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1 (electrooxidation of methanol, ethanol, and formic acid).
2 d electrolyte system consisted of 100 mmol/L formic acid.
3 he Pd(0)-mediated formation of hydrogen from formic acid.
4 rotective groups were cleaved with refluxing formic acid.
5 ate and the direct overlay of organisms with formic acid.
6 t or by renewable reductants such as formate/formic acid.
7 mary secondary amine and acidified with 0.1% formic acid.
8 s such as 5-hydroxy-methylfurfural (HMF) and formic acid.
9 der mild conditions using CO(2), formate and formic acid.
10 t uses CO(2) and hydrogen to store energy in formic acid.
11 in CO stripping and the electro-oxidation of formic acid.
12 proximately equal production of methanol and formic acid.
13 of acetonitrile/water (80:20) (v/v), with 1% formic acid.
14 1-naphthylnitrenium cation is 860 ps in 88% formic acid.
15 ion was found for 50% H2O/33% 2-propanol/17% formic acid.
16 photolysis of the appropriate azides in 88% formic acid.
17 oning all plants except its host plants with formic acid.
18 may undergo rapid aromatization, as well as formic acid.
19 ontal cortex of AD brains homogenized in 70% formic acid.
20 eloped that is based on chemical cleavage by formic acid.
21 h nitrogen atom and the hydroxyl hydrogen in formic acid.
22 that enables hydrogen gas release from neat formic acid.
23 ethane, bromochloromethane, formaldehyde and formic acid.
24 in the third step, yielding an estrogen and formic acid.
27 xtraction conditions reveals that the use of formic acid (1%), in place of the more commonly used per
30 Low-temperature 1H and 13C NMR spectra of formic acid (1) showed separate signals for the E and Z
32 d utilized for 13-carbon isotope analysis of formic acid-(13)C and acetic acid-(13)C, each highly enr
33 and Ea = 31 kJ/mol) and one-pot reactions of formic acid, 2-nitrophenol, and aldehydes into benzoxazo
34 pH 2.25; 500 mM acetic acid, pH 2.54; 200 mM formic acid, 200 mM acetic acid, pH 2.05; and 200 mM imi
37 phase of acetonitrile-water containing 0.1% formic acid (50:50, v/v) and an optimal mobile phase flo
39 ved on a C(18) column with acetonitrile/5 mM formic acid (60:40, v/v) as the mobile phase followed by
41 toxic metabolite in methanol intoxication is formic acid, a mitochondrial toxin known to inhibit the
43 od was applied to measure the enrichments of formic acid, acetic acid, and propionic acid in the perf
44 t for the low isotopomer enrichment assay of formic acid, acetic acid, propionic aicd, butyric acid,
46 ictet-Spengler cyclization of 13 in formalin/formic acid afforded the dibenzo[a,g]quinolizine 14 in 6
47 equent removal of the tert-butyl esters with formic acid affords a triacid that is coupled to three m
48 Moreover, although not explicitly sought, formic acid/ammonium formate is produced as an important
49 gregates are not dissociated by concentrated formic acid, an extremely effective solvent for otherwis
52 age systems based on liquids, in particular, formic acid and alcohols, are highly attractive hydrogen
54 low temperatures by 1H and 13C NMR for both formic acid and an adduct with hexafluoroacetone, HCO2C(
55 ates of decay of the singlet nitrenes in 88% formic acid and are as follows: p-biphenylyl (taugrowth
56 e ethylenediaminetetraacetic acid (EDTA) and formic acid and are efficient in extracting dyes, but pr
58 gradient elution with acetonitrile and 0.2% formic acid and detected on an electrospray ionization m
59 es was accomplished with mixtures of aqueous formic acid and dimethylsulfoxide with increasing concen
61 t Py catalyzes the homogeneous reductions of formic acid and formaldehyde en route to formation of CH
63 nd its two succeeding intermediates, namely, formic acid and formaldehyde, to ultimately form CH3OH.
