ライフサイエンスコーパス: exothermic

1 energies (i.e., the adsorption processes are exothermic).

2 oceeds via chairlike transition state and is exothermic.

3 because the pathway is pseudopericyclic and exothermic.

4 ) requires much lower barriers and is highly exothermic.

5 verall conversion of MeOH to CH(2)(OH)(2) is exothermic.

6 ion of one to three silver cations is highly exothermic.

7 activation of the C-CN bond was found to be exothermic.

8 n energy, and renders such cyclizations less exothermic.

9 of the interaction between IA(3) and YprA is exothermic.

10 Binding of both cytochrome c molecules is exothermic.

11 atalyzed reaction and the reaction is highly exothermic.

12 -like as the metathesis becomes increasingly exothermic.

13 dies, the aggregation process is shown to be exothermic.

14 reasing temperature and subsequently becomes exothermic.

15 cies SiCl2 was theoretically predicted to be exothermic.

16 lations indicates that the process is highly exothermic.

17 that the steps leading ultimately to NO are exothermic.

18 borylenes to multiple C-C bonds are strongly exothermic.

19 ons proceed without barrier and are the most exothermic.

20 1.3 eV) metal electrons caused by moderately exothermic (1-3 eV) chemical reactions over high work fu

21 s for a significant range of endothermic and exothermic [1,5]-shifts with different intrinsic activat

22 n of methanol to acetyl chloride is slightly exothermic (4.4 kcal/mol).

23 CPCM calculations show that the highly exothermic [4 + 2] pathway becomes kinetically more favo

24 In addition this new mechanism is very exothermic (45 kcal/mol) leading to a large net energy r

25 The reaction was calculated to be very exothermic (-69 kcal/mol), and this was confirmed via ca

26 Although loss of hydroxide ion is hugely exothermic, a concerted reaction is not enforced by the

27 ions are identified, and all are shown to be exothermic according to G3(MP2) calculations; strain ene

28 e device performance was characterized using exothermic acid-base neutralizations and a detailed nume

29 An exothermic addition/H-elimination reaction of acetylene

30 lly for systems showing complex and strongly exothermic adsorption behavior.

31 libria, while Pd/C catalyzes the subsequent, exothermic alkene hydrogenation.

32 nters act as nucleophiles) are actually both exothermic and accompanied by low activation barriers.

33 Con-G dimerization was shown to be exothermic and accompanied by positive heat capacity cha

34 n process with a high energy barrier into an exothermic and almost barrierless Huckel-Mobius transiti

35 ffect of binding the anionic carboxylates is exothermic and also, the source of positive cooperativit

36 perature is that the partitioning process is exothermic and becomes less favorable with increasing te

37 to the natural sequence ribozyme is strongly exothermic and can be analyzed in terms of sequential in

38 evealed that the interaction is spontaneous, exothermic and driven by entropy.

39 ansfer to protonated HAL and AHL triggers an exothermic and dynamically barrierless transfer of the c

40 Both exothermic and endothermic phases produce highly negativ

41 The binding data conformed to both exothermic and endothermic phases with magnitudes of Del

42 ite with distinct kinetic and thermodynamic (exothermic and endothermic) properties.

43 g reactions, which are characterized more by exothermic and enthalpic interactions.

44 Tetraloop-receptor docking is significantly exothermic and entropically unfavorable in 1 mM MgCl(2)

45 hin 3, the protonation of 2 by 1 is fast and exothermic and forms 6, an aggregate between betaine 4 (

46 uctural reorganization during dehydration is exothermic and irreversible.

47 Binding to the second site is highly exothermic and is accompanied by an unfavorable entropic

48 ing of betaine 4 in aggregate 6 are fast and exothermic and lead irreversibly to E-11, the aggregate

49 which in turn indicated that the process is exothermic and low-energy interactions are involved in t

50 C-H or C identical withC bonds are all more exothermic and more strongly activating than for the cor

51 bilization of products that makes hydrolysis exothermic and needs to be considered in achieving impro

52 ITC data indicate that binding is exothermic and occurs with a 1:1 stoichiometry.

53 Each step in the associative pathway is exothermic and occurs with small energy barriers.

54 d entropy, whereas the middle step is highly exothermic and proceeds with a large decrease in entropy

55 alpy of intact apoE4 (-39 kcal/mol) was less exothermic and rather similar to that of each fragment,

56 the binding of maltotriose to the protein is exothermic and tight, whereas no thermal effect was obse

57 hthalene-type ion is calculated to be highly exothermic and without a barrier.

