ライフサイエンスコーパス: iridium

1 kel multilayers in contact with platinum and iridium.

2 ibit many intriguing properties; for example iridium adatoms are proposed to induce a substantial top

3 osed to proceed via olefin insertion into an iridium-alkoxide bond, followed by rate-determining C-H

4 ide with the alcohol to form a square planar iridium alkoxo complex that could undergo a beta-hydride

5 gioselectivity for the branched product with iridium and among the most selective for forming branche

6 the Cp* and NHC ligands remain bound to the iridium and are not significantly degraded under reactio

7 The combination of iridium and P(OPh)3 was the first catalytic system shown

8 and 1 M KOH, better than the combination of iridium and platinum as benchmark catalysts.

9 Only noble metal catalysts based on iridium and ruthenium have been used to accomplish these

10 Polypyridyl complexes of iridium and ruthenium have served as popular photocataly

11 ng activities that can transfer electrons to iridium and thus generate detectable optical and electro

12 is 10 +/- 1 ions of cobalt, 13 +/- 4 ions of iridium, and 11 +/- 3 ions of nickel.

13 flow process was developed to perform a dual iridium- and nickel-catalyzed C(sp(2) )-C(sp(3) ) coupli

14 erent alcohols by using a sequential one-pot iridium- and rhodium-catalyzed process.

15 Iridium- and ruthenium-free approaches to protected ally

16 Elemental lithium and iridium are oxidized and transported over a distance of

17 tion of protons implies that 6 +/- 2 ions of iridium are required for proton reduction.

18 provide evidence for the coordination of the iridium atoms by the acetonitrile solvent and demonstrat

19 e reactivities of the basal-plane and apical iridium atoms.

20 cross-linked through undercoordinated oxygen/iridium atoms.

21 ic aldehydes under mild conditions, using an iridium-based catalyst designed to favor formyl over aro

22 A novel variant of an iridium-based organometallic catalyst was synthesized an

23 ty-stability factor relative to conventional iridium-based oxide materials, and an 8 times improveme

24 Iridium-based oxides (iridates) introduce strong spin-or

25 Iridium-based particles, regarded as the most promising

26 verall yield ( approximately 8.1 g), and the iridium-based photocatalyst 1a can be prepared in a 56%

27 onomers, using ultralow concentrations of an iridium-based photoredox catalyst (typically 1 ppm to mo

28 The mechanism for the iridium-BINAP catalyzed dehydrogenative decarbonylation

29 We present the first copper iridium binary metal oxide with the chemical formula Cu2

30 The highly active iridium "blue solution" chemical and electrochemical wat

31 sessed the potential impact of charge, metal-iridium bond length, and stability of terminal vs intern

32 h contains a labile molecule of water and an iridium-bonded alkenyl moiety (-C(R) horizontal lineC(R)

33 These new ligands were either cleaved from iridium by water or formed unreactive, phenoxide-bridged

34 esulting from oxygen atom insertion into the iridium-carbon and/or iridium-nitrogen bonds of phpy.

35 er to carbon, followed by insertion into the iridium-carbon bond of phpy, formed a coordinated organi

36 table performance, better than the benchmark iridium/carbon catalyst.

37 ng auxiliary group on the alkene followed by iridium-catalysed C-H silylation of an unactivated delta

38 y the Fischer indole synthesis, we report an iridium-catalysed tyrosinase-like approach to catechols,

39 enabled pi-allyl formation in the context of iridium catalysis.

40 inc or trialkylaluminium compounds), a diene-iridium catalyst (with arylboroxines), or a bisphosphine

41 nces in the interaction energies between the iridium catalyst and arene carbon.

