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1 sic conditions; statistical versus selective formylation).
2 ed by catalytic hydrogenation and subsequent formylation.
3 was converted into (+)-geissoschizine (1) by formylation.
4 d attached to the tRNA is also important for formylation.
5 h lysine was an extremely poor substrate for formylation.
6 which contains the critical determinants for formylation.
7 tive effect of the acceptor stem mutation on formylation.
8 ukaryotic protein synthesis does not involve formylation and deformylation at the N-terminus, there h
9 Protein synthesis in bacteria involves the formylation and deformylation of the N-terminal methioni
10 tion in the presence of a ketone followed by formylation and finally acid-catalyzed methanolysis comp
11 aryl moiety via combination of the Bouveault formylation and hydride reduction has been optimized usi
12 The principal modifications included lysine formylation and methionine sulfoxidation both of which o
13 ed with methionine, was a good substrate for formylation and was, consequently, quite active in initi
17 n the insertion loop (which are defective in formylation) are not protected by the initiator Met-tRNA
18 ionalization reactions such as halogenation, formylation, carboxylation, nitration, sulfonation, and
19 ted with lysine is a very poor substrate for formylation compared with the same tRNA aminoacylated wi
20 ong a reaction sequence involving a tandem N-formylation/decarboxylation that may have a mechanistic
21 cherichia coli MTF, which compensate for the formylation defect of a mutant initiator tRNA, lacking a
22 or mutations in MTF which compensate for the formylation defect of the mutant tRNA aminoacylated with
23 ects MTF against trypsin cleavage, whereas a formylation-defective mutant initiator Met-tRNA, which b
24 mnant without any functional role in protein formylation/deformylation and validates PDF as an excell
26 m easily accessible enamino keto esters by a formylation followed by in situ intramolecular cyclizati
27 thanes have been investigated: (1) Vilsmeier formylation followed by selective removal of the unwante
28 ng O-mycoloylation, pyroglutamylation, and N-formylation, for mycomembrane-associated and -secreted O
29 specific recognition of the determinants for formylation in the acceptor stem of the initiator tRNA.
31 fMet), and tRNA(fMet) shows that there is no formylation in vivo of the mitochondrial initiator Met-t
32 he initiator tRNA is not known, but in vitro formylation increases binding of Met-tRNA(f)(Met) to tra
36 hat catalyzes the ATP- and formate-dependent formylation of 5-aminoimidazole-4-carboxamide-1-beta-D-r
37 inolone-3-sulfonamide intermediates features formylation of a beta-ketosulfonamide employing dimethyl
40 groups have generally employed the Vilsmeier formylation of an acid-resistant copper or nickel porphy
44 n of the inversion as being rate-determining formylation of cis-enolate 27 from a mixture of rapidly
46 urT transformylase, catalyzes an alternative formylation of glycinamide ribonucleotide (GAR) in the d
47 ons in purine biosynthesis by catalyzing the formylation of glycinamide ribonucleotide through a cata
48 rp, conversion of Ser to dehydroalanine, and formylation of His) were observed in alphaA-crystallin f
57 modification of chromatin proteins, the N(6)-formylation of lysine that appears to be uniquely associ
58 n contrast, isopropyl group inversion during formylation of menthone with NaOMe and HCO(2)Et led, by
59 is used directly in purine biosynthesis and formylation of Met-tRNA and indirectly in the biosynthes
60 MTF, but not of an inactive mutant, leads to formylation of methionine attached to the yeast cytoplas
62 rmylmethionyl-tRNA, which indicates that the formylation of mitochondrial Met-tRNA specifies its part
63 erocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen
64 es the N-10-formyltetrahydrofolate-dependent formylation of the 4''-amine of UDP-L-Ara4N, generating
65 nique properties of E. coli initiator tRNA - formylation of the amino acid attached to the tRNA and b
66 noacylation of the tRNA, (iii) the extent of formylation of the aminoacyl-tRNA to formylaminoacyl-tRN
67 esis in yeast mitochondria can occur without formylation of the initiator methionyl-tRNA (Met-tRNA(fM
70 ionyl-tRNA transformylase results in partial formylation of the mutant tRNA and activity of the formy
71 us, the G4: C69 base pair contributes toward formylation of the tRNA and protein synthesis in E. coli
76 istinct from widely used palladium-catalyzed formylation processes, this reaction proceeds by a two-s
78 that the 1,2-boronate rearrangement for the formylation reaction could be temperature-controlled, th
82 s of carefully orchestrated steps: addition, formylation, tautomerization, and dehydration, with CuCN
83 meno[3,4-c]pyridines was achieved via a Duff formylation that is attended by an unusual cyclization r
85 amined, the slowest rate of serine/threonine formylation was found for 50% H2O/33% 2-propanol/17% for
87 st stereospecific boronate rearrangement and formylation were utilized for the practical asymmetric s
88 boronate rearrangement followed by a robust formylation with an in situ generated DCM anion has been
89 lithium, followed by carbonation with CO2 or formylation with N-formylpiperidine and subsequent depro
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