honey that was only accessible th

293 ls, but paradoxically make schooling species energetically viable and commercially attractive targets

294 A transition state for energetically viable C-H activation across a Pd-peroxo b

295 Given this conclusion, an alternative and energetically viable pathway for pyridinium reduction on

296 idiflorol, and related sesquiterpenes is not energetically viable.

297 creased activity may render some populations energetically vulnerable.

298 hysisorbed pentene, establishing a series of energetically well-separated groups of reactive surface

299 ation of the observed indole is most favored energetically, while the potential pathway to the minor

300 nd tetrahedra, respectively, were quantified energetically, with the destabilization increasing linea