58 N by apo-FRP was found to be noncooperative, exothermic, and primarily enthalpy driven.

59 O(S) formation is exothermic, and the oxygen atoms tend to avoid O-O dimer

60 The changes in molar enthalpy become more exothermic as ring number increases and as annelation st

61 DNA bending, while the 6-bp mode is modestly exothermic at all salt concentrations examined.

62 related charged phenyl radicals in different exothermic atom and group abstraction reactions in the g

63 d state, we report experimental evidence for exothermic atom-exchange chemical reactions.

64 Reactions are increasingly exothermic based on metal complex, Mo(PiPr3)2(CO)3 < W(P

65 n without exception (i.e., E(isom) is always exothermic), Be(2+)@C(10)H(16) (T(d)(); -235.5 kcal/mol)

66 from N,N'-dipp-substituted boranes underwent exothermic beta-scissions with production of dipp-Imd-BH

67 A-I to SUVs of POPC plus 0-20% (mole) FC was exothermic between 15 and 37 degrees C studied, accompan

68 plots are large and negative, indicating an exothermic binding effect, whereas the entropy changes a

69 alorimetry (ITC), the stoichiometry data and exothermic binding enthalpies indicated that, like CQ, t

70 titration calorimetry showed the sequential exothermic binding of two manganese ions in solution, wi

71 c helices were the major determinants of the exothermic binding reactions.

72 ry (ITC) studies supported these findings as exothermic binding was observed under conditions with fr

73 < PVCap < VIMA, have increasingly negative (exothermic) binding energies of -0.2 < -20.6 < -37.5 < -

74 ally driven in PF6- and TF2N-based RTILs and exothermic but entropically driven in BF4-based RTILs.

75 Formation of these 1:1 complexes was also exothermic, but additional endothermic events occurred a

76 A less exothermic, but more plausible pathway for photochemical

77 ydrogen by the FLP Rp(-)/[(Tol)Im(F4)](+) is exothermic, but the formation of the initial Lewis pair

78 alphaKG decarboxylation, is barrierless and exothermic, but the subsequent hydrogen abstraction step

79 n of ZIFs from these components at 298 K are exothermic, but the ZIFs are metastable energetically wi

80 ults, which show the two-step reaction to be exothermic by -215 kJ mol(-1), in agreement with results

81 ium-nitride linkage and was calculated to be exothermic by -3.25 kcal mol(-1).

82 SSP starts on crystal defect sites; it is exothermic by 14 kcal/mol and requires activation energy

83 erthiyl radical make the foregoing reactions exothermic by 15-34 kcal/mol.

84 tion of 1 to form 3 was found to be strongly exothermic by 176.0 kcal/mol.

85 Bergman reaction of triggered 1 is slightly exothermic by 2.8 kcal/mol.

86 Isomerization of ROONO to RONO(2) is exothermic by 22-28 kcal mol(-)(1).

87 tonation of 3 to form 5 was also found to be exothermic by 28.4 kcal/mol.

88 e with an Os(PH3)3 fragment in place of C is exothermic by 3 kcal/mol (the parent Bergman reaction is

89 The former reaction is computed to be exothermic by 37.2 kcal/mol, whereas the latter is calcu

90 The analogous decomposition is exothermic by 8 to 11 kcal mol-1 for the anions, indicat

91 The 5',8-cyclization is found to be exothermic by approximately 20 kcal/mol but kinetically

92 ngement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical,

93 g a continuous feedback loop between various exothermic catalytic reactions in the nutrient layer and

94 NA analogue of the loop, was associated with exothermic changes, consistent with predominantly outer-

95 +/- 2.5) s(-1)) reaction by two branches: an exothermic channel that produces NDMA, and an entropy-dr

96 cal calculations predict that by coupling an exothermic chemical reaction with a nanotube or nanowire

97 ion-induced mixing), or self-propagating (by exothermic chemical reaction).

98 Exothermic chemical reactions may be an important source

99 neously at planar lipid bilayers agitated by exothermic chemical reactions.

