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1 sitioning of the 3-O-sulfated beta-galactose headgroup.
2 ophobic core and the hydrophilic carboxylate headgroup.
3 h the negatively charged GD2-pentasaccharide headgroup.
4 ming oligonucleotide extensions as the lipid headgroup.
5 r to CD1d than do counterparts with the same headgroup.
6 beyond the first few carbons adjacent to the headgroup.
7 moiety anchored to the phosphatidylglycerol headgroup.
8 y focused on the special properties of their headgroup.
9 ence of phosphate or net charge on the lipid headgroup.
10 yl hydrophobic domain and a polar or charged headgroup.
11 nitroxide tag attached to the lipids' polar headgroup.
12 or with a small molecule bearing a pyridine headgroup.
13 gnificantly affect the orientation of the PC headgroup.
14 ith an emphasis on the 4'OH of the galactose headgroup.
15 and was dependent on the charge of the polar headgroup.
16 into an average orientation of the PC polar headgroup.
17 n of the terminal arginine and the detergent headgroup.
18 equirement for an acyl chain and a phosphate headgroup.
19 pin progressing to the completely deacylated headgroup.
20 ge with the negative charge on the phosphate headgroup.
21 by the functional group grafted at the lipid headgroup.
22 but not charged interactions with the lipid headgroups.
23 the JM region, and negatively charged lipid headgroups.
24 nolamine) over neutral (glycerol and serine) headgroups.
25 between charged amino acids and lipid polar headgroups.
26 bonding of the polyol species to the bilayer headgroups.
27 at is promoted by protonation of cardiolipin headgroups.
28 ding of E7 to phosphatidylethanolamine lipid headgroups.
29 ivatives that have been grafted to the lipid headgroups.
30 incorporating acidic, basic, or zwitterionic headgroups.
31 c interactions with negatively charged lipid headgroups.
32 g of Ca(2+) cations to the exposed phosphate headgroups.
33 by differential recognition of phospholipid headgroups.
34 holipids containing phosphatidylethanolamine headgroups.
35 with phosphocholine and phosphoethanolamine headgroups.
36 osyl, phosphohexose and hexose-phosphohexose headgroups.
37 rs, using natural phospholipids with various headgroups.
38 ming salt bridges to the phosphates of lipid headgroups.
39 nge of the methylation level of phospholipid headgroups.
40 and further processed by addition of various headgroups.
41 dipalmitoylphospatidyl-tempo-choline (on the headgroup), 5PC and 14PC (5-C and 14-C positions on the
42 s glycodendrimers (GDs) with d-mannose (Man) headgroups, a known routing signal for lectin-mediated t
44 eometry of DPPC and monosialoganglioside GM1 headgroups affects their close molecular packing, induci
47 bonding, and properties of the phospholipid headgroup all influence cholesterol/phospholipid interac
48 ester phosphate attached to its myo-inositol headgroup, also supported enhanced enzymatic activity of
51 with a succinimidyl ester as amine-reactive headgroup and a matrix-silane with an unreactive ethylen
52 when surfactants with a tripropargylammonium headgroup and a methacrylate-functionalized hydrophobic
53 ) of bovine mincle that encompasses both the headgroup and a portion of the attached acyl chains.
54 /PPAR modulators containing a pyrrole acidic headgroup and a urea pharmacophore were designed, synthe
55 t not only is the chemistry of the detergent headgroup and acyl-chain region central for classifying
57 s reveal how Ca(2+) binding to the PI(4,5)P2 headgroup and carbonyl regions leads to confined lipid h
58 nimization of local deviations in surfactant headgroup and counterion solvation to maintain a nearly
59 used phosphocholine spin labels on the lipid headgroup and different positions on the acyl chain to d
61 nt of the Sec17 effect varied with the lipid headgroup and fatty acyl composition of the proteoliposo
62 ions arising from the combined loss of polar headgroup and HNO2, [NO2-FA + H](+) and [NO2-FA - H](-)
63 ply that the specific chemistry of the lipid headgroup and its selective location in either monolayer
64 ated by systematically changing the aromatic headgroup and linker amino acid leading to compounds wit
66 e same structural elements of a zwitterionic headgroup and lipophilic tail, a variety of chemotypes h
70 fferent lipid species, combining 14 types of headgroups and 11 types of tails asymmetrically distribu
72 ds between the 5-HT hydroxyl group and lipid headgroups and allows 5-HT to intercept reactive oxygen
