ライフサイエンスコーパス: general acid catalyst

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1 from this intermediate presumably requires a general acid catalyst.

2 late-modified DNAs to implicate Lys-167 as a general acid catalyst.

3 idate in the vicinity that can function as a general acid catalyst.

4 K, Q, and R to probe its possible role as a general acid catalyst.

5 roposed role of this active-site serine as a general acid catalyst.

6 eracting with the 2'OH of G8, the implicated general acid catalyst.

7 o stabilize the transition state or act as a general acid catalyst after the rate-determining step.

8 te, either Asp-92 or Asp-72 functions as the general acid catalyst, and that this enzyme undergoes a

9 ics, Asp-262 was identified as the authentic general acid catalyst, donating a proton to the leaving

10 he hydroxyl group of Tyr108 might serve as a general acid catalyst during substrate turnover.

11 Asp38 serves as a general acid catalyst during the 'reverse kinase' reacti

12 of the covalent intermediate by acting as a general acid catalyst for loss of the C4 hydroxyl group.

13 base with a pK(a) of 6.0 and Tyr-74 may be a general acid catalyst for the elimination step, as we fo

14 ratase mechanism in which H61 and H79 act as general acid catalysts for the stereospecific eliminatio

15 otonation of the anion in the absence of the general acid catalyst, Glu370(H(+)).

16 e in solution and strongly supports A38 as a general acid catalyst in bond scission.

17 t difference is the absence of a carboxylate general acid catalyst in RNA triphosphatase.

18 ndicate that Tyr-95 does not function as the general acid catalyst in the reaction catalyzed by wild-

19 pproximately 10 kcal/mol when phenol, as the general-acid catalyst, is included in the gas-phase calc

20 catalysis by a proton juxtaposed at S6 via a general acid catalyst located on the E1 enzyme.

21 t a mechanism where the 2'OH of G8 acts as a general acid catalyst that is held in position through W

22 ns suggest that Tyr(381) and/or Tyr(465) are general acid catalysts that facilitate epoxide ring open

23 Glu 28 may serve directly or via water as a general acid catalyst to aid in 5-iminium cation formati

24 of His241, which has been considered as the general acid catalyst to assist departure of the leaving

25 266 to aid in the precise positioning of the general acid catalyst to the N3 of the imidazole of AICA

26 whereas the proton transfer from Asp164 (the general acid catalyst) to the inhibitor is not.

27 partic acid (Asp(60)) invoked as a candidate general acid catalyst was dispensable for phosphohydrola

28 ral base catalyst and His-144 serving as the general acid catalyst, whereas the side chain of Tyr-142

29 ortant in catalysis, most likely acting as a general acid catalyst with a pK(a) value greater than 10

30 is108 acts in a salt bridge with Asp144 as a general acid catalyst with a pK(a) value of 9.7.

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