ライフサイエンスコーパス: equilibration

1 d equilibration for 8 additional months (2nd equilibration).

2 till poorly defined, level of metal-silicate equilibration.

3 of overshooting from initiation until final equilibration.

4 omass and biofilm thickness following column equilibration.

5 ion, vapor-wall deposition, and gas-particle equilibration.

6 0(-4) M(-1) s(-1)) from the half-life of the equilibration.

7 acidic media is employed to achieve isotope equilibration.

8 urement, returning to equilibrium after 16 h equilibration.

9 on of metallacyclobutene-eta(3)-vinylcarbene equilibration.

10 samples need to be analyzed after H isotope equilibration.

11 minent fast component (62% versus 48%) of re-equilibration.

12 initial solid phase present during the first equilibration.

13 t the air-water interface was measured after equilibration.

14 ron-lattice coupling and is maintained up to equilibration.

15 ith stereocontrol arising from thermodynamic equilibration.

16 whether the enzyme catalyzes its subsequent equilibration.

17 sess the role of morphology on the diffusive equilibration.

18 s in the phenomenology of thermalisation and equilibration.

19 of life is its peculiar capability to avoid equilibration.

20 ns; a DNA catalyst is designed to accelerate equilibration.

21 e tetrahydropyrans, allowing a thermodynamic equilibration.

22 function of time during the first and second equilibrations.

23 ed to calculate compound-specific fractional equilibration achieved in situ for the PE samplers, usin

24 rinciple of measuring a pH change upon CO(2) equilibration across a membrane.

25 rbon isotope fractionation during NAPL-vapor equilibration, air-water partitioning, and diffusion of

26 The flow-through equilibration allows for continuous (~1 Hz) detection an

27 anhydrase (CA) enzymes catalyze the chemical equilibration among CO2, HCO3(-) and H(+).

28 states at the C-terminal end and a faster re-equilibration among coil states.

29 ygen, CO(2)) and promote thermally activated equilibration among different network isomers and cyclic

30 s C60 and C70 to the cage brought about a re-equilibration among the different cage diastereomers in

31 s less than 5 min, including both the column equilibration and autosampler movement.

32 les, baseline disturbances, and slow (2)D re-equilibration and demonstrate improvements in (2)D separ

33 sks and generator columns, require hours for equilibration and milliliter quantities of sample soluti

34 ope fractionation associated with NAPL-vapor equilibration and normal diffusion isotope fractionation

35 Hydrogels display nonswelling equilibration and offer temporal control over material d

36 e effect of kinetic barriers which intercept equilibration and preserve highly ordered, high energy n

37 ovalent or non-covalent bonds, thermodynamic equilibration and structure templating, are also accessi

38 The well-degradable compounds showed slow equilibration and the least mineralization in OECD 308,

39 undamental competition between thermodynamic equilibration and the persistence of metastable configur

40 ed with PE and POM to correct for incomplete equilibration, and the resulting POP concentrations, det

41 The analysis of errors shows that the slow-equilibration approximation guarantees that the errors i

42 The approach is based on the slow-equilibration approximation, which is applicable to KSEC

43 Equilibration at different pH introduces intentional Mn

44 Equilibration at high temperatures in the aftermath of g

45 a hyperpolarized LLS is populated by thermal equilibration at liquid helium temperature.

46 le at 40 degrees C for 2 h followed by water equilibration at room temperature under controlled condi

47 calculations and test against recent buffer-equilibration atomic emission spectroscopy measurements.

48 t with a single solid phase for 30 days (1st equilibration) before introducing the other two solid ph

49 otometric method to achieve flow-through CO2 equilibration between an acidified sample and an indicat

50 (Teflon AF 2400) to achieve flow-through CO2 equilibration between an acidified sample and an indicat

51 pped here is metastable and can enable rapid equilibration between bent and extended-open integrin co

52 on a simple kinetic technique to track H2O2 equilibration between cellular compartments, suggesting

53 Equilibration between Chol and Phos via thiolate-disulfi

54 of the photoproduct and is attributed to an equilibration between different K-intermediates.

