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1 snails enriched with a less common Zn stable isotope.
2 re the key challenges in separation of light isotopes.
3 on represented in global databases of foliar isotopes.
4 oron nitride crystals with nearly pure boron isotopes ((10)B and (11)B) compared to those with the na
5 cords of ocean redox chemistry with nitrogen isotope ((15)N/(14)N) values from approximately 2.31-bil
6 temporal evolution of (129)I, (236)U, and Pu isotopes ((239)Pu and (240)Pu) in seawater sampled durin
8 levels, tracking the fate of a stable sulfur isotope ((34)S) from its incorporation by microalgae as
11 s, and (2) accurately determines the percent isotope abundance of (15)N-ammonia in a cell lysate for
13 it also highlights the usefulness of stable isotope analyses as tools in the exploration of ecologic
14 al alteration, there have not yet been any K-isotope analyses of altered oceanic crustal materials.
16 ential of conducting (13)C position-specific isotope analysis of organic molecules with high precisio
19 is study illustrates the potential of a dual isotope analysis to differentiate between aerobic and an
23 MS spectra both for the naturally occurring isotopes and for the overlapping of peaks corresponding
25 r standoff detection and analysis of uranium isotopes and indicate the potential of the technique for
28 unparalleled 11-y acoustic telemetry, stable isotope, and mark-recapture dataset to test if a populat
29 This eliminates low-intensity fragments, isotopes, and adducts and may exclude relevant low-inten
34 he pentose-phosphate pathway (PPP) in stable isotope-assisted ex vivo blood incubation experiments an
36 creasing with harmonic order, the unresolved isotopes at the fundamental distribution of cytochrome c
38 distinct ocean regions to create a 'regional isotope characterization', analysed the delta(15) N valu
42 xtended the thiol-redox proteomic technique, isotope-coded affinity tag labeling, to quantify the ext
43 roach, called SNOxICAT (S-nitrosothiol redox isotope-coded affinity tag), we found that exposure to N
44 study reports the first data on mercury (Hg) isotope composition in marine European fish, for seven d
48 lcanic arcs and demonstrated that the carbon isotope composition of mean global volcanic gas is consi
56 es and come in various forms, such as stable isotopes, compound specific analyses (e.g., amino acids
57 trations (8 ngm(-3) to 302 ngm(-3)) and dual-isotope-constrained sources (19 to 73% contribution from
58 vements in instrument parameters and natural isotope correction enable more accurate measurement of m
59 ra at high resolution, we found that natural isotope correction for high-resolution labeling data req
60 on, double-spike mass spectrometry stable Pb isotope data allow clearer discrimination of historical
64 redox-sensitive trace element, and nitrogen isotope data from a Neoproterozoic (Marinoan) glacial ep
69 in the context of iron speciation and carbon isotope data suggests biogeochemical cycling across a dy
70 als, and then combined the bone and regional isotope data to track individual animal movement pattern
71 structions and ground-truthed with new Hf-Nd isotope data, suggest that uppermost mantle at one locat
74 te the utility of these metrics using stable isotope data; however, the approaches are applicable to
75 Within these limits, the carbonate carbon isotope (delta(13)C) record becomes insensitive to chang
76 h a recently published benthic stable carbon isotope (delta(13)C) record from the southernmost extent
77 ured the naturally occurring stable nitrogen isotope (delta(15) N) patterns that differentiate distin
78 on along environmental gradients in foliar N isotope (delta(15)N) and C isotopic discrimination (Delt
79 nalyze a new high-resolution deep-sea oxygen isotope (delta(18)O) record from the South Atlantic Ocea
80 ed and seasonally-resolved stalagmite oxygen isotope (delta(18)O) records from Shihua Cave, North Chi
81 nitrogen amino acid (delta(15)NPhe), and Hg isotope (Delta(199)Hg, Delta(201)Hg, delta(202)Hg) data
82 elevational movements, we measured hydrogen isotope (delta(2) H) values of metabolically inert feath
83 Barium-to-calcium ratios (Ba/Ca) and carbon isotopes (delta(13)C) measured in long-lived coralline a
85 d from foraminiferal Mg/Ca and stable oxygen isotopes, delta(18)O) in combination with a recently pub
86 frared excitation between these strongly H/D isotope-dependent VA potentials then accounts for most o
89 ith (13)C, D2-formaldehyde, and developed an isotope dilution analysis method to quantitate these org
95 with the use of liquid-chromatography-stable-isotope dilution-multiple-reaction monitoring-mass spect
97 ent and certification process included three isotope-dilution mass spectrometry approaches, with meas
98 Alaska to examine long-term trends in carbon isotope discrimination and growth of black and white spr
100 tion, this dimer surprisingly yields bimodal isotope distributions for the majority of peptides, demo
101 spectro-electrochemistry and site-selective isotope editing to monitor the CO/CN(-) stretching vibra
103 t (KIE), commitment factor (Cf), and binding isotope effect (BIE) measurements combined with quantum
104 The measurement of a deuterium equilibrium isotope effect (EIE) for the aryl CH...Cl(-) interaction
107 elow approximately 10 K, and a large kinetic isotope effect (KIE) is observed upon substituting the t
