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4 ond tethering between the glycosyl donor and glycosyl acceptor counterparts while providing a practic
5 he beneficial effects may include moving the glycosyl acceptor further out into solution and providin
7 zide analogue of 1, which may be useful as a glycosyl acceptor in the synthesis of alpha-galactosylce
8 nsfer of the anomeric sulfide group from the glycosyl acceptor to the C(2)-benzylidene donor and can
10 may diminish with the increased bulk of the glycosyl acceptor, and may be an important factor for th
11 to differentiate OH groups in an unprotected glycosyl acceptor, followed by substrate-controlled reac
12 that these derivatives are suitable for both glycosyl acceptor-bound and glycosyl donor-bound strateg
16 on between 2,6-dideoxy-sugar hemiacetals and glycosyl acceptors in good yield and high alpha-selectiv
17 ity when glycosylated with a wide variety of glycosyl acceptors including properly protected amino ac
18 ized by coupling thiophenyl 4-DP donors with glycosyl acceptors using BSP/Tf2O activation, whereas be
24 otolyl donors as well as differently crowded glycosyl acceptors; subtle differences in the stereochem
25 ution-phase synthesis of thioglycosides from glycosyl acetates and thiols in the presence of In(III)
26 of sepsis, a major cause of ALI, 3-O-beta-d-glycosyl aesculin significantly enhanced the survival of
29 w that the glycosylated aesculin, 3-O-beta-d-glycosyl aesculin, robustly activated Nrf2, inducing the
31 ydrate modification, (b) oligosaccharide and glycosyl amino acid synthesis, (c) assembly of glycoclus
34 the sequential installation of four O-linked glycosyl-amino acid cassettes into closely spaced O-glyc
35 divergent approach to C(2)-C(3) unsaturated glycosyl and alpha-D-mannopyranosyl sulfones has been de
36 set of N-substituted peptides (with methyl, glycosyl and amino acids as N-substituents), cyclic N-me
37 r of 2-deoxy-2-C-alkyl glycosides, with both glycosyl and nonglycosyl moieties at the reducing end, a
39 ying in the number and position of hydroxyl, glycosyl, and methyl groups about their aromatic core st
40 chanisms of LTA modifications with D-alanyl, glycosyl, and phosphocholine residues will be discussed
41 ed biflavonone, morelloflavone-4'''-O-beta-d-glycosyl, and the known compounds 1,3,6,7-tetrahydroxyxa
43 eptide substrate; moreover, once formed, the glycosyl aspartate reacts further to form a succinimide
46 one-pot protocol for the synthesis of novel glycosyl-beta-azido ester 3 from glycosyl olefinic ester
48 dPer adopts the anti conformation about the glycosyl bond and forms a less stable wobble pairing int
49 londG adopts the anti conformation about the glycosyl bond and that the etheno moiety is accommodated
52 n-bonding to the water molecule required for glycosyl bond hydrolysis may explain this sequence requi
53 droxyl groups in mediating both this aqueous glycosyl bond-forming reaction and the site-selectivity
57 d, the ICL is unhooked when one of the two N-glycosyl bonds forming the cross-link is cleaved by the
60 the in situ synthesis from the corresponding glycosyl bromides and activation of the OFox imidates co
61 nophosphate (Dol-P) functions as an obligate glycosyl carrier lipid in protein glycosylation reaction
62 ir enzyme that has been shown to stabilize a glycosyl cation reaction intermediate and a related tigh
