ライフサイエンスコーパス: isomerize

1 nd may be set by the proportion of rhodopsin isomerized.

2 Upon illumination, retinal is isomerized.

3 The bound complex then slowly isomerizes (0.1 s-1) to a distinct configuration that ac

4 Light isomerizes 11-cis-retinal in a retinal rod and produces

5 Absorption of a photon isomerizes 11cRAL to all-trans-retinaldehyde (atRAL), br

6 he intramolecularly sensitized precipiton 2Z isomerized 250 times faster (k(2Z-->2E) = 1.0 x 10(-3) s

7 -one (MIO)-dependent family of catalysts and isomerizes (2S)-alpha-phenylalanine to (3S)-beta-phenyla

8 Attempts to isomerize 4 to the thermodynamically favored C,C-dialkyl

9 asis of the covalent bond between enzyme and isomerized 5-FU we propose a Michael addition mechanism

10 cyclin E, mutational data suggest that Pin1 isomerizes a noncanonical proline-proline bond, with the

11 Compound 1 was shown to slowly isomerize about the C-36/C-37 double bond when stored in

12 that c-Fos represents a novel target for the isomerizing activity of Pin1 and support a role for Pin1

13 pcF and CpcE/PecF were used to show that the isomerizing activity that converts phycocyanobilin to ph

14 ive precursor for mechanistic studies of the isomerizing alkoxcarbonylation of methyl oleate.

15 al studies on the overall catalytic cycle of isomerizing alkoxycarbonylation reveal the steric conges

16 le, retinal G protein-coupled receptor (RGR) isomerizes all-trans retinal to 11-cis retinal in the re

17 n in vivo and in vitro, and that it does not isomerize along other double bonds, suggesting that it f

18 ral transitions needed for RNA polymerase to isomerize and engage with the DNA template strand.

19 AzoAMP-3 does not isomerize and exhibits emission (Phi(fl) = 0.0008) at 77

20 ests that the cyclized beta-silyl cation can isomerize and then reopen to a classical aryl-stabilized

21 methionine (AdoMet)-dependent methylation of isomerized and racemized aspartyl residues in age-damage

22 aged proteins by recognizing and methylating isomerized and racemized aspartyl residues in aging prot

23 l residues spontaneously degrade, generating isomerized and racemized aspartyl residues.

24 nzyme useful both as a reagent for detecting isomerized and racemized residues in damaged proteins an

25 ligand binding, this intramolecular agonist isomerizes and induces structural changes in the 7-trans

26 Upon absorption of light, the chromophore isomerizes and the character of the photoproducts (e.g.,

27 hore, retinal, that upon absorption of light isomerizes and thereby triggers biological functions ran

28 be modified, peptide bonds can be cleaved or isomerized, and disulfide bonds can be cleaved.

29 junctions formed through catalysis by XerD, isomerized, and were converted by XerC to reaction produ

30 Highly cracked and isomerized archaeal lipids and bacterial lipids, structu

31 ates on an ultrafast time scale, rather than isomerizing as it does on a lower surface.

32 The disilenyl germylene 5b isomerizes at 40 degrees C to the NHC-adduct of the corr

33 ctivity of ATR is downregulated by Pin1 that isomerizes ATR from cis-isomer to trans-isomer at the ph

34 of the enzyme in the "F" form, which slowly isomerize back to the E form.

35 % of molecules in the trans configuration to isomerize before binding.

36 Moreover, the full-length constructs isomerized before ADP release, which has not been observ

37 itially forming a van der Waals complex that isomerizes below the energy of the reactants and eventua

38 annels are allosteric membrane proteins that isomerize between C(losed) and O(pen) conformations.

39 states is promoted by a "Janus" ligand that isomerizes between binding modes that favor Mn(3+) or Mn

40 echanism by which this protein assembles and isomerizes between closed- and open-channel conformation

41 e-step binding mechanism where actomyosin VI isomerizes between two conformations, one competent to b

42 aintains an affinity for large substrates by isomerizing between the open and closed states with nucl

43 he brains of these embryos often become left isomerized: both sides of the brain develop morphology a

44 to pyramidalization at a carbon atom of the isomerizing bridging double bond.

