ライフサイエンスコーパス: hydride

1 a indicated rapid exchange of the proton and hydride.

2 diferrous [2Fe]H with a terminally bound Fe-hydride.

3 isolation of the first low valent organolead hydride.

4 rmediates, including a rare anionic d(10) Ni hydride.

5 and dihaloalkanes in the presence of sodium hydride.

6 ity discovered under high pressure in sulfur hydride.

7 yl benzenes with regeneration of the calcium hydride.

8 form the boronate ester product and a copper hydride.

9 transfer from the pendant amine to the metal hydride.

10 tions, which can influence the reactivity of hydrides.

11 d in the formation of only the corresponding hydrides.

12 onor strength rivals those of precious metal hydrides.

13 ynthesized at low temperature and features a hydride (1)H NMR signal (in solution 35.61 ppm; in the s

14 n storage capacity by weight among the metal hydrides (15.93 wt. % of hydrogen for LiBeH3).

15 Electrochemical studies reveal that the Ru-hydride 2 is oxidized at low potential (-0.80 V versus f

16 To some degree, hydride abstraction and adduct formation is observed, le

17 of carbocation [3](+), capable of effecting hydride abstraction and oxidation reactions.

18 -18 with Soderquist's KH* gave (R,R)-19, and hydride abstraction by TMSCl in the presence of alkenes

19 ate-limiting step in the oxidations involves hydride abstraction from the carbinol carbon of the alco

20 H2 under mild conditions, and catalyses C-H hydride abstraction plus H2 generation from a model subs

21 Notably, neither H2 activation nor C-H hydride abstraction was observed in the analogous comple

22 nd Mo(4+)-SH, are suggested to be the direct hydride acceptor and donor, respectively.

23 HDH utilises two molecules of NAD(+) as the hydride acceptor.

24 abeling studies support the involvement of a hydride addition to a gold-activated alkyne with subsequ

25 Labeling studies found rhodium hydride addition to the alkene to be largely irreversibl

26 e results support the hypothesis that copper hydride aggregates dissociate in solution.

27 terolytic cleavage of H2 into a proton and a hydride, akin to frustrated Lewis pairs.

28 ition of HCl to 2 selectively yields the cis-hydride-alkylidyne compound OsHCl2( identical withCPh)(I

29 rected to the halide gives the alkynyl-trans-hydride-alkylidyne derivatives OsH(C identical withCCO2M

30 ected to the alkylidyne leads to alkynyl-cis-hydride-alkylidyne intermediates, which rapidly evolve i

31 ition with a range of nucleophiles including hydrides, amines, cyanide, and protected enolates.

32 In a search for gold hydrides, an initial discouraging result of no theoretic

33 nd, formally splitting the Al-H linkage into hydride and an alumenium ion.

34 tant Ka(LAC) of diamagnetic transition metal hydride and dihydrogen complexes.

35 These isotope effects support concerted hydride and proton transfer for both light and heavy LDH

36 This chemical barrier involves both hydride and proton transfers to pyruvate to form l-lacta

37 the required reductive activation of a metal hydride and the resistance of metal hydrides toward redu

38 ic pathway of H2 generation from the Co(III)-hydride and/or Co(II)-hydride species.

39 r significance given that intermediate metal hydrides and hydrogen evolution may play a key role in b

40 ooperative participation of transition-metal hydrides and main group Lewis acids.

41 e S-H(+) bond breaks and H(+) attacks the Fe-hydride, and explains the observed H/D isotope effect.

42 rnative to typical silane, lithium aluminium hydride, and tin-based conditions for these reductions.

43 t interest due to the unique features of the hydride anion, most notably the absence of valence p orb

44 c-axis compressibility, suggesting that the hydride anions act as pi-blockers.

45 In contrast, the less crowded Sn(II) hydride [Ar((i)Pr4)Sn(mu-H)]2 (Ar((i)Pr4) = C6H3-2,6(C6H

46 The tin(II) hydride [Ar((i)Pr6)Sn(mu-H)]2(Ar((i)Pr6) = C6H3-2,6(C6H2

47 Inactive Os hydrides are characterized that form during catalysis.

48 Bridging iron hydrides are proposed to form at the active site of MoFe

49 Reactions of the Sn(II) hydrides [ArSn(mu-H)]2 (1) (Ar = Ar(iPr4) (1a), Ar(iPr6)

50 solid insertion protocol that uses potassium hydride as a redox-controlled reducing agent to access t

51 g transformations involving transition-metal hydrides as either reactants or products.