63 Cl4 activation or intermediate generation of glycosyl chloride as the real donor could be excluded.
65 structure of CPS34 and, in conjunction with glycosyl composition analyses, revealed the following re
66 lar as determined by gel electrophoresis and glycosyl composition analysis using gas chromatography/m
67 polysaccharide, HF-PS, was characterized by glycosyl composition and linkage analyses, mass spectrom
69 transfer of anomeric configuration make the glycosyl cross-coupling reaction a practical tool for th
72 rm the presence of motifs with evenly spaced glycosyl decorations on the xylan backbone, together wit
79 intermolecular H-bond tethering between the glycosyl donor and glycosyl acceptor counterparts while
80 date activation revealed low affinity to the glycosyl donor but high affinity to the hydroxy group of
81 osyl-(1-->6)](7) -D-mannopyranoside, and the glycosyl donor C(50) -polyprenol-phosphate-[(14) C]-mann
83 ween acceptor and catalyst and then with the glycosyl donor enables self-organization of an ordered t
84 eospecific glycosylation with an enantiopure glycosyl donor followed by separation of the derived dia
86 , thereby providing supplies of this complex glycosyl donor for future studies of lipopolysaccharide
87 kyne reductive coupling reactions and as the glycosyl donor for subsequent intramolecular glycosylati
88 roups, which decreased the reactivity of the glycosyl donor relative to the parent benzyl ether (Bn)
89 xy-2-C-alkyl glycal derivative is a suitable glycosyl donor to prepare 2-deoxy-2-C-alkyl glycosides,
90 along a reaction path involving an activated glycosyl donor with a covalent bond between the glycosyl
91 uitable for both glycosyl acceptor-bound and glycosyl donor-bound strategies, commonly employed in re
100 pwise extensions using excess monosaccharide glycosyl donors (trichloroacetimidates and thioglycoside
102 nthesis of 3,3-difluoro-3H-indol-2-yl (OFox) glycosyl donors and activation thereof can be conducted
105 Substitution of the participating group of glycosyl donors by a halogen atom is shown to specifical
106 ng blocks that can readily be converted into glycosyl donors for glycosylations that give reliably hi
107 l (TBDMS) protected fucose thioglycosides as glycosyl donors for oligosaccharide synthesis is describ
108 With a view to the eventual synthesis of glycosyl donors for the stereocontrolled synthesis of ps
110 ohexopyranosyl-1-thioglycosides were used as glycosyl donors for the stereoselective synthesis of 2-d
111 a continuum of reactivity exists where some glycosyl donors form oxacarbenium ions in glycosylation
112 old(III) activation of unprotected propargyl glycosyl donors has been shown to be effective for the s
113 e reactivity and selectivity of 3,6-tethered glycosyl donors have been studied using acceptors with d
114 ages with complete anomeric control by using glycosyl donors having a participating (S)-(phenylthiome
115 st glycosylation reactions require activated glycosyl donors in the form of nucleotide sugars to driv
116 functionality at the C(2)-amino position of glycosyl donors is crucial for the high alpha-selectivit
117 on of the C(1)-trichloroacetimidate group on glycosyl donors is necessary for the coupling process to
118 r protecting groups affect the reactivity of glycosyl donors of the thioglycoside type with the N-iod
119 A complementary concept for superarming glycosyl donors through the use of common protecting gro
121 Eight (four anomeric pairs) 3,6-bridged-glycosyl donors were synthesized in high yields from the
122 ltransferase-catalyzed reactions, artificial glycosyl donors, and a high throughput colorimetric scre
123 7, 25, or 26, using trichloroacetimidates as glycosyl donors, led to the corresponding branched dithi
130 ild, one-pot conversion of glycals into beta-glycosyl DTCs via DMDO oxidation with subsequent ring op
131 ement mechanism with formation of a covalent glycosyl-enzyme intermediate (CGE), new experimental and
132 irst crystallographic structure of a natural glycosyl-enzyme intermediate (GEI) of Saccharomyces cere
133 (1)C(4) (chair) conformation and a covalent glycosyl-enzyme intermediate in (3)S(1) (skew-boat).
