コーパス検索結果 (1語後でソート)
通し番号をクリックするとPubMedの該当ページを表示します
1 bserved for the N-O...H-C interaction (13CH3 hyperfine, a/h=0.66 MHz) in the CH3CN/TEMPO system, wher
2 5)N(-)) and extracted accurate values of the hyperfine and quadrupole couplings of both CN(-) and adt
3 unlabeled forms of the hydrazido ligand, the hyperfine and quadrupole parameters of the -N-NH2 moiety
5 spectroscopy, including relaxation-filtered hyperfine and single-matched resonance transfer (SMART)
10 hown to be fast on the time scale of the 14N hyperfine clock ( approximately 220 ns), remains fast on
15 ein, it is demonstrated that (203)Tl/(205)Tl hyperfine "clocks" are greatly superior to those provide
16 osition, wherein (1)H and (14)N serve as the hyperfine "clocks", and in arrays containing site-specif
18 rly equal population, one nearly axial, with hyperfine constant A parallel = 98 x 10(-4) cm(-1), and
19 experiments allowed the determination of the hyperfine constants ((17)O)A(z) = 10 MHz for [Fe(IV)H(3)
20 brid DFT calculations providing the separate hyperfine contributions of all distinct Mn-O-P and Fe-O-
25 FT calculations demonstrate that the lithium hyperfine coupling A((7)Li) in [Li(+){(+/-)-1(*-)}] is v
27 m which (17)O ENDOR showed a smaller 3.8 MHz hyperfine coupling and possible quadrupole splittings, i
28 using density functional theory of the (14)N hyperfine coupling and quadrupole coupling constants rep
29 relaxation and longitudinal DeltaHFC-Deltag (hyperfine coupling anisotropy--g-tensor anisotropy) cros
30 y large gzz value of 2.44 and a small copper hyperfine coupling Azz of 40 x 10(-4) cm(-1) (120 MHz).
31 gely a type 1 copper protein at low pH (with hyperfine coupling constant A( parallel) = 54 x 10(-4) c
33 isotropic signal with a g value of 2.003 and hyperfine coupling constant of 8 x 10(-4) cm(-1) to the
35 t polarity constant E(T)(N) and the nitrogen hyperfine coupling constant of the released nitroxide a(
36 Assuming a free-ion value for the Pu(4+) hyperfine coupling constant, we estimated a bare (239)ga
37 indicate that electron spin resonance (ESR) hyperfine coupling constants (aH values) computed at the
41 ons of molecular spin-orbitals (MSOs) to the hyperfine coupling constants and the spatial distributio
43 C isotope shifts in the IR spectra and (13)C hyperfine coupling constants in the EPR spectra exhibit
44 pectroscopy revealed a 9-line spectrum, with hyperfine coupling constants indicative of four almost m
45 n of the cluster is highly anisotropic, with hyperfine coupling constants of 9.1 and 2 x 33.3 G for t
46 stretching frequency and the imidazole (14)N hyperfine coupling constants show a good correlation wit
47 The Sc-based hyperfine structure with large hyperfine coupling constants shows that both oxidation a
48 Following DFT calculations, the predicted hyperfine coupling constants were used to simulate the E
49 in the ligand moiety and the (13)C isotropic hyperfine coupling constants, Aiso((13)C), for the indiv
50 agreement with the observed g values, ligand hyperfine coupling constants, and FTIR stretching freque
51 ance for predicting NMR chemical shifts, EPR hyperfine coupling constants, and low-energy transitions
52 ble-temperature magnetic susceptibility, EPR hyperfine coupling constants, and the results of X-ray c
53 et constraints on the relative amplitudes of hyperfine coupling constants, both for protons at chemic
54 ding affinity, perturb and diminish the 14NO hyperfine coupling determined by ENDOR (electron nuclear
57 ) substitution and that the isotropic (95)Mo hyperfine coupling in E(4) is a(iso) approximately 4 MHz
59 Here we report the observation of a (57)Fe hyperfine coupling interaction with the paramagnetic sig
60 Furthermore, a single exchangeable proton hyperfine coupling is resolved, both by comparing the HY
61 rted again by EPR and ENDOR results (a (13)C hyperfine coupling of approximately 7 MHz), as well as l
64 se EPR data reveal an exchangeable deuterium hyperfine coupling of strength |T| = 0.7 MHz, but no str
65 sotope incorporation and in the (17)O mu-oxo hyperfine coupling of the di-mu-oxo di-Mn(III,IV) bipyri
67 ng from a manifold of states produced by the hyperfine coupling of the S = (1/2) electron spin and I
68 ganic semiconductors have been attributed to hyperfine coupling of the spins of the charge carriers a
74 n going from high pH to low pH, a seven-line hyperfine coupling pattern associated with complete delo
77 measured across the EPR line shape, showed a hyperfine coupling range from 36 to 44 MHz for 14NO and
