ライフサイエンスコーパス: forbid

1 ) reaction coordinate is best designated as "forbidden".

2 radical ion pair A*-D*+ is thermodynamically forbidden.

3 ngth as previously calculated, are optically forbidden.

4 ons in the natal cloud core is energetically forbidden.

5 nsitions arising from hole doping are dipole forbidden.

6 of distillation boundaries that are normally forbidden.

7 into [Tp(tBu,Me)Cr(V)(O)2] (S = 1/2) is spin-forbidden.

8 vector by the ferroelectric polarization was forbidden.

9 tter interactions that are typically weak or forbidden.

10 )/mnm tetragonal, and a crystallographically forbidden 12-fold symmetry liquid quasicrystal) and prov

11 hat heteroatom substitution has on thermally forbidden [2 + 2] addition reactions using high-level de

12 Remarkably, the orbital topology-forbidden [2 + 2] process sometimes dominates over the a

13 This change triggers otherwise-forbidden actin polymerization in primary cilia, which e

14 In contrast, the spin-forbidden addition of (3)O(2) to (1)HNO was not detected

15 the active conformation of the kinase is not forbidden and can be visited transiently, it is not the

16 nts to judge attempted harms as less morally forbidden and more morally permissible.

17 s in WX2 (X = S, Se) are expected to be spin-forbidden and optically dark.

18 led that the lowest vertical transitions are forbidden and that S1 of 1 is an emissive state.

19 ed to norbornene, the energy gap between the forbidden and the allowed transition state is only 4.1 k

20 cyano-bearing carbon atom from (-)-trans-1, "forbidden" and the result of zero internal rotations fro

21 It suggests to avoid attributing graft with forbidden antigens to sensitized candidates with Luminex

22 Blood inside mammals is a forbidden area for the majority of prokaryotic microbes;

23 uench through the phase transition, which is forbidden at the mean field level.

24 -1 by reconstitution with B cells containing forbidden, autoreactive clones provides direct evidence

25 uartet state, persists for 67 ns due to spin-forbidden back-electron transfer, constituting a more th

26 oncerted pericyclic reactions are allowed or forbidden based on the number of electrons involved and

27 od practice rather than lists of generically forbidden behavior.

28 ects more likely to judge harmful actions as forbidden, but only in cases where harms were emotionall

29 ve atomic transition that would otherwise be forbidden by established spectroscopic selection rules.

30 nt species in the same tin, although this is forbidden by EU law.

31 ch the stronger single-scattering forces are forbidden by parity.

32 tion from the ground state (S(0)) to S(1) is forbidden by symmetry, making a determination of the S(1

33 adient, whereas in thermal equilibrium it is forbidden by the Bohr-van Leeuwen theorem.

34 ith H2 to yield ground-state HCl products is forbidden by the Born-Oppenheimer (BO) approximation.

35 erfect copying of unknown quantum systems is forbidden by the laws of quantum mechanics, approximate

36 Here we report measurements of the forbidden C ii emission (that is, [C II]) from gas, and

37 This diagram defines allowable and forbidden cell-fate transitions as EGF or Notch levels c

38 ic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a ma

39 al benzene derivatives are associated with a forbidden character and show marked vibrational progress

40 tant of the motion (other than energy) still forbids classically the quantum-allowed motion.

41 rance, clonal selection of lymphocytes, and "forbidden clones" of activated immune cells were forming

42 Doxycycline (DC) is forbidden compound in laying hens.

43 ucture is the transition state) and symmetry-forbidden conrotatory ring closing (whose transition sta

44 ond-assisted radiative recombination of spin-forbidden dark excitons.

45 The rest are optically (near) forbidden "dark" transitions.

46 tant precedent for extremely rapid, formally forbidden (DeltaS = 2) nonradiative relaxation as well a

47 eld view that it is nonadiabatic due to spin-forbidden (DeltaS = 2) selection rules.

48 This effect is explicable by a spin-forbidden deprotonation by OH(-) (k = 4.9 x 10(4) M(-1)

49 and is responsible for slowness of the spin-forbidden deprotonation of (1)HNO by OH(-); the spin pro

50 reaction with (3)O(2), the kinetics of spin-forbidden deprotonation reaction (1)HNO + OH(-) --> (3)N

51 t recurrent unwanted thoughts; attraction to forbidden desires; expression of objectionable social pr

52 In this regime, classically forbidden detection of completely unpolarized nuclei is

53 ry electrocyclic ring-opening, (2) thermally forbidden disrotatory electrocyclic ring-opening, or (3)

54 ergy gap between allowed conrotatory and the forbidden disrotatory pathways decreases.

55 nical advantage in accelerating the symmetry forbidden disrotatory ring opening of benzocyclobutene (

56 A true forbidden disrotatory ring-opening transition structure

57 c C-C bond cleavage, rather than a thermally forbidden disrotatory ring-opening.

58 ways, which enables us to quantify just how 'forbidden' each reaction is.

59 These predictions forbid electrically conducting states and ordered states

60 ce can play an important role in allowing or forbidding electrons from passing through a system.

