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1 configuration binding more tightly than the gluco.
4 ontaining mixed-valent Fe1(III)(mu-OH(-))(mu-GluCO(2)(-))(2)Fe2(II) and Fe1(II)(mu-GluCO(2)(-))(2)Fe2
6 lactose, (2) 2-acetamido-2-deoxy-3-O-(beta-D-gluco-4-enepyranosyluronic acid)-4-O-sulfo-D-galactose,
7 ose, and (3) 2-acetamido-2-deoxy-3-O-(beta-D-gluco-4-enepyranosyluronic acid)-6-O-sulfo-D-galactose,
8 harides, (1) 2-acetamido-2-deoxy-3-O-(beta-D-gluco-4-enepyranosyluronic acid)-D-galactose, (2) 2-acet
10 membrane impermeable d-glucose analogue, di(glucos-6-yl)poly(ethylene glycol) 600, was synthesized a
11 model compounds that mimic alpha-gluco, beta-gluco, alpha-allo, and beta-allo 2-acetamido-2-deoxy-D-a
13 s were established for the synthesis of beta-gluco and alpha- and beta-manno-configured phostones of
14 ituted iminosugars of both configurations (D-gluco and L-ido) with the aim to introduce structural fe
15 previous work, we synthesized a series of D-gluco and L-ido-configured iminosugars N-modified with a
16 ity of both lectins to differentiate between gluco and manno diastereomers was diminished in the C-gl
19 oducts of catalysis and in complex with both gluco- and galacto-configured inhibitors O-(2-acetamido-
20 sets of interaction were maintained with the gluco- and galacto-configured inhibitors, the inhibition
22 ercise in mammals, with hepatic and muscular gluco- and glyconeogenesis contributing to a lesser exte
24 Both GTDF and metformin protected against gluco- and lipotoxicity-induced osteoblast apoptosis, an
25 ammonium phosphonite-borane complexes in the gluco- and manno-like series have been developed from P(
26 roved strategy for the synthesis of P-chiral gluco- and manno-phosphonite-borane complexes is describ
27 O-benzyl-4,6-O-benzylidene-protected 3-deoxy-gluco- and mannopyranosyl thioglycosides is highly stere
29 inding protein which recognizes alpha-linked gluco-and manno-pyranosyl groups of polysaccharide chain
30 stereoselectivity of couplings to galacto-, gluco-, and mannopyranosyl thioglycosides, otherwise pro
32 nts in four model compounds that mimic alpha-gluco, beta-gluco, alpha-allo, and beta-allo 2-acetamido
33 llenging glycosidic linkages including alpha-gluco, beta-manno, and beta-rhamno have seen obtained wi
34 nd WP400 (2'-bromo-4'-epidaunorubicin, alpha-gluco configuration), is significantly less cytotoxic.
40 was acetylated prior to isolation while the gluco-dialdehyde afforded a mixture of three stereoisome
42 var. X100 with the pseudotetrasaccharides D-gluco-dihydroacarbose and acarbose have been refined to
43 ic contacts between the nonreducing end of D-gluco-dihydroacarbose and the catalytic water perturb Wa
44 ational distortion of the first residue of D-gluco-dihydroacarbose is consistent with the generation
47 configuration, ranging from 1.5 to 13, with gluco exhibiting the smallest ratio and gulo the largest
48 ide derivative of the 6-O-methyl-D-glycero-L-gluco-heptopyranose residue found in the Campylobacter j
49 we show that WcaGNCTC is not necessary for L-gluco-heptose synthesis and does not affect its producti
50 dation for elucidation of the more complex L-gluco-heptose synthesis pathway of Campylobacter jejuni
51 /C5 epimer generated by MlghB and produces L-gluco-heptose via stereospecific C4 reductase activity.
52 ycosyl residue, 3-acetimidoylamino-3-deoxy-d-gluco-hexuronic acid was identified and characterized, a
53 sions of these to a range of heparin-related gluco-ido disaccharide building blocks (various C-4 prot
54 at small intestine to study the secretion of gluco-insulinotropic peptide (GIP), glucagon-like peptid
56 heless, the degree of acetylation of xylan, (gluco)mannan, and xyloglucan as well as overall cell wal
57 the identification of GDP-D-erythro-alpha-D-gluco-octose (GDP-D-alpha-D-octose) as a key intermediat
59 tose, and resulted in the synthesis of novel gluco-oligosaccharides in which alpha1,3-linked glucosyl
61 fd-glucosyl units from sucroseto dextrans or gluco-oligosaccharides via the formation of alpha-(1-->2
63 increase hemolymph glucose, an indication of gluco-privation, but instead of increasing feeding it ei
64 -4-hydroxymethyl)-phenyl-6-O-caffeoyl-beta-d-gluco-pyranoside (2), protocatechuic acid (3), gallic ac
65 alpha-D-glucopyranosyl-(6d --> 1e)-O-alpha-D-gluco-pyranoside (6) along with two known compounds n-he
67 bolism in G4Tg mice and to determine whether gluco-regulatory adaptations exist in the non-insulin-st
70 tive providing the alpha-C-glycosides in the gluco-series and the beta-C-glycosides in the manno-seri
71 lylation and a triflate inversion to set the gluco-stereochemistry in addition to Luche reduction and
72 ing beta-selective glucosylation followed by gluco to manno epimerization at a late stage of the synt
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