45 The hydroximoyl chlorides 1Eaand 2Ea only isomerize by the nucleophilic catalysis mechanism.

46 The latter compound was isomerized by a novel enzyme, named Delta3,5,7,Delta2,4,

47 s have shown that polyunsaturated lipids are isomerized by alkanethiyl radicals (S(*)) in a cycle pro

48 ll-trans-retinaldehyde must be chemically re-isomerized by an enzyme pathway called the visual cycle.

49 monstrated that the imine double bond can be isomerized by light (365 nm LED) during the reaction lea

50 rate vision requires that opsin chromophores isomerized by light to the all-trans form be replaced wi

51 sodium amide monomers, whereas 1-pentene is isomerized by trisolvated monomers.

52 Results suggest that it isomerizes by cleavage of either the C1-C2 or C1-C3 bond

53 The hydroximate 1Zb appears to be capable of isomerizing by either mechanism.

54 hat impulsively driven protein motion by the isomerizing chromophore during the 200 fs primary transi

55 ne/threonine residues in target proteins and isomerizes cis isomers to more stable trans configuratio

56 Expression of aconitase, which isomerizes citrate into isocitrate, is controlled by sev

57 protein that oxidizes and, more importantly, isomerizes complex disulfide connectivity in substrates.

58 roscopic equilibria within the collision and isomerized complexes show an opposite relationship.

59 -H...O horizontal lineC in the Z moieties of isomerized compounds.

60 The thresholds for isomerizing conformer A to all six other conformations d

61 s that inactivate OASS and produce the fully isomerized CSC.

62 We found that Ess1 preferentially binds and isomerizes CTD heptad-repeat (YSPTSPS) peptides that are

63 spectrometry that extracts from this strain isomerized cycloeucalenol to obtusifoliol in vitro.

64 generated bismethoximes of 17-isoLGE4 or the isomerized delta11-17-isoLGE4 respectively.

65 Individuals with a symmetric, right-isomerized dHb also exhibit increased freezing.

66 contrast, larvae that have a symmetric, left-isomerized dHb, or in which just the left dHb-IPN projec

67 sylation reactions using a prop-1-enyl donor isomerized directly from an allyl glycoside.

68 lfide isomerase (PDI) oxidizes, reduces, and isomerizes disulfide bonds, modulates redox responses, a

69 vo, while the DsbC-DsbD pathway functions to isomerize disulfides.

70 developed highly stereoselective methods to isomerize electron-deficient propargylic alcohols to E-e

71 DNA-binding domain allows the holoenzyme to isomerize, engage with stably melted DNA and to transcri

72 nched oligoethylene molecule was achieved by isomerizing ethoxycarbonylation and alternatively cross

73 nterestingly, of those trajectories that did isomerize, every one of them violated conventional trans

74 mputational data predict AzoAMP-1 should not isomerize following S(2)<--S(0) excitation because of th

75 e the B-chromophores toward a bleached trans isomerized form.

76 f a bond remotely located in relation to the isomerizing fragment.

77 n makes it sterically possible for Tyr106 to isomerize from a solvent exposed configuration to a buri

78 duction in solution, owing to its failure to isomerize from cis to trans, the same could not be inves

79 nic acid sodium salt thus synthesized can be isomerized from its trans to its cis form reversibly in

80 ic surface, and coupled to this, the retinal isomerizes from 13-cis,15-anti back to the initial all-t

81 Structural studies suggest that the enzyme isomerizes from an open to closed form with coenzyme bin

82 assign to a metastable state that failed to isomerize fully.

83 ceptor-channels are allosteric proteins that isomerize ('gate') between conformations that have a low

84 olite that contains tin (Sn-Beta) is able to isomerize glucose to fructose in aqueous media with high

85 closed promoter complex conformation or the isomerized holoenzyme conformation associated with the o

86 ential oil from Saaz variety and tetra-hydro isomerized hop extract (tetra hop), were established usi

87 are synaptic ion channels that spontaneously isomerize (i.e., gate) between resting and active confor

88 mechanism to generate a borane complex that isomerizes if necessary to place the alkyl group cis to

89 dodecadienal; these primary products readily isomerize in an aqueous medium to the corresponding 6E-

90 e click amino acid (F-PSCaa) was designed to isomerize in response to visible light.