100 reactions: electronic excitation upon highly exothermic chemisorption has been observed, and indirect

101 uced when carried out concomitantly with the exothermic chlorination step.

102 The strongly exothermic cleavage of the dinitrogen bond takes place,

103 a low-temperature solution process utilizing exothermic "combustion" precursors.

104 ral bis-urea and bis-thiourea receptors form exothermic complexes with dicarboxylates in DMSO, with a

105 IV undergoes a very exothermic coupling of alkyl and hydroxy groups to give

106 a CN x H y material formed via the rapid and exothermic decomposition of a reactive triazine precurso

107 All of the products exhibit exothermic decomposition properties with heats of decomp

108 reasonably large activation energies for its exothermic decomposition to CsF+2 F2 , or to CsF3 (three

109 ost favourable Delta G vH value and the most exothermic Delta H vH.

110 n a significantly decreased affinity, a less exothermic Delta H, and a more negative Delta C(p) for s

111 , I(H(2)O), with O(2) is a 4-electron highly exothermic [DeltaE(gas) = 62.5 (DeltaE(gas) + DeltaG(sol

112 inds to Nmt1p with a Kd of 15 nM and a large exothermic deltaH (-25 kcal/mol).

113 ta show that binding of pTppAp to RNase A is exothermic (DeltaH = -60.1 +/- 4.1 kJ/mol) with a dissoc

114 t was shown that the complexation process is exothermic (DeltaH degrees approximately -7.6 kcal mol(-

115 In potassium, association is highly exothermic (DeltaH(25 degrees C) = -41.6 +/- 1.2 kcal/mo

116 of formation of 1-[eta(2)-NCNMe(2)] is more exothermic (DeltaH(degrees) = -22.0 +/- 1.0 kcal mol(-1)

117 tal-bound product is calculated to be highly exothermic, DeltaH(reg) = -36.7 kcal/mol.

118 lt concentration, but is extremely large and exothermic (DeltaHobs=-150(+/-5) kcal/mol).

119 ith an extended lysine chain triggers highly exothermic dissociation by loss of ammonia from the Gly

120 endothermic effect below 17 degrees C and an exothermic effect above, suggesting a heat capacity chan

121 dehydrogenation to form PtCH(2)(+) + H(2) is exothermic, efficient, and the only process observed at

122 te a mechanism in which the initial event is exothermic electron transfer from the hydrazone to (1)O(

123 rate at room temperature, as expected for an exothermic, electron tunneling reaction in RCs.

124 er of 22 +/- 3 kcal mol(-1) and is driven by exothermic elimination of DMSO.

125 Ni(II) and Cd(II) exhibited a characteristic exothermic-endothermic pattern that was used to infer th

126 g effect was found to be derived from a more exothermic enthalpic term.

127 othermal titration calorimetry studies yield exothermic enthalpy changes (deltaH) for protonation of

128 statherin adsorption is characterized by an exothermic enthalpy of approximately 3 kcal/mol that dim

129 The exothermic enthalpy of complex formation varies with dif

130 The interaction is entirely driven by exothermic enthalpy, consistent with the abundance of po

131 The interaction is an exothermic event that is both enthalpically and entropic

132 The exothermic F + H(2)O --> HF + OH reaction has a decidedl

133 proportionation 2SiO(s) --> Si(s)+SiO2(s) is exothermic, falling right into the series of group 14 mo

134 nthalpies of the aminoglycosides become more exothermic (favorable) with increasing pH, an observatio

135 is higher than that reported previously for exothermic feedstock type.

136 dothermic for alkyl-substituted alkenes, but exothermic for conjugated alkenes (addition of an NHC-bo

137 2O)(n+1) + H2O-->C6H5.(H2O)nH+ would also be exothermic for n > or = 4, but lack of H/D exchange with

138 + (H2O)nH+ is thermoneutral or exothermic for n > or = 4.

139 ermined from van't Hoff analysis, being more exothermic for oligoarginine binding.

140 respectively, despite being 9 kcal/mol less exothermic for RSeOH.

141 l method indicate that reaction proceeds via exothermic formation of a primary nitrosamine intermedia

142 yl = methyl, isopropyl) proceeds via initial exothermic formation of an eta(2)-nitrile complex.

