ライフサイエンスコーパス: metal bond

1 iodide for a fluoride strengthens the metal-metal bond.

2 e-electron bond is an exceedingly long metal-metal bond.

3 tal orientation and the presence of a metal--metal bond.

4 the relative weakness of newly formed carbon-metal bonds.

5 ntermediates, and products through substrate-metal bonding.

6 correlated with the increasing role of metal-metal bonding.

7 e transition metal cluster with direct metal-metal bonding.

8 nderstanding of the electron deficient metal-metal bonding.

9 moiety with systematic shifts caused by the metal bonding.

10 ions lead to hole localization with no metal-metal bonding.

11 ovides a direct experimental probe of ligand-metal bonding.

12 g carbon-carbon, carbon-hydrogen, and carbon-metal bond activation.

13 which seems to correlate with a short metal-metal bond and a higher spin state.

14 ovided a detailed understanding of the metal-metal bonding and electronic transitions that are respon

15 relation between the amounts of C-metal or O-metal bonds and the corresponding bacterial inactivation

16 delta bonding orbital of the quadruple metal-metal bond, and a strong interaction of this orbital wit

17 atory insertion of the ylide into the carbon-metal bond, and protodemetalation, the last step being t

18 structural feature, the largest metal-halide-metal bond angle.

19 s can be conjugated to peptides via a carbon-metal bond are described, and selected medicinal applica

20 interactions that preclude significant metal-metal bonding are predicted.

21 n reactions and/or direct formation of metal-metal bonds are discussed (103 references).

22 Instead of bearing a static metal-metal bond as suggested by structural X-ray diffraction

23 The expansion of the metal-metal bond becomes the controlling factor for a(b) evolu

24 Heterobimetallic catalysts, bearing a metal-metal bond between a transition metal (TM) and a tin ato

25 Our results clearly show metal-metal bonding between Tc pairs along the edge-sharing ch

26 uggesting the formation of C-O-metal and C-N-metal bonds between N-doped graphene oxide and spinel ox

27 nal sampling of the complex with constrained metal bonds by force-field-based molecular dynamics (MD)

28 This metal-metal bond can be protonated and thus functions like a b

29 Our results show how the emergence of metal-metal bonding can stabilize giant spin-lattice coupling

30 Metal-metal bonded cationic complexes of the [M(2)(DAniF)(n)(M

31 However, the role of each residue in carbon-metal bond cleavage has not been well-defined.

32 leads to a dinuclear, acetate-bridged, metal-metal bonded complex of platinum(III); dmso in the prese

33 ther by ATR-FTIR suggesting the formation of metal-bonded complexes at circumneutral to low pHc = -lo

34 this plane could be especially reactive for metal-bonded complexes, as they facilitate a mononuclear

35 e first study of a fluorophore-labeled metal-metal bonded compound, work that opens up new venues for

36 The average ligand-metal bond covalencies obtained from these pre-edges are

37 The changes in ligand-metal bond covalencies upon redox compared with DFT calc

38 small relative to the large change in ligand-metal bond covalency (30%) observed in the data.

39 ) has been employed to directly probe ligand-metal bond covalency, where it has been found that prote

40 steps that replace several C-H bonds with C-metal bonds, desorb H atoms (H*) from saturated surfaces

41 The Mn-Cr complex has an ultrashort metal-metal bond distance of 1.82 A, which is consistent with

42 nce of incorporating an additional adsorbate-metal bonding effect in the calculation is demonstrated

43 that the diiron system has delocalized metal-metal bonding electrons, which seems to correlate with a

44 w set of stable NC sizes with simpler ligand-metal bonding for researchers to explore both experiment

45 to involve the NHC's ability to induce metal-metal bond formation.

46 complexes containing short uranium-group 10 metal bonds have been prepared from monometallic IU(IV)(

47 As a result the very nature of the carbon-metal bond in the Ni(I)-CO adduct and the molecular back

48 de a multireference description of the metal-metal bond in the simple dimers MeMMMe and PhMMPh (M = C

49 port for the oxide layer theory of porcelain-metal bonding in dental alloy systems.

50 e elucidation of the mechanism for porcelain-metal bonding in dental systems, because a test capable

51 le experimental tool in the studies of metal-metal bonding in endohedral metallofullerenes and in end

52 Here, we study the nature of metal-metal bonding in the ThCr(2)Si(2) structure type by prob

53 Finally, three metal-metal bonds in experimentally characterized compounds ar

54 formation of new species containing actinide-metal bonds in good yields (Th: 6; U: 7); this photolysi

55 s for the fundamental understanding of metal-metal bonding interactions.

56 bridging carbonyl and formation of the metal-metal bond is accompanied by coordination of a phosphine

57 nyl and electron-donating ligands, the metal-metal bond is the highest occupied molecular orbital (HO

58 Metal-metal bonding is used to explain such 'abnormal' behavio

59 Protonation at metal-metal bonds is of fundamental interest in the context of

60 udy reveals the origin of the observed metal-metal bond length disorder, distinctively different for

61 well as static and dynamic disorder in metal-metal bond lengths can be obtained.

62 dral geometry and essentially bulklike metal-metal bond lengths, even for the smallest (few atom) nan

63 Samples of 3c enriched in (13)C (99%) at the metal-bonded methyl sites were also prepared and investi

64 ation where each compound contains two metal-metal bonded Mo(2)(n+) units linked by a dimethyloxamida

65 n-bonded network formation and reduced water-metal bonding observed on Pd relative to Ru.

66 The electronic structure and metal-metal bonding of 2, 6, 8, and 9 are explored through com

67 group into one of the hydride-bridged metal-metal bonds of 8.

68 ble of detecting differences among porcelain-metal bonds of various qualities is required before the

69 alculations revealed that, indeed, the metal-metal bonding orbitals in the diiron complex are much mo

70 (ii) Histidine tautomeric metal bonding patterns in ligating zinc ions are mixed.

71 Metal-metal bonds play a vital role in stabilizing key interme

72 cluster compound, those with direct metal-to-metal bonding, previously known as homogeneous molecular

73 ydrogenation steps, which replace C-H with C-metal bonds, resulting in strong inhibition by H2, also

74 also provides a new approach to probe metal-metal bonding; results for Mn2(CO)10 are provided as an

75 Unexpectedly, the two metal-metal bonded rhodium centers are capable of engaging in

76 Absolute configurations of the metal-bonded stereocenters in the diastereomerically enr

77 egular TcO6 octahedra and diminish the metal-metal bond strength compared with closely related oxides

78 The data show a trend in uranium-metal bond strength that decreases from 3-Ni down to 3-P

79 tural conformation of natural biopolymers in metal bond strength.

80 ing TcBr(6) octahedra with no apparent metal-metal bond (Tc-Tc = 3.7914(4) A).

81 isolated in all three cases, have long metal-metal bonds that are unsupported by bridging ligands, th

82 rbital-selective formation of covalent metal-metal bonds that leads to an "exclusion" of correspondin

83 In the field of metal-metal bonding, the occurrence of stable, multiple bonds

84 t have been used for the formation of carbon-metal bonds to electrode surfaces for analyses of single

85 ation [Co2Cp2(CO)4] +, 2+, which has a metal-metal bond unsupported by bridging ligands.

86 two d(10) centers so as to deem it a "metal-metal bond" vis-a-vis "metallophilic interaction." Densi

87 This strain also weakens the CO-metal bond, which will reduce the energy barrier for cat

88 lic distances that are consistent with metal-metal bonding, while the cobalt centers in Pn*2Co2 (4) e