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1 ecies or decay and, in doing so, produce the hydroxyl radical.
2 ulation of intermediates of this pathway and hydroxyl radical.
3 higher particle concentrations produced more hydroxyl radical.
4 were allowed to decay over time induced less hydroxyl radical.
5 ctive at scavenging DPPH-radical rather than hydroxyl radical.
6 e of hydrogen abstraction from isobutanol by hydroxyl radical.
7 still more important than the reaction with hydroxyl radical.
8 chamber for reaction with high levels of the hydroxyl radical.
9 ldiacylglycerol from singlet oxygen and from hydroxyl radical.
10 oxidative cycles normally controlled by the hydroxyl radical.
11 t wetland) that generated singlet oxygen and hydroxyl radical.
12 akage inhibition induced by both peroxyl and hydroxyl radicals.
13 r where it is an important source of daytime hydroxyl radicals.
14 OH oxidation and is stable towards attack by hydroxyl radicals.
15 more efficiently by sulfate radicals than by hydroxyl radicals.
16 romatic rings by substitution of hydrogen by hydroxyl radicals.
17 was attributable to the oxidation of DMF by hydroxyl radicals.
18 lidol (IC50=1.48mM) were more active towards hydroxyl radicals.
19 mediate species involved in the formation of hydroxyl radicals.
20 r reactions of EtFBA with chlorine atoms and hydroxyl radicals.
21 melatonin effectively scavenges highly toxic hydroxyl radicals.
22 nt potential towards peroxyl, superoxide and hydroxyl radicals.
23 etic resonance spectroscopy upon exposure to hydroxyl radicals.
24 ss iron can lead to the formation of harmful hydroxyl radicals.
25 ts with GSH, and react with H2 O2 generating hydroxyl radicals.
26 cesses and changes the budget of atmospheric hydroxyl radicals.
27 tended metal release and production of toxic hydroxyl radicals.
28 photochemical reactor where it reacted with hydroxyl radicals.
29 nding of the mechanism of CYN degradation by hydroxyl radical, a reactive oxygen species that can be
30 Reactions between Fe(II) and H2 O2 generate hydroxyl radical, a strong nonselective oxidant of organ
32 dation of phenols by (3)C* is faster than by hydroxyl radical, although rates depend strongly on pH,
34 undergoes O-O homolytic cleavage to yield a hydroxyl radical and Cu(II)OH rather than heterolytic cl
35 ous acid (HONO) is a photochemical source of hydroxyl radical and nitric oxide in the atmosphere that
38 le which couples the oxidation of ammonia by hydroxyl radical and the reaction of nitric acid with am
40 to TiO2 to produce three- and four-fold more hydroxyl radicals and hydrogen peroxide, respectively, t
41 e of the catalytic decomposition of ozone to hydroxyl radicals and increase of the hydrophilicity of
42 drogen peroxide (H2O2) with the formation of hydroxyl radicals and the consequent oxidation of the pe
43 r the parameters affecting the production of hydroxyl radicals and their spin trapping with DMPO were
44 Apo-transferrin increased the formation of hydroxyl radicals and this related with a faster degrada
45 n, was labeled with electro-Fenton generated hydroxyl radicals and top-down proteomics was used to ve
46 brils can destroy H2O2 and generate damaging hydroxyl radicals and, so, are not necessarily inert end
48 or 1,1-diphenyl-2-picrylhydrazyl (DPPH.) and hydroxyl radical, and substantially more reducing power.