42 ions with a silylborane as reagent and a new iridium catalyst containing an electron-deficient phenan

43 ess, has been developed using a bifunctional iridium catalyst coupled with bulky nickel or copper hyd

44 investigations suggest that the photoexcited iridium catalyst facilitated the nickel activation via s

45 Here we describe how a molecular iridium catalyst for water oxidation directly and robust

46 bstrate was shown to act as a ligand for the iridium catalyst in the absence of other ligands via NMR

47 Using an iridium catalyst modified by PhanePhos, CF3-allenes reac

48 Here we present a robust, reusable iridium catalyst that enables hydrogen gas release from

49 ion of 1,4-dienes has been realized using an iridium catalyst with a chiral N,P-ligand under mild con

50 Under the action of an iridium catalyst, N-heterocycles undergo multiple sp(3)

51 r formation of the branched product with the iridium catalyst.

52 phatic and aromatic alkenes using a cationic iridium catalyst.

53 ron catalyst is orthogonal to currently used iridium catalysts and allows isotopic labelling of compl

54 Iridium catalysts containing dative nitrogen ligands are

55 With iridium catalysts, methanol engages in redox-neutral reg

56 ed by solid-phase, molecular, pincer-ligated iridium catalysts, using ethylene or propene as hydrogen

57 Using enantiomeric iridium catalysts, vinyl aziridine 3a reacts with unprot

58 from the more commonly employed ruthenium or iridium catalysts.

59 loxylation of aryl alkyl ethers using pincer iridium catalysts.

60 conjugated dienes using a unified cobalt and iridium catalytic system in order to access a variety of

61 ration, ee and yield of an amine produced by iridium catalyzed asymmetric hydrogenation of an iminium

62 l sulfonyl compounds were prepared using the iridium catalyzed asymmetric hydrogenation reaction.

63 The three-step route commences with an iridium catalyzed C-H borylation to give a 7-borylindole

64 ct cryptocaryol A is prepared in 8 steps via iridium catalyzed enantioselective diol double C-H allyl

65 Iridium catalyzed primary alcohol oxidation triggers red

66 shed from a common intermediate prepared via iridium-catalyzed alcohol C-H tert-(hydroxy)prenylation

67 Rapid, selective, and highly controllable iridium-catalyzed allylbenzene isomerization is describe

68 rst enantio-, diastereo-, and regioselective iridium-catalyzed allylic alkylation reaction of prochir

69 The first highly enantioselective iridium-catalyzed allylic alkylation that provides acces

70 entails a highly regio- and enantioselective iridium-catalyzed alpha-alkylation of an extended enolat

71 ctive synthesis of complex polycycles by the iridium-catalyzed arylative cyclization of alkynones wit

72 Iridium-catalyzed asymmetric hydrogenation of 20 with th

73 Iridium-catalyzed asymmetric hydrogenation of N-alkyl-2-

74 When they were used in the iridium-catalyzed asymmetric hydrogenation of unfunction

75 g a remote sulfonate group enables selective iridium-catalyzed borylation of a range of common amine-

76 Here we report the iridium-catalyzed borylation of methane using bis(pinaco

77 The iridium-catalyzed borylation of mono- and disubstituted

78 We report the iridium-catalyzed borylation of primary and secondary al

79 The iridium-catalyzed borylation of pyrene, using 4,4'-dimet

80 roach to controlling regioselectivity in the iridium-catalyzed borylation of two classes of aromatic

81 tinine 2 undergoes direct and site-selective iridium-catalyzed borylation to provide boronate ester 3

82 Sequential process of iridium-catalyzed C-H borylation and palladium-catalyzed

83 A study on the iridium-catalyzed C-H borylation of heteroarenes is repo

84 In the absence of a steric directing group, iridium-catalyzed C-H borylation of N-protected indazole

85 The iridium-catalyzed C-H borylation of phosphines is descri

86 The functional group tolerance of the iridium-catalyzed C-H borylation reaction enables simple

87 An iridium-catalyzed C-H borylation/Chan-Lam procedure guid

88 The combination of a mild iridium-catalyzed C2/C7-diboronation followed by an in s

89 thesis of benz[c]acridines when allied to an iridium-catalyzed dehydrative cyclization.

