ライフサイエンスコーパス: exergonic

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1 involving both sensitizers were shown to be exergonic.

2 to phosphate, a reaction that is 15 kcal/mol exergonic.

3 ubstituted tetraenes undergo facile but less exergonic 8pi electrocyclization due to a steric clash t

4 Rate constants (k) for exergonic and endergonic electron-transfer reactions of

5 ial energy-conserving mechanism that couples exergonic and endergonic reactions of methanogenesis.

6 energy is conserved through the coupling of exergonic and endergonic reactions.

7 Back electron transfer is highly exergonic and occurs in the inverted region.

8 formation of the [3 + 2] phosphorus-ylide is exergonic, and hence, the [3 + 2] cycloaddition is kinet

9 In contrast, although NO reduction is as exergonic as O2 reduction, there are no protons pumped i

10 pending on the pH, the aqueous reactions are exergonic by deltaG = -20 to -27 kcal mol(-1), based on

11 Thermodynamic calculations suggest that the exergonic character of the formation of the Michael addu

12 se superfamily, catalyzes the Mn2+-dependent exergonic dehydration of 2-succinyl-6R-hydroxy-2,4-cyclo

13 ber of the enolase superfamily, catalyzes an exergonic dehydration reaction in the menaquinone biosyn

14 The reaction is exergonic (DeltaG = -6.16 kcal mol(-1)), and both the en

15 brium being driven forward by the subsequent exergonic dimerization of the aminoborane Me(2)N horizon

16 DFT computations predict modestly exergonic dimerization of the carbenoid, with or without

17 s we reported recently, endergonic to mildly exergonic electron transfer between neutral aromatics (b

18 electron-transfer reactions are often highly exergonic, for which Marcus theory predicts reduced elec

19 endergonic formation of H2 from NADH to the exergonic formation of H2 from reduced ferredoxin.

20 tion of mixed tetramers and resulted in less exergonic free energies of mixed dimer and mixed trimer

21 roline to form L-glutamate is coupled to the exergonic hydrolysis of ATP to ADP and inorganic phospha

22 Whereas protonation is fast and exergonic in the gas phase, it is endergonic in the pola

23 t synthesis reactions of 11 amino acids were exergonic in the hydrothermal solution, but all were end

24 s-cis to one s-trans butadiene is facile and exergonic, leading to the observed 1Z,4Z,8E-cyclodecatri

25 c ferredoxin reduction by coupling it to the exergonic NAD(+) reduction.

26 with NADH as reductant by coupling it to the exergonic NADH-dependent reduction of caffeyl-CoA.

27 bifurcating [FeFe] hydrogenase in which the exergonic oxidation of ferredoxin (midpoint potential, -

28 uctase to regenerate HS-CoM and HS-CoB is an exergonic process.

29 Although ion solvation in liquid media is an exergonic reaction overall, we find it is also associate

30 We also show that there is an exergonic reaction route via these intermediates leading

31 lectron transfer from NADH, and couples this exergonic reaction to the translocation of protons again

32 d/or physical environment or catalysis of an exergonic reaction, drives the system away from equilibr

33 highly endergonic, it must be coupled to an exergonic reaction.

34 For moderately exergonic reactions, both donor and acceptor are found t

35 For highly exergonic reactions, the donor is very hot, whereas the

36 Acidaminococcus fermentans, which couple the exergonic reduction of crotonyl-CoA to butyryl-CoA to th

37 with a limiting rate constant k(lim) in the exergonic region, followed, near the thermoneutral point

38 Weller reactions in the endergonic or weakly exergonic regions.

39 require an extraordinary 3 ps to descend an exergonic slope.

40 ction of ferredoxin with NADPH driven by the exergonic transhydrogenation from NADPH onto NAD(+).

41 ns are pumped in conjunction with the highly exergonic, two-electron reduction of Fe(III)- (-)O-O (-)

42 ton is pumped in conjunction with the weakly exergonic, two-electron reduction of Fe-bound O 2 to the

43 sis (>21 kcal/mol) and is significantly more exergonic when coupled to chloride elimination.

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