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2 omimetic building blocks containing backbone-fluorinated 1,4-disubstituted 1,2,3-triazole moieties.
3 parallel strand orientation incorporating 2'-fluorinated 2'-deoxyribonucleosides with canonical nucle
4 diated Yamamoto-type diaryl homocoupling of (fluorinated) 2,3-bis(4'-bromophenyl)quinoxaline precurso
9 oselectivity in glycosylations with a set of fluorinated alcohols as well as carbohydrate acceptors.
10 CC coupling of 1,1-disubstituted allenes and fluorinated alcohols to form homoallylic alcohols bearin
12 s (SiPcs, 1-7) with non-, partially- and per-fluorinated aliphatic (linear or branched at the alpha-c
13 ence of fluorination on the lipophilicity of fluorinated aliphatic alcohols was determined, and the l
14 h this reaction provides efficient access to fluorinated alkanes from a pool of starting materials th
16 and achieves the coupling of a wide range of fluorinated alkyl halides with alkylzinc reagents at roo
19 5.1.0]octanes) based on a domino reaction of fluorinated alpha-bromoenones with beta-amino alcohols w
20 d to generate a versatile synthon for highly fluorinated alpha-phenyl acetic acid derivatives, which
21 with sterically unhindered monomers using a fluorinated aluminum salph complex with a substoichiomet
22 nt synthesis methods for the construction of fluorinated amines rely on air and moisture sensitive re
24 With advances in cryoprobe production and fluorinated amino acid incorporation strategies, protein
25 g reaction at the C-terminal position of the fluorinated amino acid was conveniently performed under
29 eatment of [LFe3(PhPz)3OFe][OTf]2 (1) or its fluorinated analog [LFe3(F2ArPz)3OFe][OTf]2 (5) with iod
31 of PIDA is comparable if not superior to its fluorinated analog phenyliodine(III) bis(trifluoroacetat
33 lso report the synthesis and reactivity of a fluorinated analogue and the structure of its covalently
34 od was applied for gram-scale synthesis of a fluorinated analogue of G protein-coupled receptor antag
35 ns (methyl to n-butyl) as well as some omega-fluorinated analogues (3-fluoropropyl and 4-fluorobutyl)
36 lysaccharide, LPS), we designed a library of fluorinated analogues aiming for an [(18)F]-labeled radi
39 application, the synthesis of a new class of fluorinated analogues of the neuroprotective tripeptide
41 er, contains a combination of chiral-racemic fluorinated and achiral hydrogenated dendrons (RHF) in i
42 ms are explored by ab initio calculations of fluorinated and hydrogenated diamond (111) surfaces inte
48 tadentate ligand with strategically designed fluorinated arene groups in the second coordination sphe
49 en dictated by the innate electronics of the fluorinated arene, limiting the synthetic utility of the
50 otocatalytic C-F functionalization of highly fluorinated arenes is a powerful method for accessing fu
54 inding protein) using commercially available fluorinated aromatic amino acids and fluorinated precurs
55 n/Prophenol-catalyzed Mannich reaction using fluorinated aromatic ketones as nucleophilic partners fo
56 C-H bond silylation is facile with partially fluorinated aromatic substrates containing two ortho flu
59 ur strategy resulted in materials containing fluorinated azobenzenes that retain their photochemical
63 non-covalent interactions between side-chain fluorinated benzyl esters and main-chain terminal arenes
68 g that the same family of fully or partially fluorinated boron Lewis acids allows for the related H-H
70 alternative strategy, we present the use of fluorinated boronic acid-appended pyridinium salts in co
73 oute to the stereoselective synthesis of key fluorinated building blocks of high value for medicinal
74 ted by gold species meet species with either fluorinated building blocks or fluorinating reagents, ne
77 g 2'-fluoro substituents ((F)iCd, (F)iGd and fluorinated canonical 2'-deoxyribonucleosides) stabilize
80 e the pronounced polarity of C-F bonds, many fluorinated carbon compounds are hydrophobic: a controve
82 e calculated transition states show that the fluorinated catalysts have stronger N-H...O and C-H...F
84 e fluorine effect on the reactivity of alpha-fluorinated CH acids has remained largely unexplored.