52 investigation of well-defined molecular iron hydrides as precursors for catalytic N2 -to-NH3 conversi

53 Hred and Hsred to structures with a bridging hydride at the diiron site.

54 Hydride attack on the cationic ferric [(OEP)Fe(NO)(5-MeI

55 Hydride-based reagents such as LiAlH4 or diboranes are t

56 the expected insertion of CO2 into the metal-hydride bond, and the other leads to reductive cleavage

57 ce in the coordination chemistry of the zinc-hydride bond, we describe the trajectory for the approac

58 nowledge of free energies for cleaving metal hydride bonds enables the prediction of chemical reactiv

59 we describe the biophysical properties of a hydride-bound state (Hhyd) of the [FeFe]-hydrogenase fro

60 been characterized in the Ni-R state with a hydride bridging between Fe and Ni but displaced toward

61 acts similarly to the more traditional metal-hydride by reacting with acid to produce H2.

62 This cesium platinide hydride can formally be considered as a double salt of t

63 t of the cavity as a methyl group before the hydrides can be formed.

64 d, we describe the synthesis of reduced iron-hydride/carbonyl complexes that enable an electrophile-p

65 no-alcohol products using sequential, copper-hydride-catalysed hydrosilylation and hydroamination of

66 Here, we report a copper-hydride-catalysed, enantioselective synthesis of gamma-

67 ugh the large body of precedent in copper(I) hydride catalysis and the well-explored use of hydroxyla

68 Rh-hydride catalysis solves a synthetic challenge by afford

69 hydrofunctionalization of 1,3-dienes via Rh-hydride catalysis.

70 n of and open environments around the cobalt-hydride catalytic species at Zr8-SBUs are responsible fo

71 allylic hydroxylamine esters undergo copper hydride-catalyzed intramolecular hydroamination with a h

72 to convey how developments in coinage metal hydride chemistry have led to new organic transformation

73 ted intermediates of direct relevance to the hydride chemistry of these systems.

74 during turnover reveals an iron-borohydrido-hydride complex as a likely resting state of the P3(B)Fe

75 th [Et3NH][BPh4] to form the terminal Th(4+) hydride complex Cp''3ThH, 2, a reaction that formally in

76 quent coordination of the ketone to the iron hydride complex, and insertion of the ketone into the Fe

77 ive R21 and formation of a cyclometalated Ru-hydride complex, via a hydride mechanism.

78 Through the study of a stable cobalt hydride complex, we demonstrate the influence of acid ch

79 The novel Ir hydride complexes [((t)Bu-PNP*)Ir(H)2] (2) ((t)Bu-PNP*,

80 f internal and terminal alkynes by gold(III) hydride complexes [(C^N^C)AuH] was found to be mediated

81 The well-defined heterobimetallic hydride complexes act as precatalysts for the conversion

82 tal-hydrogen bonds is widespread among metal hydride complexes and has played a critical part in open

83 re stoichiometric reactions involving nickel hydride complexes and how some of these reactions are de

84 e products of heterolytic cleavage of H2, Mo hydride complexes bearing protonated amines, [CpMo(H)(CO

85 series of neutral and cationic coinage metal hydride complexes containing Cu-H-Cu and M-H-M(+) moieti

86 reactions are likely to be dissociative, but hydride complexes may be designed with equilibrated exci

87 (BArf = B(3,5-C6H3(CF3)2)4) afford the metal hydride complexes mer,trans-[ Fe(CO)3(H)(P((CH2)n)3 P)](

88 Hydride complexes of copper, silver, and gold encompass

89 The five-coordinate iridium-hydride complexes were found to catalyze H/D exchange be

90 Two metal hydride complexes, (eta(5)-C5Me5)(py-Ph)Rh-H (py-Ph = 2-

91 Nickel hydride complexes, defined herein as any molecules beari

92 prehensive overview of this specific type of hydride complexes, which has been studied extensively in

93 The terminal zinc and magnesium hydride compounds, [kappa(3)-Tism(Pr(i)Benz)]ZnH and [Ti

94 provide syntheses of new classes of thorium hydride compounds.

95 The study suggests that dense hydrides consisting of these and related hydrogen polyhe

96 Treatment of the bulky metallocene hydride Cp*2Zr(H)OMes (Cp* = pentamethylcyclopentadienyl

97 esium platinide, Cs2 Pt, and the salt cesium hydride CsH according to Cs9 Pt4 H identical with4 Cs2 P

98 The direct asymmetric copper hydride (CuH)-catalyzed coupling of alpha,beta-unsaturat

99 ng this model, we show that in the copper(I) hydride (CuH)-catalyzed hydroamination of unactivated ol

100 on a) single-electron transfer (SET), and b) hydride delivery reactions to arenes.

