ライフサイエンスコーパス: limonene

1 on (2-methyl 2-pentene), and one terpene (DL-limonene).

2 nol-benzaldehyde, octanol-octanal, and [+/-]-limonene).

3 nthesis of stolonidiol starting from (R)-(+)-limonene.

4 s in filled hydrogels reduces the release of limonene.

5 1, has been accomplished starting from S-(-)-limonene.

6 ulsed delivery of iso-amyl acetate (IAA) and limonene.

7 llylic isomer 3S-linalyl diphosphate, to (-)-limonene.

8 erted geranyl diphosphate to the monoterpene limonene.

9 of (+)-alpha-pinene, (+)-camphene, and (+/-)-limonene.

10 ction of a commercially valuable isoprenoid, limonene.

11 nditions did not change the configuration of limonene.

12 t found in the ozonolysis of cyclohexene and limonene.

13 arnesene, (-)-alpha-pinene, beta-pinene, and limonene.

14 les formed by ozonolysis of alpha-pinene and limonene.

15 hat of 4-OPA, were also reduced in line with limonene.

16 pounds responsible for aroma perception were limonene, 1,8-cineole, terpinen-4-ol, estragole and tran

17 ely high resistance; still, no production of limonene-1,2-diol and a loss of activity of the biocatal

18 bioconversion process of S-(-)-limonene into limonene-1,2-diol with the already established biotransf

19 d as an aerobic system that was catalysed by limonene-1,2-epoxide hydrolase, had an intracellular nat

20 than 1,000-fold, as well as the monoterpene limonene 10-30 fold, and seems equally suited to generat

21 ve of which were identified as alpha-pinene, limonene, 2-methoxy-3-(1-methylpropyl)-pyrazine, methyl

22 ) at 30 degrees C were 4.5 and 3.5x10(6) for limonene, 2.2 and 9.0x10(5) for linalool and 39 and 1.0x

23 nferred by two regiospecific cytochrome P450 limonene-3- and limonene-6-hydroxylases.

24 cDNAs encoding the limonene-3-hydroxylase from peppermint and the limonene-

25 y and catalytic efficiency of the peppermint limonene-3-hydroxylase.

26 he tamarinds were mainly caused by linalool, limonene, 4-hydroxy-2,5-dimethyl-3(2H)-furanone, nonanal

27 s showed decreasing amounts of monoterpenes (limonene, 4-terpineol, terpinolene, citronellol, alpha-t

28 = 3 with Mg2+ as cofactor), the monoterpenes limonene (48%), terpinolene (15%), and myrcene (15%) are

29 %), menthol (24.3%), trans-menthone (9.23%), limonene (5.84%), menthofuran (4.44%) and isomenthol (3.

30 monene-3-hydroxylase from peppermint and the limonene-6-hydroxylase from spearmint have been isolated

31 ed within secretory cell leucoplasts, (-)-4S-limonene-6-hydroxylase labeling was associated with glan

32 of a single residue (F363I) in the spearmint limonene-6-hydroxylase led to complete conversion to the

33 ynthase, spearmint (Mentha spicata) (-)-(4S)-limonene-6-hydroxylase, peppermint (-)-trans-isopiperite

34 ochemistry and facial stereochemistry of the limonene-6-hydroxylase- (CYP71D18-) mediated hydroxylati

35 egiospecific cytochrome P450 limonene-3- and limonene-6-hydroxylases.

36 The optimized strain produced 6.7 mg/L of limonene, a 2.3-fold improvement in productivity.

37 derived from ozone-initiated chemistry with limonene, a commonly occurring indoor terpene.

38 We additionally show that d-limonene, a dietary monoterpene known to induce ROS, is

39 cumulate terpenes in peel oil glands, with d-limonene accounting for approximately 97% of the total v

40 nce is related to the working pressure drop: limonene allows one to work with high centrifugal fields

41 zone with a biogenic precursor (beta-pinene, limonene, alpha-pinene) in a flow tube reactor.

42 Limonene, alpha-pinene, 3-carene, dihydromyrcenol, geran

43 The ability of methyl-isoeugenol, limonene, alpha-pinene, isovaleric acid, and isosafrole

44 exanal, 3-carene, alpha-terpinene, p-cymene, limonene, alpha-terpinolene and ethyl octanoate, were ta

45 Following hydroxylation of limonene, an apparently similar dehydrogenase oxidizes (

46 re of monoterpene (C10) olefins in which (-)-limonene and (-)-alpha- and (-)-beta-pinene are prominen

47 -)-beta-pinene are prominent components; (-)-limonene and (-)-pinene synthase activities are also ind

48 The presence of (S)-limonene and (R)-carvone as the unique enantiomeric form

49 omers of chiral analytes, including those of limonene and 1-phenylethanol.