109 Deuteration at C-3 produced a strong kinetic isotope effect for 3-hydroxylation but not 4-hydroxylati
112 eration of proton migration (inverse primary isotope effect), whereas deuteration of the methyl group
113 a different peptide matrix, changes the net isotope effect, but the proton inventory plot remains li
114 roton transfer shows a prominent H/D kinetic isotope effect, which is determined to be 8.3 x 10(8) s(
118 extended to the associated secondary kinetic isotope effects (KIEs), indicating very similar transiti
121 enrichments, with focus on mass-independent isotope effects due to symmetry, ignoring smaller mass-d
125 od is also applicable to measuring secondary isotope effects on acidity, and we could demonstrate tha
126 hment of (15)N in NDMA was indicative of the isotope effects pertinent to bond-cleavage and bond-form
127 Mechanistic studies especially using kinetic isotope effects show that cleavage by oxidative addition
128 and the absence of deuterium solvent kinetic isotope effects suggested stepwise mechanisms with thiol
130 eavy enzymes demonstrate normal heavy-enzyme isotope effects, and F159Y PNP is a rare example of an i
132 he isotopic abundance of the employed stable isotope (either (2)H or (13)C) within a specified list o
133 adjacent layers revealed the specificity of isotope engineering in a layered material, with a modifi
135 yze the fate of individual atoms from stable isotope-enriched precursors to products to deduce metabo
137 l T1), and was found accompanied by a carbon isotope enrichment of 5 per thousand and 2.9 per thousan
138 iciently at temperatures above 80 K, when an isotope exchange allows the preferential adsorption of h
139 gen bond geometry upon hydrogen-to-deuterium isotope exchange is obtained from a comparison of experi
140 ence of the dihydrogen complexes, as well as isotope exchange reactions, provide evidence for propose
141 photosynthesis and respiration, hydrospheric isotope exchange with water, and stratospheric photochem
143 foraminifera measurements of the PETM carbon isotope excursion from Maud Rise have been interpreted a
147 ratios were not consistent with the expected isotope fingerprints of CCRs, but rather mimic the compo
148 o acid-coded mass tagging (AACT) with stable isotopes followed by tandem mass spectrometry sequencing
151 ta (13)Cbulk) and nitrogen (delta (15)Nbulk) isotopes for nine bat species from different feeding gui
152 At present, the most successful groups of isotopes for this purpose are (123)I/(124)I/(131)I, (68)
153 es (measuring atmospheric mole fractions and isotopes) for constraining these geological emissions ha
154 iron bonds, we calculate an equilibrium iron isotope fractionation between silicate and iron under co
155 udy investigates for the first time hydrogen isotope fractionation during both aerobic and anaerobic
157 for the first time both carbon and chlorine isotope fractionation for three different engineered rea
158 itions, suggesting that the observed C and N isotope fractionation in NDMA may be diagnostic for NDMA
161 ellular solution pH, the pH-dependence on Mg isotope fractionation is thus due to differences in fung
163 and (15)N/(14)N ratios of NDMA give rise to isotope fractionation trends that can be used to infer N
166 Here we report the capture of heavy hydrogen isotopes from hydrogen gas by selective adsorption at Cu
167 We measured Hg, major ions, and stable water isotopes from the snowpack through the entire spring mel
169 iled a global data set for carbon and helium isotopes from volcanic arcs and demonstrated that the ca
170 evidence of Fukushima-derived (236)U and Pu isotopes has been found in this study, although further
172 esults have important implications for water isotope heterogeneity in plants and for our understandin
180 hese lipoproteins was studied using a stable isotope infusion of D3-leucine, gas chromatography/mass
181 equilibration of tracer isotopes with sample isotopes is not possible prior to beginning chemical sam
183 0000 allowed us to separate different stable isotope labeled analogues across a large range of metabo
186 receipts containing relevant levels of BPA (isotope-labeled BPA-d16) for 5 min, followed by hand-was
187 ectrometry, and phosphopeptide enrichment of isotope-labeled peptides, we examined the dynamic of the
189 a method based on high-performance chemical isotope labeling (CIL) nanoflow liquid chromatography ma
194 lubility and ionization, and utilizes stable isotope labeling for MS1 level identification of hydroph
195 y blue-native gel electrophoresis and stable isotope labeling in cell culture proteomics that the TbS
199 gh sensitivity, we developed cysteine-stable isotope labeling using amino acids in cell culture (SILA
200 affinity purification), coupled with stable isotope labeling with amino acids in cell culture (SILAC
203 ially useful in rapid carboxylic acid carbon isotope labeling, however development toward its applica
205 trometery (GC-MS) together with (13)C stable isotope-labelled glucose and glutamine as metabolic trac
206 lative change in C (C/N) based on short-term isotope-labelled mineral fertilizer additions should be
208 rane phospholipid incorporation using stable isotope labelling with deuterated precursors followed by
210 ss carbon fluxes affect the long-term carbon isotope mass balance, and may lead to reassessment of th
212 g approach of synchronizing continuous water isotope measurements to a nearby tree-ring chronology.
