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1 ydrazine has a reactivity similar to that of methylamine.
2 isible transmittance) due to dissociation of methylamine.
3 his enzyme is not essential for oxidation of methylamine.
4 times, including the first monoarylation of methylamine.
5 after treatment with a lysosomal inhibitor, methylamine.
6 ely 50% of each cofactor form at 0.8 or 2 mM methylamine.
7 ved with sodium periodate in the presence of methylamine.
8 ted a 1000-fold increase in the Km value for methylamine.
9 fld1 host by selection on plates containing methylamine.
10 adily penetrate germinated spores, including methylamine.
11 rting methyl-Arg to citrulline and releasing methylamine.
12 , none is required for growth on methanol or methylamine.
13 n was irradiated (365 nm) in the presence of methylamine.
14 dergo conformational change by reaction with methylamine.
15 e by other microorganisms not directly using methylamine.
16 al environment that assimilate nitrogen from methylamine.
17 sialic acids by covalent derivatization with methylamine.
18 cid into the corresponding N-protected alpha-methylamine.
19 ld during the growth of M. extorquens PA1 on methylamine.
20 tance of yeast to the toxic transport analog methylamine.
21 otrophs and non-methylotrophs, to metabolize methylamine.
22 yl-dH(4)MPT accumulation, enhances growth on methylamine.
23 own pathways by which methane is formed from methylamines.
24 thylamine:CoM methyl transfer from all three methylamines.
25 ved; and 6) mutual counteraction by urea and methylamines.
26 genesis in Methanosarcina barkeri growing on methylamines.
27 transferase specific for methanogenesis from methylamines.
28 tant generally is reduced by urea and/or the methylamines.
30 ed an increase in growth factors for glyoxal-methylamine (19% by vol) and methylglyoxal-methylamine (
31 h a homologous series of amines or alcohols (methylamine, 2-methyl-2-aminopropane, methanol, or 2-met
33 ) and three isomeric 15,16-bisnorpimarenyl-N-methylamines (26a-c) were synthesized and evaluated as a
36 l-methylamine (19% by vol) and methylglyoxal-methylamine (8% by vol) aerosol, indicating that unusual
38 n base treatment, this second species formed methylamine, a breakdown product characteristic of symme
40 iments on glycolaldehyde- and hydroxyacetone-methylamine aerosol found that the aerosol particles wer
45 -rice showed an excellent gas-sensitivity to methylamine among the four natural pigments sensitized f
47 covalent incorporation of (14)C from [(14)C]methylamine and benzylamine into PSII subunits has been
48 cleaved with the small-molecule nucleophiles methylamine and histamine, but when Spy0125 was mechanic
50 The D319E mutant catalyzes the oxidation of methylamine and phenethylamine, but not that of benzylam
53 epend on ion concentration, pH, the specific methylamine and substrate, and identity of even a single
55 clusion that inhibition by dansylcadaverine, methylamine, and bacitracin is not due to an alkalinizat
56 nd indoxyl sulfate, but levels of hippurate, methylamine, and dimethylamine were not significantly lo
57 ith similarity to the methanogenic methanol, methylamine, and methanethiol methyltransferases and to
60 ses initiate methanogenesis from the various methylamines, and these enzymes are encoded by genes wit
64 y = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine) are investigated in comparison to those of
65 hydrazine) and [ZnTe(ma)] (3; ma = MeNH(2) = methylamine) are two-dimensional (2-D) layered structure
66 AAmRe(O)(X)] DAAm = N,N-bis(2-arylaminoethyl)methylamine; aryl = C6F5 (X = Me, 1, COCH3, 2, Cl, 3) as
67 hylotrophs that have to switch between using methylamine as a carbon and energy source or just a nitr
69 lamide synthetase is essential for growth on methylamine as a carbon source but not as a nitrogen sou
71 thylotrophic microorganisms may also utilize methylamine as a nitrogen source, but little is known ab
73 only when cells are grown in the presence of methylamine as a sole carbon source and is repressed by
75 with ammonium sulfate as nitrogen source) or methylamine as sole nitrogen source (with glucose as car
76 ables rapid growth on high concentrations of methylamine as the primary carbon and energy substrate,
77 hway plays a pivotal role during growth with methylamine as the sole nitrogen source, which we demons
78 grow on reduced single-carbon compounds like methylamine as the sole source of carbon and energy.