90 Herein we report iridium-catalyzed enantioselective allylation reactions

91 extensively in the past two decades, but no iridium-catalyzed enantioselective borylation of C-H bon

92 We report a set of iridium-catalyzed enantioselective borylations of aromat

93 The application of an iridium-catalyzed hydrogen borrowing process to enable t

94 Highlights of the synthetic route include an iridium-catalyzed hydrogenation, iterative Roush crotyla

95 are generally postulated as intermediates in iridium-catalyzed hydrogenation.

96 An iridium-catalyzed method was developed for the synthesis

97 Herein, we report a novel, regioselective, iridium-catalyzed multicomponent synthesis of pyrimidine

98 development of our hypothesis focuses on an iridium-catalyzed process efficient mainly with activate

99 The iridium-catalyzed reaction proceeds with high branched t

100 A new iridium-catalyzed reductive Strecker reaction for the di

101 Reported herein is the iridium-catalyzed regio- and enantioselective allylic su

102 rylated arylisoquinoline dyes via a flexible iridium-catalyzed route is reported.

103 A method for the iridium-catalyzed silylation of aryl C-H bonds is descri

104 hydrazones as neutral C1-nucleophiles in the iridium-catalyzed substitution of allylic carbonates is

105 The reaction proceeds via direct iridium-catalyzed substitution of racemic allylic alcoho

106 Experimental mechanistic studies of iridium-catalyzed, enantioselective allylic substitution

107 Reported herein is an iridium-catalyzed, regioselective silylation of the arom

108 This topology directs the iridium center to activate a different C-H bond than in

109 f 1,5-cyclooctadiene (COD) is achieved on an iridium center using water as a reagent.

110 Ir prior to oxidative addition of MeI to the iridium center.

111 boryl ligand directly attached to the metal (iridium) center, as opposed to the metal itself.

112 s, provided they can weakly associate to the iridium chemosensor.

113 The zwitterionic iridium-COD complexes were tested as catalysts for the h

114 Under the cooperative catalysis by an iridium complex and a chiral phosphoric acid, alpha-bran

115 catalyzed synergistically by a metallacyclic iridium complex and benzotetramisole.

116 transfer (PCET) mediated by an excited state iridium complex and weak phosphate base to furnish a rea

117 This was realized using an iridium complex as a receptor in the presence of parahyd

118 cyclic ketones catalyzed by a metallacyclic iridium complex containing a phosphoramidite ligand deri

119 Our results show that the iridium complex displays a very strong dependence on the

120 ve amination of arylacetones catalyzed by an iridium complex for the preparation of enantiomerically

121 A chiral iridium complex formed in situ from [Ir(cod)Cl]2 and (R)

122 The reaction is catalyzed by an iridium complex generated from [Ir(COD)OMe]2 and chiral

123 or two triarylamine donors, a cyclometalated iridium complex sensitizer and a naphthalene diimide (ND

124 r two triads with a phenylene bridge between iridium complex sensitizer and NDI acceptor.

125 an alkynylboronate, which is catalyzed by an iridium complex supported by a SiNN pincer ligand.

126 -alkoxy ketones catalyzed by a metallacyclic iridium complex to form products with contiguous stereog

127 lsilanes by a square-planar pyridine-diimine iridium complex with a terminal nitrido unit leads to th

128 A pincer-ligated iridium complex, (PCP)Ir (PCP = kappa(3)-C6H3-2,6-[CH2P(

129 -thiazol-4-ones catalyzed by a metallacyclic iridium complex.

130 chelating ligand of the ruthenium (3a-g) and iridium complexes (4a-g) have been prepared.

131 T studies of five panchromatic, heteroleptic iridium complexes (four of which are new) supported by A

132 N-Heterocyclic carbene-phosphine iridium complexes (NHC-Ir) were developed/found to be a

133 A family of neutral bis-cyclometalated iridium complexes [Ir(C^N)2(LX)] has been investigated a

134 eparate transfer of protons and electrons on iridium complexes are shown.

