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1 s and aryl fluorosulfates (or alkyl sulfonyl fluorides).
2 rusion step through protonation of the naked fluoride.
3 tical route to anhydrous tetramethylammonium fluoride.
4 of alternate techniques for preparing [(18)F]fluoride.
5 ive azomethines in the presence of potassium fluoride.
6 in complex with GDP-bound RhoA and magnesium fluoride.
7 from silylamide (probase) through the use of fluoride.
8 s-electrophile coupling reaction of an alkyl fluoride.
9 related to dental caries, despite the use of fluoride.
10 ine protease inhibitor, phenylmethylsulfonyl fluoride.
11 ignal amplification and optical detection of fluoride.
12 to yield phase-pure sodium-rare earth metal fluorides.
13 c polyhedra, including nitrides, oxides, and fluorides.
14 five-, six-, and seven-membered cyclic vinyl fluorides.
15 ng substrates of low reactivity such as aryl fluorides.
16 ectronically and sterically diverse sulfonyl fluorides.
17 enesulfonyl fluorides and 1,3-dienylsulfonyl fluorides.
18 application of novel imaging techniques (6-[fluoride-18]fluoro-levodopa [(18)F-DOPA] PET-CT and gluc
19 ed polycondensation between bisalkylsulfonyl fluorides (AA monomers) and bisphenol bis(t-butyldimethy
20 ounds by a distinct mechanism proceeding via fluoride abstraction, migratory insertion, and C-F reduc
22 equivalents, generated via silylium-mediated fluoride activation, undergo insertion into sp(3) and sp
23 ced decomposition (CID) spectra of precursor fluoride adducts of the bifunctional steroid "reduced pr
26 chemoselective reaction between the sulfonyl fluoride and a conserved lysine in the ATP binding site.
27 al process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trif
28 reliable Michael addition of ethenesulfonyl fluoride and amines/anilines while the BB monomers were
29 These complexes display minimal affinity for fluoride and can detect cyanide at concentrations less t
30 e the semimetallization in sapphire, calcium fluoride and quartz and to compare this phenomenon and s
33 a range of compounds, such as amides, alkyl fluorides and bromides, alcohols, aldehydes, arenes, and
35 cid fluoride, fluoroformate, benzenesulfonyl fluoride, and aryl fluorosulfonate derivatives) are effe
36 ilar intrinsic affinities and capacities for fluoride, and did not leach harmful ions into product wa
37 ng/mL for fluoxymesterone-M) are obtained by fluoride anion attachment mass spectrometry, as compared
38 c and computational studies demonstrate that fluoride anion binding is assisted by the formation of a
39 n investigated computationally, augments the fluoride anion binding properties of 2, thus making it c
40 inding studies reveal that 2 readily binds a fluoride anion by formation of a unique B-FH-O-B hydroge
42 is approach, which is rooted in the field of fluoride anion complexation/coordination chemistry, has
43 mily of boron, aluminium and gallium [(18)F]-fluoride anion complexing agents which can be conjugated
44 sent several observations that show that the fluoride anion does not act as a one-electron reducing a
45 ospecific decompositions after attachment of fluoride anion to a specific hydroxyl group of the stero
47 d to the chemistry of these group 13 [(18)F]-fluorides anion complexing agents and their use in PET.
48 mensional MOF, enclosing a periodic array of fluoride anions in contracted square-shaped channels.
