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1 e for the reverse reaction than that for the forward reaction.
2 se reaction, despite poor utilization in the forward reaction.
3 formed at pH 8, which is the optimum for the forward reaction.
4 ion cannot increase further, neither can the forward reaction.
5 has only a minimal effect on the rate of the forward reaction.
6 ation of the collision complex limiting each forward reaction.
7 licated AMP release as rate-limiting for the forward reaction.
8 her verified a random Bi Bi mechanism in the forward reaction.
9 ate constant 3300 times smaller than for the forward reaction.
10 dicating that it does not have a role in the forward reaction.
11 hiol and disulfide groups, thus favoring the forward reaction.
12 s preferentially folded at the moment of the forward reaction.
13 f 1.2 on V and 1.7 on V/K(homoserine) on the forward reaction.
14 G smaller for the back reaction than for the forward reaction.
15 s smaller for the back reaction than for the forward reaction.
16 O-galactosides, almost as efficiently as the forward reaction.
17 BuSH, in agreement with the results from the forward reactions.
18 ps during Na(+)-Na(+) exchange while slowing forward reactions.
19 en the stereoselectivity of the back and the forward reactions.
20 e rate constant of the chemical step for the forward reaction (250 s(-)(1)) is approximately 8 times
21 the reverse of the physiologically important forward reaction; (3) acetoacetate decarboxylation to fo
23 mately 0.6 kcal/mol of stabilization for the forward reaction and approximately 2.2 kcal/mol of desta
25 er network can have on the energetics of the forward reaction and how metals or enzyme side chains ma
26 harnesses negative supercoiling to drive the forward reaction and promote recombination between prope
28 t for K165Q was decreased only 2-fold in the forward reaction and was slightly increased in the rever
29 -0.23 +/- 0.03 cm(3) mol(-1) MPa(-1) for the forward reaction, and k(r,0) = 20.7 +/- 0.8 s(-1), Delta
30 H(2)O + HF (81%) is identical to that of the forward reaction, and represents a novel neutral-catalyz
31 rect nucleotide commits the substrate to the forward reaction, and the slow reversal of the conformat
32 ts of a steady-state kinetic analysis of the forward reaction are diagnostic for a ternary complex me
35 rted to substrate (ATP) concentration in the forward reaction assay by using an ex-situ calibration c
36 uccinyl-CoA, the N150F variant catalyzes the forward reaction at a mere 1.2-fold faster rate than tha
38 temperature-dependent kinetic studies on the forward reaction between dioxygen and [Cu(I)(tmpa)(thf)]
39 e rate constant for the chemical step of the forward reaction by a factor of 15 and the rate constant
40 oribosylamine examined as substrates for the forward reaction consist of chiral derivatives of cyclop
41 to be significantly higher than that for the forward reaction, consistent with kinetic activity measu
43 s, in which a single chemical reaction (the "forward" reaction) converts a conformationally unstable
44 in binding pocket, the reaction rates of the forward reaction differ quite largely from a few ps up t
51 turnover numbers (kcat) were 394 s-1 for the forward reaction (formation of ADP and GDP) and 90 s-1 f
53 sequential ordered kinetic mechanism for the forward reaction in which ATP binds to free enzyme, foll
59 (by malonate), whereas ROS production in the forward reaction is prevented by malonate but not by atp
60 lization of guanine than hypoxanthine in the forward reaction is the result of the faster release of
62 XPRTase with respect to both guanine (in the forward reaction; Ki = 13 microM) and GMP (in the revers
63 ch is equivalent to reducing the rate of the forward reaction leading to film growth, the other analo
64 several activities include: polyP synthesis (forward reaction), nATP --> polyP(n) + nADP (Equation 1)
65 rast, in the quasi-stochastic mechanism, the forward reaction occurs quasi-stochastically in an unfol
66 tivity of NDPK, F(1)F(0) ATP synthase or the forward reaction of adenylate kinase could not fully acc
69 n of autophagy is controlled not only by the forward reaction of generating PI3P through a lipid kina
73 0 and Hsp70, suggesting that CHIP blocks the forward reaction of the Hsc70-Hsp70 substrate-binding cy
74 icate CHIP in the negative regulation of the forward reaction of the Hsc70-Hsp70 substrate-binding cy
75 k(obs,m) and k(obs,f) represent the native, forward reaction of the substrate through the radical re
83 hus, D185 appears to participate only in the forward reaction, probably required for the generation o
84 AK exhibits a 23- +/- 3-fold increase in its forward reaction rate compared with the unactivated form
87 d a significant reduction in creatine kinase forward reaction rate constant in the BD group (F = 4.69
88 cipants at 4T and quantified creatine kinase forward reaction rate constant using (31)P magnetization
91 etition between charge recombination and the forward reactions required for water splitting limits th
92 Pre-steady-state kinetic analysis of the forward reaction revealed a burst in product formation i
93 +/- 4 J mol(-1) K(-1), respectively, for the forward reaction (rhomboid to hexagon) of the equilibriu
94 ase of a correct substrate commits it to the forward reaction so that specificity is determined solel
95 ntermediate clusters in competition with the forward reactions that grow the clusters into particles.
96 all plastocyanin variants is faster than the forward reaction, the difference in free energy between
97 physiological concentrations (10 mM) in the forward reaction, they were poor inhibitors even at high
98 ing the response to it either by slowing the forward reaction through mutation or by titration of the
99 ate carboxylase have been determined for the forward reaction to form oxaloacetate, the reverse react
100 elatively higher catalytic efficiency in the forward reaction to the unusual loop structure for poor
105 45 is positioned to serve as the base in the forward reaction whereas the carboxylate side chain of G
106 143 microm with a k(cat) of 2.8 s(-1) in the forward reaction, whereas AMP and PP(i) have K(m) values
107 he relative catalytic efficiencies favor the forward reaction, which can be attributed to an unusuall
108 lBCAT3 and -4 exhibited a preference for the forward reaction, while SlBCAT1 and -2 were more active
109 This change leads to increased kcats for the forward reactions with guanine and xanthine as substrate
110 Complex II generates these ROS in both the forward reaction, with electrons supplied by succinate,
111 ion by univalent cations was observed in the forward reaction, with NH+4, Rb+ and K+ exerting the gre
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