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1 o a stretching force of 1-2 nN (depending on isomer).
2 isomer after the addition of only 10% of the isomer.
3 olarization and molecular properties of each isomer.
4 eoyl glucose was found to be the predominant isomer.
5 Z-isomer of which is less potent than the E-isomer.
6 third step leads back to the stretched trans isomer.
7 angement to the energetically favorable para isomer.
8 (3) which in solution is converted to the E-isomer.
9 ces of detecting and even isolating the bird isomer.
10 l quantities of a kinetically favored olefin isomer.
11 were explored and shown to be conformational isomers.
12 the relative stability of the peroxy radical isomers.
13 reversibly transforms to pre-vitamin D3 type isomers.
14 sections, enabling powerful analysis of many isomers.
15 stable than the corresponding pi-conjugated isomers.
16 ation of the cis faster than their all-trans isomers.
17 he nature of the features distinguishing the isomers.
18 est affording small amounts of the tail-tail isomers.
19 9% yield with a general preference for the E-isomers.
20 fractional tuning of the two configurational isomers.
21 g the stereochemically challenging anti-anti isomers.
22 tic interconversion zone between the E and Z isomers.
23 iding a second method for distinguishing the isomers.
24 dence for the relative population of the two isomers.
25 o search for these interesting and important isomers.
26 eltaDeltaDelta and LambdaLambdaLambdaLambda) isomers.
27 OH group forming six distinct peroxy radical isomers.
28 hat it contained TBPP isomers instead of ITP isomers.
29 h n > 3, as well as other metastable C6H6(+) isomers.
30 rmined the activity of the individual olefin isomers.
31 eas iso 18:0 was discriminated from cis-16:1 isomers.
32 tion) to give a mixture of in,in and out,out isomers.
33 tein binding from a mixture of equilibrating isomers.
34 OS) and their respective linear and branched isomers.
35 (mean +/- SD: 0.13% +/- 0.04%) and trans ALA isomers (0.05% +/- 0.01%) in 395 erythrocyte samples col
36 f both X1B and X2B were a monogalloylglucose isomer (1), a HHDP-glucose isomer (2), castalin (3) gall
37 highly stable conformation of the so-called isomer 2(B) has been obtained for full-length guanylin,
39 onogalloylglucose isomer (1), a HHDP-glucose isomer (2), castalin (3) gallic acid (4), vescalagin (5)
40 erization of methylenedianiline (MDA) 2-ring isomers (2,2'-, 2,4'-, and 4,4'-MDA) is reported using m
41 series of bidentate bis(pyridine) anthracene isomers (2,3-PyAn, 3,3-PyAn, 2,2-PyAn) that differ in th
42 he E-isomers (4-6) or predominantly as the Z-isomer (3) which in solution is converted to the E-isome
43 yptophan, chrysoeriol-6,8-di-C-pentoside and isomers 4, 5, 9 and 12 of diferulic acids key compounds
44 le bond was synthesized in the form of the E-isomers (4-6) or predominantly as the Z-isomer (3) which
46 d all-trans-astaxanthin, two cis-astaxanthin isomers, 5 astaxanthin monoesters, and 10 astaxanthin di
48 nyls (PCBs), 3 hexabromocyclododecane (HBCD) isomers, 6 mycotoxins, 6 inorganic compounds) together w
51 DFT calculations indicate that the [1,2-a]-isomer adopts a twisted, helical C2-symmetric structure
52 ds in both switching directions, i.e. >90% E isomer after irradiation with 470 to 530 nm light and 99
53 ned at the mobility of OTFTs having pure syn isomer after the addition of only 10% of the isomer.
55 treated with varying concentrations of each isomer alone and in different combinations revealed that
56 ortho-tetrachlorobenzoquinone over its para-isomer and 1,3-cyclohexadiene over its 1,4-isomer, perha
57 s with the addition of only 0.01% of the syn isomer and is pinned at the mobility of OTFTs having pur
58 (IMS) has proven to be useful in separating isomer and isobar ions; however, IMS-MS suffers from dec
62 ent of the stoichiometry of the two PSI-LHCI isomers and changes in the oligomeric state of the PSI-L
63 ng with their (omega)-linked or alpha-methyl isomers and ethanolamide derivatives, as well as 2-hydro
64 tial energy surface (PES) between (C2H2)n(+) isomers and provide evaporative cooling to dissipate the
65 ddition of TrFE: the cis and trans head-tail isomers and the trans head-head isomer, where the CHF gr
67 1 to 10:1 for 20 examples), favoring the cis-isomer, and good to excellent enantioselectivity (70-91%
68 hosphorus FRs (PFRs), 2 Dechlorane-Plus (DP) isomers, and 3 hexabromocyclododecane (HBCDD) isomers in
69 somers that were baseline resolved, four dp6 isomers, and the observation of a dp3 oligosaccharide.