55 rier relative to beta-actin that retards the equilibration between G- and F-monomer conformations res

56 Thus, equilibration between inactive oligomers and active mono

57 However, they assume fast equilibration between internal states and hence are inad

58 folded proteins and BiP oligomers and slower equilibration between oligomers and inactive, covalently

59 on-body sweat chloride measurement, however, equilibration between reference and test solutions has l

60 Equilibration between the blood and unbound (18)F-FMISO

61 esterol loading or depletion, there is rapid equilibration between the ER and plasma membrane cholest

62 ng observed even if there was complete label equilibration between the lactate and pyruvate pools.

63 steady-state gradients are established by an equilibration between the lifetime of a morphogen and it

64 t the indolizidine framework, allowing rapid equilibration between the major configurations (ttc and

65 Equilibration between the neutral and protonated species

66 show how the salt bridge geometry determines equilibration between the reference and test solutions.

67 Evidence is presented for BLM equilibration between the stronger and weaker binding si

68 ive urea transporters (UTs) that allow rapid equilibration between the urinary space and the hyperosm

69 ein particles HDL and LDL/VLDL, resulting in equilibration between these lipoprotein fractions.

70 of electron transfer and to facilitate redox equilibration between working electrodes and minerals in

71 porated unnatural tyrosine analogs; however, equilibration between Y122* and Y356* has not been detec

72 abolism in the citric acid cycle, incomplete equilibration by triose phosphate isomerase, or the tran

73 During NAPL-vapor equilibration, carbon, and chlorine isotope ratios evolv

74 nstrates that it is possible to minimize the equilibration (conditioning) time of SC ISEs with aqueou

75 After rapid local equilibration, cooperators expand quadratically until gl

76 demonstrate that the timescale for particle equilibration correlates with bulk viscosity and can be

77 lthy patients and early prediction of PetCO2 equilibration could therefore also be used for the titra

78 and (13)CH4) with CRDS via a closed loop gas equilibration device during a survey along an estuary an

79 d a closed air loop was established with gas equilibration devices (GED).

80 We used rectal luminal equilibration dialysis for the measurement of gut lumina

81 rcled by a CB[7] ring with a rapid shuttling equilibration distribution extended to the trans-azobenz

82 The equilibration distribution of the macrocycles on the dum

83 m-temperature measurement of singlet-triplet equilibration dynamics in this family of emitters.

84 After equilibration each tissue underwent a series of protocol

85 We propose that similar charge equilibration events accompany the IEM of unfolded prote

86 verge so rapidly that, upon further cooling, equilibration eventually becomes impossible and glass fo

87 experiments and during polydisperse droplet equilibration experiments at 75% relative humidity, and

88 Abiotic fuel-blends/aqueous-phase equilibration experiments revealed that the FAMEs of bio

89 Batch equilibration experiments were used to examine the sorpt

90 e introducing the other two solid phases and equilibration for 8 additional months (2nd equilibration

91 al a complex pattern of tissue-retention and equilibration for CD4(+) memory T cells in skin, which i

92 surprisingly slow and similar time course of equilibration for the two compounds, although memantine

93 f the bath when 50% strain was applied after equilibration in 0.5, 1, and 2x PBS, with a trend for an

94 ilicate Moon can instead reflect core-mantle equilibration in a largely to fully molten Moon.

95 consistent with high-pressure metal-silicate equilibration in a terrestrial magma ocean.

96 Following equilibration in air, mackinawite was oxidized to mainly

97 ficant negative potential drift during their equilibration in an aqueous solution.

98 ag phase for HCO(2)H formation and a lack of equilibration in pulse-chase assays) were also seen with

99 fied binding assay using micro-CT after plug equilibration in serial dilutions of each agent.

100 as used to obtain the timescale of diffusive equilibration in spines and followed by global sparse ph

101 eitol (DTT), and shows typical half-times of equilibration in the 10 h range.

102 -column EDTA concentration, including column equilibration in the absence of any EDTA, lower concentr

103 min (~120 min including extended hold and re-equilibration in the first dimension).

104 The role of the dynamics of solvent equilibration in the nature of mechanistic intermediates

105 ive gradients in thin films (DGT), diffusive equilibration in thin films (DET) and the "DGT-induced f

106 gradients in thin films (DGT) and diffusive equilibration in thin films (DET) techniques.