49 processes such as photolysis, reactions with hydroxyl radicals, and aerosol uptake were found to be i
50 xamined as hydrogen donors to DPPH, ABTS and hydroxyl radicals, and as electron donors in the FRAP as
51 four ROS studied (hydrogen peroxide, ozone, hydroxyl radicals, and superoxide anions), only H2O2 and
56 te anions or bisulfite anions) with holes or hydroxyl radicals are the active species for MO photodeg
57 footprinting approach inside cells in which hydroxyl radicals are used to oxidatively modify protein
58 cavengers of the ROS superoxide (O2(*-)) and hydroxyl radical, are preferentially internalized by T l
61 significant role as a precursor for reactive hydroxyl radicals as well as volatile nitrogen oxides in
62 lease from Hb and the subsequent reaction of hydroxyl radicals, as strong oxidizing agents, with CDs
63 contents and scavenging of ABTS(+), DPPH and hydroxyl radicals, as well as metal chelation of the sol
65 ct at an equally fast rate with atrazine (k (hydroxyl radical + atrazine) = 3 x 10(9) M(-1) s(-1)).
66 ed to show that the backbone is resistant to hydroxyl radical attack and that degradation occurs sole
67 xidation and enters the cytoplasm inflicting hydroxyl radical attack on intracellular proteins and DN
69 osamines and N-nitramines, and with ozone or hydroxyl radical-based advanced oxidation processes (AOP
70 ere we describe footprinting of Abeta1-42 by hydroxyl radical-based fast photochemical oxidation of p
72 ence is presented for in vitro generation of hydroxyl radicals because of redox cycling of environmen
74 ation and steady-state concentrations of the hydroxyl radical by cloud chemistry models and for organ
76 Further research on processes related to the hydroxyl radical chemistry in the environmental compartm
77 capacity of the air by affecting atmospheric hydroxyl radical chemistry, whereas atmospheric mercury
78 X-ray crystallography and NMR spectroscopy, hydroxyl radical cleavage data, statistical analysis and
82 idth, propeller twist, roll, helix twist and hydroxyl radical cleavage predictions for the entire gen
85 perimental data exclude the participation of hydroxyl radicals derived from Fenton-like reaction mech
88 nd DOM isolates revealed that reactions with hydroxyl radicals dominated the transformation of tested
89 en UV spectrophotometric response, effective hydroxyl radical dose delivered, and peptide and protein
90 o compare HRPF data from sample to sample, a hydroxyl radical dosimeter is needed that can measure th
91 and superoxide dismutase (SOD) prevented the hydroxyl radical driven-degradation of beta-glucan induc
92 d on activity of DPPH radical, ABTS radical, hydroxyl radical, Fe(2+) chelating ability and reducing
94 AG-binding determinants of CCL7, an unbiased hydroxyl radical footprinting approach was employed, fol
97 p aldehyde, inosine-for-guanine replacement, hydroxyl radical footprinting, and LC-MS/MS were consist
98 f small angle X-ray scattering (SAXS), X-ray hydroxyl radical footprinting, circular dichroism, and H
101 radicals were regionally more important than hydroxyl radicals for alkane oxidation and were also imp
103 ectro-Fenton reaction as a means to generate hydroxyl radicals for structural footprinting mass spect
105 exist for generating the key reagent (i.e., hydroxyl radicals) for these measurements; however, thes
106 complex which might yield Fe(IV) instead of hydroxyl radical formation as suggested in literature.
107 ammatory reactions since E. coli can inhibit hydroxyl radical formation by eliminating substrates of
111 ) water have shown that approximately 15% of hydroxyl radicals formed as a result of redox cycling.