143 The exothermic formation of salt byproducts provides a drivi

144 h epsilon-Al(13) Keggin cluster compounds is exothermic from oxide-based components but energetically

145 protein); (2) binding to membranes was very exothermic (> -60 kcal/ mol of protein); and (3) binding

146 ker Fe=N pi-bonding) and thermodynamic (more exothermic HAT) effects.

147 pproximately 30 kcal/mol) in contrast to the exothermic heat (ca. -85 kcal/mol) generated upon bindin

148 g of apoA-I to SUV is accompanied by a large exothermic heat and deletions in the C-terminal regions

149 This exothermic heat arises from an approximately 25% increas

150 hilst the demethylation reaction provoked an exothermic heat change.

151 Titration calorimetry reveals an exothermic heat for the interaction glycosaminoglycans w

152 binding in a manner that compensates for the exothermic heat generated by alpha-helix formation.

153 can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with th

154 results from the compensation of a favorable exothermic heat with an unfavorable entropy contribution

155 Our results reveal exothermic heats between -9.8 and -16.0 kcal/bp for temp

156 This is in excellent agreement with the exothermic heats of -16.8 kcal/mol and -25.7 kcal/mol fo

157 organic adsorbents, which show only moderate exothermic heats of binding, from -5 to -15 kJ/(mol I2).

158 Nanoparticles with exothermic heats of interaction were stabilized against

159 ing of K(+) to G-triplexes is accompanied by exothermic heats, and the binding of Ca(2+) with G-tripl

160 that yield highly stable cations by the most exothermic, hence least reversible 1,2-H shift.

161 heir respective hairpin cognate sequences is exothermic; however, changes in enthalpy, entropy, and h

162 .3 water molecules are still involved in the exothermic hydration of 2-oxopropanoic acid (PA) into it

163 ectron reduction in 1a(+) and 5a(+) triggers exothermic hydrogen atom migration from the terminal COO

164 h an endothermic hydrophobic interaction and exothermic hydrogen bond component.

165 owever, association of tetrahedral anions is exothermic in nature and both entropy- and enthalpy-driv

166 rsible monomer-dimer assembly that is highly exothermic in nature.

167 ylammonium metal formate series becomes less exothermic in the order Mn, Zn, Co, Ni.

168 Enthalpy of binding is less exothermic in the presence of metal-nucleotide.

169 er neat conditions and promoted by AlCl3, an exothermic in-line quench of high concentrations of prec

170 w that the binding mechanism changes from an exothermic independent two-site binding mechanism at pH

171 ceptor protein (CRP) by cAMP changes from an exothermic, independent two-site binding mechanism at pH

172 Haber cycle analysis of ITC data revealed an exothermic interaction between Rh(OH)3 nanoparticles and

173 te cleavage, and the second step is strongly exothermic, involving hydrolysis of an oxacarbenium ion

174 re-forming the COOH group and accomplishing exothermic isomerization of the initial (3H)-imidazole r

175 ecies vinylidene, and its subsequent, highly exothermic isomerization to acetylene, via electron remo

176 itration with [Co(NH(3))(6)](3+) resulted in exothermic isotherms with (dC-dG)(4) being more exotherm

177 (2) binding to membranes was relatively less exothermic (< -33 kcal/ mol of protein); and (3) binding

178 s an effective heat scavenger for the highly exothermic magnesium reduction process, promotes the for

179 this study reveal a structural basis for an exothermic maturation process probably present in many d

180 nergy upon cocrystallization agrees with the exothermic mixing of NIC and RMA liquids (a base and an

181 The net result of their activity is the exothermic movement of protons through the inner mitocho

182 HMX hydrolysis at pH 10 represents a highly exothermic multistep process involving initial deprotona

183 sistent with the absence of a barrier in the exothermic N-C bond forming reaction leading to the form

184 some experimental setups in which the highly exothermic nature of the fusion of two heavy-quark baryo

185 with increasing temperature, reflecting the exothermic nature of the process.