107 sensitive elements (e.g., Fe, Mn), Diffusive Equilibration in Thin-films (DET) devices were inserted

108 This equilibration involves the relaxation of intramolecular

109 ically controlled metalations overlaid by an equilibration involving diisopropylamine that is shown t

110 ures, indicating that the barrier for facial equilibration is >20 kcal/mol for both the Ir and Rh com

111 ical rates, because SlyD-catalyzed cis/trans equilibration is faster than conformational folding.

112 Propanal-propanol-H(2) equilibration is mediated by their chemisorption and int

113 th excess isocyanate and heat, thermodynamic equilibration is possible affording ureas.

114 tereomers was isolated, and by following the equilibration kinetics, activation barriers for all reac

115 Here, we describe a field-deployable gas equilibration mass spectrometer (GEMS) that provides con

116 te, which suggests that a polarizable charge equilibration method (PQEq) method might be needed to ta

117 The new equilibration method displays a small solvent effect and

118 ng reactive molecular dynamics with a charge equilibration method extended to describe electrochemica

119 ow how a version of the semiempirical charge equilibration method suitable for periodic materials can

120 an lead to different product compositions or equilibration mixtures than in solution.

121 ult is inconsistent with the low-energy disk equilibration model, but supports the high-energy, high-

122 d our system to investigate various pressure equilibration models and dynamic, nonuniform membrane te

123 However, whilst mineral re-equilibration occurred very rapidly on cooling, changes

124 H(2)O; the assumption is that there is rapid equilibration of (2)H (in body water) with the carbon-bo

125 At a moment's notice: Thermal equilibration of 1 and mass spectral analysis of sialyl

126 Equilibration of 1 with its 2,3-dihydro isomer 2, which

127 and dehydration, with CuCN catalyzing a key equilibration of a formyl imine to an N-formyl enamine.

128 indicate that active CT Topo I catalyzes the equilibration of a metastable secondary structure with a

129 tes that approximately 7 mus is required for equilibration of a preformed 6-peptide pore; the pore re

130 Acid-catalyzed equilibration of a series of anancomeric 2-tert-butyl-5-

131 of hemi-equilibrium, the state of partial re-equilibration of agonist, antagonist, and receptor in so

132 an any other known example the thermodynamic equilibration of alkene isomers, as the trans-2-alkenes

133 Pre-equilibration of an interconverting set of isomeric ally

134 sal membrane domains is established prior to equilibration of barrier function and that it is unaffec

135 discovered, highly selective TMSOTf-mediated equilibration of C38-epi-halichondrin A to halichondrin

136 rature appeared almost instantaneous whereas equilibration of casein was considerably slower, particu

137 ia or atrophy, organ turnover demands strict equilibration of cell production and loss.

138 The stabilization of this polaron impedes equilibration of charge density across the nanowire and

139 Given the temperature-dependent re-equilibration of clumped isotopes in aragonitic carbonat

140 ttle production of hydrogen, despite partial equilibration of CO2 with carbonic acid-a low pKa acid.

141 Equilibration of complexes 2-5 with H2 in the presence o

142 nts on the phenyl rings has been studied via equilibration of configurationally isomeric 2,2-diaryl-c

143 into the liposome results in trans-membrane equilibration of detergent and subsequent micellization

144 into the outer monolayer; 2), trans-membrane equilibration of detergent monomers between the two mono

145 netic resolution in which a rapid tautomeric equilibration of diastereomeric iminium cations is combi

146 azacyclic molecules in which dynamic kinetic equilibration of diastereomeric iminium ions precedes a

147 emission is comparable to the timescale for equilibration of electrons and phonons.

148 with the ER membrane protein Ldb16, prevents equilibration of ER and LD surface components by stabili

149 now afforded the opportunity to investigate equilibration of F3Y122* and Y356*.

150 Equilibration of initially 7 mM solutions was slow--on t

151 junctional SR [Ca2+] without assuming rapid equilibration of junctional and network SR [Ca2+].

152 quire strong scale separation or conditional equilibration of local statistics.