49 vealed, which suggested that small localized fluoride anions substituted the hydroxyl anions in hydro
54 Noncentrosymmetric mixed-metal carbonate fluorides are promising materials for deep-ultraviolet (
58 new autoinductive cascade employing benzoyl fluoride as a latent source of fluoride is reported for
63 rom the corresponding metal fluorides MF4 by fluoride-azide exchange reactions with Me3 SiN3 in the p
64 s concerns about the cost-effectiveness of a fluoride-based intervention delivered at the practice le
67 adsorption of ubiquitin on gadolinium-doped fluoride-based NPs produced residue-specific NMR line-br
70 is of aryl groups on the urea indicates that fluoride binding is dependent on sigmap and sigmam param
72 defined urea-fluoride complexes are used as fluoride-binding reagents for the nucleophilic substitut
73 rnable high-k fluoropolymer, poly(vinylidene fluoride-bromotrifluoroethylene) P(VDF-BTFE), with a die
74 This approach for colorimetric sensing of fluoride by ring-opening of the otherwise photochromic b
77 The synthetic strategy involved sequential fluoride-catalyzed nucleophilic addition of PhSCF2SiMe3
78 renes bearing simple functionalities such as fluoride, chloride, ester, amide, ether, nitrile, and tr
79 f chemistries (oxides, carbonates, bromides, fluorides, chlorides and phosphates), multiple crystal s
80 hane) and the shell (wrinkled polyvinylidene fluoride-co-trifluoroethylene/carbon nanotube layer) dur
81 The discrete (phosphinoarenesulfonate)Pd fluoride complex (PO(Bp,OMe) )PdF(lutidine), where PO(Bp
82 esis that the reactive species is a 1:1 urea-fluoride complex of type [UF](-) (U = urea) resulting fr
85 ination strength, and reactivity of the urea-fluoride complexes are tunable by modifying substituents
87 udy examining the structure of 18 novel urea-fluoride complexes in the solid state, by X-ray and neut
88 n is slower in comparison with known alcohol-fluoride complexes, but SN2 is largely favored over E2,
94 n people drink groundwater contaminated with fluoride concentrations exceeding the World Health Organ
95 cy-doubling oxides, phosphates, borates, and fluoride-containing borates were found, no transition-me
96 er-sized particles of Bioglass 45S5 (BAG) or fluoride-containing phosphate-rich bioactive glass (BAG-
99 as an inexpensive adsorbent for remediating fluoride-contaminated groundwater in resource-constraine
100 ed the deposition kinetics of polyvinylidene fluoride copolymerized with trifluoroethylene (P(VDF-TrF
101 only under certain circumstances, e.g., when fluoride displacement by a nucleophile is facilitated.
102 ostructure oxide counterpart of LaOZnSb, the fluoride DMS (Ba,K)F(Zn,Mn)As shows much improved semico
104 oupling with an isopropylidene-protected Kdo-fluoride donor to afford a protected tetrasaccharide int
105 tion between sucrosyl acceptors and glycosyl fluoride donors to yield the derived trisaccharides.
106 hemicals (theophylline, tetramethylrosamine, fluoride, dopamine, thyroxine, 2,4-dinitrotoluene) and a
107 t the side products derive from facile alpha-fluoride elimination at the 3-coordinate Pd(II) complex.
108 reaction is assumed to proceed through beta-fluoride elimination of a beta,beta,beta-trifluoroalkylr
110 delivers secondary, tertiary, or vinyl alkyl fluorides embedded within a vicinal fluoro amine functio
113 he Van Deemter optimum), the plate count for fluoride exceeded 70000 plates/m under isocratic conditi
114 addressable bis-electrophiles for sulfur(VI) fluoride exchange (SuFEx) click chemistry, in which eith
116 ns) as powerful catalysts for the sulfur(VI) fluoride exchange (SuFEx) reaction between aryl silyl et
117 een longitudinal, had individual measures of fluoride exposure, addressed the impact of prenatal expo
119 also by increasing the exothermicity of the fluoride extrusion step through protonation of the naked
120 first correlate the voltage profile of iron fluoride (FeF3), a representative conversion electrode m
121 luorine-containing electrophiles (e.g., acid fluoride, fluoroformate, benzenesulfonyl fluoride, and a
122 of [(18) F]difluoromethylarenes from [(18) F]fluoride for radiopharmaceutical discovery is reported.