80 he primary C-H bonds in linear- and branched-methylamines, as well as secondary C-H bonds in higher d
82 talytic dehydrocoupling/dehydrogenation of N-methylamine-borane, MeNH(2).BH(3) (7), to yield the solu
83 The synthesis and biological activity of a methylamine-bridged enkephalin analogue (MABE) is presen
84 port an association of LysRS1 with growth on methylamine, but not an essential role for LysRS1/LysRS2
85 carbonyl cyanide m-chlorophenylhydrazone and methylamine, but not by spermine, consistent with an act
87 erent substrates (72, 190, and 162 s(-1) for methylamine, butylamine, and benzylamine, respectively).
89 counteraction of urea effects on enzymes by methylamines can depend on ion concentration, pH, the sp
90 we report the effects of 1, 3-cyclohexanebis(methylamine) (CBM) on secretion in vivo, a compound chos
93 vitro ATP-dependent reductive activation of methylamine:CoM methyl transfer from all three methylami
96 layer-composed of a metal halide perovskite-methylamine complex-from a transparent state (68% visibl
98 ny of the persisting organisms play roles in methylamine cycling, ultimately supporting methanogenesi
101 tentials for the oxidized/reduced couples of methylamine dehydrogenase (MADH) and aromatic amine dehy
102 pared with the complex of the TTQ-containing methylamine dehydrogenase (MADH) and the cupredoxin amic
103 s for methylamine oxidation: the periplasmic methylamine dehydrogenase (MaDH) and the cytoplasmic N-m
104 tryptophylquinone (TTQ) in substrate-reduced methylamine dehydrogenase (MADH) by amicyanin is known t
110 factor tryptophan tryptophylquinone (TTQ) in methylamine dehydrogenase (MADH) involves the post-trans
114 yptophan tryptophylquinone (TTQ) cofactor of methylamine dehydrogenase (MADH) is covalently modified
118 in that mediates electron transfer (ET) from methylamine dehydrogenase (MADH) to cytochrome c-551i.
119 he diheme enzyme MauG and different forms of methylamine dehydrogenase (MADH) were subjected to kinet
122 Contrary to the TTQ-containing subunit of methylamine dehydrogenase (MADH), which is catalytically
128 nal modification of the precursor protein of methylamine dehydrogenase (preMADH) to complete biosynth
129 ional modification of a precursor protein of methylamine dehydrogenase (preMADH) to complete the bios
130 ation of a biosynthetic precursor protein of methylamine dehydrogenase (PreMADH) with partially synth
131 rent from those for the related quinoprotein methylamine dehydrogenase and its associated redox prote
132 ee-dimensional structure of the quinoprotein methylamine dehydrogenase from Paracoccus denitrificans
133 ese data in which the reduction of Cu(2+) by methylamine dehydrogenase is a true ET reaction while th
134 talyzes posttranslational modifications of a methylamine dehydrogenase precursor protein to generate
135 -studied aerobic methylotroph, a periplasmic methylamine dehydrogenase that catalyzes the primary oxi
137 ectron transfer (ET) reactions from O-quinol methylamine dehydrogenase to oxidized native and mutant
138 tophylquinone (TTQ), the prosthetic group of methylamine dehydrogenase, is formed by post-translation
140 related to M. extorquens AM1 but is lacking methylamine dehydrogenase, to dissect the genetics and p
145 es, methylotrophy is enabled by methanol and methylamine dehydrogenases and their specific electron t
147 n of Tmm and DMS oxidation in R. pomeroyi is methylamine-dependent and regulated at the post-transcri
148 ergy barrier for the ET from copper to heme, methylamine-dependent reduction of heme by the three-pro
149 try of IPA/NO, we prepared the corresponding methylamine derivative as a sodium salt that was highly
151 played positive chemotactic responses toward methylamine, dimethylamine, and trimethylamine but did n
153 small numbers of water molecules to ammonia, methylamine, dimethylamine, and trimethylamine, and thei
154 eration is found to increase the basicity of methylamine, dimethylamine, benzylamine, and N,N-dimethy
155 eration is found to increase the basicity of methylamine, dimethylamine, benzylamine, N,N-dimethylani
156 reports have shown that the organic cations methylamine, dimethylamine, ethylamine, and trimethylami
157 tion of the omega-bromo groups with ammonia, methylamine, dimethylamine, or trimethylamine provided p
158 tal structures have also been determined for methylamine-, dimethylamine-, and trimethylamine-borane,
159 Whereas the poorly nucleophilic ammonia and methylamine do not react, hydroxylamine, methoxylamine,
161 (Arg), and several primary amines including methylamine, ethylamine, n-propylamine, n-butylamine, an
162 from uric acid, glucose, ammonia, caffeine, methylamine, ethylenediamine, hydroxylamine, n-butylamin
163 f homologous nucleophiles (e.g., ammonia and methylamine) facilitates recognition and identification
164 (13)C-labeled glucose by derivatization with methylamine followed by multiple reaction monitoring sca
165 onothio-1,3-diketones with alpha-substituted methylamines, followed by their alpha-nitrosation with s
166 ines as functional groups (e.g., secondary N-methylamines) formed chloropicrin at high yields, likely
169 ssay conditions (pH and salt concentration), methylamines (glycerophosphocholine, betaine, and trimet
170 terium extorquens AM1, MaDH is essential for methylamine growth, but the NMG pathway has no known phy
171 ne > pyridine > triethylamine > ethylamine > methylamine > diethylamine > tert-butylamine > ammonia.