101 c isotope effect measured confirmed that the hydride delivery to the substrate is the rate-determinin

102 valents on FeMo-co as two [Fe-H-Fe] bridging hydrides (denoted E4(4H)).

103 The use of heavier alkaline earth hydride derivatives as pre-catalysts and intermediates i

104 chanism processes involved in these Group 14 hydride derivatives.

105 the converse, establishes that the bridging hydrides/deuterides do not exchange with solvent during

106 g either the commercially available aluminum hydride DIBAL-H or bench-stable Et3 AlDABCO as the catal

107 ond cleaving ability of a high-spin iron(II) hydride dimer with concomitant release of H2.

108 "Hydricity," the hydride donor ability of a species, is a key metric for

109 yl(tert-butyl)amine was found to be the best hydride donor for the synthesis of terminal allenes.

110 nal Ni-H moiety, for which the thermodynamic hydride donor strength rivals those of precious metal hy

111 reacts with poly(methylhydrosiloxane) as the hydride donor to afford the monomeric (IPr**)CuH complex

112 ities of several secondary amines serving as hydride donors in propargylic amines undergoing a [1,5]-

113 Here, we used simple hydrides (e.g., H-) as ligands along with phos-phines, s

114 Nitrogen hydrides, e.g., ammonia (NH3), hydrazine (N2H4) and hydr

115 as transient metallacycles to suppress beta-hydride elimination and facilitate transmetalation/reduc

116 eports the first comprehensive study of beta-hydride elimination at gold(III).

117 mide as an alkene, which cannot undergo beta-hydride elimination due to the unavailability of a syn-p

118 gests a Ru-H intermediate is formed via beta-hydride elimination from a ribose subunit in NAD(+).

119 ence of an apparently unique reversible beta-hydride elimination from the bicyclic substituted aryl/a

120 The method turns parasitic beta-hydride elimination into a strategic advantage, rapidly

121 ylphenyl carbonates as chemoselective copper-hydride elimination is faster with an achiral Cu-alkyl s

122 2) -sp(3) cross coupling, implying that beta-hydride elimination is not a significant process in this

123 of 3a or 3b into 4a or 4b occurs via a beta-hydride elimination of 1a or 1b to regenerate NBD.

124 of LiNaph/THF results in over-reduction with hydride elimination to afford the doubly boron-doped dib

125 tive migratory insertion is followed by beta-hydride elimination toward the adjacent alcohol.

126 nce of migratory insertion of ethylene, beta-hydride elimination, and olefin exchange at gold(III).

127 An Eyring plot for beta-hydride elimination-olefin rotation-reinsertion is const

128 H-atoms available for either alpha- or beta-hydride elimination.

129 associated with proto-demetalation and beta-hydride elimination.

130 olefin isomerization takes place after beta-hydride elimination.

131 elective carbometalation and endocyclic beta-hydride elimination.

132 rbon electrophile outcompetes potential beta-hydride elimination.

133 Specifically, the proton-hydride exchange appears to occur by formation of a moly

134 competing reaction is the protonation of the hydride [Fe-H-Fe] to make H2.

135 n with a discussion of reactions where metal hydrides form direct adducts with Lewis acids, elaborati

136 -evolving reaction activity may prevent iron hydride formation from poisoning the P3(B)Fe system.

137 acid choice, beyond pKa, on the kinetics of hydride formation.

138 is insertion of the alkene into a copper(I) hydride formed by reversible dissociation of HBpin from

139 The extent of interference from other hydride forming elements (As, Sb, Se) on Bi response by

140 better resistance to interference from other hydride-forming elements (Sb, Se, and Bi).

141 7)) as a consequence of the migration of the hydride from the metal center to the Calpha atom of the

142 This feature distinguishes hydrides from all other anions, and gives rise to unprec

143 ernal electrons, reduce two protons into two hydrides, from which reductive elimination generates H2.

144 A reaction mechanism involving a palladium hydride, generated from insertion of palladium to O-H of

145 and quantification is done by flow injection hydride generation atomic absorption spectrometry (FI-HG

146 An optimized flow injection hydride generation atomic absorption spectroscopy (FI-HG

147 omatography coupled to ultraviolet oxidation hydride generation atomic fluorescence spectrometry (HPL

148 Due to the equal hydride generation efficiency (and thus the sensitivitie

149 n by atomic fluorescence spectrometry with a hydride generation system (HG-AFS).