73 d, local partition coefficients at the lipid headgroups and at the lipid tails are modulated opposite
74 line and sphingomyeline which have identical headgroups and cannot be easily distinguished from anoth
75 ntact polar lipids with phosphatidylglycerol headgroups and glycerol dibiphytanyl glycerol tetraether
77 etacyt is peripherally associated with lipid headgroups and one in which it penetrates deeply into th
78 ion-pairing interactions between the sulfate headgroups and oxidized ferrocenium species, forming an
79 of cation-pi interactions between PC choline headgroups and protein tyrosines vary as a function of P
81 of spacer length (between mannose-mimicking headgroups and quaternary nitrogen centers) in modulatin
83 the vicinity of the negatively charged lipid headgroups and the very first carbon atoms of the acyl c
84 s are induced by looser packing at the lipid headgroups and tighter packing at the tails upon the add
85 bonding, and 2 cation-pi (between PC choline headgroups and Tyr residues) transient interactions with
86 lar interactions with ionic and zwitterionic headgroups and, presumably, the interfacial dipole poten
87 RB-005, in which the lipophilic tail, polar headgroup, and linker region were modified to extend the
88 ation of the phospholipid carbon chains, the headgroup, and the composition of the liposome did not a
90 een water and adhesion of water to the lipid headgroups, and so mitigating the stress induced by the
91 ogous molecule without the charged sulfonate headgroup are investigated by observing spectral diffusi
92 hiles containing mannose-mimicking shikimoyl headgroup are promising DNA vaccine carriers for dendrit
93 noparticles (NPs) featuring quaternary amine headgroups are electrostatically bound to an enzyme [bet
96 degrees C and 61 degrees C enabled the lipid headgroups as well as the peptide amide sites to be moni
98 corresponds with the location of their lipid headgroups at the border and also inside of the unit cel
99 muM preferentially interacts with the polar headgroups at the membrane-electrolyte interface, leadin
100 ses three sections: a 2-substituted 5-phenyl headgroup attached to the benzo[d]imidazole platform, wh
101 ures were identified as follows: a phosphate headgroup binding site, a hydrophobic cleft to accommoda
103 rt two structures: in both, the quinuclidine headgroup binds in the allylic (S1) site with the side c
106 l diglyceride chain as well as the remaining headgroup bound to {LGa2}(5+) as the most abundant peaks
107 T TCR requires a 7-A displacement of the LPC headgroup but stabilizes the CD1d-LPC complex in a close
108 interstitial space between the phospholipid headgroups but do not penetrate into the acyl tail regio
109 that the obstruction of the channel by lipid headgroups can be long-lived, in the range of nanosecond
110 -pi interaction between Tyr-33 and the lipid headgroups can influence conformational flexibility of t
111 non that lipids with highly charged or bulky headgroups can promote highly curved membrane architectu
112 used to determine the effect of ganglioside headgroup charge and geometry on its interactions with t
113 ratios can be explained by global effects of headgroup charge and resultant dipole moments within the
117 um by an alternative means-varying the lipid headgroup charge, thus perturbing the electrostatic inte
118 These features are closely linked to the headgroup chemistry of the surfactant and the hydrocarbo
119 vestigated to determine the effects of lipid headgroup chemistry on Nanodisc dissociation mechanisms.
120 tinuum models of lipids with large and small headgroups (choline and ethanolamine, respectively), and
121 (i) different thermal regulations and polar headgroup compositions of membrane lipids between the ep
125 CAX(CK31) required the presence of a choline headgroup-containing detergent or lipid to yield stable
126 disordered corona containing the surfactant headgroups, counterions, water, and some alkyl groups fr
127 y attracting dipalmitoyl phosphatidylcholine headgroups, curving the membrane, and allowing water pen
128 nitroxide moiety directly to the lipid polar headgroup defines the location of the measured potential
129 ts of DMSO on the membrane structure and the headgroup dehydration have been extensively studied, the
131 of salt concentrations, exhibit slight lipid headgroup dependence, and show significant stimulation b
135 raction with GlnK, and lipids with different headgroups display a range of allosteric modulation.