134 s no effect on the rates of formation of the glycosyl-enzyme intermediate, but it accelerates turnove
135 double displacement mechanism via a covalent glycosyl-enzyme intermediate, CGE) by using density func
136 h resolution structure of a trapped covalent glycosyl-enzyme intermediate, indicating that the 1,3-xy
137 omplex with a full cellononaose ligand and a glycosyl-enzyme intermediate, that reveal details of the
138 of a simpler mechanism involving a covalent glycosyl-enzyme intermediate, the most plausible mechani
139 -displacement mechanism involving a covalent glycosyl-enzyme intermediate, which was directly detecte
142 -dexoynojirimycin and two different covalent glycosyl-enzyme intermediates obtained with fluorinated
143 o the upregulation of CsAOG, involved in ABA glycosyl ester (ABAGE) synthesis, and to a moderate indu
144 n intramolecular rearrangement of a covalent glycosyl ester adduct of the HCF-1 polypeptide was propo
146 l enzyme system for which the formation of a glycosyl ester within the enzyme active site has been sh
149 irst time we reported the presence of five C-glycosyl flavones (lucenin-2, vicenin-2, stellarin-2, lu
150 dentified for the first time, namely, four C-glycosyl flavones (lucenin-2, vicenin-2, stellarin-2, lu
151 ituents in the polyphenolic extracts were C- glycosyl flavones, including schaftoside, isoschaftoside
153 cation and characterisation of nine C- and O-glycosyl flavonoids in Moro (Citrus sinensis (L.) Osbeck
154 er, the influence of the identified C- and O-glycosyl flavonoids on the antioxidant and acetylcholine
155 of the identified polymethoxylated, C- and O-glycosyl flavonoids on the total antioxidant activity ha
156 er, the influence of the identified C- and O-glycosyl flavonoids on the total antioxidant activity of
158 and scoparin), a 3-hydroxy-3-methylglutaryl glycosyl flavonol (3-hydroxy-3-methylglutaryl glycosyl q
159 tion reaction between sucrosyl acceptors and glycosyl fluoride donors to yield the derived trisacchar
160 (fukugetin) and morelloflavone-7''-O-beta-d-glycosyl (fukugeside) were isolated from the epicarp of
162 action between a substituted naphthyne and a glycosyl furan and a subsequent O-->C-glycoside rearrang
163 ically bound aroma precursors, determined as glycosyl glucose content by HPLC-IR, in Monastrell grape
167 hemical groups such as phosphate, acetyl and glycosyl groups from one protein to another protein.
170 nesulfonate donors are prepared in situ from glycosyl hemiacetals, and are coupled under mild, operat
171 is covered by two templates corresponding to glycosyl hydrolase 15 family members and the A subunit o
172 malian chitinase (AMCase) is a member of the glycosyl hydrolase 18 family (EC 3.2.1.14) that has been
173 ss diverse environments, generating the only glycosyl hydrolase 25 muramidases in plants and archaea.
174 e activity of alpha-l-arabinofuranosidase, a glycosyl hydrolase acting on the side chains of pectin i
175 REEZING 2 (SFR2) is classified as a family I glycosyl hydrolase but has recently been shown to have g
179 enes encoding putative cellulases, including glycosyl hydrolase family 7 (GH7) cellobiohydrolases.
180 gnated jiaoyao1 (jia1), in the second of the glycosyl hydrolase family 9 active site signature motifs
184 ns a domain showing sequence homology to the glycosyl hydrolase motif in the heparanase (HPSE) gene,
185 esponse pathway in the tunable regulation of glycosyl hydrolase production in response to changes in
187 H9A1/KORRIGAN1 is a membrane-bound, family 9 glycosyl hydrolase that is important for cellulose synth
188 es of the BT_1012 protein identifies it as a glycosyl hydrolase, expanding an already impressive cata
189 notation revealed unknown functions (37.2%), glycosyl hydrolases (26.5%) and redox enzymes (11.5%) as
192 oides thetaiotaomicron genome identified 172 glycosyl hydrolases and a large number of uncharacterize
195 cteristics to the heterologous production of glycosyl hydrolases in a high yielding bioenergy crop, h
196 ridium species organize cellulases and other glycosyl hydrolases into large complexes known as cellul
198 encodes a mannanase, representing a class of glycosyl hydrolases that has not previously been reporte
201 pically found in C-terminal domains of other glycosyl hydrolases, however these domains are typically
202 d cell wall-associated transglycosidases and glycosyl hydrolases, which are responsible for remodelin
213 ective silyl exchange technology (ReSET) and glycosyl iodide glycosylation have now been integrated t
216 overcome this obstacle, per-O-trimethylsilyl glycosyl iodides were investigated and shown to undergo
