ライフサイエンスコーパス: isobutane

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1 tane was 13% less than the adsorbent without isobutane.

2 the zeolite surface and the methyl groups of isobutane.

3 he reaction of dimethyldioxirane (DMDO) with isobutane.

4 ne across the double bond of propene to form isobutane.

5 fter 9 min of heating, showing desorption of isobutane.

6 s much larger than the corresponding bond in isobutane (96.5 +/- 0.4 kcal/mol), and is more typical o

7 ed such that facile reductive elimination of isobutane and activation of dinitrogen was observed.

8 The lighter branched alkanes isobutane and isopentane also react with methanol to gen

9 ghly branched carbon skeletons, for example, isobutane and neopentane, are more stable than their nor

10 ervable adsorption complex forms between the isobutane and the primary Bronsted acid site of ZSM-5, w

11 3)C shielding in the series ethane, propane, isobutane, and neopentane.

12 tion of a hydrogen atom from the C-H bond of isobutane by the hydrogen-bonded hydroxyl radical to pro

13 Specifically, the activation of isobutane C-H bonds by the solid acid zeolite HZSM-5 is

14 allowed to react with HAl(i)Bu2, eliminating isobutane en route to the Zr(III) complex.

15 ly competitive than the RTO due to recovered isobutane for the production process and are recommended

16 Here we show that immiscible isobutane forms in situ from partial transformation of a

17 The measured activation energy for isobutane H/D exchange is 57 kJ/mol.

18 ctivity for the oxidative dehydrogenation of isobutane in comparison to the closed ones.

19 lary gas chromatography-chemical ionization (isobutane)-ion-trap mass spectroscopy.

20 -2 in the gas phase oxidation of methane and isobutane is firmly established to take place on the unr

21 tween the solid catalyst surface and gaseous isobutane is quantitatively measured using isotopic (1)H

22 Isobutane-isobutylene or 2-butene alkylation gave excell

23 Isobutane-laden adsorbent was then heated with resistanc

24 exchange between the zeolite surface and the isobutane methyl groups at temperatures (273 K) much low

25 less accessible to or less reactive with the isobutane molecule.

26 for methane, ethane, propane, cyclopropane, isobutane, neopentane, tetramethylbutane, norbornane, no

27 The first step of the proposed mechanism for isobutane oxidation is abstraction of a hydrogen atom fr

28 Gases such as propane, butane, isobutane, propylene, 2-methylpropene, and 1,3-butadiene

29 In all experiments, the isobutane reagent was purified to eliminate any unsatura

30 acid site and protium gain by perdeuterated isobutane reveals a common rate constant equal to 4.1-4.

31 ion of these suspensions exhibit an n-butane/isobutane selectivity of 5.4, with an n-butane permeance

32 The GAC and ACFC systems recover adequate isobutane to pay for themselves through chemical-consump

33 cipient *OH radical to the carbon radical of isobutane to produce the C-O bond of the final product,

34 ene connected through a benzene spacer to an isobutane tripod, with each arm of the tripod ending in

35 ating, the temperature of the adsorbent with isobutane was 13% less than the adsorbent without isobut

36 h pressure strongly opposes decomposition of isobutane, which may possibly coexist in equilibrium wit

37 f the related mechanism of the reaction with isobutane with CO in HF/BF3 medium leading to methyl iso

38 The kinetics of the partial oxidation of isobutane with molecular oxygen on Rh(111) single-crysta

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