ライフサイエンスコーパス: line shape

1 or which rectangle had a slightly wider gray line (shape).

2 ent depolarization ratio, and mass-dependent line shape.

3 ne the effects of static disorder on the NMR line shape.

4 ted to a broad, asymmetric Breit-Wigner-Fano line shape.

5 of magnitude but not its final level or EPR line shape.

6 se to a third broad radical with distinctive line shape.

7 racted by a least-squares fit to a specified line shape.

8 predicated structure-factor scattering peak line shape.

9 posed to explain the observed differences in line shape.

10 molecular fragments, determined from dipolar line shapes.

11 CD3-Ala15 exhibit strong isotropic spectral line shapes.

12 omplex state affects the deuterium resonance line shapes.

13 (13)C-(14)N dipolar modulation of the powder line shapes.

14 s(-1), as determined from the deuterium MAS line shapes.

15 ed mechanism shows characteristic dispersive line shapes.

16 oduction of signal intensities, volumes, and line shapes.

17 relaxation, dipolar order parameter, and CSA line shape analyses employed in this study provides snap

18 amics that were later elucidated by means of line shape analyses of the spectral features obtained th

19 spectra, which when combined with numerical line shape analyses provided a clear description of the

20 e basis of recent elegant NMR relaxation and line-shape analyses, the energetics obtained for the var

21 The line shape analysis allowed us to obtain the methyl bond

22 new strategy is employed in combination with line shape analysis and pulsed-EPR interspin distance me

23 e determined from rate constants obtained by line shape analysis at -143.2 degrees C.

24 constants for folding and unfolding from NMR line shape analysis for the single- and double-domain pr

25 n of L-[2-2H]lysine, can be distinguished by line shape analysis from 3.

26 f (2)H NMR spectra were fit to a theoretical line shape analysis giving the retinylidene bond orienta

27 opropylterephthalamide) were determined from line shape analysis of 1H NMR spectra [methanol-d4: delt

28 Line shape analysis of continuous wave electron paramagn

29 Line shape analysis of quadrupolar echo (2)H NMR measure

30 Line shape analysis of solid state (2)H NMR spectra of a

31 of interaggregate exchange, measured by DNMR line shape analysis of the C-Li signal, orders of magnit

32 (1)H NMR line shape analysis of the CBz methylene hydrogens at th

33 The line shape analysis of the methyl labeled (d6) sample gi

34 Line shape analysis of the NMR spectra indicates that th

35 Line shape analysis of the spectra reveals that the cent

36 Line shape analysis of the spectrum suggests the bound p

37 A line shape analysis of the transient desorption signal r

38 The line shape analysis of VT 13C CPMAS and broad-band 2H NM

39 icantly from those reported from dynamic NMR line shape analysis on a variant with methionine at the

40 A quantitative line shape analysis over the entire two orders of magnit

41 mics by variable temperature NMR studies and line shape analysis were performed for the free ligands

42 bserved in the HYSCORE spectrum, and contour line shape analysis yielded coupling constants of approx

43 chniques including coalescence measurements, line shape analysis, and selective inversion experiments

44 s employed are deuteron NMR quadrupolar echo line shape analysis, and T(1Z) (Zeeman) and T(1Q) (quadr

45 tronic energy transfer rates, as revealed by line shape analysis, are mode-specific and remarkably fa

46 Here we have combined NMR line shape analysis, fluorescence spectroscopy, and isot

47 nversion in the anion, measured by (19)F NMR line shape analysis, is characterized by these activatio

48 he membrane binding of ovispirin using 2D IR line shape analysis, isotope labeling, and molecular dyn

49 = -18(+/-9) J K(-1) mol(-1) as derived from line shape analysis.

50 n transfer kinetics and variable temperature line shape analysis.

51 be studied by dynamic NMR spectroscopy using line shape analysis.

52 pH and protection factors are derived from a line shape analysis.

