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1 Me scission of the alkoxy radicals to form a methyl radical.
2 gmented to give the (2,2-diphenylcyclopropyl)methyl radical.
3 ore sensitive in detecting the production of methyl radical.
4 a pyramidal C(3v) anion to the planar D(3h) methyl radical.
5 a a mechanism that involves the formation of methyl radicals.
6 anticipated trends: 0 <or= F(C) <or= 0.3 for methyl radical, 0.4 for ethyl radical, 0.57 for n-propyl
7 on the reactivity of the 5-(2'-deoxyuridinyl)methyl radical (1) and 5-(2'-deoxycytidinyl)methyl radic
9 nyl radical (3) and 2-methylenecyclopentyl-1-methyl radical (1) were measured using the PTOC-thiol co
10 hotolysis of 2 generates 5-(2'-deoxyuridinyl)methyl radical (1), the reactive intermediate that resul
14 ttacked by the hydroxyl radical to produce a methyl radical; administration of CsA with [(12)C]DMSO p
15 ection of two new stratospheric species, the methyl radical and diacetylene, gaseous species present
17 al preference for loss of aryl radicals over methyl radicals and that the selectivity for aryl vs met
18 ysis of CpW(CO)3Me has been shown to produce methyl radicals and to cleave DNA in a single-stranded m
19 dependent generation of 5-(2'-deoxycytidinyl)methyl radical, and our results demonstrate that this ra
23 phoxide via homolytic bond cleavage leads to methyl radical formation and finally to methane in high
25 using dimethyl sulfoxide (DMSO) demonstrated methyl radical formation, revealing the production of hy
27 thymidine methyl group, 5-(2'-deoxyuridinyl)methyl radical, forms interstrand cross-links with the o
29 e independently generated 5-(2'-deoxycytidyl)methyl radical (I) in single- and double-stranded oligod
30 N) spin-trapping experiments aimed to detect methyl radical in biological systems, the nitroxides for
32 h a single transition state by transfer of a methyl radical, in contrast to previously proposed react
34 adicals and that the selectivity for aryl vs methyl radical loss is dependent on the identity of the
35 hoxybenzene anion show peaks for consecutive methyl radical losses, a feature that establishes the 1,
42 s on time scales ranging from <or=0.5 ns for methyl radical to 2.3 ns for adenosyl, the largest radic
43 dical is proposed to subsequently transfer a methyl radical to IB, thus launching the formation of b-
47 nitase and xanthine/xanthine oxidase yielded methyl radical, which was detected by ESR spin trapping.
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