71 spontaneous cis-trans isomerism, and the cis isomers are much more difficult to stabilize than the tr
72 the complex, corresponding to two different isomers, are populated at room temperature, and the two
73 lpha-conotoxins have focused on the globular isomers as the ribbon and bead isomers typically have lo
74 rization between the two product merocyanine isomers, as well as their ring-closure reaction back to
75 asurements currently possible for individual isomers at very low temperature and observations of isom
76 the experimental data available for selected isomers at very low temperature, the present results pro
78 organic product obtained from the head-tail isomers: BF3.OEt2 is selective for 1,1,2,3-tetrafluorocy
80 , HPW) are more stable than less substituted isomers but are destabilized within smaller concave envi
81 be used to discern cis and trans double-bond isomers by virtue of the differences in the fragmentatio
83 rred (from DFT calculations) trans head-head isomer (cf. 50% with PMe3) and the largest affording sma
85 ion of distinct product ion spectra for each isomer, clearly indicating the binding sites for the maj
87 e ternary complex generates the active trans-isomer competent for carbonyl bond activation by active-
88 When DMS could not separate cis and trans isomers completely, as was the case with sphingomyelins,
89 In this regime, beta hydroxy peroxy radical isomers comprise approximately 95% of the radical pool,
91 n half-lives adopt a T-shaped ground state Z isomer conformation and proceed through a T-shaped isome
94 , the presence of one hexachlorinated OH-CTT isomer could be verified in the samples, which was about
95 ryl moieties, the thermal stability of the Z-isomers could be enhanced while maintaining the advantag
96 ng the hydrazonation reaction, as only the E-isomers could undergo chelation-controlled reduction.
98 whereas transformations of the nitroso oxide isomers derived from 1b led to a set of stable products:
99 l suited to identify and characterize glycan isomers directly, which presents tremendous challenges f
103 e populated at room temperature, and the two isomers exchange on a timescale of a few picoseconds.
105 ery distinct bands corresponding to isolated isomers experiencing or not the nN --> sigma*N-H electro
106 ct isomers, presumably TTC and TTT cis-trans isomers, for the open-ring merocyanine product, and disc
109 sed photoisomerisation showed that the (5'Z)-isomer gazaniaxanthin is the main (Z)-isomer of rubixant
113 s consists of two states, in which the trans isomer has a stretched and the cis isomer a compact form
115 arison with three other known BN naphthalene isomers has established two guiding principles for predi
117 ysis shows that while CS and HS disaccharide isomers have similar drift times, they can be uniquely d
119 ond are converted by UV irradiation to the Z-isomers having bifurcated O-H...O...H-X hydrogen bond.
121 ) cluster have shown that the global minimum isomer I possesses a geometric structure which resembles
122 ficulties to be resolved from its structural isomer (i.e., phosphatidylglycerol, PG, another low-abun
123 d to reduce the energy disorder by isolating isomer ICBA-tran3 from the as-synthesized ICBA-mixture.
124 ver, the lack of formation of the anthracene isomer implies that HACA alone cannot be responsible for
127 C bond formation transition state to the S-E isomer in the case of MeQd and the R-E isomer with TMSQ
130 expense of 15-anti, which is the predominant isomer in the wild type, and abolishes the peak current
133 the contribution of individual ITP and TBPP isomers in four commercial flame retardant mixtures: FM
135 h is known but less common than other Keggin isomers in polyoxometalate and polyoxocation chemistry.
138 antioselective hydrogenation for both olefin isomers in the case of alpha,beta-dialkylvinyl esters.