150 he structure of the species arising from the hydride generator as well as the atomizer.

151 bimetallic Au(I)/Pt(II) complexes containing hydride (-H), acetylide (-C identical withCH), and vinyl

152 The S = 1/2 hydride [H1](0) was generated by reduction of [H1](+) wi

153 ynamic hydricity values for transition metal hydrides have been determined in acetonitrile or water.

154 Hydrides have been incorporated into synthetic systems,

155 However, hydrides have largely been abandoned because of oxidativ

156 adduct can be synthesized from alkali metal hydride, HCF3, and borazine Lewis acids in quantitative

157 tionally inelastic process wherein deuterium hydride (HD) (v = 1, j = 2) collides with molecular deut

158 Demethylation during generation of volatile hydrides (HG), i.e. formation of noncorresponding arsane

159 The reactivity of this "hydride", however, shows protic and not hydridic behavio

160 sed combination of benzyl bromide and sodium hydride in DMF can lead to the formation of an amine sid

161 The existence of the Fe-hydride in Hhyd was demonstrated by an unusually low Mos

162 Hence, by using (hydride-induced) anion-deficient precursors, we should b

163 udies of the reductive cyclization suggest a hydride insertion pathway, explaining the change in regi

164 lly via EECC mechanism through a Ni-centered hydride intermediate like the enzyme.

165 dinucleotide (NADH) can generate a ruthenium-hydride intermediate that catalyzes the reduction of O2

166 an E[ECEC] mechanism through an Fe-centered hydride intermediate.

167 eriments that support the intervention of Co-hydride intermediates that undergo diene insertion to ge

168 d H2 oxidation that are not reliant on metal-hydride intermediates.

169 required to cleave an M-H bond to generate a hydride ion (H(-)).

170 These hydride ion levels would allow the measurement of (239)P

171 s compound adopts the K2 NiF4 structure with hydride ions positioned exclusively at the equatorial si

172 elling studies support a mechanism where the hydride is delivered to the branched position of a Rh-al

173 A DFT model of Hhyd shows that the Fe-hydride is part of a H-bonding network with the nearby b

174 electrochemical generation of a monomeric Mn-hydride is suggested to greatly enhance the production o

175 The chemistry of metal hydrides is implicated in a range of catalytic processes

176 ganometallic ligands, such as acetylides and hydrides, is an emerging area of nanoscience.

177 Hydrides isolated on surfaces have been characterized as

178 roscopy, with a reductive elimination of two hydrides just before nitrogen binding.

179 (DBU)(+) and also presumably the mononuclear hydride LCuH, which is not directly observed.

180 oms, and a variety of fluorine, bromine, and hydride leaving groups.

181 ns in the stripper tube of the SSAMS reduced hydride levels by a factor of approximately 3 x 10(4) gi

182 its parent compound BeH2, lithium-beryllium hydride LiBeH3 exhibits a sharp increase in hydrogen mob

183 e synthetic Ni-R models reported so far, the hydride ligand is either displaced toward Fe, or termina

184 intermediate, which further reacts with the hydride ligand to give complex 4 and water.

185 m(Pr(i)Benz)]MgH, which possesses a terminal hydride ligand.

186 tallographic characterization showed the two hydride ligands to be directed into the bimetallic pocke

187 ion between a transition-metal or main-group hydride (M-H) and a protic hydrogen moiety (H-X)-is argu

188 f a cyclometalated Ru-hydride complex, via a hydride mechanism.

189 and isotope effects support a palladium(II) hydride-mediated pathway and reveal crucial roles of bbe

190 the involvement of both nonhydride and metal-hydride medium and can be switchable with water as an ad

191 is resolved by reduction of the remote (non-hydride) metal of the bimetallic unit.

192 roboration, or through an intramolecular 1,3-hydride migration as operates in the only other reported

193 mplexes that enable an electrophile-promoted hydride migration process, resulting in the reduction of

194 transfer, including an enantioselective 1,2-hydride migration.

195 A well-defined hydride Mn(I) PNP pincer complex, recently developed in

196 e(III)6(mu3-O)4(mu3-OLi)4(H)6(THF)6Li6 metal-hydride nodes that effectively catalyze hydroboration an

197 from iodine-mediated replacement of one BH3 hydride of a boranephosphonate linkage by pyridine, vari

198 aterials in many chemical transformations, a hydride of lead in oxidation state II is so far unknown.