61 d density of states, and in doing so creates forbidden energy bandgaps for thermal phonons.

62 Interband tunnelling of carriers through a forbidden energy gap, known as Zener tunnelling, is a ph

63 eral alignment options including allowing or forbidding enzyme deletion and insertion.

64 s is furnished through a low-lying optically forbidden excited state, populated through internal conv

65 erally unobtainable, being closely linked to forbidden faster than light group velocities.

66 al symmetry, exhibiting crystallographically forbidden five-fold symmetry elements.

67 eriodic pattern whose rotational symmetry is forbidden for periodic crystals (such as five-fold symme

68 ation, and we have also concluded that it is forbidden for the water molecule to form a hydrogen bond

69 udan I is a carcinogenic industrial azo-dye, forbidden for use in food.

70 however, the result of a formally "symmetry-forbidden" fragmentation is observed yielding cis,cis-cy

71 ndesirable energy sink because they are spin-forbidden from emitting light and their high binding ene

72 Water and electrolyte are forbidden from entering these very hydrophobic pores/nan

73 homo-nuclear spin pairs are both diluted and forbidden from forming strongly coupled, nearest-neighbo

74 nd a trend is found toward a reduced allowed/forbidden gap as the planarity of the cyclobutene is enf

75 , and by Freedman et al., placed the allowed/forbidden gap at greater than 15 kcal/mol.

76 ple sharp photoluminescence emissions in the forbidden gap, which are related to defects localized ar

77 law of extraordinary photons is modulated by forbidden gaps near the boundaries of photonic Brillouin

78 ub-Tg annealing can be combined to access a "forbidden glass" regime that is inaccessible through the

79 ption mechanisms across the petawatt regime, forbidding high absorption values at low laser power and

80 s give high optical gap materials owing to a forbidden HOMO to LUMO transition, yet have narrow elect

81 (1) Conformers are forbidden if they include a particular sequence of biary

82 ected flexibility allowing activation of the forbidden IFN-gamma gene after reactivation and growth.

83 ctric dipole-magnetic dipole transitions are forbidden in a far field.

84 Quasicrystals permit symmetry operations forbidden in classical crystallography, for example five

85 first-order electron-photon interactions are forbidden in free space.

86 accurate identification of five meat species forbidden in Islamic foods in a single assay platform.

87 nsidered as najasa (impurities) in Islam and forbidden in Muslim consumer products.

88 t product:substrate ratios thermodynamically forbidden in the absence of ATP.

89 ration in the mid-infrared-something that is forbidden in the absence of free electrons.

90 ational circular dichroism, methods that are forbidden in the electric dipole approximation.

91 oldenone and androstadienedione to cattle is forbidden in the European Union, while prednisolone is p

92 tes that are, for cyclic nanorings, symmetry-forbidden in the far field.

93 ement by purely local control is however not forbidden in the presence of non-Markovian dynamics, and

94 (chiral) rotation of a mechanical ratchet is forbidden in thermal equilibrium, but becomes possible i

95 recently proposed, but was later shown to be forbidden in thermal equilibrium.

96 pological domain boundary, allowing normally forbidden interactions between at least three forebrain-

97 Emission from a dipole forbidden intermediate state may even dominate the corre

98 uples, or sub-quintuples which exhibited the forbidden IR active mode due to symmetry lowering.

99 a conventional CCD-based Raman spectrometer forbids its applications under extreme conditions, inclu

100 olerance of diverse beliefs and behaviors by forbidding judgment on foreign societal codes of conduct

101 t this OCP occurs not as much through Donnan-forbidden leakage but via ion exchange.

102 as can be applied to minimize/prevent Donnan-forbidden leakage or ion exchange.

103 troduced into the eluent stream using Donnan forbidden leakage.

104 a mechanism for observing the formally spin-forbidden, ligand-based 3GC --> 1CTC transition.

105 This theory reveals that conventionally forbidden light-matter interactions--such as extremely h

106 ecomes more recalcitrant to switching as the forbidden lineage matures.

107 and ecological trait mismatches constraints (forbidden links hypothesis), and how these processes str

108 portance of morphological traits, beyond the forbidden links hypothesis, in structuring interactions

109 e to the pi-pi stacking interaction (forming forbidden low-energy excitonic transition).

110 he apparent quantum to classical transition--forbid macroscopic superpositions.

111 Extra "forbidden" meridional reflections, at orders of 43 nm, i

112 orption lineshapes are modified, or infrared-forbidden modes are detectable as a modulation of the el

113 The forbidding mortality of pancreaticoduodenectomy, approxi

114 f nitrogen to the metal cation causes the IR-forbidden N-N stretch of N2 to become active in these co

115 The Fe ligand field overcomes the spin-forbidden nature of the triplet O(2) reaction, which pot

116 s found to be facile despite the formal spin-forbidden nature of this process.

117 Dark excitons involve nominally spin-forbidden optical transitions with a zero in-plane trans

118 tion features, which are associated with the forbidden optical transitions, have been observed.

