ライフサイエンスコーパス: hydrosilylation

1 i hybrid donor-acceptor polymer by catalytic hydrosilylation.

2 There is no concomitant hydrosilylation.

3 g the catalytic cycle for the iron-catalyzed hydrosilylation.

4 on hydrogen-terminated silicon surfaces via hydrosilylation.

5 y 1/NaBAr(4) led to cascade cyclization with hydrosilylation.

6 ic acid (UDA)- or acrylic acid (AA)-mediated hydrosilylation.

7 ariant of Piers' B(C6F5)3-catalyzed carbonyl hydrosilylation.

8 ion and the mechanism for the iron-catalyzed hydrosilylation.

9 tion-metal-free hydrogenation and, likewise, hydrosilylation.

10 ed, specifically via Ir-catalyzed exhaustive hydrosilylation.

11 d dilute ligand concentration during thermal hydrosilylation.

12 is extended to include a sequential one-pot hydrosilylation.

13 screened for their effect on surface alkene hydrosilylation.

14 ng nanocubes is readily achieved via thermal hydrosilylation.

15 ylethynyl acetate, which can be subjected to hydrosilylation, alcohol substitution, and acetate depro

16 Stereocontrolled intramolecular hydrosilylation allows for the subsequent introduction o

17 t hydrogen abstraction by oxygen accelerates hydrosilylation and generates sufficient silyl radical a

18 s using sequential, copper-hydride-catalysed hydrosilylation and hydroamination of readily available

19 ntermediates in multiple bond hydrogenation, hydrosilylation and hydroboration is also described alon

20 , [Tism(Pr(i)Benz)]MgH is a catalyst for (i) hydrosilylation and hydroboration of styrene to afford t

21 In a comparative study, surface hydrosilylation and ligand oligomerization were found to

22 was synthesized from undecenoic acid through hydrosilylation and reduction, and the polymerization wa

23 of Si(cat(F))2 was suggested from catalytic hydrosilylation and silylcyanation reactions with aldehy

24 e for the hydroamination, hydroalkoxylation, hydrosilylation, and cycloisomerization of alkynes and a

25 oligomerization, polymerization, metathesis, hydrosilylation, C-C bond cleavage, acceptorless dehydro

26 1,3-diols by a sequence of hydroxyl-directed hydrosilylation, C-Si bond oxidation, and stereoselectiv

27 lanes, olefins and alkynes undergo efficient hydrosilylation catalysis to the alkylsilanes.

28 nd phenylacetylene and its conversion to the hydrosilylation catalyst CuIPhEt.

29 vinylsilanes created through regioselective hydrosilylation catalyzed by the complex [Cp*Ru(MeCN)3]P

30 currently accepted mechanism of the carbonyl hydrosilylation catalyzed by the iridium(III) pincer com

31 and promote very clean, fast, and selective hydrosilylation chemistry.

32 one motif was installed by sequential alkyne hydrosilylation, epoxidation, and Fleming-Tamao oxidatio

33 llylboration reactions and an intramolecular hydrosilylation/Fleming-Tamao oxidation sequence to esta

34 nocrystals (SiNCs) with dodecene via thermal hydrosilylation has been reexamined.

35 Regioselective methods for allene hydrosilylation have been developed, with regioselectivi

36 A Pt-catalyzed hydrosilylation helped stymie unwanted rearrangements fa

37 es have been successfully achieved, covering hydrosilylation, hydroboration, hydrovinylation, hydroge

38 cycloindoline product (3a) that results from hydrosilylation, hydrogenation, and benzylic C-H activat

39 tive alkene hydration, and asymmetric ketone hydrosilylation in 97% ee.

40 icient internal alkyne underwent cyclization/hydrosilylation in moderate yield to form products resul

41 ytic system for titanocene-catalyzed epoxide hydrosilylation is described.

42 on does not work with alkenes, and therefore hydrosilylation is not the primary mode of reaction.

43 t room temperature under conditions where no hydrosilylation is observed for isosteric substrates tha

44 Alkene hydrosilylation is typically performed with Pt catalysts

45 on atom were efficiently prepared using this hydrosilylation methodology.

46 The enantioselectivity of cyclization/hydrosilylation of 1 with disiloxanes and functionalized

47 Selective 1,2-hydrosilylation of 1,3-dienes is a challenging problem i

48 cation to the regio- and stereoselective 1,4-hydrosilylation of 1,3-dienes.