86 This strategy provided access to both new fluorinated chemical entities and nonfluorinated derivat
88 for identification of previously unreported fluorinated chemicals in a timely and cost-efficient way
90 xamples of asymmetric reactions that involve fluorinated components either as reactants, catalysts, s
91 es and polymerization thermodynamics of this fluorinated compound (1-F) were studied in comparison to
94 mulate TCE dechlorination, while some of the fluorinated compounds in certain AFFF formulations can i
95 trometry detector (LC-ESI-TOFMS) to identify fluorinated compounds in natural waters collected from l
96 e the occurrence and identity of replacement fluorinated compounds in surface water and sediment of t
98 ectfluor in acetone/water provides access to fluorinated compounds under mild and straightforward rea
99 inities, allowing for rapid screening of non-fluorinated compounds when a single fluorinated ligand f
100 ented, enabling the measurement of log P for fluorinated compounds with or without UV activity regard
104 of determining the sorption kinetics of any fluorinated contaminant, this work also highlights the s
105 yields (19)F T2 NMR relaxation values of any fluorinated contaminant, which are among the most danger
106 2,1,3-benzothiadiazole (DTBT) moiety and its fluorinated counterpart are important pi-conjugated buil
107 nus dendrimers contain either chiral-racemic fluorinated dendrons and a green fluorescent dye conjuga
108 tain environmentally friendly chiral-racemic fluorinated dendrons in their hydrophobic part (RF), one
110 a C-F bond driven Diels-Alder reaction of a fluorinated dienophile and a borole that shows remarkabl
111 isocyanate with fluorinated imines 1, while fluorinated dihydropyridin-2(1H)-ones 7 are prepared whe
112 ow that we can achieve the production of the fluorinated diketide 2-fluoro-3-hydroxybutyrate at appro
114 ition of silylated nucleobases onto model C2-fluorinated dithioacetal substrates resulted in 1,2-syn
118 work we explore how an electrolyte additive (fluorinated ethylene carbonate - FEC) mediates the thick
120 e with fluoromalonyl-CoA allows insertion of fluorinated extender units at 43% of the yield of the wi
121 sease (COPD) by using free-breathing dynamic fluorinated (fluorine 19 [(19)F]) gas magnetic resonance
122 lic alphagammaalpha-tripeptides derived from fluorinated-furanoid sugar amino acid frameworks act as
123 onic structure calculations, we predict half-fluorinated GaBi honeycomb under tensile strain to harbo
124 e computed the electronic spectrum of a half-fluorinated GaBi nanoribbon with zigzag edges, which sho
126 n MR imaging during inhalation of a normoxic fluorinated gas mixture (perfluoropropane) and by using
127 sions of high-global-warming potential (GWP) fluorinated gases, the fastest growing sector of greenho
129 nes, esters, nitriles, primary amides, alpha-fluorinated halo-acetates and perfluoroalkyl iodides.