140 he assumption of negligible influence of the headgroup-electrode contact on the molecular resistance
141 cate that PC acyl editing and phosphocholine headgroup exchange between PC and diacylglycerols contro
142 e attachment of aryl layer bearing an acidic headgroup, followed by chemical coupling leading to immo
145 pendent of the number of water molecules per headgroup for the lamellae, but they slow somewhat in th
147 of the dimerization interface; the cationic headgroups form multiple hydrogen bonds, thus crosslinki
148 differentiates between the two primary lipid headgroups found in mitochondrial membranes, phosphatidy
149 the intact lipid ion and the characteristic headgroup fragment, the regioisomer composition from fra
150 class identification by forming distinctive headgroup fragments based on the number of (13)C atoms i
152 ctant carrying a zwitterionic phosphocholine headgroup gives rise to two coexisting micelle populatio
153 ribution, differences in hydration, specific headgroup/H-bonding interactions, or a difference in the
155 ectroscopy, we found that the size of the SM headgroup had no marked effect on the thermal stability
157 ipid conjugates with the phosphatidylcholine headgroup have been shown to exhibit binding affinity fo
158 oups in combination with an acyl sulfonamide headgroup have emerged, with the acyl sulfonamide bestow
159 molecules that interact with the surfactant headgroups have hydrogen-bonding properties different fr
160 have been identified: those close to the SDS headgroup having fairly isolated O-H groups, i.e., local
161 inner leaflet, a difference in transmembrane headgroup hydration, and a different headgroup orientati
163 ands depending on the stereochemistry of the headgroup, illustrating the complex structure-functional
164 ee method to study the orientation of the PC headgroup in model membrane systems of varying compositi
167 e modifications reduce the presence of lipid headgroups in the pore, which leads to a clear and selec
169 ons with divalent ions can be used to tether headgroups in-plane, decreasing surface hydrophilicity.
170 ular determinants of specificity for several headgroups, including phosphatidylserine and phosphoinos
171 nsertion of alpha-Syn into the region of the headgroups, inducing a lateral expansion of lipid molecu
174 provide evidence for the role of protein-DDM headgroup interactions in stabilizing membrane protein s
175 Even though butanethiol SAMs manifest strong headgroup interactions, steric interactions are shown to
178 control cable residues at the membrane core-headgroup interface, causing a break in the control cabl
179 fic binding to the phosphoethanolamine-lipid headgroup is also required, which is evident from the en
180 he binding site for its redox-active quinone headgroup is approximately 20 A above the membrane surfa
181 onjugates is presented where the hydrophilic headgroup is composed of a 3-helix coiled coil with poly
182 residue of the trehalose Glcalpha1-1Glcalpha headgroup is liganded to a Ca(2+) in a manner common to
184 ating that either a glycerol or ethanolamine headgroup is the chemical determinant for substrate reco
185 the error arises from the fact that a lipid headgroup is typically smaller than the Debye length of
186 lating the methylation level of phospholipid headgroups is a simple way to control the specificity of
187 initial hexagonal arrangement of the sulfur headgroups is kept fixed during the simulations, the pha
189 se primarily choline as a positively charged headgroup; it may also be relevant for sicariid predator
190 tions are shown to dictate the nature of the headgroup itself, whether it takes on the adatom-bound m
191 focus on recently described synthetic lipid headgroups, linkers and hydrophobic domains that can pro
192 estabilize chain-chain interactions near the headgroups, making the headgroups more solvent-accessibl
193 interactions of aromatic residues with lipid headgroups may play an important role in determining the
196 unconfined lipid vesicle surfaces, the lipid headgroup mobility, and the repeat distances in multilam
199 interactions near the headgroups, making the headgroups more solvent-accessible and increasing surfac
201 d transport, whereby polar and charged lipid headgroups move through the low-dielectric environment o
202 nding among signalling lipids with phosphate headgroups, namely C1P, phosphatidic acid or their lyso-
205 d picosecond orientational relaxation of the headgroup occurring at the monolayer-air interface by em
206 an be incorporated by rational design in the headgroup of an amphiphile to generate small micelles wi
207 the interfaces between individual oleophobic headgroup of AOT molecules and their surrounding non-pol
208 widely in their preference for choline, the headgroup of both sphingomyelin and lysophosphatidylchol
209 mide tail, a carbamate linker, and a leucine headgroup of different chain lengths with a conventional
210 ler number of hydrogen bonds that the planar headgroup of FMN can form with this protein compared to
211 own previously by (2)H NMR measurements, the headgroup of phosphatidylcholine (PC) behaves like an el
212 D superfamily catalyzes the cleavage of the headgroup of phosphatidylcholine to produce phosphatidic
213 transfers an acyl chain from acyl-CoA to the headgroup of phosphatidylethanolamine (PE) to form N-acy
214 s(1,4,5)P3 or PtdIns(4,5)P2 The Ins(1,4,5)P3 headgroup of PtdIns(4,5)P2 binds in precisely the same o
215 of ceramide under the larger phosphocholine headgroup of SM could contribute to their favorable inte
216 re well defined, specific recognition of the headgroup of the zwitterionic phosphatidylcholine (PC) i
217 nging the acyl chain length, saturation, and headgroup of these LPA analogs, we established strict re
218 work the mechanism for binding of the sugar headgroup of trehalose dimycolate to mincle has been elu
219 of NaD1 that cooperatively bind the anionic headgroups of 14 PIP2 molecules through a unique 'cation
220 ultilamellar vesicles formed by crosslinking headgroups of adjacent lipid bilayers within multilamell
223 ergetically unfavorable dehydration of lipid headgroups of opposing bilayers is compensated by thermo
225 es with PtdSer to form nanodomains where the headgroups of PtdSer are maintained sufficiently separat
228 sh the initial binding of Abeta to phosphate headgroups of the bilayer driven by electrostatic intera
231 bundances do not depend on the type of polar headgroup or the number of double bonds of unsaturated a
232 embrane headgroup hydration, and a different headgroup orientation for the interacting phosphate grou
233 ilayer curvature, accompanied by a change of headgroup orientation relative to the membrane normal an
234 ciently sensitive to detect small changes in headgroup orientation upon introduction of positively an
235 ane peptides show very systematic changes in headgroup orientation, depending on the amount of charge
237 ition of phosphoethanolamine to the 1 and 4' headgroup positions by phosphoethanolamine transferases.
