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1 the charge on Cd(2+) to form an extractable ion pair.
2 ce, rather than bond rotation in an intimate ion pair.
3 ton is unimolecularly transferred within the ion pair.
4 ascribed to the dissociation of the intimate ion pair.
5 with a chiral Bronsted acid to form a chiral ion pair.
6 can explore and thus its capacity to form an ion pair.
7 the p-Xy spacer to give the p-Xy(+*)-ExV(+*) ion pair.
8 = (1.5 +/- 0.2) x 10(7) s(-1), in the second ion pair.
9 ation of methanesulfonate ion (MSA(-))H3O(+) ion pair.
10 e-organization of ground-state precursors in ion pairs.
11 ents through different types of coordination ion pairs.
12 ptors and as extractants for both anions and ion pairs.
13 -contact ion pairs and the solvent-separated ion pairs.
14 these metal ions (silver or copper) or metal ion pairs.
15 henomenon that occurs in novel Er(3+)-Tm(3+) ion pairs.
16 l carboxylate or phosphonate complexes or by ion pairs.
17 cts as well as specific interactions between ion pairs.
18 he result of loose or tight cation-dienolate ion pairs.
19 ed to nanoparticles made without hydrophobic ion pairs.
20 single-ion basis, SPICA relies on analyzing ion-pairs.
21 ociation constant and free energy change for ion pairing.
22 lize the surface during ligand stripping via ion pairing.
23 aused by ineffective charge shielding during ion pairing.
25 charged) cell metabolites, which form stable ion-pairs (1+ charged) with dicationic compounds (2+ cha
30 ed into an organic solvent via the use of an ion pairing agent, followed by a back extraction in D2O
32 formation of a thiolate-alkylammonium tight ion pair and activation of the enone electrophile by a h
33 e additional insights into the nature of the ion pair and reveal a range of important secondary inter
35 initial state of quenching, viz., the loose ion pair and the exciplex, based on the time-resolved ma
37 d has the potential to probe the geometry of ion pairing and allows the reduction potentials of molec
39 oromethane indicated the presence of contact ion pairs and provided insights into their structures an
42 ncovalent interactions (namely, hydrophobic, ion pairing, and metal-ligand coordination) can be graft
43 nt interactions, including hydrogen bonding, ion pairing, and pi stacking, have become mainstays of c
44 r, pi-pi interactions, chromophore twisting, ion pairing, and self-assembly are systematically addres
45 erred in an outer-sphere manner to afford an ion-pair, and the corresponding transition state is both
47 e nanoparticle consists of a large number of ion pairs ( approximately 60,000) in each hydrophobic co
48 etect that both the exciplex and the radical ion pair are formed during the initial quenching stage.
53 The method depends on the formation of the ion pair associate between 3-nitrotyrosine and the optic
54 The method depends on the formation of the ion pair associate between histidine and the nano optica
60 he protonation of DNB(2-), most likely by an ion pair between DNB(2-) and BMIm(+), which has been pro
61 species is the electrostatically stabilized ion pair between the TOTA(+) cation and sandwich complex
62 molecular dynamics simulations suggest that ion pairing between the ligand shell of the QD and NR4(+
63 n pathway, greatly affecting the strength of ion pairing between the oxidized photocatalyst and the b
65 )), we have investigated the dynamics of the ion pairs between lysine side-chain NH3(+) amino groups
66 ent study of the preferred structures of the ion pairs between tetrabutylammonium and 22 common inorg
67 amase hydrolysis via the formation of unique ion-pairs between their carboxylate anions and cationic
68 we combine experiment and theory to quantify ion-pair binding and to separate allostery from electros
69 C.NaX + MC, which is associated with contact ion-pair binding of NaI (alpha = 1300, DeltaGalpha = -18