132 molecules to this organelle, we synthesized fluorinated hydrophobic analogues of the fluorophore rho
133 al pathway controlled by the ER, we linked a fluorinated hydrophobic rhodol to 5-nitrofuran-2-acrylal
135 ed by the reaction of phenyl isocyanate with fluorinated imines 1, while fluorinated dihydropyridin-2
137 n conjunction with our previous work on PNAs fluorinated in backbone and at N-terminus, it is evident
140 oil at AFFF-impacted sites and suggests that fluorinated intermediates that are not routinely measure
144 phosphorylated, hydroxylated), and labeled (fluorinated, isotopically labeled) side chains to be add
145 ullerene organic solar cells (OSCs) based on fluorinated ITIC-Th1 electron acceptor and a wide-bandga
148 g of non-fluorinated compounds when a single fluorinated ligand for the binding pocket of interest is
149 perfluoropolyether (PFPE), formulated these fluorinated ligands as aqueous nanoemulsions, and then m
150 This work demonstrates the usefulness of fluorinated ligands in designing molecule-selective and
152 Therefore, (18)F-GE-180 is a promising new fluorinated longer-half-life tracer that reveals the pre
154 copolymers, providing facile access to semi-fluorinated macromolecules using a single methodology wi
155 ssing, fabrication, and functionalization of fluorinated materials with easy removal of the volatile
156 y for the fabrication of a chemically stable fluorinated metal-organic framework (MOF) material (NbOF
157 rate construction of a hydrolytically stable fluorinated metal-organic framework (MOF), NbOFFIVE-1-Ni
162 ein, we report the synthesis of a library of fluorinated molecules that contain nonafluoro-tert-butyl
163 Various applications could benefit from new fluorinated molecules that offer chemical handles for qu
164 We have been investigating the mechanism of fluorinated monomer insertion by three of the six differ
166 control of the polymerization of main chain fluorinated monomers as exemplified by vinylidene fluori
167 TREN (TREN = tris(2-aminoethyl amine)), semi-fluorinated monomers with side chains containing between
169 ionine S-adenosyl transferase-2 (MAT2A) with fluorinated N,N-dialkylaminostilbenes (FIDAS agents) off
170 d indole derivatives incorporating partially fluorinated n-propyl and n-butyl groups is described alo
172 s of blend films are improved by using these fluorinated n-type polymers to result in enhanced photoc
174 but our ability to produce site-selectively fluorinated natural products remains limited by challeng
175 Therefore, new approaches for accessing fluorinated nitrogen heterocycles are of great significa
178 pare the duplex stabilizing properties of 2'-fluorinated nucleic acid analogues with furanose and non
179 Our studies support further evaluation of fluorinated nucleic acid analogues with non-furanose sug
180 organoruthenium(II) chlorido complexes with fluorinated O,O-ligands [(eta(6)-p-cymene)Ru(F3C-acac-Ar
181 minium ions were successfully generated from fluorinated O-acetyl-N,O-acetal l-tartaric acid derivati
184 orption properties often exhibited by highly fluorinated organic compounds, that is molecules rich in
189 The utility of Tf2NH-TiCl4 activation of fluorinated oxazaborolidines is documented by examples i
191 ional functionalities and the formation of 3-fluorinated oxindoles exhibiting an array of four adjace
193 sing Selectfluor to afford the corresponding fluorinated paraconic esters in good yields as a single
198 route into valuable, densely functionalized fluorinated phosphonates that takes advantage of (i) a C
200 d was demonstrated on both unfluorinated and fluorinated plastics, demonstrating high tracer recoveri
201 , we herein report the chemical synthesis of fluorinated PNA monomers and biophysical studies of deri
202 rse phase HPLC show higher hydrophobicity of fluorinated PNA oligomers, dependent on the number and s
203 ne and at N-terminus, it is evident that the fluorinated PNAs have potential to emerge as a new class
206 the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed
207 erein, we report a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed
208 remarkable reactivity enable rapid access to fluorinated poly(aryl thioethers), but also opens new av
209 of the volatile catalyst and TMSF byproducts.Fluorinated poly(aryl thioethers), unlike their poly(ary
210 can be used as a monomer in vivo to produce fluorinated poly(hydroxyalkanoate) (PHA) bioplastics wit
211 ated by laser-desorption of the near-planar, fluorinated polycyclic aromatic hydrocarbon (PAH), C60H2
212 A modular synthesis of regiospecifically fluorinated polycyclic aromatic hydrocarbons (PAHs) is d
213 assembling giant surfactants consisting of a fluorinated polyhedral oligomeric silsesquioxane (FPOSS)
214 -b-PEO) diblock copolymer tail tethered to a fluorinated polyhedral oligomeric silsesquioxane (FPOSS)
216 hat, among others, degradation of side-chain fluorinated polymers in the environment and landfills ca
217 eir properties to those of the analogous non-fluorinated polymers shows that backbone fluorination le
218 polymers (FTACPs) are a class of side-chain fluorinated polymers used for a variety of commercial ap
220 n of these molecules, leading to a series of fluorinated polysubstituted imidazoles in gram scale.