91 These intermediates can isomerize in situ to yield a eta(1) nitrile complex.

92 esulted in olefinic isomers that were easily isomerized in acidic conditions.

93 The resultant azobenzene bridge isomerized in response to light, thereby changing the co

94 composes to form unrearranged carbene, which isomerizes in 5 ps.

95 ic carbon-bearing molecules that dynamically isomerize, interconverting between enantiomers without c

96 that the reaction proceeds through a rapidly isomerizing intermediate.

97 V23, may play an important enzymatic role in isomerizing intermolecular disulfide bonds during eggshe

98 ex (RPc), where DNA is double stranded, must isomerize into an open promoter complex (RPo), where the

99 s decomposition, isoxazole was also found to isomerize into several products: 2-formyl-2H-azirine, 3-

100 e significant consequences on its ability to isomerize into the corresponding extended duplex (ED) fo

101 Here, we found that NHPI can be isomerized into isatoic anhydride by an unusually facile

102 d 2,2'-disubstituted terminal alkenes can be isomerized into the more stable internal (Z)- and (E)-al

103 nducting; however, this intermediate rapidly isomerizes into a tighter, fully inhibitory receptor-inh

104 rate-channeling activity, indicating that it isomerizes into the active state under assay conditions.

105 rm in the presence of the Lewis acid center, isomerizes into the acyclic form of fructose, and finall

106 The cis-enediolate quantitatively isomerizes intramolecularly to the trans-enediolate in C

107 that can further react to predominantly form isomerized isoAsp residues upon rehydration (imbibition)

108 f the PTP, the recombinant truncated AaIPPI1 isomerized isopentenyl pyrophosphate (IPP) to dimethyl a

109 way that phosphorylates the C-4 hydroxyl and isomerizes it to a C-3 hydroxy compound, which is catabo

110 s-retinal (a vitamin A derivative) and light isomerizes it to all-trans-retinal, which activates the

111 of the alpha-subunit of phycoerythrin II and isomerizes it to phycourobilin.

112 photon by a rhodopsin or cone-opsin pigment isomerizes its 11-cis-retinaldehyde (11-cis-RAL) chromop

113 e (SAM), and pyridoxal 5'-phosphate (PLP) to isomerize L-alpha-lysine to L-beta-lysine.

114 oerythrocyanin alpha-subunit phycocyanobilin isomerizing lyase, PecE/PecF, from Noctoc sp. PCC 7120.

115 To isomerize M6P to F6P requires a rotation of its C2-C3 bo

116 A flash causing a few hundred isomerized melanopsin molecules in a retina is sufficien

117 early demonstrated that ACO is in fact a non-isomerizing member of the CCE family.

118 gradient created by binding of Arr2 to photo-isomerized metarhodopsin.

119 The synthetic utility of isomerizing metatheses is demonstrated by various new ap

120 Overall, the concept of isomerizing metatheses promises to open up new synthetic

121 d further carbonylation are slow compared to isomerizing methoxycarbonylation of monounsaturated fatt

122 local effective temperature at which a photo-isomerizing molecule attacks its orientationally confini

123 the native form slowly and the remaining 23% isomerizes more rapidly (1.5 s-1).

124 Liberated CypD then isomerizes multiple proteins including p53 (causing p53

125 with the opposite regiochemistry to deliver isomerized N(2)-acyl-2-aminoimidazoles with broad substr

126 terized in the context of the loosely folded isomerized native-like state {N(iso)} predicted in simul

127 currents from adult mouse muscle AChRs that isomerize normally without agonists but have only a sing

128 nsfer an H* back to the metal, generating an isomerized olefin, or (2) add intramolecularly to a doub

129 ing such highly active catalyst systems, the isomerizing olefin metathesis becomes an efficient way t

130 The hydroximate 2Zb may be isomerizing only by iminium ion rotation.

131 le and unloadable conformations subsequently isomerizes or resets the configuration of the nucleotide

132 siae regulates RNA polymerase II (pol II) by isomerizing peptide bonds within the pol II carboxy-term

