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1 etic behavior for the AV(3)(OH)(6)(SO(4))(2) jarosites.
2 rts per trillion to 100 parts per billion in jarosite, a sulfate-rich mineral associated with liquid
5 3(OH)6(SO4)2, along with the selenate-capped jarosite analogues of potassium, KFe3(OH)6(SeO4)2, and r
6 at the Tl L3-edge, partly Tl(I)-substituted jarosite and avicennite (Tl2O3) were identified as Tl-be
7 h secondary Mn (birnessite) and Fe minerals (jarosite and goethite), which together accounted for nea
8 Cu, and Zn are associated with metal-bearing jarosite and other minerals (e.g., clays, Fe-(oxy)hydrox
9 unity identified the ferric sulphate mineral jarosite and possible relicts of gypsum at the Meridiani
10 A four-step extraction procedure to quantify jarosite and schwertmannite separately with various solu
11 ification of the fractions of Tl(III), Tl(I)-jarosite and Tl(I)-illite in bulk samples based on XAS i
15 loped for the preparation of a new series of jarosites, AV(3)(OH)(6)(SO(4))(2) (A = Na(+), K(+), Rb(+
17 that Fe(2+)-induced transformation of As/Sb-jarosite can increase Sb mobility and exert major influe
18 nt a new approach for the preparation of the jarosite class of compounds, which for the past several
23 vironment and Tl is readily released from Tl-jarosite during both abiotic and biotic dissolution.
26 ot proceed to completion, and that following jarosite formation, arid conditions must have prevailed.
27 examined the dissolution of synthetic Tl(I)-jarosite, (H(3)O)(0.29)Tl(0.71)Fe(2.74)(SO(4))(2)(OH)(5.
29 ter in hydrated minerals, such as gypsum and jarosite, has numerous applications in studies of recent
31 is needed to verify that schwertmannite and jarosite in the pit sediment do not convert to goethite,
35 n of a new series of stoichiometrically pure jarosites of the formula, AV(3)(OH)(6)(SO(4))(2) with A
37 of abiotic Fe(2+)-induced transformation of jarosite on the mobility, speciation, and partitioning o
39 V) during the dissolution of synthetic Pb-As jarosite (PbFe(3)(SO(4),AsO(4))(2)(OH)(6)) by Shewanella
41 ining magnetostructural correlations for the jarosites possessing various interlayer cation and cappi
44 te minerals (including magnesium sulfate and jarosite) that constitute several tens of percent of the
45 tic techniques on the magnetic properties of jarosites, the V(3+) jarosites were also prepared accord
46 AFe3(OH)6(SO4)2 (A = Na+, K+, Rb+ and NH4+) jarosites, these compounds provide a framework for probi
47 entojarosite, AgFe3(OH)6(SO4)2, and thallium jarosite, TlFe3(OH)6(SO4)2, along with the selenate-capp
48 (10 and 20 mM) rapidly (<10 min) transformed jarosite to a green rust intermediary, prior to the subs
49 trigger the Fe(2+)-induced transformation of jarosite to more stable Fe(III) minerals, such as goethi
50 magnetic properties of jarosites, the V(3+) jarosites were also prepared according to the nonredox t
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