70 Nanoporous organic networks which include ion pairs bound in a covalent manner are of special impo
71 hanging selectivity is not solely to enforce ion pairing, but rather that interactions between the io
72 most consistent with a model wherein the non-ion-paired C1(2+*) excited state traps the halide and pr
73 le result is that a 1:1 iodide:excited-state ion-pair, [C1(2+), I(-)](+*), underwent diffusional elec
74 o in DME afforded a mixture of the separated ion pair [(cAACMe )2 Si:(.) ](+) I(-) (1), which feature
77 pments in the burgeoning field of asymmetric ion-pairing catalysis with an emphasis on the insights t
82 Two chromatography columns were tested: (i) ion-pair chromatography and (ii) ion exchange chromatogr
83 The reported UHPLC-MS/MS approach employes ion-pairing chromatography to separate CoA-metabolites c
86 ded single crystals of the solvent separated ion pair complex [Li(THF)4] [Mo2(Me)2(mu-Me){mu-HC(NDipp
87 receptor forms a charge-separated polymeric ion pair complex with K(+) and HPO4(2-) via formation of
88 With TBAHSO4 the receptor forms a contact ion pair complex, where both the TBA(+) and SO4(2-) grou
89 ng, but rather that interactions between the ion paired complex and the solvent also contribute to De
90 of a counterion to a charged catalyst in an ion paired complex gives rise to strong electrostatic in
91 ide catalyst, only a small distortion of the ion-pair complex is required to achieve its geometry in
92 it[7]uril, and they show dissociation of the ion-pair complex upon addition of cucurbit[7]uril and re
93 e salts by switching the geometry of the 1:1 ion-paired complex from receptor-separated to close-cont
94 n the fact that formation of the competitive ion-pairing complex of Sb(III) and Sb(V) with Victoria P
95 erimental and theoretical data reveal mainly ion pair complexes providing strong hydrogen bonds with
98 were done by NMR for the cation-carboxylate ion-pair complexes with cucurbit[7]uril, and they show d
100 respectively, To summarize, optimization of ion pair concentration and PEF parameters caused a 1.5 o
102 The observation of complementary product ion pairs confirms the correctness of the sequence and a
105 ents that corresponded to lanthanide nitrate ion pairs coordinated with the separations ligand octyl,
106 red-shift was caused by the formation of an ion pair created by shock-triggered proton transfer from
107 n series due to the symmetry between b and y ion pairs created by collisional activation methods (or
109 of the Coulombic work terms associated with ion pairing, DeltaGw, that were directly correlated with
115 nding cations as well as with the results on ion pair dynamics reported in preceding papers for gener
116 andpoint, very little is known to date about ion-pair dynamics in biological macromolecular systems.
117 t development, and how utilizing hydrophobic ion pairing enabled this promising nanoparticle formulat
118 photoredox catalysts with respect to CT and ion pairing enables their application toward the polymer
119 face distances, and this separation/weakened ion-pairing enables the activation/insertion of more ste
121 ometric, Keq 1 > 10(6) M(-1), and the second ion-pair equilibrium was estimated to be Keq 2 = (2.4 +/
124 om temperature to give the solvent-separated ion pair [(FI)Ti(CH2SiMe3)2][MeB(C6F5)3], which catalyti
125 d more broadly demonstrates the viability of ion-pairing for control of regiochemistry in transition-
126 novel effect between concentration dependent ion pair formation and anion stability at reducing poten
128 tionship is consistent with the mechanism of ion pair formation suggested by the "law of matching wat
129 ind that Mg electrolytes are highly prone to ion pair formation, even at modest concentrations, for a
132 describe kinetic and mechanistic aspects of ion-pair formation, and we obtain NBO-based bonding indi
134 surfactants, exploiting the retention of the ion-pairs formed with Methylene Blue on the muMNPC.