133 ation site by comparing the MS/MS spectra of isomerized peptides with and without (18)O incorporation

134 The isomerized permeate was subsequently purified to a lactu

135 Ess1 is proposed to control transcription by isomerizing phospho-Ser-Pro peptide bonds within the CTD

136 ned a mystery because the effect of a single isomerized pigment molecule in cones, unlike that in rod

137 Rod absolute threshold corresponded to 12-15 isomerized pigment molecules (R*) in image fields of 800

138 HcmA I90V and I90A mutant enzymes could also isomerize pivalyl- and isovaleryl-CoA, albeit at >10 tim

139 with an indium cocatalyst and Bronsted acid isomerize primary and secondary propargylic alcohols in

140 ferent selectivity toward main metathesis or isomerized products.

141 e (Tyr or Trp) in a position adjacent to the isomerizing proline (if one is not already present) and

142 d plant carotenoid isomerase (CRTISO), which isomerizes prolycopene to all-trans-lycopene.

143 l proliferation, and differentiation through isomerizing prophosphorylated substrates.

144 By isomerizing pSer/Thr-Pro bonds, Pin1 can regulate the co

145 that antibodies containing either one or two isomerized residues were not effective in inhibiting EGF

146 Light isomerizes rhodopsin's retinal chromophore and triggers

147 motifs used by sigma factors to melt DNA and isomerize RNA polymerase to form functional open promote

148 A class I lyase-like family of aminomutases isomerizes (S)-alpha-arylalanines to the corresponding b

149 tase from Chondromyces crocatus (CcTAM) that isomerizes (S)-alpha-tyrosine to (R)-beta-tyrosine.

150 Thus, the isomerizing self-metathesis of oleic and other fatty aci

151 I from becoming trapped with substrates that isomerize slowly.

152 n essential protein that can peptidyl-prolyl-isomerize small phosphopeptides.

153 In contrast, the oxiranyl derivative isomerized smoothly.

154 Some members also isomerize specific double bonds in their substrates to y

155 However, red cone pigment isomerizes spontaneously 10,000 times more frequently th

156 all-trans-retinal which, upon illumination, isomerizes stereospecifically to the 11-cis isomer.

157 ienol ring by protonating C(8) to produce an isomerized structure.

158 rd oxygen and water as well as a tendency to isomerize substrates and react with internal olefin prod

159 framework tin or titanium Lewis acid centers isomerizes sugars, e.g., glucose, via reaction pathways

160 0% of the vinylidenes equilibrated at 1440 K isomerized, suggesting average lifetimes >1 ps for vibra

161 pattern found in frequency-domain spectra of isomerizing systems.

162 (5-FU), reveals a covalent bond between the isomerized target base and tyrosine 140.

163 ose that FKBP51 can use the Hsp90 complex to isomerize tau, altering its phosphorylation pattern and

164 The prolyl isomerase Pin1 binds and isomerizes tau and has been implicated in protecting aga

165 al(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position.

166 jaundice may be managed with phototherapy to isomerize the biosynthetic 4Z,15Z-bilirubin-IXalpha to m

167 ective epoxidation/deoxygenation sequence to isomerize the C(13,14) olefin, and a biomimetic quinone-

168 ement of the blocks and therefore Mcm10 must isomerize the CMG-DNA complex to achieve the bypass func

169 deprotection/reprotection step concurrently isomerize the conjugated chromophore to the all-E isomer

170 stoichiometric amount of reduced species can isomerize the entire mixture.

171 ains and use ATP hydrolysis-driven energy to isomerize the RNA polymerase-sigma(54) complex during tr

172 ger loop, and active-center side chains that isomerize the triphosphate of bound NTP and two Mg(2+) i

173 In this model, Ess1 binds and isomerizes the CTD of RNA polymerase II, thus altering i

174 erein we describe a system that specifically isomerizes the retinylidene protonated Schiff base both

175 Importantly, Pin1 isomerizes the serine118-proline119 bond from a cis to t

176 h PDI and ERp72 reduce Py, ERp57 principally isomerizes the virus in vitro, a reaction that requires

177 inear pentenes via hydrogen bonding, rapidly isomerizing the double bond.