64 redicted to undergo fragmentation to produce formic acid and formaldehyde, with regeneration of (*)OH
67 electric field is switched on and identifies formic acid and formamide as key intermediate products o
69 tandem process involving dehydrogenation of formic acid and hydrogenation of C-C multiple bonds usin
71 actions, namely, the hydrogenation of CO2 to formic acid and methanol and the reverse dehydrogenation
73 talytic activity and very high stability for formic acid and methanol oxidation and the oxygen reduct
74 lower onset potentials for the oxidation of formic acid and methanol than either pure Pt or Pt-Ru na
75 higher oxidation current densities for both formic acid and methanol than pure Pt, Pt-Ru, or atomica
76 solar energy to convert CO2 to fuels (e.g., formic acid and methanol) apparently could simultaneousl
79 yde dehydrogenase to convert formaldehyde to formic acid and monitors the creation of an NADH analog
80 foliation syndrome (XFS) were homogenized in formic acid and subjected to cyanogen bromide (CNBr) cle
81 furic anhydride (FSA), that is produced from formic acid and sulfur trioxide under supersonic jet con
83 itionally, acidities were calculated for the formic acid and vinyl alcohol vinylogues in which the fo
84 (70%) provided lower conductivity than 0.25% formic acid and was evaluated as low ionic-strength and
85 to both internal and terminal alkynes using formic acid and Zn as the terminal reductants has been d
86 f a mobile phase comprising water (with 0.5% formic acid) and acetonitrile (90:10, v/v) on Phenomenex
87 h a gradient system of ultrapure water (0.1% formic acid) and acetonitrile, a temperature of 35 degre
88 homogenised sample with 20 ml methanol (+1% formic acid) and measurement by LC-MS/MS multiple reacti
89 ed to rapidly convert 100% of gaseous CO2 to formic acid, and >500 mM formate was observed to accumul
91 a mixture of a functionalized PDMS oligomer, formic acid, and an IL (or lithium-in-IL solution), a re
93 tion methods, including the direct, on-plate formic acid, and ethanol/formic acid tube extraction met
94 ented using incubation with Pronase E and/or formic acid, and in each case a complete set of fluoresc
95 methods typically involved the use of HPLC, formic acid, and large amounts of expensive radiolabeled
96 cpcT mutant and wild type were cleaved with formic acid, and the products were analyzed by SDS-PAGE.
97 nanoparticle structure, slow dehydration of formic acid, and weak binding of CO on Au147@Pt surface.
98 concentration is also monitored by employing formic acid as a chemical probe, which is shown to adsor
102 the presence of [Rh2(OAc)4] as catalyst and formic acid as reducing agent, leading to the high yield
103 transfer hydrogenation conditions employing formic acid as terminal reductant, 2-butyne couples to a
104 e analytes were collected in 21 muL of 10 mM formic acid as the acceptor phase, and the extracts were
108 quantify the stoichiometric accumulation of formic acid as the product of the reaction and demonstra
112 ing, we infer a substantial emission flux of formic acid at the canopy level ( approximately 1 nmol m
115 protein detection from complex mixtures: (1) formic acid-based formulations, (2) perfluorooctanoic ac
116 d 94 (M + H)+ ions, 119 were observed from a formic acid-based matrix with no more than 10 common to
117 a user-supplemented database and an on-plate formic acid-based preparation method and compared result
119 ate in the presence of sodium metal to yield formic acid, [bis(N,N-diisopropylamino)phosphino]-beta-(
123 can be completely dissolved in concentrated formic acid, but a soluble protein oligomer containing t
124 for A beta40 and A beta42 extractable in 70% formic acid, by assessment of amyloid plaque formation u
125 Photochemical reduction of CO(2) (to produce formic acid) can be seen both as a method to produce a t
126 equired during the hydrogenation of CO(2) to formic acid catalyzed by ruthenium trimethylphosphine co
128 1,4-dimethoxy-2,5-bis(2-pyridyl)benzene bis(formic acid) complex 10, and 1,4-dimethoxy-2,5-bis(2-pyr
129 the reaction could not be fully stopped with formic acid concentrations up to 0.75 mM (the maximum ty
131 osphates, however, mixtures of acidic (0.1 M formic acid-containing) acetonitrile/water (80:20) or ac
133 lysts, as demonstrated here for the cases of formic acid decomposition and formic acid electro-oxidat
135 three-step extractions (TBS, detergent, and formic acid) demonstrated that the lower level of total
136 ernal standards ((13)C-labeled), addition of formic acid (denaturation agent), and dilution with wate
137 egate of expanded polyQ that is insoluble in formic acid, does not enter polyacrylamide gels, but is
140 smenyl (vinyl-ether) containing lipids using formic acid enabled these species to be readily differen
141 the addition of a modifier (acetic acid and formic acid) enhanced the degree of preferential ionizat
142 onic strength mobile phases at low pH (e.g., formic acid), even with highly inert silica RP-HPLC colu
144 grees C are in the order pre-LGA < pre-HMF < formic acid, explaining why LGA is the kinetically favor
146 e evaluated BACE activity, BACE protein, and formic acid-extractable A beta levels in cohorts of youn
148 a with treatment up to 5 weeks in WT mice or formic acid-extractable brain Abeta with 3 month treatme
149 -treated mice in cortical levels of soluble, formic acid extracted, or histologically detectable beta
150 beta plaque load and biochemical analysis of formic acid-extracted Abetax-40 and Abetax-42 levels and
151 relative efficiencies of the HCl, EDTA, and formic acid extraction methods are compared by analyzing
152 ion of nucleobases and nucleobase analogs in formic acid extracts of 12 different meteorites by liqui
154 found that the widely used conditions, 0.1% formic acid (FA) and NH(4)Ac at different pH, are far fr
155 This report describes a short, on-plate formic acid (FA) extraction method for the identificatio
162 ne phase in low-pH, volatile buffers such as formic acid, favored for mass spectrometric analysis.