50 soluble SOA generated from two monoterpenes, limonene and alpha-pinene, and two different oxidants, o

51 tely 1% of two chiral monoterpene molecules, limonene and camphor, are irradiated by a circularly pol

52 on of natural sources of pure enantiomers of limonene and carvone, is performed by using on-line coup

53 agent, substantially lower concentrations of limonene and formaldehyde were observed.

54 I (-) data for SOAs produced by oxidation of limonene and isoprene and compared them online to O/C me

55 of eugenol, carvacrol, thymol, alpha-pinene, limonene and linalool was determined.

56 lar cleaning agents emitted terpenes, mainly limonene and linalool.

57 tivity patterns evoked by the enantiomers of limonene and of terpinen-4-ol were not statistically dif

58 ) was produced from 0.5 ppm mixing ratios of limonene and ozone in a 5 m(3) Teflon chamber.

59 Monoterpenes such as d-limonene and perillyl alcohol derived from orange peels

60 including the monoterpenes alpha-pinene and limonene and the aromatic catechol (benzene-1,2-diol).

61 uice were observed due to the degradation of limonene and the formation of alpha-terpineol, an off-fl

62 positive chemotaxis (70-80%), alpha-pinene, limonene and tridecane were intermediate (54-60%), and 2

63 omarkers of exposure and dimethyl disulfide, limonene, and 2-ethyl-1-hexanol as biomarkers of disease

64 made of beta-ionone, (+/-)-citronellal, (+)-limonene, and flavone dissolved in DMSO-d6/GL-d8 (5:5, v

65 alpha-terpineol, an oxygenated derivative of limonene, and found that the reaction products and kinet

66 yloctanoic acid, 3-methylindole (skatole), d-limonene, and indole.

67 OCs (i.e., alpha,beta-pinene, Delta3-carene, limonene, and isoprene) supporting the results from the

68 rpenes camphene, alpha- and beta-pinene, and limonene, and the sesquiterpene compounds alpha- and bet

69 ated hydroxylation of the monoterpene olefin limonene are determined by the absolute configuration of

70 econdary organic aerosol (SOA) produced from limonene are known to form brown carbon (BrC) with a dis

71 e (3-methyl butane nitrile) and temperature (limonene) are identified through a multi-trait analysis.

72 ata, confocal microscopy, and the release of limonene as assessed by solid-phase microextraction usin

73 Oxidation of (R)-limonene at 25 degrees C occurred at the C-1,2-cyclic al

74 ze the regiospecific hydroxylation of (-)-4S-limonene at C3 or C6 exclusively.

75 c aerosol (SOA) formation from ozonolysis of limonene at total aerosol mass loadings ranging from 3.2

76 rich in monoterpenes, including 1,8-cineole, limonene, beta-myrcene, alpha- and beta-pinene, sabinene

77 ffer in three floral terpenoid volatiles - d-limonene, beta-myrcene, and E-beta-ocimene - that are at

78 Abies grandis was expressed to optimize the limonene biosynthetic pathway.

79 terise the bioconversion of R-(+)- and S-(-)-limonene by cellular detoxification using ultra-structur

80 ion; no flavour complexes were reported with limonene by itself but were observed when added in binar

81 sized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus indust

82 thases of conifers, [(-)-pinene (C(10)), (-)-limonene (C(10)), (E)-alpha-bisabolene (C(15)), delta-se

83 ver, the magnitude of alterations depends on limonene concentration, model membrane composition and,

84 iments were conducted at realistic ozone and limonene concentrations in a 240 m(3) chamber configured

85 nverse correlation between the increase in d-limonene content and the decrease in the defense respons

86 Surface and encapsulated limonene content was determined by measurement of the ab

87 The surface limonene content was significant, especially for gellan

88 s, the KCl gels had the greater encapsulated limonene content.

89 linalyl diphosphate, as shown previously for limonene cyclase.

90 doubled in these KCl gels, the encapsulated limonene decreased.

91 c monoterpenes (alpha-pinene, beta-pinene, D-limonene, Delta(3)-carene) monitored with the ASGDI quad

92 The 24% higher limonene density is a difference with heptane that has m

93 The strongest fluorescence for the limonene-derived SOA was observed for lambdaexcitation =

94 presence of airborne odorants (amyl acetate, limonene, earthworm wash vapor, fish water vapor, earthw

95 Specifically deuterated limonene enantiomers were prepared to investigate the ne

96 nable materials synthesis process in which d-Limonene functions simultaneously both as a solvent for

97 ujene, camphene, sabinene, delta-3-carene, d-limonene, gamma-terpinene, camphor, beta-citronellene, a

98 g lemon essential oil incorporated terpenes (limonene, gamma-terpinene, p-cymene and alpha-citral) to

99 Limonene has a strong tendency to form secondary organic

100 tive kinetic mechanism, indicating that (4R)-limonene has sufficient freedom of motion within the act

101 Limonene has the capability to be a "green" alternative

102 from elemental sulfur, gamma-terpinene, and limonene in 61% yield.