49 he highly stereoselective and regiodivergent hydrosilylation of 1,3-disubstituted allenes have been d

50 mol %) catalyzed the asymmetric cyclization/hydrosilylation of 2 and triethylsilane at -32 degrees C

51 Using diphenylsilane as the appendage point, hydrosilylation of a protected allyl alcohol followed by

52 Complex 5 was used as a precatalyst for the hydrosilylation of a variety of ketones in the presence

53 er-bound N-heterocyclic carbene (NHC) in the hydrosilylation of a variety of structurally diverse ket

54 x [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes.

55 on atom promotes the highly enantioselective hydrosilylation of acetophenone derivatives without assi

56 of them to be highly enantioselective in the hydrosilylation of acetophenone.

57 Compound 2 serves as a precatalyst for the hydrosilylation of acrylates to give alpha-silyl esters

58 lanes with either water or methanol and (ii) hydrosilylation of aldehydes, ketones, and carbon dioxid

59 zes the reductive transfer hydrogenation and hydrosilylation of aldimines through amine-boranes and s

60 on quantum dots (SiQDs) were synthesized via hydrosilylation of aliphatic ketones on hydride-terminat

61 inescent nanocrystalline silicon enables the hydrosilylation of alkenes and alkynes, providing stabil

62 for the Lewis acid-catalyzed trans-selective hydrosilylation of alkenes has been developed.

63 exes are shown to catalyze the high-yielding hydrosilylation of alkenes, dienes, alkynes, aldehydes,

64 e oxindole ring system as well as a directed hydrosilylation of an alkyne to access the ethyl ketone

65 ion of a protected allyl alcohol followed by hydrosilylation of an enamide generates a complex organo

66 which are highly active catalysts for tandem hydrosilylation of aryl ketones and aldehydes followed b

67 rido)silyl ethers that are formed in situ by hydrosilylation of benzophenone or its derivatives under

68 s the formation of triethoxysilyl formate by hydrosilylation of carbon dioxide with triethoxysilane.

69 m, and (e) kinetic analysis of the catalytic hydrosilylation of carbonyl compounds by 1.

70 uation of an unprecedented mechanism for the hydrosilylation of carbonyl compounds catalyzed by (PPh3

71 (C6F5)3] generates catalytic systems for the hydrosilylation of CO2 by R3SiH to afford sequentially t

72 tter provides the first example of catalytic hydrosilylation of CO2 involving a magnesium compound.

73 We report the first selective 1,2-hydrosilylation of conjugated dienes including butadiene

74 The Lewis base-promoted hydrosilylation of cyclic malonates provides a convenien

75 nism for the palladium-catalyzed cyclization/hydrosilylation of dimethyl diallylmalonate (1) with tri

76 mol %) catalyzed the asymmetric cyclization/hydrosilylation of dimethyl diallylmalonate (2) and trie

77 and B(C(6)F(5))(3) catalyzed the cyclization/hydrosilylation of dimethyl dipropargylmalonate (1) and

78 A highly regioselective Rh(I)-catalyzed hydrosilylation of enamides is presented.

79 The catalytic hydrosilylation of highly hindered and functionalized ke

80 omplexes were developed as catalysts for the hydrosilylation of industry-relevant and challenging sil

81 approach involves the relay of Ir-catalyzed hydrosilylation of inexpensive and readily available phe

82 ization of the catalyst for the Rh-catalyzed hydrosilylation of ketones showed that ligand 3 afforded

83 ibe a tungsten catalyst for the solvent-free hydrosilylation of ketones that retains its activity unt

84 detailed mechanistic study of the catalytic hydrosilylation of ketones with the highly active and en

85 mplex is a highly active precatalyst for the hydrosilylation of ketones, exhibiting TOFs of up to 76,

86 activity in the rhodium-catalyzed asymmetric hydrosilylation of ketones.

87 White-light initiated hydrosilylation of nanocrystalline porous silicon was fo

88 thioethers facilitate the platinum-catalyzed hydrosilylation of olefins with phenyldimethylsilane.

89 d the first example of a non-metal-catalyzed hydrosilylation of P-P bonds to produce silylphosphines

90 analogues, Re(N)Cl2(PR3)2 (3), catalyze the hydrosilylation of PhCHO under ambient conditions, with

91 ective for 1,4-dearomative hydroboration and hydrosilylation of pyridines and quinolines.

92 Cyclization/hydrosilylation of substituted 1-vinyl-1-(3-butenyl)cycl

93 Cyclization/hydrosilylation of substituted 3-(3-butenyl)cycloalkenes

94 reusable single-site solid catalysts for the hydrosilylation of terminal olefins.