53 ecies of bisanilide 2 were determined by NMR line shape analysis.

54 xtracted from temperature dependent emission line shape analysis.

55 An Eyring plot of rates obtained from line-shape analysis and 1-D EXCHSY NMR yields an activat

56 lts were confirmed with (2)H solid-state NMR line-shape analysis and spin-lattice relaxation at 76.78

57 hosphoryl transfer, derived from qualitative line-shape analysis of (1)H-(15)N correlation spectra ta

58 to C-C single-bond isomerization, we applied line-shape analysis of the dynamic rotational spectrum t

59 r to helical interconversion, as measured by line-shape analysis of the temperature-dependent (1)H NM

60 e-AgX complexes is nearly identical based on line-shape analysis of these (31)P NMR spectra as a func

61 NMR line-shape analysis was used to determine the folding an

62 etime similar to that previously measured by line-shape analysis, and provides an important calibrati

63 From line-shape analysis, assuming a two-site conformational

64 re 13C CPMAS NMR and quadrupolar echo 2H NMR line-shape analysis: 12.8 kcal/mol for 1A and 14.6 kcal/

65 ft in the peak frequency without a change in line shape and (2) changes in the overall line shape whi

66 However, little change in the EPR line shape and accessibility of spin-labels was observed

67 (1) the EPR spectra of YZ. and YD. differ in line shape and line width.

68 However, simulation of the EPR line shape and measurement of the isotropic g value was

69 Deuterium line shape and relaxation data were used to model motion

70 ng deuterium magic angle spinning ((2)H MAS) line shape and spin-lattice relaxation measurements.

71 The electronic absorption line shape and Stark spectrum of the lowest energy Q(y)(

72 The changes in the EPR spectral line shape and the rotational correlation time of the sp

73 ining data from multiple (15)N(1)H-(13)C(1)H line shapes and analogous data from other 3D (1)H-(13)C(

74 as a result exhibits strikingly sharper 15N line shapes and higher intensities for NH3 cross-peaks t

75 The EPR line shapes and mobility of these peptides when bound to

76 of the electron paramagnetic resonance (EPR) line shapes and nonexponential spin-echo decays, which u

77 ON CP) ensures the accuracy of the extracted line shapes and provides enhanced sensitivity relative t

78 EPR line shapes and relaxation data indicate that residues 2

79 cesses are evaluated via analysis of the NMR line shapes and relaxation times observed between 12 and

80 tants showed striking alterations in the EPR line shapes and revealed two discrete subpopulations in

81 in solid-state NMR spectra as characteristic line shapes and temperature-dependent line narrowing or

82 The EPR spectral line shapes and the influence of nonpolar O2 or polar po

83 the electron paramagnetic resonance spectral line shapes and the influence of O2 on the saturation be

84 nables the facile measurement of undistorted line shapes and two-dimensional (1)H-(17)O HETCOR NMR sp

85 ntrast, more complex spectral changes in the line-shape and maximal hyperfine splitting are observed

86 h explains the observed Fano-type absorption line-shapes and tuning of the absorption strengths with

87 ructural changes, as assessed by the amide I line shape, and (5) contributions to the FT-IR spectrum

88 vidence that the site-dependent variation in line shape, and hence motion of the spin label, is due l

89 o the conventional (slow-passage) derivative line shape, and is a more reliable way to collect spectr

90 Zero-field splitting parameters, line shape, and Jahn-Teller distortion in the temperatur

91 fit that accurately predicted the intensity, line shape, and position of the observed signals.

