ライフサイエンスコーパス: esterification

1 electrophilic C-atom at its carbonyl group (esterification).

2 y and calcium pectate contents and degree of esterification).

3 esides, H. chilense has additional genes for esterification.

4 sterol, including membrane incorporation and esterification.

5 ntioxidant system and enhanced pectin methyl esterification.

6 sters via membrane electrolysis and biphasic esterification.

7 nt-free system involving both hydrolysis and esterification.

8 s well as a decrease in the degree of pectin esterification.

9 ng to B-ring substitution, glucosylation and esterification.

10 nd merged with the first fragment via Shiina esterification.

11 ible bis-Mosher esters (16) was then made by esterification.

12 to form the anthraquinone ring, and finally esterification.

13 marked increase in ACAT-mediated cholesterol esterification.

14 products of lactonization or intermolecular esterification.

15 of ER cholesterol or the rate of cholesterol esterification.

16 ransferase, an enzyme that catalyzes retinol esterification.

17 their isoelectric points (pIs) after methyl esterification.

18 of inhibitor charged groups by amidation or esterification.

19 the pIs for peptides with and without methyl esterification.

20 sed the percentage of fatty acids going into esterification.

21 n WT than KO, arguing against impaired lipid esterification.

22 chromosomes 7D and 7H(ch) are important for esterification.

23 tin changed significantly (P<0.05) after OSA esterification.

24 olyzed from the amylopectin molecules during esterification.

25 pancreatic cancer by inhibiting cholesterol esterification.

26 d hyperlipidemia due to increased fatty acid esterification.

27 uman health and can be produced by enzymatic esterification.

28 the candidate enzymes catalyzing astaxanthin esterification.

29 self-assembled monolayer and in situ Fischer esterification, a simple and reversible chemical reactio

30 the bilayer to the phospholipase A2-like and esterification active sites of LCAT, respectively.

31 fluorescence method to accurately detect the esterification activity of lecithin:cholesterol acyltran

32 ith control HDL-2, and increased cholesterol esterification activity resided within the apoE-HDL frac

33 tain accurate and robust measurement of LCAT esterification activity.

34 on of enzymes involved in hepatic fatty acid esterification, ameliorates hepatic steatosis and lipid-

35 linkage of each glycan using the solid-phase esterification/amidation strategy.

36 L to spherical HDL by catalyzing cholesterol esterification, an essential step in RCT.

37 re winterization), (iii) two-steps enzymatic esterification and (iv) triacylglycerols (TAG) purificat

38 uki coupling, a Stille coupling, a Yamaguchi esterification and a Yamaguchi macrolactonization.

39 lic acid derivatives has been carried out by esterification and amidation reactions.

40 in sources, while variation in the degree of esterification and amidation, respectively, had negligib

41 t of apple pectins having similar degrees of esterification and amidation, respectively.

42 protection is compatible with commonly used esterification and amide bond formation techniques, incl

43 ich can effectively catalyze pentyl valerate esterification and be easily separated by an external ma

44 ally achieved via enzymatic enantioselective esterification and ester hydrolysis.

45 lusively to HG that has a very low degree of esterification and in the presence of divalent ions.

46 free fatty acid delivery to the liver for re-esterification and increased de-novo lipogenesis.

47 Olefin cross-metathesis, trans-esterification and Nozaki-Hiyama-Kishi (NHK) macrocycliz

48 ed to provide a third new synthesis based on esterification and Nozaki-Hiyama-Kishi reaction.

49 pite the postprandial decrease in FFA-driven esterification and oxidation, VLDL-TAG secretion is main

50 of genes involved in lipogenesis/fatty acid esterification and resultant hepatic steatosis (simple f

51 a newer and more practical approach based on esterification and ring-closing metathesis reaction.

52 cription of genes responsible for fatty acid esterification and steatosis.