95 ed to a methyl ketone through intramolecular hydrosilylation of the alkyne and Tamao oxidation of the

96 These materials were prepared via hydrosilylation of the corresponding o-acetoxy arylacety

97 e subsequent reduction steps 2-4, namely the hydrosilylation of the more basic intermediates [1 to H2

98 silylenones are accessed by a regioselective hydrosilylation of the ynone precursor.

99 polymerization of conjugated polar alkenes, hydrosilylation of unactivated alkenes, and hydrodefluor

100 mployed as enantioselective catalyst for the hydrosilylation of various imines.

101 y enantioselective CuH-catalyzed Markovnikov hydrosilylation of vinylarenes and vinyl heterocycles.

102 ive catalyst capable of effecting asymmetric hydrosilylations of aromatic ketones at temperatures bet

103 OCOP = 2,6-[OP(tBu)(2)](2)C(6)H(3)} catalyze hydrosilylations of CO(2).

104 Aromatic ketones undergo hydrosilylation on H-SiQD surfaces at room temperature w

105 Asymmetric cyclization/hydrosilylation/oxidation employing benzhydryldimethylsi

106 Hydrosilylation proceeds through a Pt(II/IV) cycle, and

107 ach of the three legs of the tripod upon the hydrosilylation process accompanying attachment.

108 water solubility via two different methods: hydrosilylation produced 3-aminopropenyl-terminated Si Q

109 atalytic activity of gold nanoparticles in a hydrosilylation reaction is controlled by irradiation wi

110 The light-promoted hydrosilylation reaction is quenched by reagents that qu

111 ented which indicate that the light promoted hydrosilylation reaction is unique to photoluminescent s

112 The hydrosilylation reaction of alpha,beta-unsaturated carbo

113 orms a tandem catalytic alkene isomerization/hydrosilylation reaction that converts multiple isomers

114 gations into the diastereoselectivity of the hydrosilylation reaction through the preparation of impo

115 hat this exciton can be harnessed to drive a hydrosilylation reaction with an alkene; the Si-C bond f

116 atalytic competence of intermediate 2 in the hydrosilylation reaction, (c) 1H and 31P{1H} NMR and ESI

117 Lewis base-mediated intramolecular carbonyl hydrosilylation reaction.

118 d dehydroamino acid hydrogenation and ketone hydrosilylation reactions (eqs 1, 2).

119 e various olefin ring closing metathesis and hydrosilylation reactions in aqueous medium.

120 n by combining the Huisgen cycloaddition and hydrosilylation reactions in one pot, yielding a range o

121 n employed as catalysts for enantioselective hydrosilylation reactions with unprecedented activity an

122 gamma-substituted propylamines in a one-pot hydrosilylation/reductive amination process.

123 new approach for the access to either formal hydrosilylation regioisomer of unsymmetrical aliphatic-s

124 synthesis of alcohols via a trans-selective hydrosilylation/Tamao-Fleming oxidation sequence, comple

125 rt a Co catalyst for anti-Markovnikov alkene hydrosilylation that can be used without added solvent a

126 Alkene hydrosilylation, the addition of a silicon hydride (Si-H

127 In comparative studies of alkyne hydrosilylations, the [NDI]Ni2 catalyst is found to be s

128 ic substitution underwent facile cyclization/hydrosilylation to form silylated 1,2-dialkylidene cyclo

129 Platinum-catalyzed diyne cyclization/hydrosilylation tolerated a range of functional groups i

130 necyclopentanes formed via diyne cyclization/hydrosilylation underwent a range of transformations inc

131 reduction of the carbonyl functionality via hydrosilylation using a copper(I) catalyst bearing the a

132 Hydrosilylation using a reactive center generated from a

133 Mechanistic studies of hydrosilylation using an optically active silane substra

134 as achieved via novel sonochemical activated hydrosilylation, utilizing just a simple ultrasonic bath

135 he same complex is active in internal alkyne hydrosilylation, where absolute selectivity for the tran

136 s illustrated through highly selective trans-hydrosilylations, which enabled the synthesis of a beta-

137 stituted tetralones could be accomplished by hydrosilylation with a chiral titanocene catalyst.

138 The first mirror is chemically modified by hydrosilylation with dodecene before the etching of the

139 lective reduction of CO2 into CH4 via tandem hydrosilylation with mixed main-group organo-Lewis acid