92 The wavelength, line shape, and relative intensities of these plasmon ba

93 ates folded globular proteins with broadened line shapes; and "D" are nonglobular, "unfolded" polypep

94 lvation-induced frequency shifts, but the 2D line shapes, anharmonic shifts, and lifetimes obtained f

95 The width and the intensity of this line shape are analyzed in terms of the DQ relaxation an

96 he EPR spectrum broadens, but the changes in line shape are modulated by both changes in label correl

97 Microwave frequency sweeps through the EPR line shape are shown as a time domain strategy to signif

98 The spectral line shapes are accurately reproduced using a Holstein H

99 In all cases, the deuterium line shapes are characterized by fast methyl group rotat

100 dues in proteins are complicated because the line shapes are derived from the overlap of both the 1L(

101 ime broadening contributions to the spectral line shape arising from electronic-vibrational coupling.

102 he signal magnitude as well as the resonance line shape at various H(2)O/D(2)O solvent mixtures.

103 cing the aqueous phase, and the EPR spectral line shapes at these sites indicate considerable motiona

104 nhancement increases and the absorption band line shape becomes more asymmetric as the AgNCs' LSPR fr

105 Analyte concentration and collisional line shape broadening are simultaneously determined by a

106 in distance was estimated from the extent of line shape broadening in the double-labeled proteins.

107 Line shape broadening resulting from spin-spin coupling

108 f-field transition, Fourier deconvolution of line-shape broadening, and computer simulation of line-s

109 field splitting and broadening the spectral line shapes but had no effect on oxidized enzyme.

110 We compare our experimental results to 2D IR line shapes calculated using the lowest free energy stru

111 resonances with a characteristic asymmetric line shape can be observed in light scattering, transmis

112 re present, the amplitude and phase of the R line shape can vary significantly with phi, leading to d

113 ent of NiR with (63)Cu isotope caused an EPR line shape change showing copper involvement.

114 Carbon-13 NMR line shape changes are attributed to inversion via a lat

115 NMR line shape changes due to the dynamics of bimolecular C,

116 Carbon-13 NMR line shape changes indicate that the system undergoes a

117 Similar spectral line shape changes of FR3 are caused by the FrdC E29L mu

118 NMR line shape changes of the sample containing 24 have been

119 NMR line shape changes show that 9en, 9ex, 13en, and 13ex al

120 PIXMb show no temperature-dependent spectral line shape changes suggestive of Jahn-Teller dynamics, a

121 Line-shape changes provided a spectral signature that co

122 shape broadening, and computer simulation of line-shape changes.

123 3)-Leu51) along the TM-PLB peptide exhibited line shapes characteristic of either methyl group reorie

124 Caille analysis of the small-angle x-ray line shape confirms that for 7:3 wt:wt CTAT:SDBS bilayer

125 lypeptide ligand, showed changes in spectral line shape consistent with restricted motion of the nitr

126 The resulting asymmetry in the phonon line shape, conspicuous at low temperatures, diminishes

127 ork utilises HPLC-MS and a constrained total-line-shape (CTLS) approach applied to (1)H NMR spectra t

128 ose ring motion to the analysis of deuterium line shape data obtained from sugar rings in solid hydra

129 systems are readily measured from the powder line shape data.

130 extrapolated by Oas and co-workers from NMR line-shape data.

131 The line shape, decay, and other properties of this new radi

132 (2)H quadrupolar line shapes deliver rich information about protein dynam

133 -limited absorption-mode over magnitude-mode line shape depends on the collision mechanism: factor of

134 developed to accurately simulate the 2H NMR line shape due to the distribution of bond angles and th

135 d, appearing as evolution of the 2D spectral line-shape during the first 200 fs after excitation.

136 , we demonstrate that protein fingerprint by line shape enhancement (PROFILE), a 1D (1)H NMR spectros

137 Finally, 2D spectral line shape evolution reveals that it takes the monolayer

138 Using solid-state (2)H NMR line shape experiments performed on selectively deuterat

139 2)H quadrupolar parameters obtained from the line-shape fitting identify side-chain motions.

140 the peptide but only a slight change in the line shape for POPC bilayers, indicating that the peptid

141 he 3D (2)H-(13)C-(13)C spectrum reveals (2)H line shapes for 140 resolved aliphatic deuterium sites.