53 PARgamma target genes involved in fatty acid esterification and storage in 3T3-L1-derived adipocytes.

54 Here we discuss catalytic esterification and transesterification solutions to the

55 e propose that the close proximity of sterol esterification and transport proteins to each other comb

56 port into memory CD8+ T cells for fatty acid esterification and triglyceride (TAG) synthesis and stor

57 tabolism (lipogenesis, oxidation, lipolysis, esterification) and fatty acid uptake in >9000 primary o

58 d alpha2,6-linked sialic acids through ethyl esterification, and alpha2,3-linked sialic acids via ami

59 yte triglyceride accumulation and fatty acid esterification, and decreasing fatty acid oxidation and

60 include modified Crimmins aldols, Yamaguchi esterification, and Grubbs ring-closing metathesis react

61 Placental FA uptake, esterification, and oxidation pathways were studied by m

62 pocytes as mediating free fatty acid influx, esterification, and storage as triglyceride.

63 up in this repeating unit through methyl (de)esterification, another known dynamic trigger in planta.

64 of this useful catalytic asymmetric allylic esterification are defined.

65 vides striking evidence for the mechanism of esterification as the pathway for possible oligomerizati

66 palmitic vs. linoleic) and regioselectivity (esterification at positions 3 vs. 3').

67 TGN) long before it becomes available for re-esterification at the endoplasmic reticulum (ER) or for

68 ity of SseJ suggest that cholesterol and its esterification at the SCV are functionally important for

69 esised by both chemical and lipase catalysed esterification between fatty acids and methionol.

70 can be used as reagents, exemplified by some esterifications between simple acids and alcohols.

71 owed substantial decreases in pectin amount, esterification, branching, hydration, and mobility in an

72 lodextrins causes an increase in cholesterol esterification by acyl CoA:cholesterol acyl transferase,

73 sterol to the endoplasmic reticulum (ER) for esterification by acyl-CoA acyltransferase (ACAT) and fo

74 Compound 1a increased esterification by acyl-coenzyme A:cholesteryl acyltransf

75 cholesterol efflux, facilitates cholesterol esterification by promoting fatty acid synthesis, and in

76 Thus, MTP enhances cellular cholesterol esterification by removing cholesteryl esters from their

77 ) cholesterol efflux and reduced cholesterol esterification by sterol-O-acyltransferase 1 (SOAT1).

78 Host FA are assimilated via esterification by the bacterial acyl-acyl carrier protei

79 d oil, concentration of PUFAs, and enzymatic esterification by the Celite-immobilized lipase.

80 In secondary cell walls, mannan esterification can prevent probe recognition of epitopes

81 this study was the evaluation of cholesterol esterification (CE) fraction (esterified cholesterol vs.

82 Fatty acid esterification, common in naturally occurring astaxanthi

83 ds from beta,gamma-butenolides by an in situ esterification, condensation, and reduction in a one-pot

84 Esterification condensations were observed in the assays

85 The reaction proceeds under mild esterification conditions and yields the product with a

86 Thus, esterification could provide a general means to deliver

87 rase 2 act coordinately in the hydrolysis/re-esterification cycle of TAGs on lipid droplets.

88 for automated determination pectin degree of esterification (DE) using micro sequential injection lab

89 intrinsic viscosity [eta](w), and degree of esterification (DE) were compared to those parameters ob

90 Increased esterification decelerated degradation of all-trans-asta

91 onal groups and at determining the effect of esterification degree on resistance and pasting characte

92 aste used to produce retrograded starch, and esterification degree, on selected properties of the res

93 Esterification does not protect the drugs against acid-c

94 vitro experiments indicated that astaxanthin esterification drove the formation and accumulation of a

95 Abrogation of cholesterol esterification, either by an ACAT-1 inhibitor or by shRN

96 nctional impairment of cholesterol efflux or esterification, either of which would be expected to imp

97 ll sialic acids regardless of linkage, while esterification enables differentiation between alpha2,3-

98 gical inhibition of ACAT1, a key cholesterol esterification enzyme, led to potentiated effector funct

99 ecific sources of other diesters, by further esterification followed by hydrogenolysis.

100 r building blocks, and carbodiimide-mediated esterification for building up the various dendrimers.