178 , the amine 8a was obtained and found not to isomerize thermally to the anticipated atropisomer 8b (i

179 Monosubstituted carbodiimides isomerize thermally to the corresponding cyanamides (e.g

180 ile none of the mutant enzymes is capable of isomerizing these substrates, the R207Q (single and doub

181 isomerization conditions, (Z)-7 can readily isomerize to (E)-7.

182 dehydro[10]annulene (2), a molecule known to isomerize to 1,5-didehydronaphthalene (4) above -50 degr

183 estigation suggests that 3-butenenitrile can isomerize to 2-butenenitrile, a conjugated nitrile, befo

184 S4-symmetric structure and then subsequently isomerize to a T-symmetric tetrahedron for better accomm

185 nitrosamine intermediate, CH3NHNO, which can isomerize to an alkyldiazohydroxide, CH3NNOH, and furthe

186 rming ureate ligands, which upon thermolysis isomerize to bridging carbodiimides.

187 derive from endoperoxide intermediates that isomerize to D/E-ring forms or that are reduced to F-rin

188 mic compound ajmaline, or alternatively, can isomerize to form perakine, an alkaloid with a structura

189 Specific ligand complexes, however, slowly isomerize to give a high-affinity complex.

190 lable starting materials, have been found to isomerize to high E/Z ratios after storage at -20 degree

191 Previously, we hypothesized that dGh could isomerize to iminoallantoin (dIa) via a mechanism simila

192 , RNA polymerase must change conformation or isomerize to its active form.

193 ecified early in the transcription cycle and isomerize to other forms slowly.

194 s complete Diels-Alder reaction and does not isomerize to Q.

195 The resulting 1-pyrazolines isomerize to regioisomeric 2-pyrazolines (a or b) or und

196 ions (13+ to 6+) yield products that rapidly isomerize to structures that have smaller collision cros

197 cal test of whether an inactive filament can isomerize to the active state.

198 th the trans form of proline 168, which must isomerize to the cis form during refolding.

199 All nitrile imines isomerize to the corresponding carbodiimides both therma

200 cal anion of the Z isomer is able to rapidly isomerize to the corresponding E configured counterpart

201 initial encounter reaction, and subsequently isomerize to the final tertiary fold in a second slower

202 omplex with proR9 at the same rate but which isomerize to the fully folded complex at much different

203 Fluorescent DCCs, formed by this enzyme, isomerize to the respective NDCCs in weakly acidic mediu

204 rane(5) anion derived from 9-BBN is found to isomerize to two regioisomeric species via a proposed me

205 -phosphate (MTR 1-P) and adenine; MTR 1-P is isomerized to 1-methylthio-d-xylulose 5-phosphate (MTXu

206 On rapid heating, the resulting carbenes isomerized to 2,4-didehydroadamantanes by intramolecular

207 ion, the chromophore 11-cis retinal is first isomerized to all-trans retinal, followed by conversion

208 n, contains an 11-cis retinyl moiety that is isomerized to all-trans upon light absorption.

209 On absorption of light, 11-cis-retinal is isomerized to all-trans-retinal, constituting a one-way

210 ost opsins is 11-cis-retinaldehyde, which is isomerized to all-trans-retinaldehyde by absorption of a

211 (i) Allylic hydroperoxides may be isomerized to alpha,beta-epoxyalcohols by a heterolytic

212 (IDH2) to form isocitrate, which can then be isomerized to citrate.

213 These isomerized to diastereomeric hydroxymethylphosphonamidat

214 a normal diet, indicating that MAA could be isomerized to FAA in the absence of MAAI.

215 ecular disulfide bond with C207 that must be isomerized to form the active C207-C207 intermolecular b

216 sted and Lewis acid sites is that glucose is isomerized to fructose at low temperatures, while direct

217 (S)-alpha-arylalanine was enantioselectively isomerized to its corresponding (R)-beta-product.