112 ticles (Fe3O4 MNPs) to the medium to produce hydroxyl radicals from H2O2, owing to the peroxidase-lik
113 ture (295 +/- 3K) kinetics of oxidation with hydroxyl radicals from light and dark sources yield an a
114 se results demonstrate that plasma-generated hydroxyl radicals from water can be used to map protein
115 omolecules), that generates micros bursts of hydroxyl radicals from water, to measure changes in prot
117 (RP-MS), first introduced in 1999, utilizes hydroxyl radicals generated directly within aqueous solu
118 degraded in aqueous systems in presence of a hydroxyl radical generating system such as ascorbic/iron
120 in, after accounting for both differences in hydroxyl radical generation and nonanalyte radical consu
121 reas ovotransferrin completely inhibited the hydroxyl radical generation by a system containing ascor
123 showed that Ag NPs were not able to catalyse hydroxyl radical generation, but that they directly oxid
124 NPs under SSL exposure could be explained by hydroxyl radical generation, the enhanced toxicity of Ag
125 gen abstraction reactions from isobutanol by hydroxyl radical have been calculated using multi-path v
126 so suggested that SO4(*-) was transformed to hydroxyl radical (HO(*)) and carbonate radical (CO3(*-))
129 (2)), is typically assumed to be a source of hydroxyl radical (HO(*)) in natural systems, however, fo
130 nned a range of reactivity with UV light and hydroxyl radical (HO(*)) in three different types of sou
131 ersulfate into sulfate radical (SO4(*-)) and hydroxyl radical (HO(*)) over time scales of several wee
132 o acids (FAA) against Fenton system-mediated hydroxyl radical (HO(*)) production in aqueous solution,
134 ed state dissolved organic matter ((3)DOM*), hydroxyl radical (HO(*)), and singlet oxygen ((1)O2).
137 dation process that produces highly reactive hydroxyl radicals (HO(*)) and chlorine radicals (Cl(*))
140 advanced oxidation processes (AOPs) produce hydroxyl radicals (HO*) which can completely oxidize ele
141 ased mixing ratio of hydroperoxyl radical to hydroxyl radical ([HO2]/[OH]) and increased [NO2]/[NO] w
142 10(3) L mgC(-1) s(-1) (mgC = mg carbon); k (hydroxyl radical + humic acids) = 1.4 x 10(4) L mgC(-1)
143 ment of the contributions of singlet oxygen, hydroxyl radical, hydrogen peroxide, and triplet dissolv
144 photogeneration of equimolar superoxide and hydroxyl radical in desiccated and aqueous soils, respec
145 We provide an extensive view on the role of hydroxyl radical in different environmental compartments
147 and reproducible generation system of "dark" hydroxyl radical in the gas phase was developed and opti
148 d retinal pigmented epithelial cells against hydroxyl radicals in a dose-dependent manner by maintain
150 y as an easily accessible tool for producing hydroxyl radicals in order to oxidize a range of intact
151 NIA (FER), is required for the production of hydroxyl radicals in the female gametophyte, which cause
153 hophorothioated DNA reacted to both H2O2 and hydroxyl radicals in vivo, and protected genomic DNA as
155 secondary organic aerosol (SOA) derived from hydroxyl radical-initiated oxidation of toluene, p-xylen
156 iled DNA strand from scission by peroxyl and hydroxyl radicals into the nicked circular form was also
158 lysis of voltammograms demonstrated that the hydroxyl radical is a principal contributor to the volta
160 ely, these results suggest that formation of hydroxyl radicals is partially responsible for cell deat
161 (kO3) (<0.1-7.9 x 10(3) M(-1) s(-1)) or with hydroxyl radicals (k(*)OH) (0.9 x 10(9) - 6.5 x 10(9) M(
164 stress to E. coli occurred via formation of hydroxyl radicals leading to lipid peroxidation as the p
165 potential, good scavenging capacity against hydroxyl radicals, low cytotoxicity, and high cytoprotec
166 ferrin and ovotransferrin; could prevent the hydroxyl radical mediated degradation of beta-glucan.