101 , e-Lcy from H. chilense and the high lutein esterification found in tritordeum may serve to explain

102 The cholesterol esterification fraction is a valid biomarker for liver s

103 esterol loading or inhibition of cholesterol esterification further elevated CHOP expression in ARV1

104 We show that methyl esterification generates 3-isopropylmalate-1-methyl este

105 ditions for attachment of the spin-label via esterification have been optimized on the direct synthes

106 When processed to low degrees of esterification, HG can form complexes with divalent calc

107 rom OFI cladodes (UAEPC) has a low degree of esterification, high uronic acid content, important func

108 involving methylation and one-pot Mitsunobu esterification-hydrolysis.

109 c or oleic acid as acyl donors, reaching 90% esterification in 3h with the recombinant enzyme.

110 are now greatly improved by their enzymatic esterification in ionic liquids (ILs).

111 ementation of n-3 significantly decreased FA esterification in isolated trophoblasts without affectin

112 factors accelerating cholesterol efflux and esterification in model discoidal lipoproteins (includin

113 Inhibiting cholesterol esterification in T cells by genetic ablation or pharmac

114 nown if glucose regulates LCFA oxidation and esterification in the MBH and, if so, which hypothalamic

115 of PME activity and homogalacturonan methyl esterification in the seed.

116 tors show that ACAT plays a key role in PREG esterification in various cell types examined.

117 ysis in rat digestive fluid, and cellular re-esterification in vivo, were evaluated to examine the me

118 trate; with cholesterol, the V(max) for PREG esterification increases by 100-fold.

119 explained by the observation that palmitate esterification influenced the cis-trans equilibrium.

120 Rates of fatty acid esterification into hepatic triglyceride were found to b

121 )C] palmitate to measure rates of fatty acid esterification into hepatic triglyceride while varying p

122 glucose increases palmitate, but not oleate, esterification into neutral lipids in neurons and MBH sl

123 Transmembrane transport (CD36) and esterification into triglycerides (DGAT) may be rate-lim

124 The reaction proceeds via a domino esterification/intramolecular 1,4-addition-type Friedel-

125 port from the plasma membrane to the site of esterification is associated with the physical interacti

126 tive and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic e

127 vealed that in intact tomato fruit pectin de-esterification is endogenously regulated by physical res

128 ic itinerary of cholesterol when cholesterol esterification is inhibited only in the liver, and provi

129 Although retinol esterification is mostly catalyzed by lecithin:retinol a

130 High selectivity for esterification is observed even in the presence of unpro

131 zene-1,2,4,5-tetracarboxylic dianhydride) in esterification, leading to regioselective methods to gen

132 ellulose biosynthesis can be affected by the esterification levels of pectin, possibly through modify

133 ization led to an alternative intramolecular esterification/macrolactamization strategy employing the

134 could be attributed to decreased fatty acid esterification measured by the incorporation of [U-(13)

135 The understanding of the esterification mechanism provides useful knowledge for m

136 present genetic and biochemical data for the esterification mechanism.

137 genes associated with fatty acid transport, esterification, mitochondrial import, and beta-oxidation

138 Methyl esterification neutralizes the negative charge of the pr

139 es rapid, high-capacity sterol transport and esterification, obviating any requirement for soluble in

140 that both free astaxanthin biosynthesis and esterification occurred in the endoplasmic reticulum, an

141 omers in a mixture, while the stereospecific esterification of 1,2- or 2,3-isopropylidene-sn-glycerol

142 ixture combinations for the oxidative methyl esterification of 1-octanol at 60 degrees C in methanol.

143 In Muller cells, esterification of 11-cis-retinol was four times greater

144 Selective esterification of 11-cis-ROL is one possibility.

145 disproportionation is arrested by silylative esterification of a mono-CO2 adduct.

146 Methyl esterification of a peptide converts carboxylic acids, s

147 mitations and efficiently catalyze the redox esterification of a whole series of alpha/beta-substitut

148 Tomato ASATs catalyze the sequential esterification of acyl-coenzyme A thioesters to the R4,

149 n the presence of oxygen, the cross and self-esterification of alcohols to esters proceeds in good to

150 have been developed for the direct oxidative esterification of alcohols using molecular oxygen as ben

151 t a one-pot process for the direct oxidative esterification of aliphatic alcohols that is significant

152 s and light energy to drive direct oxidative esterification of aliphatic alcohols under base-free, mi

153 Selective esterification of aliphatic and aromatic carboxylic acid

154 ((13)C-TrEnDi), which results in the methyl esterification of all acidic sites and the conversion of

155 f 11-cis-retinol was four times greater than esterification of all-trans-retinol.