142 -(13)C=(18)O labeling, we measured the 2D IR line shapes for 15 of the 18 residues in this peptide.

143 Barriers to rotation, DeltaH from NMR line shapes for 5, 6, 7, and 8 respectively, are 19.8, 1

144 The dramatically different spectral line shapes for both aggregates are shown to arise from

145 endent changes in the 2D IR vibrational echo line shapes for both of the substates are analyzed using

146 ion of the magnetic axes and analysis of NMR line shapes for H. thermophilus ferricytochrome c(552) i

147 The triplet line shapes for MgMPIXMb and MGPPIXMb show no temperatur

148 partially relaxed) solid-state deuterium NMR line shapes for the sample [2' '-2H]-2'-deoxycytidine at

149 nsion, and a strong correlation with 13C NMR line shapes for the terminal methyl group of the hydroca

150 ear in analyte concentration and has a Raman line shape free of nonresonant background distortions.

151 ermine the relative contributions to the NMR line shape from the electric field gradient and the anis

152 aphy were used to examine the origins of EPR line shapes from spin-labels at the protein-lipid interf

153 An analysis of the EPR line shapes from this region indicates that the linker i

154 The deuteron line shapes give an excellent fit to a three-mode motion

155 10E requires the simulation of two different line shapes, implying two different copper-bound species

156 allows us to follow the formation of a Fano line shape in time.

157 he time-dependent buildup of asymmetric Fano line shapes in absorption spectra has been of great theo

158 rving the corresponding (1)H line widths and line shapes in water-saturated spider dragline silk.

159 his approach provides an absorption envelope line shape, in contrast to the conventional (slow-passag

160 Moreover, (19)F NMR line shapes indicate that this molecular knife undergoes

161 changes in tyrosyl radical intensity or EPR line shape, indicating that the oxyferryl heme, and not

162 The LSPR peak shift and line shape induced by a resonant molecule vary with wave

163 The line shape is Gaussian.

164 The split-signal line shape is simulated with dipolar and exchange coupli

165 Structural interpretation of the amide I line shapes is enabled by spectral simulations carried o

166 s of cell contact into adhesive and flexible line-shaped junctions.

167 induce a pronounced asymmetry in the phonon line shape, known as the Fano resonance.

168 si-angular distributions from amide III band line shapes measured in 204-nm UV Raman spectra.

169 Moreover, the 2D solid-state NMR line shapes near the unfolding midpoint do not fit a sim

170 15N solid-state NMR powder pattern line shapes obtained on unoriented samples demonstrate t

171 constant (38.8-39.8 kHz from analysis of the line shape of a powder-type sample).

172 local chemical environment on the intrinsic line shape of isolated carbon nanotubes are discussed.

173 d state play a major role in determining the line shape of such CT absorption bands.

174 Additionally, the line shape of the 2H NMR spectrum of CD3-Ala24 reveals m

175 To explain the line shape of the CO bands, we suggest that in addition

176 fect the position, splitting, amplitude, and line shape of the cross-peaks and diagonal peaks.

177 e width of the Chl(Z)(+) EPR signal, but the line shape of the D1-H118Q mutant remained unchanged.

178 uency irradiation intensity and measures the line shape of the DQ transition.

179 The time-dependent line shape of the fluorescent signal enables detection o

180 fluence of surface segregation of tin on the line shape of the localized surface plasmon resonance (L

181 The characteristic line shape of the primary model is the log-normal distri

182 ectron paramagnetic resonance (EPR) spectral line shape of the reduced [2Fe-2S] cluster, which remain

183 We show that the line shape of the resonance arising from adsorbed ions i

184 spin-lattice relaxation of YD.; because the line shape of the S2-state multiline EPR signal is domin

185 mutation has a significant impact on the EPR line shape of Z*.

186 The absorption line shapes of a series of linear and star-shaped peryle

187 The (2)H NMR line shapes of all CD(3)-labeled leucines are very simil

188 al dynamics on the vibrational sum-frequency line shapes of aqueous interfaces.