173 and N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine, has been proposed to attack C-H bonds by an
176 ich prevents acidification of endosomes) and methylamine HCl (which neutralizes acidification of endo
177 t (4-bromo-3,6-dimethoxybenzocyclobuten-1-yl)methylamine hydrobromide (TCB-2) enhanced C-fiber-evoked
179 st 4-bromo-3,6-dimethoxybenzocyclobuten-1-yl)methylamine hydrobromide, binds less to the mGlu2 promot
180 5,5-bis-(4-fluorophenyl)tetrahydrofuran-2-yl]methylamine hydrochloride, NCC1048) in a model of hypoxi
181 respect to nucleophilic addition to ammonia, methylamine, hydroxylamine, methoxylamine, and hydrazine
183 rom the dark reactions of methylglyoxal with methylamine in simulated evaporated cloud droplets.
185 C3), we coupled the free sulfhydryl group of methylamine-inactivated C3 to a thiolSepharose matrix.
189 ion in the adenine base to incorporate [(3)H]methylamine into the synthesis of [(3)H]MRS2279 to high
193 is(2-[2-(N',N'-4-dimethylamino)pyridyl]ethyl)methylamine) is described, to model aspects of the chemi
196 The method employs neutron encoded (NeuCode) methylamine labels ((13)C or (15)N enriched) that are af
198 -N-(2,2,2-trifluoroethylsulfonyl)-pyrid-3-yl methylamine (LY487379) is a selective positive allosteri
199 id (OxA) on NPF from the reaction of MSA and methylamine (MA) at 1 atm and 294 K in the presence and
202 h trimethylamine (TMA), dimethylamine (DMA), methylamine (MA), and ammonia over the range of 21-28 de
203 with the primary and secondary alkylamines: methylamine (MA), dimethylamine (DMA), and ethylamine (E
204 th the radioactive analog of ammonium [(14)C]methylamine (MA), had an apparent EC(50) of 1.6 mm and a
206 No measurable amounts of cadaverine (CAD) or methylamine (MEA) were found, showing no spoilage sympto
207 (tfepma = (bis[bis(trifluoroethoxy)phosphino]methylamine, MeN(P[OCH2CF3]2)2), have been prepared by t
209 lized and the effects of Etn, MeEtn, Me2Etn, methylamine (MeNH2), and dimethylamine (Me2NH) were stud
210 hylated ethanolamines (MeEtn and Me2Etn) and methylamines (MeNH2, Me2NH) were used as Etn models that
211 type of DeltappylT reveals the deficiency in methylamine metabolism expected of a Methanosarcina spec
212 ysine derivative encoded by the UAG codon in methylamine methyltransferase genes of Methanosarcina ba
217 have been characterized previously, a set of methylamine methyltransferases in which Pyl is assumed t
219 codon in genes encoding proteins such as the methylamine methyltransferases present in some Archaea a
222 were comparable with those determined using methylamine-modified alpha(2)M, suggesting that higher-o
223 n the presence of excess substrate, the next methylamine molecule initiates a nucleophilic attack of
224 pe, the DeltappylT strain cannot grow on any methylamine, nor use monomethylamine as sole nitrogen so
225 anomalous basicity effect of ammonia and the methylamines on going from the gas phase to aqueous solu
227 atial arrangement, namely to the interior of methylamine or ammonia-treated alpha(2)M and to the exte
229 prepared from nitrophenyl carbamate 14a and methylamine or directly from 5-aminoimidazole-4-carboxam
230 Aminolyses of these isoquinolinediones with methylamine or ethanolamine produced the isoquinolinedio
231 he compound 3 reacts at normal pressure with methylamine or ethylamine, forming N-alkylpyridinium sal
236 lly or chemically in solutions of hydrazine, methylamine, or pyridine to produce electronically coupl
240 mutation had no effect on the parameters for methylamine oxidation by MADH, but significantly affecte
241 ection of proteins for the N-methylglutamate methylamine oxidation pathway that appears to be auxilia
242 omparable, while profiles of Y305A-catalyzed methylamine oxidation suggest the pH-dependent build-up