186 The discovery of this exothermic, net redox process was enabled by the simple

187 CAPTEAR process with Cu(NO3)2.2.5H2O uses an exothermic nitrate moiety to suppress empty-cage fullere

188 The exothermic oxidative dehydrogenation of propane reaction

189 Each system exhibited exothermic pathways via formation of cyclic intermediate

190 The exothermic peak at 78.5 degrees C probably corresponds t

191 dominated by favorable entropic changes, the exothermic phase has about 6.7 kcal/mol enthalpic advant

192 The initial exothermic phase of adsorption exhibited by native stath

193 l of bound Ni(2+) from PDF(Ec) abolished the exothermic phase without affecting the endothermic phase

194 through non-radiative energy dissipation and exothermic photochemical reactions.

195 plex for which the enthalpy of formation was exothermic, presumably because of DOPE amine group proto

196 herichia coli QueF binds preQ0 in a strongly exothermic process (DeltaH = -80.3 kJ/mol; -TDeltaS = 37

197 changes the folding enthalpy from a strongly exothermic process [e.g., DeltaH degrees = -26(2) kcal/m

198 ees = -26(2) kcal/mol at 180 mM] to a weakly exothermic process [e.g., DeltaH degrees = -4(1) kcal/mo

199 This is consistent with the existence of an exothermic process leading from the initial diyl to the

200 e, P22, showed that capsid maturation was an exothermic process that resulted in a release of 90 kJ m

201 air-free reaction proceeds via a significant exothermic process to form marcasite.

202 Mixing of water and DMF is an exothermic process where the micelle formation process o

203 he inclusion of rutin into HP-beta-CD was an exothermic process which occurred spontaneously.

204 riple bonded nitrogen completely in a highly exothermic process.

205 d to proceed without barrier and is a highly exothermic process.

206 lization of the metal sulfide is a much less exothermic process.

207 showed that apoE binding to emulsions was an exothermic process.

208 results indicated that the adsorption was an exothermic process.

209 1), the dissociation of water becomes a very exothermic process.

210 fety concerns due to the reaction's inherent exothermic profile.

211 These states underwent facile exothermic proton migrations to form aminoketyl radical

212 in the model peptide dication, facilitating exothermic proton transfer from one of the two sites of

213 Exothermic pyrolysis of refuse, which is hypothesized to

214 he corrosive nature of triflic acid, and the exothermic quenching were addressed by designing a suita

215 preferred CO(2)-AlCl(3) complex forms in an exothermic reaction (-6.0 kcal/mol) as does CO(2)AlCl(2)

216 ediyne 1 is triggered by NADPH in a strongly exothermic reaction (-88 kcal/mol), which involves a num

217 in two exemplary applications: First, a fast exothermic reaction (Michael addition) was monitored wit

218 ed proteins catalyzed by HlyC was overall an exothermic reaction driven by a negative enthalpy.

219 trong binding enables a quark-rearrangement, exothermic reaction in which two heavy baryons (Lambdac)

220 l remains a significant challenge due to the exothermic reaction nature.

221 three solvents that lead to endothermic and exothermic reaction processes, and we show that within t

222 calculated activation barrier for the highly exothermic reaction to a classical Lewis structure never

223 id and thereby stabilized against the highly exothermic reaction with atmospheric oxygen.

224 acetyl-lysine-bearing peptides revealing an exothermic reaction with relatively little discriminatio

225 -I interaction with POPC/SM SUVs produces an exothermic reaction, characterized as nonclassical hydro

226 Binding and cleavage is an exothermic reaction, while binding to D99 has negligible

227 diastereoselectivity unusual for a strongly exothermic reaction.

228 which involves propagation of self-sustained exothermic reactions along an aqueous or sol-gel media.

229 Exothermic reactions and photons generate hot electrons

230 This growth can be attributed to the exothermic reactions going inside the remnant.

231 olution of few muW as required to follow low exothermic reactions like oxidation.

232 Here, we report that exothermic reactions of fluorine (F) atoms in d3-acetoni

233 Our ab initio calculations identify new exothermic reactions of KHP forming a cyclic peroxide is

234 nique can be applied more generally to other exothermic reactions that are not readily accessible to

235 inst conventional notions that expect highly exothermic reactions to be irreversible.

236 ze to 1H-diazirenes of the type 24 in mildly exothermic reactions with activation energies in the ran

237 ipyridine, were calculated to undergo highly exothermic reactions with ArN3 to form the nitrene activ

238 electron transfer, this time being a highly exothermic reduction of the rearranged species to genera

239 ity, low tendency for carbon deposition, and exothermic reduction reactions.