135 We report a family of iridium complexes as the first homogeneous catalysts for

136 olid-state devices of a series of 8 cationic iridium complexes bearing different numbers of methoxy g

137 Organometallic iridium complexes bearing oxidatively stable chelate lig

138 Recently, several novel iridium complexes have been shown to catalyse group tran

139 A series of ruthenium and iridium complexes have been synthesized and characterize

140 n-hydrogen (C-H) silylation using rhodium or iridium complexes in the presence of excess hydrogen acc

141 bonds through the insertion of well-defined iridium complexes into the aromatic ring of simple alkyl

142 Chiral iridium complexes modified by SEGPHOS catalyze the 2-pro

143 Iridium complexes of sterically unhindered pincer ligand

144 The unprecedented ability of these iridium complexes to generate H2 O2 by catalytic hydride

145 lexes are more active than the corresponding iridium complexes.

146 ity and imparts grafting capabilities to the iridium complexes.

147 The new ruthenium and iridium compounds increased caspase-3 activity in A2780

148 The iridium congener of the optimized cobalt catalyst, 6-(H)

149 In a recent paper, Wang et al. found an iridium-containing compound with a formal oxidation stat

150 based ligand that was cyclometalated onto an iridium core to form three phosphorescent heteroleptic m

151 ture of an iridium oxide shell on a metallic iridium core, formed through the fast dealloying of osmi

152 In contrast, iridium cyclopentadienyl catalysts cause cancer cell dea

153 s the full orbital structure of the relevant iridium d-orbitals and the strong but finite spin-orbit

154 the helical NHC P/M stereochemistry and the iridium Delta/Lambda stereochemistry.

155 vity of single-layer graphene decorated with iridium deposited in ultra-high vacuum at low temperatur

156 ntroduced the chirality by a stereoselective iridium-diamine-catalyzed asymmetric transfer hydrogenat

157 complexes results in observation of two new iridium-dihydrogen complexes.

158 ater or formed unreactive, phenoxide-bridged iridium dimers.

159 Iridium dioxide (IrO2) is an efficient catalyst for oxyg

160 eoritic siderophiles (for example nickel and iridium) found throughout the rock reach a level in the

161 The pincer-iridium fragment ((iPr)PCP)Ir ((R)PCP = kappa(3)-2,6-C6H

162 and characterization of discrete rhodium and iridium fragments bound site-specifically in a kappa(2)-

163 e of benzene made possible by a four-pronged iridium gig that yields a "spring-loaded" norbornadiene-

164 is instead used to trigger rapid movement of iridium-gold Janus microsphere motors.

165 These Janus micromotors rely on an iridium hemispheric layer for the catalytic decompositio

166 ev interaction is ferromagnetic, as in 5d(5) iridium honeycomb oxides, and indeed defines the largest

167 heir relatively high stability and activity, iridium (hydr)oxides have been identified as the most pr

168 sigma-Alkyl iridium hydride complexes are generally postulated as in

169 addition are very late, resembling the aryl iridium hydride intermediate with a fully formed Ir-C bo

170 The five-coordinate iridium-hydride complexes were found to catalyze H/D exc

171 allenging as they affect regioselectivity of iridium-hydride insertion.

172 (eta(2)-Allylic alcohol)iridium(I) and (eta(3)-allyl)iridium(III) complexes were

173 Iridium(I) and rhodium(I) ethyl complexes, (PONOP)M(C2H5

174 An iridium(I) catalyst system, modified with the wide-bite-

175 orylation catalyzed by the combination of an iridium(I) precursor and tetramethylphenanthroline.

176 P)M(C2H5) (M = Ir (1-Et), Rh (2-Et)) and the iridium(I) propyl complex (PONOP)Ir(C3H7) (1-Pr), where

177 ected borylation method complements existing iridium(I)- and rhodium(I)-catalyzed C-H borylation reac

178 ed delta-lactams via a highly chemoselective iridium(I)-catalyzed reduction.