199 te having very different ligands, the cobalt hydrides of both catalysts possess nearly identical hete

200 ough the photoinduced re of the two bridging hydrides of E4(4H) as H2.

201 Although hydrides of the group 14 elements are well-known as vers

202 Metal hydrides offer ample storage capacity and do not require

203 Successful coupling occurs from a hydride on Fe' with a proton on thiolate S and requires

204 unactivated aliphatic C-H bonds via a metal-hydride pathway.

205 fractive imaging to image defects during the hydriding phase transformation of palladium nanocrystals

206 deep in a Pd nanoparticle during the forward hydriding phase transformation that heal during the reve

207 al methods) and a survey of transition metal hydride photochemistry organized by transition metal gro

208 Rhodium-hydride PNP pincer complex 1 is shown to add CO2 in two

209 This bimetallic W/Zr hydride precatalyst proved to be more efficient (TON = 1

210 ature showed the easy formation of zirconium hydride, probably facilitated by tungsten hydride which

211 d at -45 degrees C produced two monometallic hydride products, namely, (C5Me4H)3ThH, 5, and [K(2.2.2-

212 bility of the metallodithiolate ligand), and hydride-proton coupling routes.

213 in heavy LDH, the concerted mechanism of the hydride-proton transfer reaction is not altered.

214 f the mechanism of H2 formation by the metal-hydride protonation reaction.

215 the nitrogenase mechanism of H2 formation by hydride protonation, but also illustrates a strategy for

216 Transition-metal hydride radical cations (TMHRCs) are involved in a varie

217 -1-ene, and hex-1-ene with a dimeric calcium hydride-react with protio and deutero benzene at 60 degr

218 ey metric for understanding transition metal hydride reactivity, but comprehensive studies of aqueous

219 which enables the correct orientation of the hydride receiving orbital of N5.

220 Moreover, these compounds recover from hydride reduction with dramatically improved efficiency.

221 All the new tin hydrides remain metallic over their predicted range of s

222 FPP] to design and synthesize a new class of hydride-rich silver NCs.

223 opose a new mechanism which involves a C2-C1 hydride shift followed by intramolecular trapping of a d

224 involve a novel N-assisted, transannular 1,5-hydride shift.

225 Lewis acid component of the FLP acting as a hydride shuttle that enables alkyne 1,2-hydrocarbation.

226 as both the boron reagent and stoichiometric hydride source has been developed.

227 de adenine dinucleotide (NADH) is a possible hydride source inside the cell based on studies using py

228 rated hydrocarbons utilizing water as formal hydride source is described.

229 led an unexpected substitution effect of the hydride source itself.

230 l triflates as electrophiles and silane as a hydride source.

231 nes with isocyanates using alkyl bromides as hydride sources has been developed.

232 oration of benzothiazolidines as alternative hydride sources revealed an unexpected substitution effe

233 In acetonitrile, the hydricity of metal hydrides spans a range of more than 50 kcal/mol.

234 The use of hydride species for substrate reductions avoids strong r

235 ng to the formation of mononuclear ruthenium hydride species is suggested.

236 defined binary, low-oxidation-state aluminum hydride species that is stable at ambient temperature, n

237 ation from the Co(III)-hydride and/or Co(II)-hydride species.

238 ion occurs in the recently discovered sulfur hydride superconductor with a superconducting transition

239 xcessive signal noise due to fluctuations of hydride supply to an atomizer, a new design of a gas-liq

240 ns to [Ni-Fe](+) produces H2 from coupling a hydride temporarily stored on Fe(NO)2 (Lewis acid) and a

241 g two reducing equivalents in adjacent metal hydrides that evolve H2 upon substrate binding is remini

242 a straightforward preparation of titanocene hydrides that leads to a reaction with low catalyst load

243 Ni(II)2(H)2](-) having two adjacent terminal hydrides thus represent a masked version of a highly rea

244 been prepared from addition of a parent gold hydride to a bent d(10) copper(I) fragment.

245 Instead, initial HAT from a metal hydride to directly generate a carbon-centered radical a

246 nation of the olefin and the transfer of the hydride to the carbenium ion.

247 on intermediates by transferring the allenic hydride to the oxidant, thus generating 1,3-enynes (E1 p

248 able of completely striping-off hydrogen and hydrides to generate the first cationic phosphonio-stann

249 uctive elimination of two [Fe-H-Fe] bridging hydrides to make H2.