119 potential energy surfaces so that otherwise forbidden or slow processes proceed under mild condition

120 e confinement with materials or systems that forbid outgoing waves.

121 complex formation, which revealed a formally forbidden pathway in [2+2] cycloaddition reactions of ma

122 ry product can be formed directly through a "forbidden" pathway.

123 ong both their symmetry-allowed and symmetry-forbidden pathways, which enables us to quantify just ho

124 Fourth Lateran Council, a papal edict which forbade physicians (most of whom where clergy) from perf

125 S(3P):S(1D) = 1.44:1), mostly through a spin-forbidden process.

126 The first mechanistic study of a spin-forbidden proton-transfer reaction in aqueous solution i

127 gh it requires the formation of two normally forbidden purine-purine base pairs.

128 i-parallel spin configuration with generally forbidden radiative emission.

129 tate will be much more efficient than the BO-forbidden reaction of the excited spin-orbit state.

130 r-wave interference of reaction products and forbidden reaction pathways.

131 Our study indicates that spin-forbidden reactions are the probable pathways in the rea

132 thermore, our results indicate that the spin-forbidden reactions of (3)O2 with closed-shell clusters

133 by lowering the barrier to the formally spin-forbidden reactions of triplet dioxygen with the closed

134 ligand addition) is proposed for these spin forbidden reactions that gives good agreement with the n

135 rimental benchmarks for mechanically induced forbidden reactions, and in some cases suggest revisions

136 Forbidden reactions, such as those that violate orbital

137 -molecule pathway analysis of 'allowed' and 'forbidden' reactions reveals that sulfur-sulfur substitu

138 around the C3 aroyl group and the sterically forbidden region around the indole ring.

139 e and forces the nucleophilic residue into a forbidden region of Ramachandran space.

140 s two nuclei will be found in this classical forbidden region.

141 Yet, this "forbidden" region is well populated in folded proteins,

142 nstraints, and hence the sets of allowed and forbidden residue substitutions are similar.

143 bulge of the epsilon signal and generates a "forbidden" residue at the -3 position of the signal pept

144 n transfer over a range of 0.35 A, the state forbidden ring planarization does not occur.

145 the ~0.1 s timescale of the experiments, the forbidden ring-opening reactions of benzocyclobutene, ge

146 evirapine complex revealed how NNRTI binding forbids RT from forming a polymerase competent complex.

147 product is only marginally favored over the forbidden sr product; that is, si/sr is 2.4.

148 ortex that carried signals selective for the forbidden stimulus.

149 imethylcyclohexenes through orbital symmetry-forbidden suprafacial,retention and antarafacial,inversi

150 ranges in which the propagation of light is forbidden-that make them well-suited to the scientific a

151 g site close to the symmetry axes sterically forbids the binding of more than one Fab molecule per sp

152 +).(+)AdoMet has a methyl in position, which forbids the formation of the water channel.

153 The orbital symmetry forbidden thermal electrocyclic equilibria between a ser

154 ting, ordering, and counting compulsions; 2) forbidden thoughts: aggression, sexual, religious, and s

155 The forbidden tilt pattern we observe arises through couplin

156 e measurements and because such fermions are forbidden to exist in conventional materials harbouring

157 rmations of GlyB20 and GlyB23 are ordinarily forbidden to L-amino acids, turn architecture may contri

158 asiperiodic atomic structures and symmetries forbidden to ordinary periodic crystals-e.g., 5-fold sym

159 ine-2,4-dioxygenase (HOD) catalyzes the spin-forbidden transfer of dioxygen to its N-heteroaromatic s

160 al process which provides an example of spin-forbidden transformation with a characteristic spin sele

161 to one chromium atom, which involves a spin-forbidden transformation.

162 rocess is employed to overcome a first order forbidden transition and the first, second and third Foc

163 sponding to a two-photon allowed, one-photon forbidden transition) for rhodol bearing 1-aza-15-crown-

164 ted by the observation of the DeltaMs = +/-2 forbidden transition, electron spin resonance (ESR) simu

165 ) is proposed to be 3.6-3.7 eV with a direct-forbidden transition.

166 ly addressable transitions, with one being a forbidden transition.

167 We also show that forbidden transitions between discrete quantum levels in

168 void the higher barriers imposed by the spin-forbidden transitions required for unassisted O(2) disso

169 in species due to the challenge of accessing forbidden transitions.

170 ple points, ten allowed transitions and two 'forbidden' transitions, as well as complex hysteresis lo

171 m, with Fe3+ acting as a buffer for the spin-forbidden two-electron redox process between PCA and O(2

172 ase the reduction of EC is thermodynamically forbidden, whereas in bulk solvent it is likely to under

173 cal forms of beta-1a and beta-1b is symmetry forbidden, while the photochemical transformation is sym

174 f anabolic substances in animal husbandry is forbidden within the EU and well controlled by detecting

175 ns) for two transitions, one allowed and one forbidden, within the S = (3)/2 spin manifold.