153 The reversible equilibration of meizothrombin between zymogen- and prot

154 The equilibration of monomeric (Z)-1 and (E)-1 in THF as the

155 and that Snf2 and Asf1 promote thermodynamic equilibration of nucleosomal arrays.

156 sides has been developed on the basis of the equilibration of O-sialyl hydroxylamines by reversible h

157 proposed nonvesicular pathways for the rapid equilibration of oxysterols between membranes, direct im

158 6, -8, +10, -12, +14 breaths/min and awaited equilibration of Petco2.

159 nd the rate determining processes during the equilibration of poly(3,4-ethylenedioxythiophene):polyst

160 The cohort platelet counts achieved after equilibration of production and consumption both enumera

161 ross mitotic clone boundaries and enable the equilibration of protein between transcriptionally mosai

162 It thus remained unclear how equilibration of protein disulfides with the IMS glutath

163 After equilibration of soils with citric or oxalic acids, the

164 ing solid was sufficiently hydrated to allow equilibration of sorbed Hg species with the aqueous solu

165 and Fe(II) sorption to Feppt, combined with equilibration of sorbed iron and with Fe(II)aq using pub

166 We show equilibration of structural kinetic transitions in the m

167 se consensus responses reveal a timeline for equilibration of sub-communities of micro-organisms with

168 of excited state decay that involves initial equilibration of the (3)MLCT and pyrene triplet states f

169 After electrolysis, full equilibration of the alkalized solution with air led to

170 The reactions are the slow equilibration of the CO(2) hydration-dehydration reactio

171 of 7 min, including the clean-up and the re-equilibration of the column.

172 ysis of metal uptake kinetics indicated that equilibration of the cytoplasm with externally applied h

173 ration structure seems responsible for local equilibration of the defective surface in water and even

174 Equilibration of the heat flow from the substrate to the

175 surements overestimated pH due to incomplete equilibration of the hyperpolarized (13)C label between

176 plain this observation are (1) extracellular equilibration of the inorganic phosphate in the soil; (2

177 Conditioning refers to the equilibration of the ion-selective electrode in an aqueo

178 irradiation above 2000 cm(-1) results in an equilibration of the isotopomeric ratio.

179 sodium methoxide) have been found to promote equilibration of the kinetically favored products from I

180 : (1) deprotonation of pro-R or pro-S-H, (2) equilibration of the lithiated stereogenic carbanion, (3

181 sition of a SPB without the need for thermal equilibration of the measurement chamber and, thus, has

182 ed by a response model that assumes complete equilibration of the membrane at every applied potential

183 The thermal equilibration of the methyl esters of endiandric acids D

184 Equilibration of the mother liquor (enriched in 2R) to a

185 milar or shorter time scales compared to the equilibration of the optically populated excited state.

186 From the kinetic measurement of the bulk equilibration of the pH, we fully determine the adsorpti

187 s inversion at S and accounts for the facile equilibration of the SAuPPh3 units, with an energy barri

188 or impact on the system leading to a fast re-equilibration of the solid to a Ba1-xRaxSO4 solid soluti

189 omers of 8 was reducing faster to 9 than the equilibration of the stereocenter of 8.

190 results from unrestrained molecular dynamics equilibration of the structure.

191 alkyl sulfonates were determined at pH 7 by equilibration of the test analytes between fiber and wat

192 For three enol-ketone pairs, equilibration of the thermodynamically disfavored tautom

193 Equilibration of the three possible tetraphenylbenzenes

194 ergodicity of the fast subsystem impedes the equilibration of the whole system because of the presenc

195 Further, equilibration of the zwitterionic benzotriazolyl species

196 liums and the kinetics of the diastereomeric equilibration of these and one other example.

197 oth the tracer and sample isotopes when full equilibration of tracer isotopes with sample isotopes is

198 Equilibration of Y356*, Y731*, and Y730* was recently ob

199 mantle region that underwent metal-silicate equilibration or a product of large-scale magmatic diffe

200 Our results also indicated that a pre-equilibration period is essential for growth and stabili

201 ate collected during the final 10 min of the equilibration period to measure unstimulated release rat

202 Following an equilibration period, baseline brain levels of glucose (

203 h faster than Pu(V) sorption over the 30 day equilibration period.