141 n spectrum discovered the coexistence of two isomers in the ion beam, including the one with the Al=A
142 ionisation efficiency of vitamin D3 and its isomers in UHPLC-MS/MS and improved the separation and f
143 nd 3, we revealed two calix[2]pseudorotaxane isomers in which the calix-wheel adopts 1,2,3-alternate
145 acterization of the separated constitutional isomers indicated that they possess different melting po
154 solvent: in highly polar solvents, the meta isomer is the most reactive, whereas the ortho isomer is
155 ycolytic interconversion of phosphoglycerate isomers is catalysed in numerous pathogenic microorganis
159 creased by the co-analysis of its structural isomer, lactosylceramide (LacCer), which is not an alpha
164 nonprotease-cleavable enantiomer, the VC(R) isomer, mediated effective cell killing with a cysteine-
167 e and p-tolualdehyde leads to the open-chain isomers, namely (2-hydroxybenzylidene)hydrazono-2-phenyl
168 es, and heteroanalogues) and the other known isomers, namely, corrphycene, hemiporphycene, and isopor
169 ternary S,N,O anions such as the structural isomers NSO(-)/SNO(-) and SSNO(-) are rarely mentioned i
171 to be general, implying that the metastable isomer of a photoswitch can be isomerized to the more st
177 (5'Z)-isomer gazaniaxanthin is the main (Z)-isomer of rubixanthin and the (13Z)-isomer is the main (
180 ngly, the spontaneous resolution of chiral S-isomer of the 1-SH adduct occurred during crystallizatio
181 shift affords stereospecifically the E or Z isomer of the 5-alkenyl-4-iminohydantoin products from t
182 ochemistry of its alkene; alternatively, one isomer of the compound can be subjected to stereoselecti
186 group at the C3-position favors the C-bound isomer of the ligand-supported palladium(II) complexes a
189 revealed the conversion of the cis to trans isomer of unsaturated fatty acid upon short-term nZVI ex
191 inazolin-4(3H)-one nucleus of both aS and aR isomers of 1 had a critical effect on the inhibitory act
195 We have prepared and fully characterized two isomers of [Ir(IV) (dpyp)2 ] (dpyp=meso-2,4-di(2-pyridin
203 ecent report showed that the bead and ribbon isomers of GeXIVA are more potent than the globular isom
204 roscopy for the identification of positional isomers of hydroxy-atorvastatins, the primary metabolite
206 ification and quantification of types of (Z)-isomers of lycopene and rubixanthin in both rosehips and
208 a family of powerful odorants, including the isomers of mintlactone and menthofurolactone that occur
209 ein report the preparation of constitutional isomers of pentahydroxy-functionalized pillar[5]arenes v
210 carrier that binds the all-trans and 11-cis isomers of retinal and retinol, and this facilitates the
213 and other seed oils, while the (2)D allowed isomers of TAG containing 18:3 fatty acyl chains as well
214 nt, including para-functionalized structural isomers of the type M2(p-dobdc) (p-dobdc(4-) = 2,5-dioxi
215 s from the existence of higher-energy Zundel isomers of this cluster and the role these isomers might
217 uene, ethylbenzene, and the three structural isomers of xylene (BTEX) in the concentration range of 0
218 However, coexisting structurally similar isomers often render an unambiguous identification impos
219 i-substituted borate anion consisting of two isomers, one with both nitramido ligands attached to B t
222 alf ( approximately 60%) of all hypothetical isomer pairs, including leucine and isoleucine, whereas
223 a-isomer and 1,3-cyclohexadiene over its 1,4-isomer, perhaps hinting at the potential for concerted 2
224 different combinations revealed that the two isomers potentiate the induced-inhibition of protein ger
227 natural product in 69 % yield from the minor isomer present in an equilibrating mixture of labile ena
229 spectra, we identify two spectrally distinct isomers, presumably TTC and TTT cis-trans isomers, for t
230 tion of the cofactor, for which two distinct isomers, prFMN(ketimine) and prFMN(iminium), have been o
231 nal matrix of isotopic shifts is specific to isomers, providing a fundamentally new approach to the c
232 oxazol-5(3H)-ylidene)ethanal (10), the trans isomers recombined forming the corresponding nitro and n
233 efins capable of precisely targeting a given isomer regardless of the nature of the features distingu
238 ypically, switching from more to less stable isomer(s) is performed by irradiation with UV or visible
240 rity of the highest affinity HMO ligands (or isomer sets that contain the highest affinity ligands) i
241 ctra of 2, 6, 8, and 9 show a clear trend in isomer shift (delta), with a decrease in delta as metal-
242 pectra for the cis and trans-Zundel and ring isomers show prominent features that do not match with e
243 (199 Da) parent ions, whereas in MALDI each isomer shows significant formation of three precursor io
244 g of the photoelectron spectrum of the ortho isomer shows that the ground state of the anion is a tri
246 chiral drugs and metabolites, constitutional isomers, stereoisomers, and organohalogenated species.