103 sient AMFs" from ozonolysis of pulse-emitted limonene in a ventilated chamber, for 18 experiments at

104 The encapsulation of limonene in freeze-dried gellan systems was investigated

105 eta-pinene, myrcene, delta3-carene, ocimene, limonene) in seawater and air during three cruises in th

106 It was found that limonene incorporates into lipid monolayers causing thei

107 ence of strong volatility and evaporation of limonene increasing with temperature.

108 ready established biotransformation of R-(+)-limonene into alpha-terpineol using the same biocatalyst

109 compared the bioconversion process of S-(-)-limonene into limonene-1,2-diol with the already establi

110 Limonene is a biorenewable cycloterpene solvent coming f

111 evaporation is dependent on whether SOA from limonene is formed before or during the formation of SOA

112 (-)-(4S)-Limonene is hydroxylated at the C6 allylic position to g

113 (4S)-Limonene is oxygenated with almost complete stereospecif

114 Moreover, the influence of limonene is stronger at lower temperatures and, in the l

115 growth from direct reactions of (3)IC* with limonene, isoprene, alpha-pinene, beta-pinene, and tolue

116 that photosensitized production of SOA from limonene, isoprene, alpha-pinene, beta-pinene, and tolue

117 The oxygenation of (4R)-limonene leading to the formation of (+/-)-trans-carveol

118 In nature, d-limonene levels increase in orange fruit once the seeds

119 0muM JA increased the linalool, eugenol, and limonene levels, while 1muM JA caused the highest increa

120 Limonene, linalool and citral are common non-phenolic te

121 esults indicate that antioxidant behavior of limonene, linalool and citral occurs by co-oxidation wit

122 Eucalyptol, limonene, linalool, thymol, parthenolide, andrographolid

123 oduction of various monoterpenes such as (-)-limonene, (-)-linalool, (-)-alpha-pinene/beta-pinene or

124 antioxidant actions of thymoquinone (TQ) and limonene (LMN) were investigated by giving 1 ml of 10mg

125 l aging of SOA produced by the ozonolysis of limonene (LSOA) in the presence of gaseous ammonia.

126 ganic aerosol produced through ozonolysis of limonene (LSOA).

127 The polar and apolar phases of the limonene/methanol/water 10/9/1 v/v have -0.025 g/cm(3) d

128 The limonene/methanol/water and heptane/methanol/water phase

129 the five major aphid-induced VOCs (ethanone, limonene, methyl salicylate, myrcene, ocimene) triggered

130 The double bonds of the limonene molecule allows for possible pi-pi interactions

131 cineole cassette' monoterpenes 1,8-cineole, limonene, myrcene, beta-pinene, alpha-pinene, sabinene a

132 nsistent with allelic variation at two loci, LIMONENE-MYRCENE SYNTHASE (LMS) and OCIMENE SYNTHASE (OS

133 this, we probe the possibility that SOA from limonene+NO3 and beta-pinene+NO3 reactions is highly vis

134 The SOA yields from limonene+NO3 are approximately constant ( approximately

135 mally dilute the oxidation products from the limonene+NO3 reaction at 25 degrees C and observe neglig

136 Herein the influence of limonene on artificial membranes was studied to verify t

137 i-MJ either promotes the bioformation of (+)-limonene or inhibits that of (-)-limonene to a greater e

138 carvone, but not between the enantiomers of limonene or terpinen-4-ol, in an olfactory habituation t

139 tection of recombination products of IC with limonene or with itself, in bulk and flow tube experimen

140 xposed to either caproic acid, butyric acid, limonene, or purified air and the spatial distribution o

141 uce either the monoterpenes alpha-pinene and limonene, or the sesquiterpene 7-epizingiberene, with th

142 of BrC material produced by the reaction of limonene + ozone SOA with ammonia vapor (aged LIM/O3 SOA

143 fractions of alpha-pinene, d-limonene (R-(+)-limonene), p-cymene, and camphene (a terpene not present

144 s observed in alpha-pinene where growth of d-limonene, p-cymene, and camphene has been observed in tr

145 ta-pinene and alpha-pinene, with growth of d-limonene, p-cymene, and camphene, in nickel-plated carbo

146 ave -0.025 g/cm(3) density difference (lower limonene phase) compared to +0.132 g/cm(3) with heptane

147 The system is stable for the production of limonene, pinene and sabinene, and can operate continuou

148 The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change.

149 enzyme fidelity analysis [percentage of (-)-limonene produced] indicated which residues are most lik

150 us limon were expressed in cyanobacteria for limonene production.

151 ith the remaining exocyclic bond of oxidized limonene products in the SOA phase.

