ライフサイエンスコーパス: heterolytic cleavage

1 ut the hydrogen molecule is activated toward heterolytic cleavage.

2 peroxyanion and a peroxide activated toward heterolytic cleavage.

3 ide toward the proximal oxygen, facilitating heterolytic cleavage.

4 t the rate-limiting step in the reaction was heterolytic cleavage.

5 th the presence of the substrate retards the heterolytic cleavage and gives rise to homolytic O-OH cl

6 c cleavage via traditional Fenton chemistry, heterolytic cleavage, and nucleophilic attack.

7 ct formation cis to the ReX bond followed by heterolytic cleavage at the electrophilic rhenium center

8 ane was experimentally determined versus the heterolytic cleavage energy of hydrogen in acetonitrile,

9 kcal/mol larger Marcus intrinsic barrier for heterolytic cleavage of 1-F than for cleavage of 1-Cl is

10 adical anion as a critical step, followed by heterolytic cleavage of a carbon-halogen bond.

11 oxygenase (HO) enzymes could proceed through heterolytic cleavage of an iron(III)-hydroperoxo interme

12 and 4-chlorophenyltrimethylsilane caused the heterolytic cleavage of aryl-chlorine bonds to give the

13 Heterolytic cleavage of dihydrogen into a proton and a h

14 Heterolytic cleavage of H(2) by 3 at room temperature fo

15 le) based on the DFT calculations shows that heterolytic cleavage of H(2) can occur from (eta(2)-H(2)

16 dride complexes that can be generated by the heterolytic cleavage of H(2) gas to form B-H bonds.

17 3-H(2)](+) is consistent with intramolecular heterolytic cleavage of H(2) mediated by the pendant ami

18 utational studies indicate a low barrier for heterolytic cleavage of H(2).

19 Such data signify a heterolytic cleavage of H(2)O(2) with HRP as pristine na

20 es in nature use hydrogen as a fuel, but the heterolytic cleavage of H-H bonds cannot be readily obse

21 cently been proposed to interpret the facile heterolytic cleavage of H2 by frustrated Lewis pairs (FL

22 We show how the rate of reversible heterolytic cleavage of H2 can be controlled, spanning 4

23 he dihydrogen complex and the product of the heterolytic cleavage of H2 in a functional model of the

24 We report the facile, reversible heterolytic cleavage of H2 in a manganese complex bearin

25 method involves measuring the equilibrium of heterolytic cleavage of H2 in the presence of a base, an

26 groups on N and P), have been developed for heterolytic cleavage of H2 into a proton and a hydride,

27 r 1a has been measured (49.5(1) kcal/mol) by heterolytic cleavage of H2 with Et3N in CH3CN.

28 The products of heterolytic cleavage of H2, Mo hydride complexes bearing

29 providing a design principle for controlling heterolytic cleavage of H2.

30 Our results rule out a substrate-assisted heterolytic cleavage of H2O2 en route to Cpd I.

31 l role in catalysis, acting as a base in the heterolytic cleavage of hydrogen.

32 r, Q203V PGHS-1 and PGHS-2 mutants catalyzed heterolytic cleavage of peroxides and exhibited native C

33 PGHS POX catalyzes heterolytic cleavage of primary and secondary hydroperox

34 Direct stand breaks result from heterolytic cleavage of the adjacent C3'-carbon-oxygen b

35 deformylated substrate complex indicate that heterolytic cleavage of the C-C bond in the enzyme envir

36 roton sources like MeOH and PhOH, the facile heterolytic cleavage of the C-OH bond in intermediate II

37 utases, which catalyze homolytic rather than heterolytic cleavage of the carbon-cobalt bond, can use

38 d by competing backward SET and irreversible heterolytic cleavage of the carbon-hydrogen bond at the

39 sm where the rate-limiting step changes from heterolytic cleavage of the carbon-oxygen bond in the al

40 (Co1+Cbl) species, which can be obtained by heterolytic cleavage of the Co-C bond in methylcobalamin

41 Heterolytic cleavage of the Co-C bonds is much more favo

42 bending; (2) The bent nitrosyl promotes the heterolytic cleavage of the H-H bond and protonation of

43 ts Lewis acidic iron(II) centre promotes the heterolytic cleavage of the H-H bond and this non-redox

44 Controlling the heterolytic cleavage of the H-H bond of dihydrogen is cr

45 major product of the reaction, demonstrating heterolytic cleavage of the methylcobamide carbon-cobalt

46 um hydride/cyanide species and isobutene via heterolytic cleavage of the N-Bu(t) bond.

47 A reaction mechanism of a heterolytic cleavage of the NOCF3 bond followed by recom

48 A significant amount of heterolytic cleavage of the O-O bond of cumene hydropero

49 ydroperoxoferri-HO (D140A) instead undergoes heterolytic cleavage of the O-O bond, ultimately yieldin

50 to the hydroperoxy intermediate resulting in heterolytic cleavage of the peroxide O-O bond and format

51 These radicals then undergo heterolytic cleavage of the phosphate group to yield alk

52 (4a) proceeds via a sigma-adduct followed by heterolytic cleavage of the Si-H bond and transfer of si

53 could be initiated either by homolytic or by heterolytic cleavage of this bond.

54 Heterolytic cleavage of this tyrosine radical at the Cal

55 nds up with H(2) coordination and subsequent heterolytic cleavage, regenerating the gold(I)-hydride a

56 ond cleavage were clearly identified: a fast heterolytic cleavage (tau = 108 ps) was observed in prot

57 hosphate leaving group is then expelled in a heterolytic cleavage to give a contact alkene radical ca

58 a hydroxyl radical and Cu(II)OH rather than heterolytic cleavage to yield water and a Cu(II)-O(*-) s