179 Metal-ligand cooperation between iridium(III) and a 1,3-N,O-chelating phosphoramidate lig

180 d through sensitization, using a polypyridyl iridium(III) catalyst, to form bridged cyclobutanes.

181 tutionally labile chiral-at-metal octahedral iridium(III) complex exclusively bears achiral ligands a

182 With the use of an iridium(III) complex, Ir(diFppy)2(bpy)PF6 [diFppy = 2-(2

183 terization of a series of new cyclometalated iridium(III) complexes [Ir(ppy)2(N(wedge)N)][PF6] in whi

184 A number of known heteroleptic iridium(III) complexes are prepared in up to 96% yield.

185 clometalated benzimidazole ruthenium(II) and iridium(III) complexes of the types [(eta(6)-p-cymene)Ru

186 Allylic alcohol)iridium(I) and (eta(3)-allyl)iridium(III) complexes were synthesized and characterize

187 Strongly luminescent iridium(III) complexes, [Ir(C,N)2 (S,S)](+) (1) and [Ir(

188 otoxic activity of the new ruthenium(II) and iridium(III) compounds has been evaluated in a panel of

189 Two phosphorescent dinuclear iridium(III) diastereomers (LambdaDelta/DeltaLambda) and

190 It is demonstrated that a cationic iridium(III) dichloride phenanthroline complex is capabl

191 yl-2,2'-dipyridyl)-bis(2-phenylpyridine(1H))-iridium(III) hexafluorophosphate [Ir(ppy)2(dtbbpy)][PF6]

192 a-vinyl and ortho-aryl positions, to give an iridium(III) metalloindene intermediate; this intermedia

193 he carbonyl hydrosilylation catalyzed by the iridium(III) pincer complex introduced by Brookhart.

194 reparation of valuable cationic heteroleptic iridium(III) polypyridyl photosensitizers.

195 , palladium(II), platinum(II), rhodium(III), iridium(III), and ruthenium(II).

196 c anti-Markovnikov O-phosphoramidation using iridium(III), including characterization of rare reactiv

197 drogenation reaction using novel N,P-ligated iridium imidazole-based catalysts (Crabtree type).

198 vely stable chelate ligands are bound to the iridium in addition to the Cp*, the oxidized precursors

199 ariants of the P450 enzyme CYP119 containing iridium in place of iron catalyze insertions of carbenes

200 en ions with synergistic oxidative effect of iridium ions and chlorine atoms.

201 The chemical change in iridium is coupled to a decrease in surface hydroxide, p

202 A single bonding site for the iridium is identified on the nodes of NU-1000, whereas t

203 etals, such as the reduction of IrCl6(3-) to iridium, is capable of electrocatalytically reducing pro

204 es are identified on UiO-66, although at low iridium loadings only one site is occupied.

205 nuing a major search (so far concentrated on iridium materials) for realizations of the celebrated Ki

206 Recent results suggest that iridium may offer opportunities to address challenges in

207 Based on that premise, iridium-mediated C-H activation has enabled facile insta

208 Iridium-mediated dehydrogenation of ethanol to acetaldeh

209 7-delta pyrochlore is also free of expensive iridium metal and thus is a cost-effective candidate for

210 methyl group in the methanol product is the iridium-methyl bond in the [Cp*Ir(NHC)Me(CD2Cl2)][BAr(F)

211 x intermediates in the hydrogenolysis of the iridium-methyl bond of (PONOP)Ir(H)(Me)(+) (1) [PONOP =

212 s involve the first reported examples of 1,4-iridium migration.