221 ailable fluorinated aromatic amino acids and fluorinated precursors as example applications of the me
222 Intramolecular response was measured in fluorinated probes and intermolecular quenching by mixin
224 nces in the isomeric ratio and the yields of fluorinated products obtained from N,N-disubstituted-phe
230 uous flow synthesis of highly functionalized fluorinated pyrazoles and pyrazolines has been developed
233 H, CH2F, and CH2CF3, are used as a source of fluorinated radicals to add fluoroalkyl groups to electr
235 ylacetates, the synthetic equivalence of the fluorinated reagent with alpha-nitro-alpha-diazo carbony
237 er a competitive equilibrium with a selected fluorinated reporter ligand, the dissociation constant (
239 e a strong focus on the development of novel fluorinated RNA derivatives that are powerful in NMR spe
241 in, a series of 6-halopurines decorated with fluorinated side chains have been synthesized and evalua
242 his, two cholesterol analogs with truncated, fluorinated side chains have been synthesized and shown
244 ne illustrates the potential ease with which fluorinated small molecules relevant to neuroscience dru
245 g the potential to generate a broad range of fluorinated small-molecule targets in living cells.
246 of the HFC solvent in tandem with the highly fluorinated, solubilizing, weakly coordinating [Al(OR(f)
247 y simply modulating the starting peptide and fluorinated solvent concentrations during synthesis.
249 e to its greater oxidizing abilities in this fluorinated solvent such that in HFIP the reactivity of
250 o repel extremely-low-energy liquids such as fluorinated solvents, which completely wet even the most
251 omniphobic surface that can super-repel even fluorinated solvents, which highly wet all materials.
252 (19)F long-lived states in suitably designed fluorinated spy molecules allows one to perform competit
255 s is observed and calculated for planar ring-fluorinated stilbenes, trans-2,3,5,6,2',3',5',6'-octoflu
257 This work presents the synthesis of various fluorinated structural analogues of FTY720, their in vit
259 yl)pyrrolidin-2-one derivatives, bearing the fluorinated substituent on a tetrasubstituted carbon.
260 presence of the highly electron-withdrawing fluorinated substituent, cyclic alpha-trifluoromethylate
261 d herein, several alternative substrates and fluorinated substrate analogs were prepared to investiga
263 describe the field of reactions of partially fluorinated substrates with transition metal atoms, ions
264 ity of the Povarov reaction to unprecedented fluorinated substrates, generating scaffolds that contai
265 e of substrates to give medicinally relevant fluorinated substructures with complete regiocontrol.
266 al analysis suggested a strong preference of fluorinated sugar rings for either a 2'-endo, 3'-exo (So
267 radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible-light photore
268 nly describes a new synthetic application of fluorinated sulfones, but also provides a new route to f
269 eview, we present the specific properties of fluorinated sulfoximines (including important bioactivit
270 This work demonstrated the utilization of fluorinated sulfur ylides as versatile reagents for Core
272 eal that "polar hydrophobicity" of the fully fluorinated surfaces is caused by a negligible surface/w
273 sites in Ontario, Canada, and two commercial fluorinated surfactant concentrates were characterized i
274 spectrometry assigned molecular formulas to fluorinated surfactant ions, while collision induced dis
277 ge number of novel and infrequently reported fluorinated surfactants in different AFFF formulations.
278 e interfacial tensions using hydrocarbon and fluorinated surfactants including stimuli-responsive and
279 investigated whether commercially available fluorinated surfactants, such as Scotchgard fabric prote
281 we show that lower charge separation in the fluorinated system is associated with the formation of b
284 ane at room temperature, gives rise to novel fluorinated tetrahydrofuran-fused tetrahydroquinolines i
287 erminal end of the alkyl group is completely fluorinated, the balance tips toward fluorophobicity and
289 a wide bandgap polymer donor PM6 containing fluorinated thienyl benzodithiophene (BDT-2F) unit and a
291 The antiparallel self-assembled pore of the fluorinated tripeptides illustrates the selective ion-tr
293 metric properties of urea and thiourea-based fluorinated tripodal receptors are explored here for the
295 rks (MOFs) were synthesized from extensively fluorinated tritopic carboxylate- and tetrazolate-based
296 Supporting this model, substitution with fluorinated Trp analogues, with increased H-bonding prop
299 this protocol, we quantified the amount of a fluorinated xenobiotic (heptafluorobutyric acid, HFBA) i
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