80 ermediate with a g = 2 EPR signal that shows hyperfine coupling to both 55Mn and 57Fe accumulates alm
81 ic Cr(III), EPR (HYSCORE) spectroscopy shows hyperfine coupling to nitrogen only when the amide precu
82 amid relative to the other with strong super hyperfine coupling to one PMe3 and weak SHFC to the othe
84 tributed over the two iron atoms with strong hyperfine coupling to the bridging hydride (A(iso) = -75
85 ation, while the observation of an isotropic hyperfine coupling to the cation by ENDOR measurements e
88 enters, as indicated by the magnitude of the hyperfine coupling to the phosphine ligands trans to the
89 intermediate having a g-value of 2.0025 with hyperfine coupling to two spin 1/2 nuclei, each with a s
90 ar characteristics, i.e. a large anisotropic hyperfine coupling together with an almost zero isotropi
91 tion and pi back-donation, whereas the (13)C hyperfine coupling was rationalized by incongruent alpha
92 lope modulations of the Mn(2+) signal due to hyperfine coupling with protons outside the quantum dots
93 howed a (17)O hyperfine signal with a 11 MHz hyperfine coupling, tentatively assigned as mu-oxo-(17)O
97 d REcovery (PESTRE) protocol for determining hyperfine-coupling signs; and Raw-DATA (RD)-PESTRE, a PE
100 accessible spin states, and (55)Mn isotropic hyperfine couplings are computed with quantum chemical m
102 C owing to the fact that the (203)Tl/(205)Tl hyperfine couplings are much larger (15-25 G) than those
104 tions of these three substrates by measuring hyperfine couplings between substrate deuterium atoms an
106 n polarization pattern and pronounced methyl hyperfine couplings characteristic of asymmetric H-bondi
109 determination of the signed isotropic (57)Fe hyperfine couplings for five of the seven iron sites of
110 mplementary similarity between the isotropic hyperfine couplings for the bridging hydrides in 3 and E
111 ble information about (1)H, (15)N, and (13)C hyperfine couplings for the Q(H) site and to describe th
113 mponents from two anisotropic beta-2'-F-atom hyperfine couplings identify the C3'* formation in one-e
116 ith phylloquinone, but the absence of methyl hyperfine couplings in the quinone contribution to the P
117 or the study of the (13)C methyl and methoxy hyperfine couplings in the semiquinone generated in the
118 mparison between calculated and experimental hyperfine couplings is performed where good agreement is
120 he TEMPO/CH3CONH2 system yield 13CH3 and 15N hyperfine couplings of a/h=0.16 and -0.50 MHz, respectiv
121 denced by (1)H, (2)H, and (13)C ENDOR, where hyperfine couplings of approximately 6 MHz for (13)C and
125 parameter D were observed, while the proton hyperfine couplings show no change in the extent of trip
126 s employed to clearly discriminate the (17)O hyperfine couplings that overlap with (14)N (I = 1) sign
127 samples (35 GHz, 77 K) showed several H-bond hyperfine couplings that were similar to those for QB-*
129 nuclear double resonance data reveal similar hyperfine couplings to those of other Mn(IV) species, in
131 plitting parameter D and much smaller proton hyperfine couplings with respect to the monomeric unit,
133 owed us for the first time to determine weak hyperfine couplings with the side-chain nitrogens from a
134 with auxotrophs was used to characterize the hyperfine couplings with the side-chain nitrogens from r
135 provide quantitative characteristics of the hyperfine couplings with these nitrogens, which can be u
138 tate delocalization can be obtained from the hyperfine couplings, while interpretation of the zero-fi
145 ctra with partially resolved lines caused by hyperfine couplings; the differences between the couplin
147 (85)Rb) according to the placement of their hyperfine energy states in a two-dimensional spectrum.
148 spin probe exhibits a splitting of the outer hyperfine extrema (2A'(zz)) significantly smaller than t
149 a high-field EPR spectrum with well-resolved hyperfine features devoid of zero-field splitting, chara
150 rise to characteristic (14)NO and (15)NO EPR hyperfine features indicating NO involvement, and enrich
151 nterstitial) can be assigned on the basis of hyperfine (Fermi contact) shifts and quadrupolar nutatio
152 these solutions which serves to modulate the hyperfine (Fermi-contact) interaction with nitrogen nucl
153 exhibits at 4.2 K a large, positive magnetic hyperfine field, Bint = +68.1 T, and an effective g valu
154 acteristics that affect the electron-nuclear hyperfine field, the metallic shift, and magnetic order.