156 tors in ethanol achieved near-complete ethyl esterification of alpha2,6-linked sialic acids and lacto

157 We now report the nickel-catalyzed esterification of amides derived from aliphatic carboxyl

158 The esterification of amphiphilic alcohols with fatty acids

159 Selective esterification of apoptolidins A and H with 5-azidopenta

160 , and NMR spectroscopy indicated complete de-esterification of arabinoxylan oligosaccharides from whe

161 Therefore, in planta, CUS1 can catalyze the esterification of both primary and secondary alcohol gro

162 Furthermore, in these mutants, the esterification of both sn-1,3 and sn-2 positions of glyc

163 Chemical inhibition of MTP also decreases esterification of cholesterol in Caco-2 and HepG2 cells.

164 n the induction of hypertriglyceridemia, the esterification of cholesterol of very low-density lipopr

165 process activated by apoA-I, leading to the esterification of cholesterol, which creates a hydrophob

166 he absorption of dietary fat involves the re-esterification of digested triacylglycerol in the entero

167 rein, four different ILs were tested for the esterification of dihydrocaffeic acid with hexanol and t

168 dentify a specific role for hepatic DGAT1 in esterification of exogenous fatty acids and indicate tha

169 mains and a significant decrease (53-36%) in esterification of exogenous sterol.

170 Although esterification of free cholesterol to cholesteryl ester

171 is of diacylglycerols in rapeseed oil by the esterification of free fatty acids and monoacylglycerols

172 y acid, leading to a radical increase in the esterification of free fatty acids into triacylglycerol.

173 involved in lipid storage through efficient esterification of free fatty acids.

174 irect evidence for the role of Fum14p in the esterification of fumonisins.

175 sults suggest that FUM14 is required for the esterification of fumonisins.

176 Esterification of GFP with 2-diazo-2-(p-methylphenyl)-N,

177 IalphaI is essential for the trans-esterification of HCs onto hyaluronan (HA).

178 lasma fraction was able to promote the trans-esterification of HCs to HA in the presence of TSG-6, wh

179 cholesterol and sphingolipids and defective esterification of LDL-derived cholesterol.

180 glucose flux into glycerol-3-phosphate, and esterification of long chain CoAs resulting in rapid con

181 The esterification of methylecgonine (2-carbomethoxy-3beta-t

182 derivatives were obtained by simple one-step esterification of oleanolic acid prior to pharmacologica

183 Deletion of LPT1 abrogated the esterification of other lysophospholipids, and overexpre

184 high-pressure pretreated tomatoes), with de-esterification of pectin by PME, which resulted in a hig

185 omato tissue on the other hand, intensive de-esterification of pectin by the activity of PME occurred

186 n, total polyphenols index and the degree of esterification of pectins.

187 ides, lignins, pectins) and by the degree of esterification of pectins.

188 Esterification of phytosterols with DHA may render impro

189 the major source of hepatic lipid synthesis, esterification of preformed fatty acids, is primarily de

190 ighly effective for aerobic oxidative methyl esterification of primary alcohols.

191 In this context, we review evidence that esterification of retinol and retinol-based drugs within

192 nol acyl transferase (LRAT), which catalyzes esterification of retinol to its storage species retinyl

193 Therefore, the esterification of retinol with fatty acyl moieties to ge

194 onent of eukaryotic lipid homeostasis is the esterification of sterols with fatty acids by sterol O-a

195 Esterification of the 11-OH of 17-AAG eliminated Hsp90 b

196 in the biogenesis of HDL due to inefficient esterification of the cholesterol of the prebeta1-HDL pa

197 ease in cutin deposition, mid-chain hydroxyl esterification of the dihydroxyhexadecanoic acid was aff

198 onformation-controlled highly regioselective esterification of the glucose diol in the disaccharide c

199 so synthesized double prodrugs by additional esterification of the hydroxamate moiety.

200 nic phosphinates containing two P-C bonds or esterification of the phosphonate group.