189 re found to profoundly affect the absorption line shapes of both linear and symmetric complexes for s

190 By using a dipolar model that includes the line shapes of both the YD. and S2-state multiline EPR s

191 Line shapes of EPR spectra also indicate that this regio

192 spectra and electron paramagnetic resonance line shapes of labeled mutants are blue-shifted and more

193 Static (31)P NMR line shapes of lipid membranes with a range of compositi

194 As a consequence of this phenomenon, 15N line shapes of NH3 signals in a conventional 1H-15N hete

195 Due to the sensitivity of EPR line shapes of oriented spin-coupled pairs to the inters

196 Binding-induced changes in the line shapes of S100B backbone (1)H and (15)N resonances

197 re, electron paramagnetic resonance spectral line shapes of sites in the N-terminal domain are narrow

198 EPR line shapes of spin-labeled mutants located with the Ca(

199 ver, complex electron paramagnetic resonance line shapes of spin-labeled mutants suggest several conf

200 exciton band and the absorption and emission line shapes of the 0 <-- 0 transition.

201 However, significant differences in the line shapes of the 2H NMR spectra were observed in the l

202 The intensities and line shapes of the cross peaks in the spectrum reflected

203 ertain cases, initially symmetric Lorentzian line shapes of the G-band features with narrow line widt

204 s of the spinning sideband envelopes and the line shapes of the individual spinning sidebands corresp

205 Here, we have used the redshifts and line shapes of the isotopically decoupled IR oxygen-deut

206 The line shapes of the J-coupled (15)N signals suggest rapid

207 The photoemission line shapes of the optimally doped cuprate Bi(2)Sr(2)CaC

208 The line shapes of the S(1) and S(2) state multiline EPR sig

209 Detailed analysis of the polarization line shapes of the SH intensities obtained by continuous

210 Upon Ca2+ or membrane binding, the EPR line shapes of these mutants reveal dramatic decreases i

211 ial and shielding functions), we predict the line shapes of Xe in SSZ-24 zeolite under various condit

212 We show that the line-shape of the measured resonant elastic X-ray respon

213 cosatetraenoic acid and also retains the EPR line-shape of the native peroxide-induced 29-30-G wide s

214 ohmic losses that can drastically alter the line shape on the millielectron volt scale that is now o

215 Line shapes on the myristoylated N-terminal end indicate

216 Isotopic editing resulted in an altered line shape only when tyrosine residues of the enzyme wer

217 analyzed on the basis of 31P and 2H spectral line shapes, order parameters, and T1 relaxation measure

218 Line-shape parameters for these sites were determined fr

219 ion to explaining the unusual brightness and line shape peculiarities, this result leads to the predi

220 6 G in PGHS-1; 21 G in PGHS-2), and the same line shapes persisted throughout the reactions.

221 d-type E. coli QFR, HQNO causes EPR spectral line shape perturbations of the iron-sulfur cluster FR3.

222 are in fair agreement with the experimental line shape presented herein.

223 are in good agreement with the experimental line shapes presented herein.

224 we demonstrate that the characteristic Fano line shape results from the spectral interference of a b

225 A comparison of the line shapes reveals an oscillation in the inhomogeneous

226 Simulations of titration curves and line shapes show that a primary dissociation constant as

227 Changes in the 13C NMR line shapes show that the diphenyl compound 8 undergoes

228 The line shapes show that the predominant pathway for exchan

229 trogen of NO and, as measured across the EPR line shape, showed a hyperfine coupling range from 36 to

230 rmediate, assigned to a Mn(V) species, had a line shape similar to that of the later intermediate, as

231 inhomogeneous broadening of the conventional line shapes, similar to multiply spin-labeled membranous

232 nd H(delta1)/H48 resonances was confirmed by line shape simulation that follows the McConnell equatio