167 the effect the iron(II) concentration on the hydroxyl radical-mediated degradation of beta-glucan and
168 of archaeal RNase P, we used a site-specific hydroxyl radical-mediated footprinting strategy to pinpo
169 copies that bound the RPR and site-specific hydroxyl radical-mediated footprinting to localize the K
170 ess (e.g., hydrogen peroxide, superoxide and hydroxyl radicals, nitric oxide, ascorbic acid, and glut
172 ate coefficient for the reaction between the hydroxyl radical (OH) and methanol--one of the most abun
173 el air through a PAM reactor over integrated hydroxyl radical (OH) exposures ranging from approximate
177 At BAO, the reactivity of VOCs with the hydroxyl radical (OH) was dominated by C(2)-C(6) alkanes
178 nic aerosol (SOA) via aqueous reactions with hydroxyl radical (OH), singlet oxygen ((1)O2*), and exci
180 pproximately 60% to the primary formation of hydroxyl radical (OH), which is a key oxidant in the deg
182 of nitroblue tetrazolium into formazan, and hydroxyl radicals (OH( *)) were detected by the hydroxyl
184 is work, we have elucidated the mechanism of hydroxyl radicals (OH(*)) generation and its life time m
189 be competitive with multiphase oxidation by hydroxyl radicals (OH) and ozonolysis of gaseous alpha-t
192 sphere is initiated primarily by addition of hydroxyl radicals (OH) to C4 or C1 in a ratio 0.57 +/- 0
193 phase oxidation of cis-pinonic acid (CPA) by hydroxyl radicals (OH) was studied using a relative rate
196 ap, 5,5-dimethyl-1-pyrroline-N-oxide (DMPO), hydroxyl radical ((*)OH) and sulfate radical anion (SO4(
197 n rates, illustrating a possible role of the hydroxyl radical ((*)OH) in the anodic formation of sulf
201 nsitizers from hydroxylating species such as hydroxyl radical ((*)OH) present in dissolved organic ma
202 micropollutants according to their ozone and hydroxyl radical ((*)OH) rate constants and normalizing
203 the UV/H2O2 AOP via UV direct photolysis and hydroxyl radical ((*)OH) reaction, so that DBPs most lik
204 dicals are recognized to form as products of hydroxyl radical ((*)OH) scavenging by halides, their co
205 -MWCNTs generated singlet oxygen ((1)O2) and hydroxyl radical ((*)OH) under UVA light, which exhibite
206 els, forming: (1) nitrogen dioxide (NO2) and hydroxyl radical ((*)OH), (2) nitrite (NO2(-)) and oxyge
207 ived reactive intermediates (RIs), including hydroxyl radical ((*)OH), singlet oxygen ((1)O2) and sup
210 generation of reactive oxygen species (ROS) [hydroxyl radicals ((*)OH) and hydrogen peroxide (H2O2)]
212 dence of the photochemical production of the hydroxyl radical (*OH) from dissolved organic matter (DO
214 Exposure of the protein to a brief pulse of hydroxyl radical (.OH) at different time points during f
215 ctivity of the impregnated solids to produce hydroxyl radical (.OH) from H2O2 decomposition was evalu
216 s evaluated by (DPPH.), superoxide (O2(.-)), hydroxyl radicals (.OH) and hypochlorous acid (HOCl) ass
217 side, the impact of the reactivity of indoor hydroxyl radicals on health and well-being is another em
218 found able to scavenge superoxide anion and hydroxyl radicals, organic nitro-radicals (ABTS, DPPH) a
219 l precursor/product mix formed after aqueous hydroxyl radical oxidation and droplet evaporation under
220 rganic aerosol (SOA) have largely focused on hydroxyl radical oxidation, but here we show that triple
221 er of atmospheric oxidants, most notably the hydroxyl radical, ozone, the nitrate radical (NO3) and n
222 nt contributor to RNA strand scission by the hydroxyl radical, particularly under anaerobic condition
223 n from a variety of oxidants including H2O2, hydroxyl radical, peroxynitrite, hypochlorous acid, hypo
225 ption, sucralose makes a suitable full scale hydroxyl radical probe fit even for drinking water treat
226 nature, sucralose can be used as an in situ hydroxyl radical probe for UV-based and ozone-based AOP
227 terium exchange coupled to NMR spectroscopy, hydroxyl radical probing detected by mass spectrometry,
235 n rate constant, consistent with the reduced hydroxyl radical production and enhanced adsorption.