247 ate sn-positional and double-bond-positional isomers, such as the regioisomeric phosphatidylcholines
249 n the separation and identification of lipid isomers that differ only in site(s) of unsaturation or g
250 which should consider not only charge state isomers that include salt bridges but also protonation a
251 dies are the first to report a set of olefin isomers that synergistically inhibit GGDPS, thus establi
252 zation (dp) ranging from dp4 to dp8, two dp4 isomers that were baseline resolved, four dp6 isomers, a
253 ve been able to estimate in the photoinduced isomer the distance between hydrogen atom and carbon ato
256 ty switch, allowing both linear and branched isomers to be prepared with high selectivity in an effic
257 ate studies trace the preference for E and Z isomers to tetrasolvated- and pentasolvated-monomer-base
258 s acidic MCl2; cagelike adducts of the in,in isomer, trans- Cl2(P((CH2)14)3 P) (M = 2/Pt, 3/Pd, 4/Ni)
259 f first-principles calculations, we find two isomers, two-atom wide ribbon and single-atom chain, lin
260 the globular isomers as the ribbon and bead isomers typically have lower potency at nAChRs than the
261 addition, the Z-delta hydroxy peroxy radical isomers undergo unimolecular 1,6 H-shift isomerization.
262 ant formation of three (of the possible six) isomers upon oxidative cycloaddition of TrFE: the cis an
263 Conversion was only observed for the cis-isomer, verifying that this is a true intermediate and n
264 c equilibration with the [Zr]-O-CH2-B(C6F5)2 isomer was deduced, which showed typical reactions of an
266 ed to a set of stable products: the cis/anti isomer was transformed into (3,4,7-trimethyl-3a,4-dihydr
267 oso compounds, and the most reactive cis/syn isomer was transformed into ortho-nitrosobenzyl alcohol
268 distribution of the different constitutional isomers was dependent on the nature of the substitution,
269 ences in experimental pKa values between the isomers was found to arise from solvation effects, provi
271 lanthracene (DPA) acceptor mediated by these isomers was used as a proxy for the efficacy of orbital
272 ridged (Si(H)SiH) and di-bridged (Si(H2 )Si) isomers, was initially formed in the gas-phase reaction
273 (TBECH or DBE-DBCH) and the pure beta-TBECH isomer were subjected to in vitro biotransformation by h
274 while those for the beta-, gamma-, delta-HCH isomers were -29.0 +/- 0.3 per thousand, -29.5 +/- 0.4 p
275 ) in >/=98% of the samples, whereas the o,p' isomers were above the LOD in at least 80% of the sample
276 on, six molecular probes using available DNP isomers were developed and investigated to evaluate the
277 ic conditions, two cis-trans styrylflavylium isomers were identified, which could be interconverted d
278 bitrap MS system, isobaric peptide and sugar isomers were successfully resolved and the identities of
282 d promotes the generation of chiral benzylic isomers, when combined with a Hantzsch ester as the redu
283 ns head-tail isomers and the trans head-head isomer, where the CHF group is defined as the TrFE "head
284 that permit the simultaneous discernment of isomers which differ in both the positions of acyl chain
286 Here we show that Lewis and blood group isomers, which have identical fragmentation spectra, exh
287 presence of ribose generated kinetin and its isomer, while its reaction with adenosine generated kine
290 lly stable under ambient conditions, and the isomer with two N-connected ligands was characterized by
291 in T1 energies are observed when going from isomers with linear connectivity of the fused benzene ri
292 devise an alternative approach resulting in isomers with the desired orientation of the nucleobase.
294 orm field ion mobility for a narrow scope of isomers with variations in both bond coordination and st
295 of GeXIVA are more potent than the globular isomer, with low nanomolar half-maximal inhibitory conce
296 ntioseparation of E(R), Z(R), E(S), and Z(S) isomers, with a characteristic interconversion zone betw
297 s relative to their corresponding structural isomers, with the Fe, Co, and Ni variants showing more t
298 identification of cis and trans double-bond isomers within intact complex lipid mixtures using elect
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