163 The SECM tip, which generated a constant formic acid flux, was scanned above the array and the ox
164 ylurea and p-toluenesulfinic acid in aqueous formic acid followed by reaction of the obtained N-[(2-a
170 and that an acid that reduces Pd(+2) salts, formic acid, functions better than other carboxylic acid
171 numerous substrates, including citric acid, formic acid, glucose 6-phosphate, capric acid, gamma-hyd
172 bably promoting the release of formaldehyde, formic acid, glycolaldehyde, glyoxal, acetic acid, glyco
175 CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and acetic acid (CH3 COOH), employin
180 tic cycles, involving the decarboxylation of formic acid, hydration of the alkyne, and hydrogenation
183 gainst the toxic actions of methanol-derived formic acid in a rodent model of methanol toxicity.
184 Briefly, the samples were extracted with 1% formic acid in acetonitrile and directly analysed with H
186 hat are very selective for the production of formic acid in dimethylformamide (DMF)/water mixtures (F
187 ence cluster Fe(3)O(MeCOO)(6)(H(2)O)(3) with formic acid in dimethylformamide exposed to air at 110 d
190 T in chloroform/methanol (2:1, v/v), with 1% formic acid in the final mixture, 57 lipid entities were
191 aqueous and organic mobile phases were 0.1% formic acid in water and acetonitrile, respectively.
194 mobile phase consisting of solvents A (0.1% formic acid in water), and B (0.1% formic acid in methan
195 surements of OVOCs, including high levels of formic acid, in the atmosphere (measured by an online hi
197 oom-temperature photocatalytic conversion of formic acid into either hydrogen or carbon monoxide.
202 he solubility of the polymerized material in formic acid is controlled by the degree of graft copolym
207 novel catalytic cycle for the reaction with formic acid is proposed and subjected to a variety of ex
208 n carolinus, although topically sensitive to formic acid, is able to prey on formic acid-spraying ant
209 on of CO2 into energy-dense liquids, such as formic acid, is desirable as a hydrogen carrier and a ch
211 tiful atmospheric abundance of FA, makes the formic acid mediated hydrolysis reaction a potentially i
212 duction reaction, and oxidation reactions of formic acid, methanol and carbon monoxide) of noble meta
213 r the direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are thoroughly
215 gen-dependent reduction of carbon dioxide to formic acid offers a promising route to greenhouse gas s
217 The integral heat of molecular adsorption of formic acid on clean Pt(111) at 100 K is 62.5 kJ/mol at
218 d by studying the dissociative adsorption of formic acid on oxygen-presaturated (O-sat) Pt(111) to ma
219 tational results, the oxidation mechanism of formic acid on Pt(111) electrodes modified by the incorp
220 at the chemical shift value of an adsorbate (formic acid) on metal colloid catalysts measured by (13)
221 tein precipitation, only dilution with 0.1 M formic acid, one aliquot of 100 microL of serum was inje
222 ergent-insoluble fraction extracted with 70% formic acid or 6 M guanidine hydrochloride decreased mar
224 ects responsible for the enhanced acidity of formic acid over methanol, accounting for between roughl
225 "score." We found that a heavy smear with a formic acid overlay (H+FA) produced optimal MALDI-TOF MS
229 dation, benzoquinone (BQ) reduction, and the formic acid oxidation reaction (FAOR) at a Pt microelect
231 atio) as a better electrocatalyst toward the formic acid oxidation than pure Pd or Pt in 0.1 M KHCO(3
232 bes and spheres (including oxygen reduction, formic acid oxidation, and methanol oxidation) were test
233 exhibited enhanced catalytic activity toward formic acid oxidation, with a current density 2.5 and 7.