218 tis MSMEG2785 resulted in altered growth and glycosyl linkage analysis revealed the absence of AG alp
219 rmined by enzyme degradation, permethylation glycosyl linkage analysis, electron microscopy, and muta
222 e presence of a diarylborinic acid catalyst, glycosyl methanesulfonates engage in regio- and stereose
224 ntually solvent-separated ion pairs with the glycosyl moiety and the leaving group being separated by
225 cosyl donor with a covalent bond between the glycosyl moiety and the leaving group, followed by forma
226 minations highlighted that the presence of a glycosyl moiety bound to the chalcone structure dramatic
228 c Sm1 is produced as a glycoprotein, but the glycosyl moiety is missing from its dimeric form, and Ep
229 d by formation of contact ion pairs with the glycosyl moiety loosely bound to the leaving group, and
230 is of novel glycosyl-beta-azido ester 3 from glycosyl olefinic ester 1 under mild conditions has been
231 lation/disproportionation reactions in which glycosyl or dextrinyl units are transferred among linear
232 dified dATP and South-MC-dATP each adopt syn glycosyl orientations to form Hoogsteen base pairs with
233 tricyclic systems, invoking an intermediate glycosyl oxocarbenium ion reacting through a boat confor
235 nucleophilic attack of putative intermediate glycosyl oxocarbenium ions suggests that the observed se
237 ducts to the endoplasmic reticulum (ER), the glycosyl phosphatidylinositol (GPI)-anchor likely functi
243 investigated whether reverse signaling via a glycosyl-phosphatidylinositol (GPI)-linked ephrin contro
245 zed by the partial or complete deficiency of glycosyl-phosphatidylinositol (GPI)-linked membrane prot
250 -PLC) capable of hydrolyzing PI and cleaving glycosyl-PI (GPI)-linked proteins from cell surfaces.
252 lycosyl flavonol (3-hydroxy-3-methylglutaryl glycosyl quercetin) and a flavone O-glycosides (chrysoer
253 uits, enzymatically hydrolysed to remove the glycosyl residues from the phenolic ingredients was able
255 ment of expressed msp2(p44) paralogs and the glycosyl residues modifying Msp2(P44) varied considerabl
259 lecular dynamic simulations suggest that the glycosyl substitutions in xylan are not only sterically
260 ate pyrimidine metabolic flux to provide the glycosyl subunits required for protein glycosylation and
261 condition for the exclusive preparation beta-glycosyl thiol derivatives has been developed successful
263 14, where both pseudosugar conformation and glycosyl torsion angle are opposite with respect to the
264 zed in the anti orientation about the pseudo-glycosyl torsion angle, which mimics precisely the mutag
265 al is quantitatively converted into an alpha-glycosyl tosylate, which is presumably the reactive spec
267 echanistic insights into the function of the glycosyl transfer polymerase that is related to the viru
272 rom the Carbohydrate-Active Enzymes database glycosyl transferase families GT61, GT47, and GT43, prev
274 imary wall CesAs, several Csl genes, and GT8 glycosyl transferase genes, and are correlated with the
276 ely, as they do not carry out glycosidase or glycosyl transferase reactions, and they are of nonimmun
277 the order Rhizobiales, where bgsA encodes a glycosyl transferase with domain resemblance and phyloge
279 on patterns of their genes, (5) other HRGPs, glycosyl transferase, prolyl 4-hydroxylase, and peroxida
281 rmed four contigs (two cytochromes P450, one glycosyl-transferase and one glutathione-S-transferase)
282 ty acid omega-hydroxylase CYP704B1, putative glycosyl transferases At1g27600 and At1g33430, 4-coumara
283 rhamnose, suggesting that one or more of the glycosyl transferases encoded by the epaBCD operon are n
284 o-enzymatic methods, which employ a range of glycosyl transferases to modify a synthetic oligosacchar
285 s of endoplasmic reticulum and Golgi-located glycosyl transferases whose activities are difficult to
286 hesis of HS involves an array of specialized glycosyl transferases, epimerase, and sulfotransferases,
291 secretory cargo and exogenous Golgi resident glycosyl-transferases are exchanged between separated Go
292 beta-selectivity at the anomeric carbon of N-glycosyl trichloroacetamides depends on the nature of th
295 ol % of Pd(CH(3)CN)(4)(BF(4))(2) to activate glycosyl trichloroacetimidate donors at room temperature
296 ethod for stereoselective glycosylation with glycosyl trichloroacetimidate donors employing cationic
300 en nucleophiles to provide the corresponding glycosyl ureas in moderate to good yields and with no lo
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