233 The number of free parameters in the line shape simulation was reduced by independent measure

234 Line shape simulations indicate that RTD-1 induces the f

235 mma)-C(delta) bond axes as indicated by (2)H line-shape simulations and reduced quadrupolar splitting

236 ynamic 1H NMR spectroscopic measurements and line-shape simulations suggested that the energy barrier

237 R3) in U-shaped, L-shaped, and long straight line-shaped (SL-shape) conformations are assembled into

238 Proton, 13C, 6Li, and 15N NMR line-shape studies of exo,exo-1-trimethylsilyl-3-(dimeth

239 tary method to other techniques that utilize line shapes, such as fluorescence, NMR, and ESR spectros

240 spectrum of the cluster shows an asymmetric line shape that is broader than what would be expected f

241 segregated near the surface show a symmetric line shape that suggests weak or no damping of the plasm

242 nyl)amino]styryl}-2,5-dicyanobenzene exhibit line shapes that vary strongly with temperature, display

243 ine how water chemistry in main distribution lines shape the microbiome in drinking water biofilms an

244 gnetic field and an analysis of the (2)H NMR line shapes, the angles between the individual C-CD(3) b

245 unt of information contained in the spectral line shapes, the problems with sensitivity and resolutio

246 The theory is based on a non-Markovian line shape theory and includes exciton delocalization, v

247 demonstrates that B and C formulas from EPR line shape theory are useful for qualitative analysis of

248 overbroadening arising from this approximate line shape theory, we demonstrate that our model Hamilto

249 Analysis of amide I band line shapes through Fourier deconvolution and nonlinear

250 ak at 279.9 eV and subtracted from the O(1s) line shape to aid identification.

251 udiating the common practice of using such a line shape to infer the absence of metallic species.

252 were obtained by fitting the deuterium ssNMR line shape to specific motional models.

253 field sensitivity based on variations in ESR line shapes to be approximately 50 muT/ radicalHz.

254 tected EPR spectra of yeast Y* reveal an EPR line shape typical of a tyrosyl radical; however, when c

255 rated no change in high-field (1)H and (13)C line shapes up to 573K in 1, 3-([D(3)]methoxy)benzene.

256 residues on SecB showed changes in spectral line shape upon addition of SecA.

257 Line shape variations with the partial pressure of the m

258 We have simulated numerous line shapes varying the adjustable parameters, including

259 mpound lacks beta-methylene protons, the EPR line shape was dramatically altered when compared to tha

260 e temperature dependence of (17)O NMR powder line shapes, we have not only confirmed that the SO(3)(-

261 The spectral line shapes were analyzed as a function of side chain st

262 Spectral line shapes were analyzed in terms of side-chain mobilit

263 tronger in the presence of acidic lipid, EPR line shapes were not strongly affected by the presence o

264 branes were illuminated at 15 K, and the EPR line shapes were relatively broad.

265 Voigt line shapes were used to fit absorption spectra of sodiu

266 nges according to the observed deuterium NMR line shapes, whereas the furanose rings of nucleotides m

267 in line shape and (2) changes in the overall line shape which may or may not be accompanied by a freq

268 QA(-) exhibit a derivative-like, complicated line shape, which differs considerably from the HF ENDOR

269 nt inhomogenous contribution to the spectral line shape, which is quantified by simulations.

270 not alter the [2Fe-2S] cluster EPR spectral line shapes, which remain indicative of one ubiquinone o

271 different positions yielded nearly identical line shapes while a fourth 15-mer containing AAATT produ

272 ion is resolved into two bands of Lorentzian line shape, while the DNA-bound monomer spectrum in this

273 The transition rate exhibited a resonance line shape with an extremely narrow width as small as 1.

274 e phase-memory time T2M and conventional EPR line shapes with predominantly homogeneous broadening, o

275 tral diffusion (time dependence of the 2D-IR line shapes) with and without the disulfide bond.