237 5 mM naphthalene trisulfonate (NTS) in 0.4 M formic acid, pH 2.0 is developed for detection of UV tra
238 ion of metabolic acidosis, the inhibition of formic acid production, the achievment of therapeutic pl
239 technology or as a cell factory dedicated to formic acid production, which is a commodity in itself a
240 equential in nature (in which the formate to formic acid protonation can be assisted by a negatively
241 Thus, extraction of textiles with EDTA or formic acid reagents can yield significantly more inform
242 ed complexes among the most promising CO2-to-formic acid reducing catalysts developed to date; addres
245 sin and eluted with acidified methanol (0.1% formic acid), resulting in analyte recoveries generally
247 umns and adding TFA as an acid modifier to a formic acid/reversed phase gradient, providing additiona
248 hich, when deleted in combination, predicted formic acid secretion in Saccharomyces cerevisiae under
249 mate dehydrogenase mutant (fdh1 fdh2), while formic acid secretion in wild-type yeast was undetectabl
250 tant strain showed the predicted increase in formic acid secretion relative to a formate dehydrogenas
252 igand-capped cadmium sulfide nanocrystals in formic acid/sodium formate release up to 116+/-14 mmol H
253 changes in sodium dodecyl sulfate-soluble or formic acid-soluble Abeta pools or Abeta oligomers in Tg
254 ort that the levels of detergent-soluble and formic acid-soluble levels of Abeta and deposition are e
257 he conductivities of aqueous acetic acid and formic acid solutions were measured from 0.1% to 100% co
260 The resistance of oligomer and polymer to formic acid suggests the participation of covalent bonds
261 a lack of (18)O incorporation in the product formic acid, supporting only the Compound I pathway.
263 based on extraction with acetonitrile/water/formic acid, ten-fold dilution and analysis by LC-MS/MS
264 isoning tolerance in the electrooxidation of formic acid than Pt cubes; the oxidation of CO on Pt nan
265 eport a new (13)C-tagging method using (13)C-formic acid that delivers high sensitivity, good quantit
266 ized lignin under mild conditions in aqueous formic acid that results in more than 60wt% yield of low
267 process may produce a few Tg/year of gaseous formic acid, the amount comparable to its primary source
268 otonated, this species preferentially expels formic acid through an O-O cleavage transition state.
269 zyme from Escherichia coli normally oxidizes formic acid to carbon dioxide and couples that reaction
272 egral heat of the dissociative adsorption of formic acid to make monodentate formate (HCOOmon,ad) plu
273 istic studies point to the unique ability of formic acid to mediate the cyclization forming the clusi
274 as eluted with 30% acetonitrile plus 100 muM formic acid to provide sufficient hydrogen ions to ioniz
276 catalytically active for dehydrogenation of formic acid (TOF = 1718 h(-1) and Ea = 31 kJ/mol) and on
277 was performed under mild conditions with the formic acid/triethylamine (5:2) system as the hydrogen s
278 substituted substrates, the more established formic acid/triethylamine system gives superior results.
279 he direct, on-plate formic acid, and ethanol/formic acid tube extraction methods, were evaluated for
280 nes 25-26 were synthesized in one step using formic acid, urea, guanidine carbonate, and phenylisocya
281 er mobile phase (80:20, v/v) containing 0.1% formic acid using isocratic flow at 0.15 mL/min for 13 m
282 We report electrocatalytic oxidation of formic acid using monometallic and bimetallic dendrimer-
283 cetate and hexane in the presence/absence of formic acid, using different extraction times and temper
285 ray and the oxidation current generated when formic acid was collected by active electrocatalytic spo
288 of iron(III) rhodotoluate was improved when formic acid was replaced by the ion-pairing reagent hept
291 membrane inlet system, and formaldehyde and formic acid were detected by ESI-MS after a derivatizati
292 ation of methanol generates formaldehyde and formic acid which then condense with methanol to form di
293 analysis of the oxygen atoms of the product (formic acid), which exchange with the solvent (water) un
294 rate salt) (11) establishes that reaction of formic acid with 9 does not form an ionic pyridinium sal
295 ne of the few catalysts that reduce CO2 into formic acid with high selectivity but at high overpotent
296 ctions of acetic acid, acetic-d3 acid-d, and formic acid with the Ge(100)-2 x 1 surface have been inv
298 f photoreceptors to the cytotoxic actions of formic acid, with a partial recovery of rod-dominated re
299 roved practical to degas and electrolyze 95% formic acid (without added electrolyte) due to adequate
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