201 An increase in the total degree of esterification of the produced ADA-R-preparation caused

202 triesters were found to effect quantitative esterification of the pyromellitate system under autocat

203 In Arabidopsis seeds, esterification of the R-group of hydroxylated GSLs (OH-G

204 The mechanism of esterification of the secondary alcohol 1-(1-naphthyl)et

205 active lead compound was made accessible by esterification of the terpenols with commercially availa

206 f the peroxisomal membrane for subsequent re-esterification of the VLCFAs.

207 Esterification of this alcohol with a C1-C19 carboxylic

208 The purified enzyme catalyzed the sequential esterification of trehalose with two palmitoyl groups, g

209 GC-MS system was used for the trans-esterification of triglycerides to fatty acid methyl est

210 Lastly, analysis of the methyl esterification of ubiquitin and single point mutation of

211 s tested for the production of capsinoids by esterification of vanillyl alcohol (VA) with free fatty

212 and evaluated as (pre)catalysts in the redox esterification of various alpha- or beta-substituted ena

213 of fatty alcohols on the reaction rate, the esterifications of C4-C18 straight-chain fatty alcohol w

214 Esterification or amidation in solution effectively prot

215 ated multidrug resistance was established by esterification or etherification of hydroxylated 5alpha/

216 te, and trapping of this arrangement through esterification or ring-closing metathesis produces the c

217 zo dyes have been prepared and via synthetic esterification or subsequent enzymatic hydrolysis at the

218 been synthesized at 28 degrees C via direct esterification or transesterification catalyzed by the v

219 adamantanes (guest moieties) via controlled esterification or with beta-cyclodextrins (host moieties

220 fied the fatty acids involved in carotenoids esterification: palmitic (C16:0), myristic (C14:0) and s

221 ethyl carbonate) were partly consumed via an esterification pathway.

222 the esterified fraction, suggesting that the esterification process facilitates the accumulation of t

223 During the esterification process, both their aromatic and aliphati

224 donor molecules involved in the xanthophyll esterification process.

225 The deamidation-methyl esterification products are greatly enhanced with elevat

226 esulting lack of substrates for triglyceride esterification protects severely hypothyroid mice agains

227 d as high-methoxyl pectin with the degree of esterification ranged from 82% to 90%.

228 the free fatty acids did not improve direct esterification rate, and the enzyme did not convert one

229 otein metabolism (HDL-cholesterol fractional esterification rate, cholesteryl ester transfer protein,

230 sulin levels decreased myocardial fatty acid esterification rates but increased the percentage of fat

231 rdial fatty acid utilization, oxidation, and esterification rates increased with increasing plasma FF

232 o-step reaction consisting of hydrolysis and esterification, rather than alcoholysis.

233 restored cellulose levels, and restored the esterification ratio of pectin to wild-type levels.

234 yzed "click" reaction and P(n-Bu)3-catalyzed esterification reaction as stoppering reactions.

235 Afterwards, the esterification reaction between HbA1c and T3BA produces

236 The methyl esterification reaction drastically improves the fragmen

237 otected amino acids via a one-pot activation/esterification reaction in the presence of various dialk

238 he deamidation followed by subsequent methyl esterification reaction mechanism is proposed based on t

239 A serendipitously discovered oxidative esterification reaction of cyclohexane hexacarboxylic ac

240 trate that Cas1 catalyses an efficient trans-esterification reaction on branched DNA substrates, whic

241 lability was tested by applying the in situ esterification reaction to the structurally distinct car

242 The K(eq) for the pABA esterification reaction was found to be 3 x 10(-3).

243 induced proton concentration can catalyze an esterification reaction, and greatly alter the volume of

244 In a trans-esterification reaction, triglycerides esterified from a

245 poxides, followed by an intramolecular trans-esterification reaction.

246 The esterification reactions are allosterically activated by

247 y and selectivity in biodiesel synthesis and esterification reactions at room temperature.