218 HP)-O-P=C=NHC in which the PCO unit has been isomerized to OPC.

219 e-1,4-dicarboxylate (10), which subsequently isomerized to produce trans-1,2-cyclohexanebis-alpha-acr

220 The initial all-trans-form isomerized to the 13-cis isomer more rapidly at 80 degre

221 by BCMO1, part of the 9-cis-double bond was isomerized to the all-trans-stereoisomer, yielding all-t

222 fmDMAPP) are alternate substrates, which are isomerized to the corresponding IPP derivatives.

223 he third last residue is posttranslationally isomerized to the d configuration.

224 , neuropeptides that have the second residue isomerized to the D-isoform are distinguished from their

225 inal metathesis conditions while the Z-diene isomerized to the E-isomer.

226 lytic, in which the hydroperoxy substrate is isomerized to the epoxyalcohol or keto product.

227 ing of the rapid formation of a complex that isomerized to the final charge-transfer complex.

228 he metastable isomer of a photoswitch can be isomerized to the more stable one catalytically upon red

229 Under UV irradiation, the SP was isomerized to the open merocyanine (MC) form, causing th

230 one-pot fashion, an allyl glycoside is first isomerized to the reactive 1-prop-en-yl glycoside interm

231 e product, vinylacetyl-CoA, which is further isomerized to the thermodynamically stable normal produc

232 However, the S-isomer is rapidly isomerized to the trans-trans-2,4-conjugated diene.

233 etinol and all-trans-13-desmethylretinol are isomerized to their corresponding 11-cis-alcohols, altho

234 Erythrose 4-phosphate is epimerized and/or isomerized to threose 4-phosphate, which is subsequently

235 +/- 1 cal mol(-1) K(-1)), which subsequently isomerizes to (eta(2)-O(2))V(N[(t)Bu]Ar)(3) (3) (DeltaH(

236 14 then isomerizes to 15, thus connecting low- and high-temperat

237 ylnitrene 35 to 1-cyanoindene 36, which then isomerizes to 3- and 2-cyanoindenes 12 and 13.

238 acid or conditions, to give [t-H3](+), which isomerizes to [t-H3'](+), wherein all PMe(3) ligands are

239 1,2,4-triazin-4(3H)-ol (4-OH), which rapidly isomerizes to a 3,4-dihydro-1,2,4-triazine-based nitrone

240 mu-1,2-O2(2-))](2+) (2(P)) that subsequently isomerizes to a bis-mu-oxodicopper(III) complex, [{((DMM

241 on of an initial collision complex (EI) that isomerizes to a highly stable complex (EI*) from which I

242 se separation is induced when the precipiton isomerizes to a low-solubility form.

243 ontains non-native structure that rearranges/isomerizes to a more native-like species.

244 The ED(o1) further isomerizes to a more stable open complex, ED(o2), with a

245 s rapidly dissociate, whereupon the antibody isomerizes to a nonbinding isomer.

246 in which the open channel:inhibitor complex isomerizes to a nonconducting receptor form.

247 m, the conducting receptor:inhibitor complex isomerizes to a nonconducting state with a rate constant

248 the cation radical of 1g, which sequentially isomerizes to a novel sigma-radical with an O,O 3e bond

249 ever, the first intermediate is unstable and isomerizes to a second intermediate, which was isolated.

250 disubstituted pi-allylruthenium complex that isomerizes to a thermodynamically more stable monosubsti

251 nducting channel intermediate, which rapidly isomerizes to a tighter complex.

252 e isomeric a(7)-PhobPH has been detected but isomerizes to a(5)-PhobPH rapidly in the presence of wat

253 that 6 forms via a carbene complex (1d) that isomerizes to aminomethyl complex 7d.

254 Allenyl carbinol ester 3 isomerizes to an E,Z mixture of the corresponding diene

255 ives formation of a tetramer, mR1(4a), which isomerizes to an inactive form, mR1(4b), and ATP binding

256 This complex isomerizes to an open complex, ED(o1), in an energetical

257 t 300 degrees C, bicyclo[4.2.0]oct-2-ene (1) isomerizes to bicyclo[2.2.2]oct-2-ene (2) via a formal [

258 egrees C, the kinetically formed allylborane isomerizes to give the thermodynamic allylborane 12E wit

259 1:1), a readily available starting material, isomerizes to high E/Z ratios by storage at -20 degrees

260 ations, the initial collision complex either isomerizes to its cis-form or undergoes a hydrogen atom

261 In room light, marinomycin A slowly isomerizes to its geometrical isomers marinomycins B and

262 carbene Ph-C-R and different LiCN species or isomerizes to PhCRCNLi in the presence of LiX (X = Cl, I

263 the Rho-RNA species PR1, which subsequently isomerizes to PR2 with a rate constant 21 s(-1).