240 tively charged phospholipids with the serine headgroup (PS) exerted significant stabilizing effects i
241 through a novel surface-localized, phosphate headgroup recognition centre connected to an interior hy
242 The patches form grooves for specific lipid headgroup recognition or flat surfaces for non-specific
245 the aqueous buffer, solvated in the vesicle headgroup region and solvated in the acyl chain bilayer
246 with the membranes and penetrates below the headgroup region into the upper part of the fatty acyl c
247 ults demonstrate that VSTx1 localizes to the headgroup region of lipid membranes and produces a thinn
250 s by decreasing the negative pressure in the headgroup region of the outer leaflet and increasing the
251 peptides aggregate in the lipopolysaccharide headgroup region of the outer membrane with limited tend
252 e, the drug was found to locate in the polar headgroup region of the phospholipid bilayer, to induce
254 , the membrane atomic density profile of the headgroup region produced by the HMMM model is essential
255 nd suggest a large contribution of the polar headgroup region to the dielectric response of the lipid
256 e inclusion will soften the bilayer near the headgroup region, an effect that may weaken curvature in
257 ure and position of the functionality at the headgroup region, we envision them to perform as functio
262 s of reducing the size of the phosphocholine headgroup (removing one, two, or three methyls on the ch
263 EN-like domain with negatively charged lipid headgroups results in nanoclustering of PIP2 molecules i
264 tatics, specific recognition of phospholipid headgroups, sensitivity to phospholipid acyl chain compo
265 ding a GSL with a monosaccharide sialic acid headgroup (sGSL); for all 11 E. huxleyi strains we teste
266 water-soluble version of the metal carbonyl headgroup shows that water hydrogen bond rearrangement d
267 n n-octyl chain, respectively, and a charged headgroup similar to that in malachite green (MG, 1).
268 chain resonances not previously observed and headgroup sites important for the characterization of th
269 ment ability had different origins, with the headgroup size primarily influencing tN-Ras binding to p
270 ers of lipids, namely acyl chain saturation, headgroup size, and acyl chain length, modulate the capa
273 rol is preferentially enriched, at the lipid headgroup/solvent interface, and that this glycerol-enri
274 to methane starvation, including changes in headgroup-specific fatty acid saturation levels, and red
275 phospholipase Cdelta1 (PHPLCdelta1), mediate headgroup-specific interactions with corresponding phosp
276 st evidence for a potential phosphoglyceride headgroup-specific regulatory interaction site(s) existi
278 gulant primarily because their bulky choline headgroups sterically hinder access to their phosphates.
282 es and phospholipids with negatively charged headgroups, such as the late endosomal phospholipid bis(
284 novel bromodomain binding mode of a phenolic headgroup that led to the unusual displacement of water
285 azobenzene and a quaternary ammonium bromide headgroup that self-assembles into highly charged nanofi
286 e discovered that individual monolayers with headgroups that coat the bilayer-aqueous interface with
287 ical SNARE levels, neutral lipids with small headgroups that tend to form non-bilayer structures (pho
288 terfacial hydroxylation, the identity of the headgroup, the length of the N-acyl chain, and the posit
289 urfactants containing an amide bond near the headgroup, the MINPs had a layer of hydrogen-bonding gro
290 and carbonyl regions leads to confined lipid headgroup tilting and conformational rearrangements.
292 ongly indicate that PI-PLC interacts with PC headgroups via cation-pi interactions with tyrosine resi
296 hich is characteristic of the phosphocholine headgroup, were then used to confirm the lipid classific
297 ss of the exact chemical nature of the lipid headgroup, whereas GlpF was not sensitive to changes in
298 inverse-phosphocholine (iPC) lipids contain headgroups with an inverted charge orientation relative
299 id mixing, binding peripherally to the lipid headgroups with minimal perturbation to the bilayer stru
300 nst the calculated log P of the nanoparticle headgroups, with an essentially linear increase in immun
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