ライフサイエンスコーパス: homolytic cleavage

1 d tert-butyl hydroperoxide, t-BuOOH) undergo homolytic cleavage.

2 n rearrangement, but not able to undergo O-O homolytic cleavage.

3 -chlorophenol, via a mechanism involving O-O homolytic cleavage.

4 at one mass unit above the mass expected for homolytic cleavage.

5 Photodissociation with 266 nm light yields homolytic cleavage at the modification site, generating

6 tions, 1,4-dihydropyridines (DHPs) undergo a homolytic cleavage, forming exclusively a Csp(3)-centere

7 ture, which may be important in facilitating homolytic cleavage, is the long cobalt-nitrogen bond lin

8 a number of possible pathways including O-O homolytic cleavage, M-O homolytic cleavage, nucleophilic

9 ch the cofactor's Co-C bond is activated for homolytic cleavage may be operative for all base-off/His

10 The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray

11 migration for extradiol cleavage and an O-O homolytic cleavage mechanism for intradiol cleavage.

12 ketoheptan-1-ol, also consistent with an O-O homolytic cleavage mechanism, and not consistent with a

13 thways including O-O homolytic cleavage, M-O homolytic cleavage, nucleophilic O-atom transfer, and el

14 Asn, Glu, Asp, or Lys residues augmented the homolytic cleavage of 8R-HPODE with formation of 10-hydr

15 l hydrogen atom transfer reactions, in which homolytic cleavage of a C-H bond is accomplished by a si

16 inactivation of P450 by aldehydes occurs via homolytic cleavage of a peroxyhemiacetal intermediate to

17 tion by those aldehydes apparently occurs by homolytic cleavage of a peroxyhemiacetal intermediate to

18 lsilyl radical may be initially generated by homolytic cleavage of a weakened Si-H bond of a hypercoo

19 reaction with aerobic, aqueous photoinduced homolytic cleavage of adenosylcobalamin, indicating that

20 We report ammonia oxidation by homolytic cleavage of all three H atoms from a [Mo-NH3](

21 istribution due to a high-energy barrier for homolytic cleavage of an exo bond in the intermediate cy

22 The radicals generated by the homolytic cleavage of an X-H bond from the guanine.cytos

23 basis of this evidence, it was proposed that homolytic cleavage of C-H bonds for CH(3)CN and CH(3)OH

24 function by radical mechanisms involving the homolytic cleavage of C-H or C-C bonds, i.e., biotin syn

25 ade, whereas Fenton catalysis results in the homolytic cleavage of H(2)O(2) producing free radicals t

26 A reversible bond dissociation enthalpy for homolytic cleavage of Me-Cbl is calculated as 31 +/- 2 k

27 r while longer wavelengths of light initiate homolytic cleavage of metal-carbon bonds that, after int

28 defined with respect to the heterolytic and homolytic cleavage of O-O bonds.

29 dical (GS*), a reaction product derived from homolytic cleavage of S-nitrosoglutathione (GSNO).

30 deprotonation of radical cation, followed by homolytic cleavage of the alcohol OH group from the phen

31 ylium radical 1(*+) which is generated via a homolytic cleavage of the B-B bond of 3.

32 and inactivation by 12-IODE is initiated by homolytic cleavage of the C(11)-H bond.

33 radicals on neutral tyrosine side chains by homolytic cleavage of the C-I bond.

34 from Lactobacillus leichmannii catalyzes the homolytic cleavage of the carbon-cobalt bond of adenosyl

35 The homolytic cleavage of the Co(III)-Ado or Co(III)-Me bond

36 Thermal treatment of the oxidized MOF causes homolytic cleavage of the Co(III)-halogen bonds, reducti

37 Visible light excitation induced homolytic cleavage of the Co-C bond and the formation of

38 Homolytic cleavage of the Co-C bond of anAdoCbl at the a

39 f the activating monocation to stimulate the homolytic cleavage of the Co-C5' bond in adenosylcobalam

40 adenosylcobalamin (coenzyme B12) results in homolytic cleavage of the Co-C5' bond, forming cob(II)al

41 Homolytic cleavage of the cobalt-carbon bond of the anal

42 ns, the 5'-deoxyadenosyl radical arises from homolytic cleavage of the cobalt-carbon bond, and it ini

43 bl-dependent enzymes accelerate the rate for homolytic cleavage of the cofactor's Co-C bond by approx

44 cobalamin, AdoCbl)-dependent enzymes promote homolytic cleavage of the cofactor's Co-C bond to initia

45 in each case catalysis is initiated through homolytic cleavage of the cofactor's Co-C bond.

46 Absorption at naphthalene causes homolytic cleavage of the connecting carbon-sulfur bond

47 the chemistry proceeds by rate limiting Cu-O homolytic cleavage of the Cu(II)-(OOH) species, followed

48 ity, suggesting that Asn(964) may facilitate homolytic cleavage of the dioxygen bond of 9R-HPODE with

49 nction as a sensitizer, thereby facilitating homolytic cleavage of the ditin reagent.

50 e formation of the oxon derivative, and (ii) homolytic cleavage of the N-C and C-S bonds of the organ

51 trong evidence of a grafting mechanism where homolytic cleavage of the N2(+) species occurs together

52 anism I, and the Ni-C bond length suggests a homolytic cleavage of the Ni(III)-methyl bond in the sub

53 The nonconcerted process involving homolytic cleavage of the O-N bond in 5 was found to be

54 late ligand of the diiron centre may trigger homolytic cleavage of the O-O bond by transferring a pro

55 t the hydroxylation reaction is initiated by homolytic cleavage of the O-O bond in the C(4a)-hydroper

56 The observed homolytic cleavage of the O-O bond of 1 is explored with

57 tudies revealed that I435 is not formed upon homolytic cleavage of the O-O bond of PN, but instead ar

58 Importantly, there is a barrier for homolytic cleavage of the O-O bond on the high-spin pote

59 ough an iron(III)-bound peroxynitrite before homolytic cleavage of the O-O bond to form an iron(IV)-o

60 Homolytic cleavage of the O-O bond yields the catalytica

61 ystems show similar reactivities and undergo homolytic cleavage of the O-O bond.

62 p in the thermal decomposition of PPE is the homolytic cleavage of the oxygen-carbon bond.

63 the metal, a process triggered by an unusual homolytic cleavage of the peroxide bond, forming a disto

64 te fragmentation of the ozonide initiated by homolytic cleavage of the peroxide bridge followed by re

65 Homolytic cleavage of the pyrrole NH leads to the format

66 roteins generate an adenosyl radical via the homolytic cleavage of the S-C(5') bond of SAM.

67 particular, hyper-long Co-N bonds may favor homolytic cleavage of the trans-cobalt-carbon bond in th

68 imately 10(12)-fold rate acceleration of the homolytic cleavage of the upper axial cobalt-carbon bond

69 rged as a major biochemical strategy for the homolytic cleavage of unactivated C-H bonds.

70 ails are explored by DFT supporting a simple homolytic cleavage pathway from a kappa(1)-ONO bound int

71 artitions between Calpha-Cbeta oxidation and homolytic cleavage pathways.

72 ation of a stable radical (by abstraction or homolytic cleavage reactions) increases the acidity of a

73 *)Cys) was the radical-directed Calpha-Cbeta homolytic cleavage, resulting in the formation of glycyl

74 s, which then undergoes both heterolytic and homolytic cleavage to form iron(IV) pi-radical cations a

75 cating that a Cu(I)OOH species undergoes O-O homolytic cleavage to yield a hydroxyl radical and Cu(II

76 re calculated for three different reactions: homolytic cleavage via traditional Fenton chemistry, het