204 their increasing ease of thermal atropisomer equilibration, permitting the recycling of any newly gen

205 nsition from HF to LF-occurs during the fast equilibration phase of the system, leading to sudden inc

206 ebenzylation/spiroketalisation/thermodynamic equilibration procedure, afforded the tetracyclic struct

207 ansient overshoots during equilibration; the equilibration process follows serpentine trajectories in

208 ty, V260A introduces a temperature-dependent equilibration process not previously reported by such me

209 new insights into the dynamic assembling and equilibration process of obligate homo-oligomeric membra

210 advised, and, after that step, preanalytical equilibration rarely exceeds 3 h.

211 f vanishing particle-to-wall mass ratio, the equilibration rates remain strictly positive only when t

212 tion in C. hyperboreus is maintained through equilibration rather than feeding.

213 Assay time is <6 min, with no re-equilibration required between runs.

214 10.0 mus timescales were observed, with post-equilibration sampling providing detailed representation

215 cid-mediated delta-hydroxy enone cyclization/equilibration sequence, and a functional-group-tolerant

216 bitor, mNOX-E36, the intrahepatic macrophage equilibration shifted toward the "restorative" Ly-6C(-)

217 hown to be good indicators of sampler-tissue equilibration status.

218 s, followed by a Lewis acid-mediated product equilibration step.

219 toinduced electron transfer preceding energy equilibration still poses many experimental and conceptu

220 the three triphenylbenzenes, TfOH-catalyzed equilibration strongly (>95%) favors the 1,3,5-triphenyl

221 er trap on a gaseous hydrogen-water platinum equilibration system.

222 increase in the response time of solution P equilibration (Tc) was observed.

223 enthalpies (BDE) in t-butanol by EPR radical equilibration technique consistently indicated a ca. 1.5

224 dimethylsulfoxide) by using the EPR radical equilibration technique.

225 e lower at 1 h than at 4 h of the peritoneal equilibration test but the reductions in cytokine releas

226 ched controls using 3.86% glucose peritoneal equilibration tests.

227 pe fractionation is larger during NAPL-vapor equilibration than air-water partitioning.

228 > Smectitic, while at the end of the second equilibration the organic system was the least effective

229 ersion into its previtamin D form by thermal equilibration, the corresponding 19-nor-compound 26 was

230 However, after one year of equilibration, the extent of Pu(V) adsorption was simila

231 After equilibration, the fully deprotonated citrate ion is pre

232 y polar solvents, and even the mechanism for equilibration-the presence or absence of supramolecular

233 curs, we observe transient overshoots during equilibration; the equilibration process follows serpent

234 Brine was mixed with CO(2) for equilibration, then the mixture was circulated through a

235 .5 mL min(-1)), mobile phase composition and equilibration time (1-5 min).

236 l as between changes in respiratory rate and equilibration time (teq) for mechanically ventilated pat

237 Both the partition coefficient and equilibration time agree well with predictions from the

238 The required equilibration time benefits from the acceptor solution i

239 tive (subnanomolar detection limits), rapid (equilibration time constants approximately 8 min), and s

240 ions and (ii) a mismatch-induced increase of equilibration time in respect to that of a fully matched

241 The gas-particle equilibration time scale depends on the gas-particle acc

242 kinetics was studied experimentally, and the equilibration time scale for impervious surfaces was fou

243 scribes the observed evaporation, suggesting equilibration time scales of atmospheric SOA on the orde

244 ght to be "glassy." Here, we investigate the equilibration time scales of SOA formed from alpha-pinen

245 atmospheric conditions, this translates into equilibration time scales on the order of minutes to ten

246 The DEHP-particle sorption equilibration time was demonstrated to be less than 1 mi

247 mple in the NMR tube, mixing, waiting for an equilibration time, and acquisition of a second spectrum

248 teristics (theoretical response slope, short equilibration time, excellent potential stability, etc.)

249 and after a minimum approximately 30 min of equilibration time.

250 concentration, type of surface complex, and equilibration time.

251 ption increased with increasing silicate pre-equilibration time.

252 254)), and Hg(II)-DOM and Hg(II)-DOM-sulfide equilibration times (4-142 h).

