ライフサイエンスコーパス: isoelectronic

1 he azomethine and its analogous vinylene are isoelectronic.

2 , and on the other hand, exogenous Cu(+) and isoelectronic Ag(+) ions disrupt the DNA binding of Mac1

3 tronic structure and chemical bonding of two isoelectronic Al-doped boron clusters, AlB(6)(-) and AlB

4 In contrast to the side-on binding of isoelectronic alkene donors, an alternative mono(sigma-B

5 The 13C NMR chemical shifts of the isoelectronic analogue tert-butyl cation were also calcu

6 Additions of NO(+)BF4(-) give the isoelectronic and isosteric cations [ Fe(CO)2(NO)(P((CH2

7 irs of not necessarily adjacent C atoms with isoelectronic and isosteric pairs of B and N atoms.

8 tions confirmed that these compounds are the isoelectronic and isostructural analogues of the hydroca

9 13C NMR chemical shifts of the corresponding isoelectronic and isostructural carbocations were calcul

10 frustrated lattice of the largest series of isoelectronic and isostructural kagome systems yet disco

11 um-carbonium dications and the corresponding isoelectronic and isostructural onium-boronium cations w

12 old(III) complexes, containing metal centers isoelectronic and isostructural to cisplatin, are promis

13 minimum for the NO2He3+ trication, which is isoelectronic and isostructural with the previously stud

14 arylimido dianions studied here are formally isoelectronic and possess comparable frontier molecular

15 H(12) compounds 2a and 2b resemble the known isoelectronic arachno-6,9-SCB(8)H(12), the phosphorus an

16 let arylnitrenium ions (Ar-NH(+)) than their isoelectronic arylnitrene (Ar-N) counterparts.

17 mic is observed to mimic that present in the isoelectronic atom.

18 dy on AuO (-) and AuO 2 (-) and their valent isoelectronic AuS (-) and AuS 2 (-) species to probe the

19 Formal exchange of C=C units with isoelectronic B=N or B=P units can provide access to mol

20 ied p-type transport in neutral systems with isoelectronic backbones.

21 ut its normal, the assigned resonances of an isoelectronic, bis-cyano complex of meso-nitro-etioheme

22 egy is the replacement of a CC unit with its isoelectronic BN unit.

23 re of 1,3-dehydro-5-adamantyl cation and its isoelectronic boron analogue 1,3-dehydro-5-boraadamantan

24 ications (C(n)H(2n+2)2+), n = 1-5) and their isoelectronic boron cation analogues was carried out usi

25 The isoelectronic carbene transfer to olefins, a widely used

26 This establishes isoelectronic centres as a promising platform for quantu

27 exciton qubits, we demonstrate that nitrogen isoelectronic centres in GaAs combine both the uniformit

28 its all-carbon counterpart and to assess the isoelectronic character of the two bonds.

29 -based applications of the largest series of isoelectronic clusters yet discovered.

30 mations complement the coupling reactions of isoelectronic CO, and they may prove synthetically usefu

31 In comparison with the isoelectronic cyano-ethylene system, the cyanoethylene (

32 of "trapping" this molecule (or the valence-isoelectronic cyclic thiozone, S3) in transition metal c

33 s have been widely investigated, the valence isoelectronic diatomic molecules EX (E = group 13 elemen

34 with the same leaving group, rather than the isoelectronic diester complex.

35 nerate p-type monolayer Mo1-x Wx Se2 through isoelectronic doping.

36 ared with photoelectron images collected for isoelectronic early transition metal heterogeneous diato

37 ter rearrangements, it is predicted that the isoelectronic eight-centered rearrangements of imidates

38 mic electronic structures reminiscent of the isoelectronic elements appearing on the periodic table,

39 Comparisons with the isoelectronic EuCl6(3-) indicated that the amount of Cl

40 longer than the current record lifetime for isoelectronic Fe(II) complexes, which are of significant

41 Upon substitution of Zn with the isoelectronic Fe, no charge carriers are introduced in t

42 The Fe-CO and C-O bond strengths in the isoelectronic ferrous carbonyl complexes are widely reco

43 substituting the oxide ions in [IrO6](8-) by isoelectronic fluorides to form the fluorido-iridate: [I

44 ealization of a complex containing a valence isoelectronic group 13/group 17 analogue of CO and N(2).

45 tionality has been replaced by isosteric and isoelectronic groups, have been synthesized and have bee

46 limited to azides, but generalizes to other isoelectronic heteroallene functions, such as isocyanate

47 nitride (SiN) and the cyano radical (CN) are isoelectronic; however, their chemical reactivities and

48 Oxamate, an isosteric and isoelectronic inhibitory analogue of pyruvate, enhances

49 tive elimination of benzene from a series of isoelectronic Ir(III) phenyl hydride complexes, measured

50 xos and nitrenes, C(sp(3))-H alkylations via isoelectronic iron carbene intermediates have thus far b

51 ion activity when directly compared with its isoelectronic/isostructural analogues where the boryl un

52 ostatic potential surfaces revealed a unique isoelectronic/isostructural relationship between these a

53 on monoxide (CO) stretching frequency in the isoelectronic MbII(H64L)CO mutant versus native MbCO.

54 comparable stability with other better known isoelectronic metallofullerene (C(80))(6-) cage species

55 gniture faster than what is observed for the isoelectronic metcyano complex; in both the ferrous CO a

56 n displaying again the divergent behavior of isoelectronic Mn(I) and Fe(II) PNP pincer systems.