213 possesses only a small fraction of the total iridium moment, without evidence for long-range order up

214 d hydrogen activation was accomplished by an iridium monohydride cation ligated in a pentadentate fas

215 Therefore, separate sections consider iridium N,P-, NHC-, P,S-, and O,P-catalysts, and rhodium

216 catalytic activity for water oxidation of an iridium-N-dimethylimidazolin-2-ylidene (Ir-NHC-Me2) comp

217 Iridium nanoparticles have only been reported with rough

218 lating growth mechanism involving the use of iridium nanoparticles on the cathode surface may be resp

219 l detection of femtomolar amounts of cobalt, iridium, nickel, and iron ions in solution by electrocat

220 FT), direct addition of the Si-H bond to the iridium nitrido unit is proposed.

221 tom insertion into the iridium-carbon and/or iridium-nitrogen bonds of phpy.

222 C-C coupling reactions that are catalyzed by iridium or ruthenium complexes have been developed, whic

223 y dopants comprising singlet fluorophores or iridium organometallic compounds provided further improv

224 The electronic conductivity of films of iridium oxide (IrO(x)) composed of ca. 2 nm nanoparticle

225 method for electrochemical deposition of an iridium oxide (IrOx) film onto a designated microelectro

226 The on-chip iridium oxide (IrOx) pseudo-reference electrode provides

227 r is based on a highly sensitive membrane of iridium oxide (IrOx).

228 Here we report an iridium oxide/strontium iridium oxide (IrOx/SrIrO3) catalyst formed during elect

229 (Pt Bl), tungsten/tungsten oxide (W/WO3) and iridium oxide (Pt/IrO2) working ultramicroelectrodes wer

230 disc microelectrode modified with a film of iridium oxide and lower pH values were found in A. tequi

231 A pH sensitive iridium oxide electrode electrodeposited on the disk ele

232 doped diamond (BDD) and thermally decomposed iridium oxide film (TDIROF) anodes.

233 dged binuclear ZrOCo(II) group coupled to an iridium oxide nanocluster (IrO(x)) was assembled on an S

234 An iridium oxide nanoparticle electrocatalyst under oxygen

235 (SPCE) modified with polythionine (PTH) and iridium oxide nanoparticles (IrO2 NPs) is presented.

236 tic nanoparticles (MNPs) functionalized with iridium oxide nanoparticles (IrOx NPs) and tyrosinase (T

237 f cycles to reduce graphene oxide, volume of iridium oxide nanoparticles and tyrosinase solution.

238 electrochemically reduced graphene oxide and iridium oxide nanoparticles for the detection of angiote

239 electrochemically reduced graphene oxide and iridium oxide nanoparticles matrix.

240 ggests that the oxygen evolution reaction on iridium oxide occurs through an OOH-mediated deprotonati

241 nverse relationship with enzyme loading, and iridium oxide pH sensors were found to have super-Nernst

242 dvance of this probe is the inclusion of two iridium oxide reference electrodes to improve sensor acc

243 hly conductive nanoporous architecture of an iridium oxide shell on a metallic iridium core, formed t

244 In several iridium oxide systems, the spin-orbital entangled state,

245 studies show that it does not decompose into iridium oxide, thus preserving its molecular identity, a

246 cathodes, and water oxidation kinetics over iridium oxide.

247 observable evidence for the decomposition to iridium oxide.

248 rodes of a new geometry, namely nanotubes of iridium oxide.

249 electrodeposition of a thin layer of hydrous iridium oxide.

250 Here we report an iridium oxide/strontium iridium oxide (IrOx/SrIrO3) cata

251 spin-orbit coupling and correlation effects, iridium oxides hold a prominent place in the search for

252 The quest for other iridium oxides that present tests of the underlying SOC

253 ave ruled out the formation of heterogeneous iridium oxides, either as colloids in solution or as dep

254 is emerging area are the 5d transition metal iridium oxides.

255 Iridium-(P,olefin) complex-catalyzed enantio- and diaste

256 e proximity-induced magnetization, including iridium, palladium and platinum but not gold.

257 ellent levels of enantioselectivity using an iridium-PhanePhos catalyst.