156 spin-singlet and spin-triplet states due to hyperfine fields is suppressed by microwave driving.
159 nless nuclear, the materials have negligible hyperfine interaction (HFI) and the same intrinsic SOC,
162 der a small magnetic field due to their weak hyperfine interaction and slight difference of g-factor
164 However, this advantage is offset by the hyperfine interaction between the electron spin and the
165 n echo envelope modulation (ESEEM) from (2)H-hyperfine interaction with D2O is determined for stearic
166 MCR red2a state exhibits a very large proton hyperfine interaction with principal values A((1)H) = [-
167 he effective magnetic noise arising from the hyperfine interaction with uncontrolled nuclear spins in
169 ity in the 4f shell, manifest in the (171)Yb hyperfine interaction, and (iv) the principal values of
170 ulti-spin-qubit state under the influence of hyperfine interaction, and clearly demonstrate that the
171 r, as measured via the isotropic NN nitrogen hyperfine interaction, and the strength of the D --> A i
172 ho techniques have been used to mitigate the hyperfine interaction, but completely cancelling the eff
173 ted by the lattice nuclear spins through the hyperfine interaction, while the dynamics of the single
179 These signals are broadened significantly by hyperfine interactions (A((17)O) approximately 180 MHz).
180 ) 2.00592, and g(z) 2.00230 and with altered hyperfine interactions (apparent triplet collapsed to a
181 coordinates predict experimentally observed hyperfine interactions and a shift in g values away from
183 We investigate the effect of variations in hyperfine interactions between different copies of simpl
186 observe that the size of the spin-orbit and hyperfine interactions depends on the magnitude and dire
189 es of Hg lamp experiments is not a result of hyperfine interactions making predissociation of (17)O c
190 tetrapyrrolic arrays entails analysis of the hyperfine interactions observed in the electron paramagn
191 etrapyrrolic array relies on analysis of the hyperfine interactions observed in the EPR spectrum of t
194 omparison of the experimental (1)H and (17)O hyperfine interactions with those calculated using DFT h
195 -spin density at ligand nuclei (via the weak hyperfine interactions) in molecular thorium(III) and ur
196 e meso-13C label provides a "clock" (via the hyperfine interactions) that allows investigation of a t
197 To probe these protein-derived carboxylate hyperfine interactions, which give direct bonding inform
202 These observations suggest that each pair of hyperfine levels hosted within [V(C8S8)3](2-) are candid
203 d by the EPR spectra, which exhibit multiple hyperfine lines due to the coupling of the unpaired elec
206 nents prevent the specific identification of hyperfine molecular information of different substances,
207 l small paramagnetic complexes combine large hyperfine NMR shifts with large magnetic anisotropies.
208 ectronic structure driving the variations in hyperfine parameters across the range of materials.
209 itrite, and an analysis of the resulting EPR hyperfine parameters confirms that mARC is remarkably si
211 upporting evidence for the assignment of the hyperfine parameters to Fe(II) bound to basal planes and
213 he low pH form and reveal that its four-line hyperfine pattern results from the large EPR spectral ef
219 gned to LiMn6-TM(tet) sites, specifically, a hyperfine shift related to a small fraction of re-entran
220 e required to reproduce the experimental NMR hyperfine shift results, the best theory vs experiment p
221 Co(II)-Bc in DMSO shows relatively sharper hyperfine-shifted (1)H NMR signals compared with the spe
223 o carry out comprehensive assignments of the hyperfine-shifted (13)C and (15)N signals of the rubredo
224 n as a quantum register and demonstrate that hyperfine-shifted resonances can be separated upon prope
226 on the basis of the correlations between Li hyperfine shifts and Li local structures, and two differ
227 stal helices, together with the magnitude of hyperfine shifts and paramagnetic relaxation, establish
228 so find interesting correlations between the hyperfine shifts and the bond and ring critical point pr
229 as well as the mean low-field bias of methyl hyperfine shifts and their paramagnetic relaxivity relat
231 olecules theory, in addition to finding that hyperfine shifts can be well-predicted by using an empir
232 is indicates that the pattern of heme methyl hyperfine shifts cannot be used alone to determine the i