123 en the acetaldehyde enolate anion and methyl fluoride, for both O-methylation and C-methylation, in o
124 selectivity in fluorine functionalization is fluoride fragmentation from the radical anion of the mul
128 a maximum 4-fold signal enhancement for each fluoride generated, as well as a self-propagating cycle
129 ch either the alkenyl moiety or the sulfonyl fluoride group can be the exclusive site of nucleophilic
135 18)F]7 from up to 285 GBq (7.7 Ci) of [(18)F]fluoride in 50 min (uncorrected radiochemical yield, spe
137 tive electrode technique was used to measure fluoride in archived urine samples taken from mothers du
141 of fluorene, allows "naked-eye" detection of fluoride in subppm levels (<1.0 ppm) in THF as well as i
142 is the strain of box deformation that keeps fluoride in the middle of the box, and freezes what woul
143 ew structure is able to solubilize potassium fluoride in toluene solution much more efficiently than
145 dynamically disfavored alkenyl chlorides and fluorides in high yield and with exceptional stereoselec
147 obtain many alkenyl chlorides, bromides and fluorides in up to 91 per cent yield and complete Z sele
149 fferential effect of dasatinib between (18)F-fluoride incorporation in tumor and normal bone, (18)F-f
150 n Mg(2+)i was also present; and 4) beryllium fluoride induced maximal IH even in the absence of nucle
151 yloxy-substituted diarylpyrans subsequent to fluoride-induced ring opening are remarkably high (330-4
155 te-limiting step is the release of the first fluoride ion from the difluoromethylphenolate intermedia
156 renes (1a-1u) with cyclotron-produced [(18)F]fluoride ion rapidly affords no-carrier-added [(18)F]flu
157 available phosphonate smoothly reacts with a fluoride ion to liberate a difluorocarbene intermediate
158 uence through steric hindrance of transverse fluoride ion vibrations, which directly controls the the
159 e Halex reaction of pentachloropyridine with fluoride ion was studied experimentally and computationa
162 Nevertheless, they allow the detection of fluoride ions at micromolar concentration by the naked e
166 oying benzoyl fluoride as a latent source of fluoride is reported for signal amplification and optica
168 on the structure and reactivity of complexed fluoride is therefore important for catalysis and numero
178 ochip that is dragged along a polyvinylidene fluoride membrane so that as proteins exit the chip they
179 ion sulfonyl fluoride poly(perfluorosulfonyl fluoride) membranes with the photoacid 8-hydroxypyrene-1
180 titative yields from the corresponding metal fluorides MF4 by fluoride-azide exchange reactions with
181 nzyme structures in the PDB containing metal fluorides (MFx ) as ligands that imitate either a phosph
182 ave previously reported that PET using (18)F-fluoride (NaF PET) for assessment of osseous metastatic
183 have previously reported that PET with (18)F-fluoride (NaF PET) for assessment of osseous metastatic
184 f degradation species: newly observed sodium fluoride (NaF) and the expected sodium carbonate (Na2CO3
188 ryl fluoride (SO2F2) and tetramethylammonium fluoride (NMe4F) via aryl fluorosulfonate (ArOFs) interm
189 we found that an increase in maternal urine fluoride of 0.5mg/L (approximately the IQR) predicted 3.
190 for the end-functionalization of vinylidene fluoride oligomers (OVDF) via a radical reaction between
191 transported ions, nucleotides, and beryllium fluoride) on IH and, for comparison, on transient curren
196 Ethenesulfonyl fluoride (i.e., vinylsulfonyl fluoride, or ESF) undergoes beta-arylation with stable a
198 odide, phosphate, nitrate, nitrite, bromide, fluoride, persulphate, acetate, thiosulphate, arsenite,
203 ted whether motion correction of gated (18)F-fluoride PET/CT and PET/MRI of the aortic valve could im
206 nes was achieved by reacting Nafion sulfonyl fluoride poly(perfluorosulfonyl fluoride) membranes with
207 om the life cycle of perfluorooctanesulfonyl fluoride (POSF)-based products in 1958-2030 is presented
210 ting the utility of lysine-targeted sulfonyl fluoride probes in demanding chemoproteomic applications
213 ehydrochlorination of 2-chloroethanesulfonyl fluoride proceeds neatly with magnesium oxide as the bas
218 der basic conditions with tetrabutylammonium fluoride provides the 1:1 adduct as the free alcohol.
220 hydrophobic polymers such as polyvinylidene fluoride (PVDF) have been widely used for membrane disti
221 s (GOQDs) onto amino modified polyvinylidene fluoride (PVDF) membrane has generated a new type of nan
222 the fabrication of omniphobic polyvinylidene fluoride (PVDF) membranes that repel both water and oil.