57 e-CO complexes of NP4, NP4(D30N), and NP7 as isoelectronic models for the ferriheme-NO complexes.

58 of negatively charged atomic ions and their isoelectronic molecular counterparts.

59 By contrast, the valence isoelectronic molecules EX (E = group 13 element, X = gr

60 Sterically crowded isoelectronic nf(3) (C(5)Me(5))(3)M complexes of neodymi

61 similar ionic radius (i.e., Nd(III) ) and an isoelectronic one (Eu(III) ).

62 oordinated onium-carbonium dications and the isoelectronic onium-boronium cation analogs.

63 replacing the hydroxymethylene with various isoelectronic or isosteric groups.

64 Along with an isoelectronic oxo, we quantify the electronic structure

65 2)2C6H4], a heretofore missing member of the isoelectronic [p-(Ph3EC2)2C6H4] (E = groups 13-15 elemen

66 This is in sharp contrast to isoelectronic (PCP)Ir systems in which hydrogenation pro

67 This isoelectronic perturbation allows for direct comparisons

68 e of N(2)S(2) are compared with those for an isoelectronic pi system, Li(2)C(4)H(4), motivated by the

69 radical substituent is also compared against isoelectronic radical groups.

70 Compared to the isoelectronic reaction of the cyano radical (CN) with ac

71 arkably, diamagnetic complexes deriving from isoelectronic replacement of CO by NO(+), {(mu-SRS)[Fe(C

72 s of heme protein complexes with HNO and the isoelectronic RNO (R = alkyl and aryl) molecules (metabo

73 the structure is quite similar to the known isoelectronic RSn(9)(3-) ions (e.g., R = i-Pr).

74 tivation of CO2 was observed, similar to the isoelectronic Ru(II) analogue.

75 easures of the An-E bond covalency within an isoelectronic series and supported significant 5f-orbita

76 ucture calculations were carried out for the isoelectronic series ClF(4)(+), BrF(4)(+), IF(4)(+) and

77 relative energy, structure, and size) to an isoelectronic series of well-defined M(+)-acceptor pairs

78 fitting experimental ionization energies in isoelectronic series.

79 thermochemistry, and chemical bonding of the isoelectronic silaisocyanoacetylene and cyanoacetylene p

80 ature dependence, previously observed in the isoelectronic sperm whale myoglobin complex.

81 es and open a new avenue for BP as a valence isoelectronic substitute for CC in arene systems.

82 e(10) (0 < or = x < or = 2) was generated by isoelectronic substitution in octahedral positions of Pb

83 e5-xTex (x = 0-0.5) with space group through isoelectronic substitution of Te for Se have been prepar

84 ese aspects of their behaviour with those of isoelectronic sulfur oxides and N,O anions.

85 titution of a small amount of tellurium with isoelectronic sulfur.

86 ormational change of BH(3)NH(3), which is an isoelectronic system with ethane.

87 ructures is explored through calculations on isoelectronic systems containing boron atoms.

88 orbital energy and composition for formally isoelectronic tetraoxometalates are evaluated in terms o

89 )(Ru(5))(22-) results in a (Ru(5))(22-) ring isoelectronic to (Cd(5))(2-).

90 is presumably mediated by a borenium species isoelectronic to 2-aminophenylboranes.

91 alent iron bound to a nitroxido anion and is isoelectronic to an iron(II) peroxo complex.

92 O3- and SO3(2-) anions, and O5(2-) is valent isoelectronic to ClO4- and SO4(2-).

93 Despite being isoelectronic to phenylnitrene 4, the phenyloxenium ion

94 ormalism involving E(8)(8)(-) rings that are isoelectronic to S(8).

95 HNO is isoelectronic to singlet O(2), and we have previously re

96 Ar'MMAr'](2)(-) and [ArMMAr](2)(-) which are isoelectronic to the corresponding doubly bonded, neutra

97 O4(2-) is valent isoelectronic to the well-known ClO3- and SO3(2-) anions

98 ons for a variety of ketones, in addition to isoelectronic transposition of F(+) for O.

99 containing an unsaturated two-boron bridge, isoelectronic with a C=C double bond, was achieved by re

100 Bis(Lewis base)borylene adducts are isoelectronic with amines and phosphines.

101 h the trigonal planar [AgSn3]11- units being isoelectronic with CO(3)2-.

102 or Gln, and neutral Glu is isostructural and isoelectronic with Gln.

103 D5h star-like CsF5 , formally isoelectronic with known XeF5 (-) ion, is computed to be

104 Mono(Lewis base)-stabilized borylenes are isoelectronic with singlet carbenes, and their reactivit

105 In addition, we reveal that Cd, nominally isoelectronic with Sn, favorably impacts the electronic

106 m ions 1 are reactive intermediates that are isoelectronic with the better known arylcarbenium and ar

107 Indeed, the boron center in PhBCO is isoelectronic with the carbene center in PhCH.

108 bstituted acepentalene derivatives which are isoelectronic with the known acepentalenediide dianion a

109 e9(Sn(i)Pr3)3](2-) that resembles but is not isoelectronic with the known borane version B21H18(-) or

110 is predicts that (BF)4 and (BCl)4, which are isoelectronic with, respectively, (CO)4 and (CS)4, shoul

111 The stability of isoelectronic X(3) systems thus decreases when moving fr

112 Their geometry and bonding resemble that of isoelectronic XeF(n) molecules, showing a caesium atom t

113 the H-Cl stretch on formation of the linear isoelectronic Y...H-Cl complexes (Y = N(2), CO, BF) have