152 ease in the defense response suggests that d-limonene promotes infection by microorganisms that are l

153 while the mole fractions of alpha-pinene, d-limonene (R-(+)-limonene), p-cymene, and camphene (a ter

154 C-MS) chirality analysis showed that (R)-(+)-limonene, (R)-(-)-linalool, (S)-(-)-alpha-terpineol and

155 Knowing the AER and initial ozone-limonene ratio is crucial to predict indoor transient SO

156 decreasing AERs and increasing initial ozone-limonene ratios, which together likely promoted more ozo

157 hange rates (AER) with varying initial ozone-limonene ratios.

158 Furthermore, highly oxygenated limonene reaction products were detected, clearly explai

159 ne/terpenoid surface reactions), for ozone/D-limonene reactions on stainless steel.

160 IAA and limonene reproducibly activated different subsets of rec

161 centrations of carvone, (-) citronellal, and limonene, respectively.

162 (alpha-pinene, beta-pinene, Delta-3-carene, limonene, sabinene, and beta-caryophyllene), were invest

163 tones are closely related to the monoterpene-limonene secondary biotransformation and menthofuran has

164 omposed of ammonium sulfate (AS) and either: limonene secondary organic carbon (LSOC), alpha, 4-dihyd

165 alpha-pinene, gamma-terpinene, p-cymene and limonene showed significant variations with drying trial

166 le pi-pi interactions with solutes rendering limonene slightly more polar than heptane giving small d

167 sis of two structural monoterpene isomers: D-limonene SOA (LSOA) and alpha-pinene SOA (PSOA).

168 -dicarbonyl structural motif present in many limonene SOA compounds.

169 ilarity was attributed to high solubility of limonene SOA in water.

170 ated, and aged at <5%, 50 and 90% RH, and on limonene SOA particles at <5% and 90% RH.

171 demonstrated by reacting 2-MP with 4-OPA or limonene SOA, both of which produced BrC with absorption

172 capable of browning by the same mechanism as limonene SOA.

173 Monoterpenes such as (R)-(+)-limonene stimulated both glucose uptake (17.4%) and lipo

174 predict that indoor spaces in which ozone/D-limonene surface reactions would likely lead to meaningf

175 Crystal structural data for (4S)-limonene synthase [(4S)-LS] of spearmint (Mentha spicata

176 n be inferred by homology modeling of (-)-4S-limonene synthase based on the three-dimensional structu

177 duction of limonene was two-fold higher with limonene synthase from M. spicata than that from C. limo

178 The crystal structure of (4S)-limonene synthase from Mentha spic ata, a metal ion-depe

179 eport, we showed that down-regulation of a d-limonene synthase gene alters monoterpene levels in oran

180 (-)-4S-Limonene synthase preprotein from spearmint bears a long

181 e deduced amino acid sequences indicated the limonene synthase to be 637 residues in length (73.5 kDa

182 The monoterpene cyclase limonene synthase transforms geranyl diphosphate to a mo

183 transgenic expression of a gene encoding (+)-limonene synthase was used to accumulate elevated levels

184 ry showed that these sequences encoded a (-)-limonene synthase, a myrcene synthase, and a (-)-pinene

185 Developmental immunoblotting of limonene synthase, which catalyzes the committed step of

186 Limonene synthases from the plants Mentha spicata and Ci

187 This precludes the use of this limonene system with hydrodynamic CCC columns that need

188 Gellan gels encapsulated greater amounts of limonene than solutions.

189 is procedure is used to isolate the peak for limonene, the largest peak in the analytical-ion chromat

190 ated products formed from the degradation of limonene, the most ubiquitous terpenoid species in the i

191 tion of (+)-limonene or inhibits that of (-)-limonene to a greater extent than the other three MJ ste

192 ruits revealed that the down-regulation of d-limonene up-regulated genes involved in the innate immun

193 he chemistry of peroxy radicals derived from limonene upon addition of oxygen explains the formation

194 rat mammary carcinomas treated with dietary limonene using a newly developed method termed subtracti

195 Limonene was added at two different concentrations (1 an

196 However, when the concentration of limonene was doubled in these KCl gels, the encapsulated

197 The SOA mass using 15 ppb limonene was strongly dependent on O(3) concentrations a

198 Production of limonene was two-fold higher with limonene synthase from

199 as used to accumulate elevated levels of (+)-limonene, which allows oil derived from transgenic plant

200 ion of ozone reactions with surface-sorbed D-limonene, which is common indoors.

201 ted that the major volatile compound was the limonene with relative percentage of 3.1, 7.5 and 10.8,

202 o identify major products of the reaction of limonene with the triplet state of IC by direct (+/-)ESI

203 arveol as the only product, whereas (+)-(4R)-limonene yields multiple hydroxylation products with (+)