237 ous-phase oxidation reaction: iron-catalyzed hydroxyl radical production from hydrogen peroxide (Fent
239 oeostasis can induce cellular damage through hydroxyl radical production, which can cause the oxidati
241 lows mass spectrometry-based high-resolution hydroxyl radical protein footprinting (HR-HRPF) measurem
243 r dissociation-based high spatial resolution hydroxyl radical protein footprinting to identify two se
244 r dissociation-based high spatial resolution hydroxyl radical protein footprinting, which shows great
245 Bimolecular reaction rate constants with hydroxyl radicals ranged from (2.04 +/- 0.37) x 10(9) to
248 unted for 17 +/- 19% of the regional kinetic hydroxyl radical reactivity of nonbiogenic VOCs suggesti
249 dical, formed in the oxidation of ammonia by hydroxyl radical, reacts with nitric acid regenerating a
250 oxidation by active chlorine, as well as by hydroxyl radicals resulting from its reaction with iron
251 II)-concentrations, absence vs presence of a hydroxyl radical scavenger (dimethyl sulfoxide, DMSO), a
254 cies levels (nitric oxide, superoxide anion, hydroxyl radical scavenger capacity) and cellular antiox
256 trolysine yields decreased in the absence of hydroxyl radical scavengers, suggesting that future rese
257 icryl-hydrazyl (DPPH-RS), peroxyl (PRS), and hydroxyl radical scavenging (HRS) and reducing power (RP
258 ities with GSH and/or carnosine by examining hydroxyl radical scavenging activity by electron spin re
261 age air temperature (r=0.705, p<0.01), while hydroxyl radical scavenging capacity had a negative corr
262 l as determined by ABTS and DPPH assays, and hydroxyl radical scavenging capacity, reducing power as
264 ous Ion-chelating Ability, 221.46 mug mL(-1) Hydroxyl radical scavenging, 279.02 mug mL(-1) Peroxyl r
265 phenolics, flavonoids, ABTS free radical and hydroxyl radicals scavenging and anti-inflammatory activ
267 d similar antioxidant properties, except for hydroxyl radical-scavenging activity, higher on green te
268 y-state concentrations of carbonate radical, hydroxyl radical, singlet oxygen, and triplet-excited st
271 of 2c, 2f, and 2p against peroxyl radicals, hydroxyl radicals, superoxide anion, singlet oxygen, and
273 roduced higher amounts of singlet oxygen and hydroxyl radicals than free MB, possibly due to better d
276 s contrasts with the behavior of ROS such as hydroxyl radicals that selectively abstract allylic and/
277 ltraviolet (UV) radiation (lambda=254nm) and hydroxyl radicals, the intensity of the emitted photolum
278 in particular have the potential to generate hydroxyl radicals, the most hazardous among all ROS.
279 ples, a previously developed assay that uses hydroxyl radical to oxidize precursors to perfluorinated
282 of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols a
284 that the molecules investigated reacted with hydroxyl radical via both HAT and SPLET in the solvents
285 ated Fe(II) represent an important source of hydroxyl radical via the Fenton reaction in cloudwater.
287 or loss of parent molecule via reaction with hydroxyl radical was determined to be (1.56 +/- 0.03).10
288 activity (RSA) of CS against ABTS, DPPH and hydroxyl radical was noted with EC50 values 19.1, 26.4 a
292 on experiments suggested that superoxide and hydroxyl radicals were together responsible for the ssaB
293 ce of nitrate, MON was primarily degraded by hydroxyl radicals, whereas SAL showed reactivity toward
294 f atmospheric oxidants such as ozone and the hydroxyl radical, which controls the self-cleansing capa
295 a-glucan in solution causes the formation of hydroxyl radical, which further oxidises the polysacchar
297 de superoxide, hydrogen peroxide (H2O2), and hydroxyl radicals, whose killing is amplified by iron vi
298 n to the atmosphere followed by oxidation by hydroxyl radical with a predicted lifetime of 3-20 days.
299 r to the rate constants for the reactions of hydroxyl radical with either ammonia or nitric acid.
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