250 Intramolecular hydride-to-CO migrations are extremely rare, and to our

251 ficient (TON = 1436) than the monometallic W hydride (TON = 650) in the metathesis of n-decane at 150

252 a metal hydride and the resistance of metal hydrides toward reduction.

253 de reduction are proposed to proceed through hydride transfer and the sulfo group of the oxidized and

254 as a continuum in water: the free energy of hydride transfer changes with pH, buffer composition, an

255 local to the active site play a role in the hydride transfer chemistry, while the protein-only "heav

256 The direct or indirect hydride transfer electrochemical reduction of CO2 to for

257 n function and a CAN-catalyzed reduction via hydride transfer from ethanol.

258 are equal to the intrinsic 1 degrees DKIE on hydride transfer from NADL to GA; (iii) similar intrinsi

259 , M(-1) s(-1)) for dianion (X(2-)) activated hydride transfer from NADL to glycolaldehyde (GA) cataly

260 hydrogen bonding with water molecules during hydride transfer from the Co center to the CO2 molecule.

261 ducts occurs after a common initial stage of hydride transfer from the NHC-borane to the acetylenedic

262 ue acts as a catalytic base facilitating the hydride transfer from the substrate to the cofactor.

263 oop during the chemical step, we studied the hydride transfer in wild type (WT) ecDHFR using hybrid q

264 Aqueous hydride transfer is a fundamental step in emerging alter

265 related enzymes likely operate via a simple hydride transfer mechanism and are effective in catalyzi

266 talyzes the oxidation of the substrate via a hydride transfer mechanism and concomitant reduction of

267 Subsequently, intermolecular hydride transfer occurs, with the Lewis acid component o

268 A hitherto unidentified hydride transfer pathway involving Lewis and Bronsted ac

269 nformation only has a moderate effect on the hydride transfer rate and donor-acceptor distance dynami

270 ors in propargylic amines undergoing a [1,5]-hydride transfer reaction to yield the respective termin

271 o the enzyme isotope effect on the reductive hydride transfer reaction, but their contributions are n

272 nsional transition state optimization to the hydride transfer step in human dihydrofolate reductase s

273 ts a closed conformation during the chemical hydride transfer step.

274 stablished that protonation at N5 of H2F and hydride transfer to C6 occur in a stepwise mechanism.

275 catalysis by altering the thermodynamics for hydride transfer to CO2 from a key dihydride intermediat

276 s via a process that involves intermolecular hydride transfer to generate an imine intermediate that

277 Cleavage of the H-H bond is followed by hydride transfer to the enzyme's organic substrate, H4MP

278 ia oxidative cleavage at Ru with concomitant hydride transfer to Zn.

279 nism investigation was realized and showed a hydride transfer which led to a dismutation of the inter

280 show that these reactions proceed through a hydride transfer within a charge transfer complex.

281 ided a mechanistic rationale via Rh-mediated hydride transfer.

282 model of the Michaelis complex formed during hydride transfer.

283 H4(+), for C-N rotation in amides, and for a hydride transfer.

284 ule situated in a way that would allow for a hydride transfer.

285 ical reactions, including proton transfer or hydride transfer.

286 Consecutive intramolecular 1,3-hydride transfers from the ruthenium center to coordinat

287 related PL intensity in undoped GaN grown by hydride vapor phase epitaxy increases linearly with the

288 breaks a C-C bond and results in net loss of hydride, via steps that are not clear.

289 tic method that efficiently combines a silyl hydride, vinyl-B(pin) (pin=pinacolato) and (E)-1,2-disub

290 The palladium hydride was also found to be directly involved in the pr

291 With SEGPHOS as the ligand, a dimeric copper hydride was observed as the dominant species during the

292 ry thin (~5 nm) interfacial layer of uranium hydride was observed at the oxide-metal interface.

293 The thermolabile dimeric organolead hydride was synthesized at low temperature and features

294 the case of HNO3 formation of corresponding hydrides was preserved for MAs(V) and DMAs(V) but not fo

295 um hydride, probably facilitated by tungsten hydride which was formed at this temperature.

296 d leads to an unprecedented cationic Au(III) hydride, which gives a (1)H NMR resonance at delta -8.34

297 Lithium-beryllium metal hydrides, which are structurally related to their parent

298 and a proton addition produce a semibridging hydride with a short Fe-H bond like other structured [Ni

299 uding boron and hydrogen, leading to complex hydrides with extreme flexibility in composition, struct

300 ted facile recombination of the two terminal hydrides within the bimetallic cleft, with a moderate en