233 st quantum chemical investigations of 1H NMR hyperfine shifts in the blue copper proteins (BCPs): ami
234 )C and (1)H nuclear magnetic resonance (NMR) hyperfine shifts of heme aided by density functional the
235 pretation of the pattern of substrate methyl hyperfine shifts, however, indicates substrate rotations
236 ents to provide both the H-bond strength and hyperfine shifts, the latter of which were used to quant
238 ltihour (17)O exchange, which showed a (17)O hyperfine signal with a 11 MHz hyperfine coupling, tenta
241 an S = (1)/(2) EPR signal exhibiting (59)Co hyperfine splitting (A = 24 G) typical of a low-spin Co(
242 siological range from 6 to 8, the phosphorus hyperfine splitting acting as a convenient and highly se
246 calculated from the orientational-dependent hyperfine splitting in the EPR spectra, and (3) EPR spec
248 susceptibility data and by the appearance of hyperfine splitting in the zero-field (5)(7)Fe Mossbauer
251 orientation of the principal axes of the 13C hyperfine splitting tensor shows that the long axis of t
252 d exchange interactions as well as the 1-13C hyperfine splitting tensor were analyzed via spectral si
253 oublet radical signal with an 11 G principal hyperfine splitting was detected within the first millis
254 bismuth, has a large zero-field ground state hyperfine splitting, comparable to that of rubidium, upo
256 pling interaction of TN biradicals, their g, hyperfine-splitting, and zero-field-splitting interactio
257 e peptide can be easily calculated using the hyperfine splittings gleaned from the orientational depe
258 k absorption near 800 nm and narrow parallel hyperfine splittings in electron paramagnetic resonance
259 he so-called specific difference between the hyperfine splittings in hydrogen-like and lithium-like b
262 equation was developed for relating nuclear hyperfine splittings to electron spin distributions in f
263 rong pH-induced changes to the corresponding hyperfine splittings, Delta hfs approximately (300-1000)
264 esults is the use of different pairs of 9Be+ hyperfine states for robust qubit storage, readout, and
268 ESR spectra of the ion radicals have a rich hyperfine structure caused by two pairs of equivalent Sc
270 ve been developed that enable studies of the hyperfine structure of antihydrogen-the antimatter count
274 eable proton hyperfine couplings resolved in hyperfine sublevel correlation (HYSCORE) spectra of the
275 lectron-nuclear double resonance (ENDOR) and hyperfine sublevel correlation (HYSCORE) spectroscopies
276 on spin echo envelope modulation (ESEEM) and hyperfine sublevel correlation (HYSCORE) spectroscopy cl
280 n a bidentate fashion, which is confirmed by Hyperfine Sublevel Correlation (HYSCORE) spectroscopy.
281 ectron-nuclear double resonance (ENDOR), and hyperfine sublevel correlation (HYSCORE)) electron param
282 ve electron paramagnetic resonance (CW-EPR), hyperfine sublevel correlation (HYSCORE), and IR fingerp
283 UV-visible, electron paramagnetic resonance, hyperfine sublevel correlation (HYSCORE), and Mossbauer
285 We utilize high-resolution two-dimensional hyperfine sublevel correlation spectroscopy to directly
287 or ultracold atoms through the 'dressing' of hyperfine sublevels of the atomic ground state, where th
288 rincipal values and orientations of both the hyperfine tensor ((14)N, A(iso) = -6.25 MHz, T = -0.94 M
289 ear spin coupled to the FeMo cofactor with a hyperfine tensor A = [0.9, 1.4, 0.45] MHz establishing t
290 or two exchangeable protons with anisotropic hyperfine tensor components, T, both in the range 4.6-5.
291 ition, (19)F chemical shift measurements and hyperfine tensor measurements of biocatalyst formulation
292 bridge hyperfine tensor to the (14)N((15)N) hyperfine tensor of the D1-His332 ligand suggests that t
293 entation of the putative (17)O mu-oxo bridge hyperfine tensor to the (14)N((15)N) hyperfine tensor of
294 fferent spin density distributions and g and hyperfine tensors for different protonation states.
296 roscopy, the g tensor of the radical and the hyperfine tensors of several N and H nuclei in the radic
297 ata allow a detailed analysis of the dipolar hyperfine tensors of two of the four symmetry distinct p
298 is of the zero-field splittings and magnetic hyperfine tensors suggests that the dihedral O horizonta
300 easurements were performed on a ground-state hyperfine transition of europium ion dopants in yttrium
WebLSDに未収録の専門用語(用法)は "新規対訳" から投稿できます。