248 Chemical and lipase-catalysed esterification reactions between fatty acids of C4-C18 a

249 After esterification reactions between pentynoic acid and the

250 Triethylamine (Et3N) mediates esterification reactions between the title reagent (1) a

251 Turnover rates for condensation and esterification reactions decrease with increasing Cu dis

252 ione, BN82685, block the second of two trans-esterification reactions in splicing, preventing the rel

253 ipids on the phospholipase A and cholesterol esterification reactions of the enzyme were similar, ind

254 alyzed Meinwald rearrangement, and Mitsunobu esterification reactions were used as key steps.

255 l events for base-catalyzed condensation and esterification reactions, indicate that both reactions i

256 talyzed transesterification, hydrolysis, and esterification reactions, is used to demonstrate the pot

257 thiol-ene "click" chemistry and traditional esterification reactions.

258 , 0.2 mol/l in methanol) was used as a trans-esterification reagent.

259 mounts of 9-cis isomer whereas monopalmitate esterification resulted in increased 13-cis isomerizatio

260 ayer as a model system, we show that in situ esterification results in the creation of subtle chemica

261 r oxygenates via aldol-type condensation and esterification routes without detectable involvement of

262 diols and 2,4-diene-1,6-diols, and by a DODH/esterification sequence of sugar acids to unsaturated es

263 l Fischer titration method suffering from an esterification side reaction which generates water as a

264 may be utilized to also reveal phospholipid esterification site information in tandem mass spectrome

265 n of the acyl chains at the two phospholipid esterification sites has been performed based on the R(1

266 f PME6 rescues guard cell wall pectin methyl-esterification status, stomatal function, and plant grow

267 In addition, we added a peptide esterification step to increase phosphopeptide specifici

268 ine (PC) to the active site, rather than the esterification step.

269 process by combining other reactions such as esterification, Suzuki-Miyaura coupling, hydrogenolysis,

270 f B. anthracis encodes a cell wall d-alanine esterification system that is initiated by transcription

271 er of hepatic processes including fatty acid esterification, the pentose phosphate pathway, and gluco

272 As a function of esterification, the SiPcs 1-7 exhibit moderate-to-good s

273 Esterification then provided vinyl boronate esters as us

274 d similar trend of increase in pectin methyl esterification through decreasing PME activity as observ

275 ponents were finally stitched together by an esterification to afford the target rotaxane.

276 e the C1-C13 alkyl scaffold, and a Yamaguchi esterification to set the side chain.

277 The effect of flavan-3-ols on pectin methyl esterification under salt stressed conditions was furthe

278 of a small-molecule fluorophore is masked by esterification until entry into a cell, where endogenous

279 ants produced higher degree of pectin methyl esterification via decreasing pectin methyl esterase (PM

280 The impact of esterification was also studied using three triglyceride

281 Direct esterification was conducted in biphasic isooctane: wate

282 The reversible nature of boronate esterification was exploited to switch the receptor sequ

283 ine residues and myristic acid; this type of esterification was further confirmed by its resistance t

284 Esterification was shown to play the most significant ro

285 Fatty acid esterification was transient in the fasted state but con

286 Esterification was used to simultaneously increase solub

287 atization procedure, N-acetyl methyl (NACME) esterification, was developed to improve the accuracy an

288 pyl-, octyl-, octadecyl-trimethoxysilane and esterification) were estimated to 1.10, 1.02, 0.86, and

289 synthesis, which is important for fatty acid esterification when dietary fat is in excess.

290 on HDL-mediated cell cholesterol efflux and esterification, which are obligatory early steps in chol

291 and the retinal significance of cholesterol esterification, which could be cell-specific and both be

292 Esterification with 3% OSA results in starch that has OS

293 ctivity with the exception of increased self-esterification with a methanol solvent, resulting in met

294 For general esterification with alcohols, partial ester acid chlorid

295 blend using Candida cylindracea followed by esterification with glycerol using Lipozyme RM1M.

296 indicating that PNPLA1 catalyses the omega-O-esterification with linoleic acid to form acylceramides.

297 erivatization, in which FAs are sent through esterification with the acidic catalyst boron trifluorid

298 polysis promotes fatty acid oxidation and re-esterification within adipocytes.

299 zolin-5-one was realized by direct enzymatic esterification without need of further protective groups

300 s and of enzymes involved in free fatty acid esterification, without affecting those of de novo lipog