253 built on GC and Au had significantly shorter equilibration times (between 5 and 13 min) than the SC e

254 lenge because at length scales of 10-100 mum equilibration times already become prohibitively long.

255 w detection limit of LFA and associated long equilibration times are due to kinetically limited surfa

256 Equilibration times are fast (less than a minute) becaus

257 Because of the low aqueous concentrations, equilibration times are very long and BCFs are sensitive

258 vol) aerosol, indicating that unusually long equilibration times can be required for HTDMA measuremen

259 The Hg(II)-DOM or Hg(II)-DOM-sulfide equilibration times did not significantly influence the

260 io between the characteristic separation and equilibration times does not exceed 0.1.

261 ce for the selection of appropriate sorption equilibration times for experiments that are designed to

262 Such significant differences in the equilibration times of SC ISEs built on different substr

263 m decreased chromatographic resolution, long equilibration times, indefinite retention, and column bl

264 and used these transients to determine their equilibration times.

265 ould determine a robust relation between the equilibration timescale and a generalized shape factor c

266 tion of the aldol product A with LDA induces equilibration to form the minor diastereomer of Michael

267 ed mantle fluids precipitate diamond upon re-equilibration to lighter species in the upwelling mantle

268 ional variants of proteins and that the slow equilibration to multiple stable conformations in soluti

269 Re-equilibration to physiological pH restores the fixed neg

270 en into two pieces, and can heal by siloxane equilibration to restore the original strength of the si

271 The rapid isotopic re-equilibration to the new MeHg-food source reflects its h

272 alance of a resting rotor, following thermal equilibration under high vacuum, closely corresponded to

273 ved-gas concentrations in water by gas/water equilibration using membrane contractors (gas-equilibriu

274 perature control, obviates extended detector equilibration wait times.

275 It is shown that equilibration was faster in dense suspensions and at hig

276 Experimentally, we found that diffusive equilibration was often slower, but rarely faster than p

277 which measures the heat dissipation rate for equilibration, was found to be on the order of approxima

278 The films obtained after drying and equilibration were characterised in terms of composition

279 d Cu for the systems at the end of the first equilibration were Fe-Ox > Organic > Smectitic, while at

280 The differences in the rate of equilibration were interpreted as a consequence of diffe

281 50-125 muL/g water:solid ratio, and 24-48 h equilibration were used.

282 of the cytoplasm that leads to slow pressure equilibration when compared to the timescale of bleb exp

283 of an in situ base-promoted alkyne to allene equilibration which takes place prior to the silylcuprat

284 r the option of enforcing the so-called "pre-equilibration" which evaluates thermodynamic concentrati

285 The bubbling action allows for quick equilibration while the small size of the chamber limits

286 erpolarization to approximately -80 mV), via equilibration with 145 mm [K(+)]o (depolarization to app

287 enantioselectivity, where 3-sulfolene is in equilibration with 2-sulfolene by base-catalyzed isomeri

288 electrolyte of 100 mM NaCl and 1 mM CaCl2 in equilibration with 400 ppmv CO2(g) ([U(VI)] = 4 muM and

289 If it remains unchanged (e.g., due to fast equilibration with a sediment acting as a large source p

290 pyruvate carboxylase activity and incomplete equilibration with fumarate.

291 influenced by modern volcanic degassing and equilibration with liquid water.

292 h three different concentrations of NaOH and equilibration with multiple pressures of CO2.

293 s with carrier aldehydes showed only limited equilibration with P450 2E1-bound aldehydes, indicative

294 orted by faster voltage-dependent blocker re-equilibration with several experimental manipulations of

295 ringy billiards and their random models show equilibration with similar positive rates.

296 es expected for enzymatic-mediated phosphate equilibration with soil-water.

297 rom the dynamic NMR behavior, its endergonic equilibration with the [Zr]-O-CH2-B(C6F5)2 isomer was de

298 phases, but Hg speciation indicated lack of equilibration with the final solution.

299 llus subtilis, this labile pool is sensed by equilibration with the metalloregulator Zur, as an indic

300 omitant increase in the intraviral pH due to equilibration with the pH of an external buffer.