258 Cubic (space group: Fmm) iridium phosphide, Ir2P, has been synthesized at high pr

259 l alcohol, catalyzed by using axially chiral iridium phosphoramidites PR/S-Ir and cinchona amine is e

260 In this protocol, an excited-state iridium photocatalyst and a weak phosphate base cooperat

261 a electron transfer between an excited-state iridium photocatalyst and an amine substrate.

262 by a combination of a thiol catalyst with an iridium photocatalyst and subsequent radical-radical cou

263 An iridium photocatalyst and visible light facilitate a roo

264 cribe a dual catalyst system comprised of an iridium photocatalyst and weak phosphate base that is ca

265 Evidence suggests that the iridium photocatalyst facilitates nickel excitation and

266 A visible-light-promoted iridium photoredox and nickel dual-catalyzed cross-coupl

267 prolinols, in combination with a thiophenol, iridium photoredox catalyst and visible light, have been

268 Application of an iridium photoredox catalyst in tandem with a nickel cata

269 thiol catalyst and a commercially available iridium photoredox catalyst in the presence of household

270 of novel acridinium salts as alternatives to iridium photoredox catalysts and show their comparabilit

271 enzylamine architectures using a synergistic iridium photoredox/nickel cross-coupling dual catalysis

272 In order to achieve reproducibility during iridium-photoredox and nickel dual-catalyzed sp(3)-sp(2)

273 ur system, composed of a nickel catalyst, an iridium photosensitizer, and an amine electron donor, is

274 The oxidative stress induced by iridium photosensitizers during photoactivation can incr

275 showed 46-64-fold improved affinity for the iridium pianostool complex [(eta(5)-Cp*)Ir(pico)Cl].

276 based on the incorporation of a biotinylated iridium pianostool complex within streptavidin (Sav) iso

277 In this context we have examined the use of iridium pincer catalysts for the hydrosilylative reducti

278 New carbazolide-based iridium pincer complexes ((carb)PNP)Ir(C2H4), 3a, and ((

279 An iridium pincer dihydride catalyst was immobilized on car

280 arge transfer (MLCT) states of ruthenium and iridium polypyridyl complexes.

281 om a thermophilic organism and containing an iridium porphyrin cofactor (Ir(Me)-PIX) in place of the

282 tuted artificial metalloenzyme containing an iridium porphyrin that exhibits kinetic parameters simil

283 secondary benzylic C-H bonds catalyzed by an iridium precursor and 3,4,7,8-tetramethyl-1,10-phenanthr

284 Iridium reacts much faster than rhodium (~ 1100 times at

285 A similar analysis for iridium reduction and the corresponding catalytic reduct

286 ution facilitates triflate dissociation from iridium, resulting in unsaturated five-coordinate Ir-H c

287 bubbles (rho approximately 0) to osmium and iridium (rho approximately 23 g/cm(3)).

288 Iridium, rhodium, and ruthenium complexes all catalyze t

289 Specifically, we use an iridium salt (K2IrCl6) to probe serum for reducing activ

290 activation pathway: Energy transfer from an iridium sensitizer produces an excited-state nickel comp

291 gous system with a fac-tris(2-phenylpyridine)iridium sensitizer.

292 ion dynamics around the catalytically active iridium sites to be robustly characterized.

293 ygen atom transfer generated an unidentified iridium species (the "oxidized complex").

294 n water oxidation catalyzed by a homogeneous iridium species in solution.

295 f an -SH-functionalized modulating agent via iridium staining revealed that the COF domains are termi

296 ll time) by fusing the blended mixture on an iridium strip resistance heater in an argon-purged chamb

297 de ligand was shown to remain coordinated to iridium throughout the reaction, and release of carbon m

298 alcohols can be achieved using "unprotected" iridium transfer hydrogenation catalysts inside living c

299 Under OER conditions, iridium undergoes a change in oxidation state from Ir(IV

300 ng reversible binding of molecular oxygen to iridium, which contributes to the air tolerance of the c