240 The exothermic S(N)2 reaction is inefficient compared with p

241 initiation steps is subsequently utilized in exothermic secondary reactions, leading finally to forma

242 ading axis, and may be driven by the heat of exothermic serpentinization reactions between sea water

243 With Mg2+ as the ligand, two separate exothermic sites are obtained by ITC, one of Kd = 46 mic

244 on the entire nervous system, especially in exothermic species.

245 The reaction sequence involved two exothermic steps where the standard procedure demands sl

246 ic proton-transfer reaction with a competing exothermic substitution (S(N)2) channel, F(-) with boran

247 ithium leading to polylithiated benzenes are exothermic, suggesting that it may be posible to prepare

248 thermic isotherms with (dC-dG)(4) being more exothermic than (dm(5)C-dG)(4) by 720 cal/mol basepair.

249 with both Al metal and Al clusters are more exothermic than are reactions of Cl2 with them.

250 roton transfer is usually significantly more exothermic than electron transfer.

251 etween -20 and -30 kJ mol(-1), slightly more exothermic than enthalpies of condensation (-16.1 kJ mol

252 action energy of SB-3CT is 8.0 kcal/mol more exothermic than that of its oxirane analogue.

253 nts to the substituted CHTE species are more exothermic than that of the parent PC.

254 with lower activation barriers and are more exothermic than the analogous process involving the pare

255 of the C-F bond at the metal is usually more exothermic than the corresponding reaction of the C-H bo

256 ase of -63 kcal/mol and is considerably more exothermic than the ECO2 path whose energy release is -2

257 HF)(3)-3(C) x (THF)(3) are 6-8 kcal/mol less exothermic than the experimentally determined values in

258 because the second ion-pairing step is more exothermic than the first, and the reduction of [KA] (A

259 the reduction of [KA] (A = COT, NB) is more exothermic than the reduction of A(-1).

260 action of neutral 1 is computed to be highly exothermic, the finding that 1*- apparently does not und

261 All the compounds exhibit exothermic thermal decomposition except the quinuclidini

262 nd subjected to DSC analysis, they underwent exothermic thermodenaturation with transition temperatur

263 con-T possesses a single exothermic tight binding site for Ca2+, Mg2+, and Zn2+,

264 In particular, garnet minerals undergo exothermic transformations near this depth, acting to co

265 a small hump near 60 degrees C, and a broad exothermic transition at 78.5 degrees C, whereas the PPC

266 This exothermic transition disappears in the subsequent heati

267 hydro-phenanthrene intermediate, followed by exothermic unimolecular isomerization to a 9,10-dihydrop

268 yield markedly distinct ITC profiles (i.e., exothermic versus endothermic) upon interaction with act

269 thermodynamic point of view, the reaction is exothermic whatever the substituent R (from approximatel

270 (oxy)anions (As, B, and PO4) is consistently exothermic, whereas surface complexation of cations (Ca

271 use, radical chlorination is barrierless and exothermic, whereas the analogous hydroxylation is found

272 t different sites on VO2.CeO2(111) is highly exothermic with adsorption energies of 1.8 to 1.9 eV (HS

273 the binding reactions are noncooperative and exothermic with binding enthalpies (DeltaHb) ranging fro

274 Complexation is exothermic with large negative entropy, consistent with

275 uid crystalline temperature, partitioning is exothermic with negative changes in entropy.

276 from endothermic with the wild-type hSBDb to exothermic with the hSBDb* variant.

277 the syncon promoter to the RNA polymerase is exothermic, with a binding constant (K(b)) = 2.1 +/- 0.2

278 ated and the results suggest the reaction is exothermic, with a calculated overall energy change betw

279 The substrate binding step is exothermic, with a DeltaG of -5.2 kcal/mol at 37 degrees

280 rriers, and the reactions are computed to be exothermic, with all intermediates and transition states

281 The binding of PutA52 to operator 2 is exothermic, with an enthalpy of -1.8 kcal/mol and a diss

282 he release of 2.5 protons, which is slightly exothermic, with DeltaHrxn of -2.0 kcal mol-1, and large

283 Crystallization of the capsules is highly exothermic, with the most favorable DeltaH(cryst)(o) of

284 Binding to serum albumin is exothermic, yielding enthalpies (DeltaH(obs)) of -3 to -