135 This study investigates the formation of the ion pairs from a covalent intermediate, 2,3,4,6-tetra-O-
136 olvement of a common intermediate, a radical ion pair, generated from photoexcitation of an initially
137 the hydrogen-bonded complex to achieve the "ion-pair" geometry in the cycloaddition transition state
142 od colouring in soft drink was determined by ion-pair high performance liquid chromatography with pho
144 charge separation to form a contact radical ion pair, hole transport to form the Sa(-*)/Sd(+*) charg
145 ddition of calcium cations to the tetratopic ion-pair host 1 allosterically switched "on" chloride bi
146 ons revealed in this study of the tetratopic ion-pair host 1 can be used to design better cooperative
148 xtraction and quantification of histamine by ion-pair HPLC method with post-column derivatization and
150 yzed GAGs in C. elegans using reversed-phase ion-pairing HPLC, mass spectrometry and immunohistochemi
152 basis of selected complexes with respect to ion pairing, hydrogen bonding, electrostatic contributio
153 e role of soft epitaxial binding mechanisms, ion pairing, hydrogen bonds, hydrophobic interactions, a
154 to be favored over Wynberg's widely accepted ion pair-hydrogen bonding model and represent the first
155 The successful engineering of an artificial ion pair in a highly hydrophobic environment suggests th
156 1) affords [(bisNHC)AlBr2](+)Br(-) (2) as an ion pair in high yield, representing the first example o
158 e, a water molecule is coordinated to a zinc ion pair in the active site but is imperfectly oriented
160 Measurements of the ratio of free ions and ion pairs in different electrolyte concentrations allowe
161 uorinated long chain alkyl carboxylates form ion pairs in liquid ammonia, but the equilibrium dissoci
163 corresponding azolium-trichloromethyl anion ion pairs: in the former case, the complex evolves towar
168 n interacts mainly through direct H-bond and ion-pair interactions, whereas the YPIII beta-hairpin po
169 nd assemble onto the SAM surface by specific ion-pairing interactions between the sulfate headgroups
170 rly on, we have argued that repulsion-driven ion-pairing interactions with anionic lipids account for
173 e of naphthalimide moiety results in radical ion pair intermediates that survive >10,000-fold longer
175 ked intermediates on reverse phase media, an ion-pairing (IP) approach using N,N-dimethylhexylamine w
176 a neutral base catalyst in which the contact ion pair is maintained in the course of the reaction.
179 we describe and apply a novel reversed-phase ion-pair liquid chromatography purification method for d
181 en to be significantly less dependent on TFA-ion pairing, making it ideal for MS applications where h
183 thiourea compound, operating through a novel ion pairing mechanism, is an efficient organocatalyst fo
185 aried pH of the eluent and hydrophobicity of ion-pairing modifier to achieve good separation orthogon
188 etal ions such as silver and copper or metal ion pairs namely, silver-copper (Janus bionanocage) and
189 cycles (MC) to be semiflexible, which allows ion pairs (NaX; X = anion) to make contact, and to be mo
192 ethyl imidazolium analogues is attributed to ion pairing of the cationic imidazolium with Asp 70, alt
194 anchored catalytic units (e.g., single metal ions, pairs of metal ions, or well-defined metal-ion-con
195 he red-shifted features only emerge when the ion pairs oligomerize together into larger (TOTA.[CS2BF4
197 phere and suggest possible roles of oriented ion pairs or anion-bridged cations in the ion atmosphere
198 e ion at high polarization; in that case, no ion-pairing or charge screening by co-ions were observed
202 ely studied, the details of the HMSA-induced ion pair particle formation at the air-water interface a
203 ional theory calculations to investigate the ion pair particle formation from HMSA and (R1)(R2)NH (fo
204 as useful leads for understanding about the ion pair particle formation from other precursors in for
205 Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleoph
206 ll fluorophores originates from antiparallel ion pair-pi attraction to their polarized excited state.
207 ifferences between antiparallel and parallel ion pair-pi interactions are identified and quantitative
208 ate; i.e., parallel rather than antiparallel ion pair-pi interactions are preferred, despite repulsio
213 In contrast, the complementary parallel ion pair-pi repulsion is spectroscopically irrelevant, i
214 In contrast to the conventional picture, ion pairs prefer to bind at the upper edge of the step w
215 n is proposed to proceed through the radical ion pair [R3N(*+).CO2(*-)] generated by the photoionizat
217 cal in refluxing toluene engenders a contact ion-pair (radical cation) that leads, in the first insta
218 nterferences inherent in the tissues and the ion-pair reagent have been successfully eliminated.