224 oreactor was retrofitted with polyvinylidene fluoride (PVDF) microfiltration membrane units, each of
226 olyimide (PI) in the shell of polyvinylidene fluoride (PVdF) was prepared using a facile one-pot elec
228 R) sensitive Er(3+) modified poly(vinylidene fluoride) (PVDF) (Er-PVDF) film is developed for convert
230 ectric phase transition in a poly(vinylidene fluoride) (PVDF) thin film by leveraging its phototherma
231 ad zirconate titanate (PZT), poly(vinylidene fluoride) (PVDF), 2D materials, and composite materials
232 ene 955) and a fluoropolymer (polyvinylidene fluoride, PVDF) were analyzed in powder raw material for
233 agents (m-chloroperbenzoic acid and hydrogen fluoride pyridine) and a simple chiral aryl iodide catal
239 suggest that bauxite could be an affordable fluoride-remediation adsorbent with the potential to imp
241 g technique could be useful for initiating a fluoride removal program undertaken by governmental and
243 nt), the iron responsive elements (29 nt), a fluoride riboswitch from Bacillus anthracis(48 nt), and
245 aches to the in situ generation of anhydrous fluoride salts for applications in nucleophilic aromatic
246 adium-catalyzed fluorination reactions using fluoride salts, controlling the regioselectivity present
249 istological and micro PET/CT analysis, (18)F-fluoride selectively highlighted microcalcification.
250 bust, and field portable smartphone platform fluoride sensor that can detect and analyze fluoride con
251 e deoxyfluorination of phenols with sulfuryl fluoride (SO2F2) and tetramethylammonium fluoride (NMe4F
252 lammonium 2,6-dimethylphenoxide and sulfuryl fluoride (SO2F2) serves as a particularly practical rout
256 thodology uses HF*pyridine as a nucleophilic fluoride source with a peracid stoichiometric oxidant, a
259 glycolytic inhibitors iodoacetate and sodium fluoride synergistically cooperated with NDI, thus furth
260 Air-stable and soluble tetrabutylammonium fluoride (TBAF) is demonstrated as an efficient n-type d
261 rist, and head (secondary endpoints) lithium fluoride thermoluminescent dosimeter, and randomizing at
262 ic voltammetry, theoretical calculation, and fluoride titration experiments, providing detailed under
263 he oxide ions in [IrO6](8-) by isoelectronic fluorides to form the fluorido-iridate: [IrF6](2-).
264 ntake and DMFT was weaker in adults who used fluoride toothpaste daily than in those using it less of
266 rnish, toothbrush, a 50-mL tube of 1,450 ppm fluoride toothpaste, and standardized prevention advice)
267 varnish, toothbrush, 50-mL tube of 1,450 ppm fluoride toothpaste, and standardized, evidence-based pr
269 is paper we report the direct measurement of fluoride transport across lipid bilayers facilitated by
270 synthetic anion transporters despite natural fluoride transport channels being recently discovered.
271 ncorporation in tumor and normal bone, (18)F-fluoride transport in bone metastases, correlation with
272 Herein, we report a new and controllable fluoride treatment for the non-discriminate extraction o
273 surface screening charges on poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] thin films.
274 on and alignment of multiple poly(vinylidene fluoride-trifluoroethylene) piezoelectric fiber bundles
280 d conversion of aryl iodide to aryl sulfonyl fluorides using DABSO and Selectfluor has been developed
281 d to a one-pot conversion of phenols to aryl fluorides using the combination of SO2F2 and NMe4F.
283 ation was associated with the application of fluoride varnish (P < 0.001), ensuring a greater reducti
284 diode laser, respectively); G2, G4, and G6 (fluoride varnish application + 0.5 W, 0.7 W, and 1 W dio
285 or children and 4 for parents), along with 4 fluoride varnish applications delivered in Head Start du
287 s recruited) to the intervention (22,600-ppm fluoride varnish, toothbrush, 50-mL tube of 1,450 ppm fl
288 lly randomized into intervention (22,600 ppm fluoride varnish, toothbrush, a 50-mL tube of 1,450 ppm
291 inated monomers as exemplified by vinylidene fluoride (VDF) and for the synthesis of their block copo
292 }C6 H4 )(2-SO3 -5-MeC6 H3 )P, inserts vinyl fluoride (VF) to form (PO(Bp,OMe) )PdCH2 CHF2 (lutidine)
293 r radiofluorination of anilines with [(18) F]fluoride via N-arylsydnone intermediates is described.
294 s developed whereby cyclotron-produced (18)F-fluoride was trapped on a quaternary methyl ammonium ani
295 e non-hydrolyzable ATP analog, ADP-beryllium fluoride, we observe additional interactions between the
296 he non-hydrolyzable ATP analog ADP-beryllium fluoride, we studied the NtrC1-sigma(54) AID complex usi
298 than that of the corresponding aryl sulfonyl fluorides, which are better characterized with regard to
300 mate the association of prenatal exposure to fluoride with offspring neurocognitive development.
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