243 ination of the steady state species of D319E methylamine oxidation, in combination with the kinetic d
247 cterium extorquens AM1 encode two routes for methylamine oxidation: the periplasmic methylamine dehyd
251 led that aniline and aliphatic amines (e.g., methylamine) prefer to attack C8 of intermediate 4a, aff
254 shown that an mtdB mutant is able to grow on methylamine, providing a system to study the role of Mtd
260 hyltransferase activity, including MtbA, the methylamine-specific CoM methylase and the pyl operon re
263 ion of Km of wild-type enzyme by urea and/or methylamines that is partially additive, whereas at the
264 omotropic weak bases (NH4Cl, chloroquine, or methylamine) that increased lysosomal pH and sensitized
266 es in aquatic habitats on the utilization of methylamine, the simplest methylated amine, have mainly
267 pid immobility in and the slow permeation of methylamine through the inner membrane of dormant spores
268 sintegration, either by serum treatment with methylamine to block C4 and C3 split product binding or
271 cterium extorquens AM1 oxidizes methanol and methylamine to formaldehyde and subsequently to formate,
272 nase that catalyzes the primary oxidation of methylamine to formaldehyde has been examined in great d
273 ylamine demonstrated that ozonation converts methylamine to nitromethane at approximately 100% yield.
274 ion and (b) S(N)2 substitution reaction with methylamine to provide diamine 14 with inversion of conf
275 laterally separated by 120 A, whereas in the methylamine-transformed alpha2M, the epitopes are at the
279 tory and assimilatory modules suggested that methylamine use via the N-methylglutamate pathway requir
280 B-like and sox-like genes play a key role in methylamine utilization and encode N-methylglutamate syn
281 ded by the amber codon in genes required for methylamine utilization by members of the Methanosarcina
282 rrectly assembled MADH, eight genes from the methylamine utilization gene cluster of P. denitrificans
283 lete genome of a model obligate methanol and methylamine utilizer, Methylobacillus flagellatus (strai
285 teomics facilitated identification of active methylamine-utilizing Alpha- and Gammaproteobacteria.
286 re firstly exposed to atmospheres containing methylamine vapours with concentrations over the range 2
287 ibition of ANR activity by hydroxylamine and methylamine was due to formation of the glutamine analog
289 yano-induced cleavage of cysteinyl proteins, methylamine was found to be superior to ammonia for cyan
291 participating in coenzyme M methylation with methylamines, was not inhibited by dimethylsulfide and d
292 he improved NPF descriptions for ammonia and methylamines, we placed special focus on the potential t
293 series of N-substituted (2-phenylcyclopropyl)methylamines were designed and synthesized, with the aim
294 l reacted (presumably on chamber walls) with methylamine with a rate constant k = (9 +/- 2) x 10(-17)
295 Both forms are rapidly reduced by substrate methylamine with a rate constant of 199 s(-1) but behave
296 mann-type coupling reactions of methanol and methylamine with iodobenzene by beta-diketone- and 1,10-
297 uctive amination of an epoxy aldehyde with N-methylamine with subsequent intramolecular oxirane ring
298 ethanosarcina spp. begin methanogenesis from methylamines with methyltransferases made via the transl
299 ion showed highest reporter gene activity on methylamines with much lower expression on CO or methano
300 f lysK or lysS grew normally on methanol and methylamines with wild-type levels of monomethylamine me
301 mational change upon thiol ester cleavage by methylamine, with the presence of crosslinks correlating
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