219 C-ESI-MS is conducted either with a volatile ion-pair reagent, which could compromise the analyte sep
223 as pH of the mobile phase, concentration of ion pairing reagents, types and length of analytical col
225 and trifluoroacetic acid (TFA) as the mixed ion-pairing reagents was developed and applied to seleni
229 cular interactions can be combined, e.g., in ion-pair recognition, preorganization by intramolecular
230 cleotides can be resolved and purified using ion-pair, reverse-phase high-performance liquid chromato
235 DTA complex, and its subsequent detection by Ion-Pair-Reversed Phase-High Performance Liquid Chromato
239 t incremental solvation before rate-limiting ion-pair separation and provided an estimate of the entr
240 CA identified 6461 statistically significant ion-pairs, several of which putatively mapped to folic a
241 Pdx in assisting the release of Asp251 from ion pairs so that it can participate in proton-coupled e
242 tion led to the formation of two consecutive ion-paired species, [Ru(2+), Br(-)](+) and [Ru(2+), 2Br(
246 n the electronic singlet and triplet radical ion pair states as described by the radical pair mechani
247 te the six possible energetically degenerate ion-pair states, as suggested by electron paramagnetic r
250 ytically active species is proposed to be an ion pair that consists of the chiral boroxinate anion an
251 s of the urea lead to the association of the ion pair that results from protonation of the imine subs
252 lammonium oleate, phosphonate, and carbamate ion pairs that bind with greater affinity than primary n
253 l through zeolite windows and form transient ion pairs that participate in an oxygen (O2)-mediated Cu
254 tes in the reaction, and it is through these ion-pairs that the selective enantiofacial approach of t
255 of complementary functionality (for example, ion-pairing) that bind to one another at the oil-water i
256 the observation of a spin correlated radical ion pair, the formation of the localized (3)*TPD state u
259 h dielectric constant reported by the buried ion pair, there is no evidence that the presence of two
260 yl ligand, react with B(C6F5)3 to afford the ion pairs, {[Tism(Pr(i)Benz)]M}[HB(C6F5)3] (M = Zn, Mg),
261 -phosphate dehydrogenase (GPDH) and forms an ion pair to the phosphodianion of substrate dihydroxyace
262 se proximity of K(+) ions, which are tightly ion paired to the three [8]annulenyl dianion rings.
263 t changing the solvent dielectric to enforce ion pairing to a SbF6(-) counterion changes the regiosel
265 nsition states in high solvent dielectric to ion paired transition states in low solvent dielectric (
268 e by charge separation generates the radical ion pair Trp285(+)-Trp233(-) with a dipole moment of app
269 we observe that, at Mg metal potentials, the ion pair undergoes partial reduction at the Mg cation ce
271 eptor capable of recognizing both anions and ion pairs was designed, synthesized, and characterized.
274 he TBI study, 3530 statistically significant ion-pairs were identified, from which numerous putative
275 at buccal cavity pH and able to form stable ion pairs which penetrated the cells as one entity; whil
276 can exhibit distinct frequency shifts due to ion pairing, which can be explained in the framework of
277 , which crystallized as a solvent-separated ion pair with a [Na(18-crown-6)(THF)2 ](+) cation (where
279 reased ability of the alkyl sulfate anion to ion pair with the SAM-bound ferrocenium, resulting in ox
280 that the van der Waals interaction promotes ion pairing with longer-chain counterions and more effec
281 osed to regulate alphaIIbbeta3 activation by ion pairing with nearby lipids, plays opposite roles in
282 ionpair-pi interactions and repulsion-driven ion pairing with self-assembled fluorophiles as innovati
284 nly polycations are able to form cooperative ion pairs with dinonylnaphthalenesulfonate adsorbed to t
286 g., Cl(-), NO3(-), Br(-), and I(-), can form ion pairs with MB(+) and interfere with Epton's end poin
287 ving group, and eventually solvent-separated ion pairs with the glycosyl moiety and the leaving group
288 ving group, followed by formation of contact ion pairs with the glycosyl moiety loosely bound to the
290 f AZD2811 was increased through formation of ion pairs with these hydrophobic counterions, producing
291 port formulation of the complexes as contact ion pairs with weak agostic Mo-CH3...Li interactions, wh
294 ther propose that hypervalent silicates form ion-pairs with pentanidinium and bisguanidinium as inter
295 ectra revealed that the halides formed tight ion-pairs with the amide and alcohol groups of the dea l
296 olutions through the association of ions and ion pairs without significant participation of larger io
298 ption spectroscopy, and the exchanged, bound-ion-pair X-type ligated nanocrystals are characterized b
299 ly stable for elemental analysis.) The bound-ion-pair X-type ligation is fully reversed to L-type n-o
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