217 northwestern Nevada using (13) C and (15) N isotopes obtained from "Modern" (2008-2013 CE), "Histori
224 ) (m/z 200) baseline resolved peaks of (13)C isotopes of unlabeled and monoisotopic peaks of (15)N la
225 SINA) on the Rosetta spacecraft analyzed the isotopes of xenon in the coma of comet 67P/Churyumov-Ger
227 combination of (29)N2 and (30)N2 production (isotope pairing), denitrification potential measurements
228 ed compounds based on combining a simplified isotope pattern and mass defect cluster analysis was dev
229 lorine (Deltadelta(13)C vs Deltadelta(37)Cl) isotope patterns for oxidation by thermally activated pe
230 d based on distinct spacing between adjacent isotope peaks, and the addition of metal cations and lig
231 Summed multiple charge states and multiple isotopes per charge state of the analyte were used durin
233 sus Deltadelta(37)Cl versus Deltadelta(13)C) isotope plot, which opens further possibilities for path
235 be two new complementary approaches - stable isotope probing coupled with nanoscale secondary ion mas
237 ple, sensitive, and robust method for sulfur isotope ratio ((34)S/(32)S) analysis of ppm-level organi
239 verall discrimination potential of strontium isotope ratio is evidenced in the final statistical disc
240 en in the past for these measurements, i.e., isotope ratio mass spectrometry (IRMS), with very encour
241 13)C-enriched CO2 samples, a newly developed isotope ratio mid-infrared spectrometer was introduced w
242 y (irm-(13)C NMR) was mainly used to measure isotope ratio monitoring with the potential of conductin
243 ology for the determination of stable carbon isotope ratio was evaluated in comparison with the metho
245 set of carbon, hydrogen, and chlorine stable isotope ratios (delta(13)C, delta(2)H, delta(37)Cl) of i
247 delta(2)H and Deltadelta(13)C are changes in isotope ratios during degradation) resulted in clearly d
250 ybdates, a new approach for determination of isotope ratios of individual thiomolybdate species was d
251 horus to nitrogen, and carbon ratios, oxygen isotope ratios of phosphate in vegetation, and phosphata
252 uation, which relates the change in measured isotope ratios to the decreasing substrate fractions and
253 and Sr ((87)Sr/(86)Sr = 0.70923 +/- 0.00024) isotope ratios were not consistent with the expected iso
254 lybdates, collecting each peak and analyzing isotope ratios with multicollector inductively coupled p
261 he spatial variation of ammonium and nitrate isotopes show that nitrification is a key process govern
263 Virginia and North Carolina dated to Marine Isotope Stage (MIS) 3, from 50 to 35 ka, are surprisingl
264 ic measurements of modern and palaeo (Marine Isotope Stage (MIS) 5e) tidal notches on Bonaire (southe
265 g the sea level lowstand accompanying marine isotope stage 6, rejecting earlier records of bison in N
266 ay procedure involved addition of the stable isotope standards [(15)N5]dG-gx-dC and [(15)N5]dG-gx-dA
269 ay remain undetected by whole-rock or zircon isotope studies, and that assimilation of altered roof m
271 ell is localization of organelle proteins by isotope tagging (LOPIT), which combines biochemical cell
272 These REE minerals show higher initial Nd isotope than primary REE-rich minerals (varepsilonNd(t)=
274 HRMS data stems partly from the presence of isotopes that give rise to more peaks to interpret compa
275 ing mass-independent fractionation of sulfur isotopes that took place in the Archean atmosphere of Ea
277 lishing a more robust framework for using Cr isotopes to track the evolution of the Earth's atmospher
278 bolites will have incorporated the labelling isotope, to a degree that depends on the metabolic turno
281 owpacks and melted snow using mercury stable isotope tracer experiments, as well as quantifying conce
283 interest has developed in alternative stable isotope tracer techniques that overcome these limitation
284 er the curve value was measured using stable isotope tracers and gas chromatography/mass spectrometry
285 The application of substrate-specific stable isotope tracers has permitted exquisite insight into ami
286 e limitations to 'substrate-specific' stable isotope tracers, which limit physiological insight, e.g.
291 ions from trees had an average stable carbon isotope value (delta(13)C) of -66.2 +/- 6.4 per mil, con
293 during winter - inferred from feather stable isotope values - induces residual effects that carry ove
294 the calculated aragonite equilibrium oxygen isotope values implies shallow calcification depths for
297 method to recover both the tracer and sample isotopes when full equilibration of tracer isotopes with
298 r satellites for nuclear [Formula: see text] isotopes, whereas NMR of the "bulk" lattice is nominally
299 e isotopes when full equilibration of tracer isotopes with sample isotopes is not possible prior to b
300 ucts have no equivalent in the corresponding isotope world with ca. 43 new species in the D world and
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