264 The PR2 isomerizes to PR3 with a rate constant of 32 s(-1) in th

265 The first form, Q*, either reacts with Cp or isomerizes to Q, a form that is significantly less react

266 photon, the covalently bound 11- cis-retinal isomerizes to the all- trans form, enabling rhodopsin to

267 nterior of the visual receptor rhodopsin and isomerizes to the all-trans configuration following abso

268 This radical isomerizes to the beta-Lys* radical (state 4(Lys*)), whi

269 lly found in the outermost layer of skin and isomerizes to the cis isomer upon exposure to UV radiati

270 cinnamate attached to the active-site serine isomerizes to the cis isomer which then rapidly lactoniz

271 nerates an isotoluene-type intermediate that isomerizes to the isolated aromatic product upon exposur

272 In this model, 77% of the subtilisin isomerizes to the native form slowly and the remaining 2

273 lled abnormal C-5 NHC lithium complex slowly isomerizes to the normal C-2 NHC, and the process can be

274 )-CHCHC(6)H(4)S)Mo(PMe(3))(4), which rapidly isomerizes to the olefin-thiophenolate and 1-metallacycl

275 which the initially formed substrate radical isomerizes to the product radical during the rearrangeme

276 n the trigonal bipyramid, which subsequently isomerizes to the thermodynamic isomer with axial chlori

277 y formed E isomer in solution (CDCl3) slowly isomerizes to the Z isomer, indicating greater stability

278 gth before disengaging from the promoter and isomerizing to a stable elongation complex.

279 transporter from binding substrate and from isomerizing to an inward-facing conformation.

280 We find that the enthalpic barrier for N2O4 isomerizing to trans-ONO-NO2 is 43.9 kcal/mol, ruling ou

281 The pseudouridine synthases isomerize (U) in RNA to pseudouridine (Psi), and the mec

282 e of the propensity of these alkyl groups to isomerize under the reaction conditions.

283 (Me(3)Si)(2)CNN isomerizes upon addition of traces of [Me(3)Si](+) ions

284 The pseuoduridine synthases (psi synthases) isomerize uridine (U) to pseudouridine (psi) in RNA, and

285 A subfamily of PUSs, a class of enzymes that isomerize uridine to pseudouridine in noncoding RNAs, su

286 molog of pseudouridine (Psi) synthase, which isomerizes uridine to Psi in noncoding RNAs.

287 Monosilylated divinyl ethers can be isomerized using a cationic iridium(I) catalyst followed

288 (2) collision complex, which is also able to isomerize via a hydrogen shift to the SiNCHCH(3) interme

289 nalized by the ability of the ortho ester to isomerize via an intermediate benzylic cation and examin

290 bacterial and vertebrate rhodopsins start to isomerize via distinct implementations of the same bicyc

291 hrough a short-lived CO(4) intermediate that isomerizes via a symmetric CO(4) transition state contai

292 rangement indicates that the primary product isomerizes via an associative mechanism in DNA.

293 The cis-HCCHBS intermediate either isomerizes via hydrogen atom shift from the carbon to th

294 Depending on the nature of the isomerized VOCs, their next generation oxidation forms h

295 photoswitches, as well as photoswitches that isomerize with red and near-infrared light.

296 The double bond geometry can be optionally isomerized with I(2) to furnish the all-(E)-species.

297 lectron-rich substituents can be effectively isomerized with red light (630-660 nm), a wavelength ran

298 bond is more flexible at the methyl end and isomerizes with shorter correlation times.

299 that, upon S0-S1 excitation, gas-phase CHBr3 isomerizes within 100 fs into the BrHCBr-Br species, whi

300 f a BF(2)-azo complex that can be induced to isomerize without the need of deleterious UV light.