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   1 ydrazine has a reactivity similar to that of methylamine.                                            
     2 isible transmittance) due to dissociation of methylamine.                                            
     3 his enzyme is not essential for oxidation of methylamine.                                            
     4  times, including the first monoarylation of methylamine.                                            
     5  after treatment with a lysosomal inhibitor, methylamine.                                            
     6 ely 50% of each cofactor form at 0.8 or 2 mM methylamine.                                            
     7 ved with sodium periodate in the presence of methylamine.                                            
     8 ted a 1000-fold increase in the Km value for methylamine.                                            
     9  fld1 host by selection on plates containing methylamine.                                            
    10 adily penetrate germinated spores, including methylamine.                                            
    11 rting methyl-Arg to citrulline and releasing methylamine.                                            
    12 , none is required for growth on methanol or methylamine.                                            
    13 n was irradiated (365 nm) in the presence of methylamine.                                            
    14 dergo conformational change by reaction with methylamine.                                            
    15 e by other microorganisms not directly using methylamine.                                            
    16 al environment that assimilate nitrogen from methylamine.                                            
    17 sialic acids by covalent derivatization with methylamine.                                            
    18 cid into the corresponding N-protected alpha-methylamine.                                            
    19 ld during the growth of M. extorquens PA1 on methylamine.                                            
    20 tance of yeast to the toxic transport analog methylamine.                                            
    21 otrophs and non-methylotrophs, to metabolize methylamine.                                            
    22 yl-dH(4)MPT accumulation, enhances growth on methylamine.                                            
    23 own pathways by which methane is formed from methylamines.                                           
    24 thylamine:CoM methyl transfer from all three methylamines.                                           
    25 ved; and 6) mutual counteraction by urea and methylamines.                                           
    26 genesis in Methanosarcina barkeri growing on methylamines.                                           
    27 transferase specific for methanogenesis from methylamines.                                           
    28 tant generally is reduced by urea and/or the methylamines.                                           
  
    30 ed an increase in growth factors for glyoxal-methylamine (19% by vol) and methylglyoxal-methylamine (
    31 h a homologous series of amines or alcohols (methylamine, 2-methyl-2-aminopropane, methanol, or 2-met
  
    33 ) and three isomeric 15,16-bisnorpimarenyl-N-methylamines (26a-c) were synthesized and evaluated as a
  
  
    36 l-methylamine (19% by vol) and methylglyoxal-methylamine (8% by vol) aerosol, indicating that unusual
  
    38 n base treatment, this second species formed methylamine, a breakdown product characteristic of symme
  
    40 iments on glycolaldehyde- and hydroxyacetone-methylamine aerosol found that the aerosol particles wer
  
  
  
  
    45 -rice showed an excellent gas-sensitivity to methylamine among the four natural pigments sensitized f
  
    47  covalent incorporation of (14)C from [(14)C]methylamine and benzylamine into PSII subunits has been 
    48 cleaved with the small-molecule nucleophiles methylamine and histamine, but when Spy0125 was mechanic
  
    50  The D319E mutant catalyzes the oxidation of methylamine and phenethylamine, but not that of benzylam
  
  
    53 epend on ion concentration, pH, the specific methylamine and substrate, and identity of even a single
  
    55 clusion that inhibition by dansylcadaverine, methylamine, and bacitracin is not due to an alkalinizat
    56 nd indoxyl sulfate, but levels of hippurate, methylamine, and dimethylamine were not significantly lo
    57 ith similarity to the methanogenic methanol, methylamine, and methanethiol methyltransferases and to 
  
  
    60 ses initiate methanogenesis from the various methylamines, and these enzymes are encoded by genes wit
  
  
  
    64 y = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine) are investigated in comparison to those of 
    65 hydrazine) and [ZnTe(ma)] (3; ma = MeNH(2) = methylamine) are two-dimensional (2-D) layered structure
    66 AAmRe(O)(X)] DAAm = N,N-bis(2-arylaminoethyl)methylamine; aryl = C6F5 (X = Me, 1, COCH3, 2, Cl, 3) as
    67 hylotrophs that have to switch between using methylamine as a carbon and energy source or just a nitr
  
    69 lamide synthetase is essential for growth on methylamine as a carbon source but not as a nitrogen sou
  
    71 thylotrophic microorganisms may also utilize methylamine as a nitrogen source, but little is known ab
  
    73 only when cells are grown in the presence of methylamine as a sole carbon source and is repressed by 
  
    75 with ammonium sulfate as nitrogen source) or methylamine as sole nitrogen source (with glucose as car
    76 ables rapid growth on high concentrations of methylamine as the primary carbon and energy substrate, 
    77 hway plays a pivotal role during growth with methylamine as the sole nitrogen source, which we demons
    78 grow on reduced single-carbon compounds like methylamine as the sole source of carbon and energy.    
  
    80 he primary C-H bonds in linear- and branched-methylamines, as well as secondary C-H bonds in higher d
  
    82 talytic dehydrocoupling/dehydrogenation of N-methylamine-borane, MeNH(2).BH(3) (7), to yield the solu
    83   The synthesis and biological activity of a methylamine-bridged enkephalin analogue (MABE) is presen
    84 port an association of LysRS1 with growth on methylamine, but not an essential role for LysRS1/LysRS2
    85 carbonyl cyanide m-chlorophenylhydrazone and methylamine, but not by spermine, consistent with an act
  
    87 erent substrates (72, 190, and 162 s(-1) for methylamine, butylamine, and benzylamine, respectively).
  
    89  counteraction of urea effects on enzymes by methylamines can depend on ion concentration, pH, the sp
    90 we report the effects of 1, 3-cyclohexanebis(methylamine) (CBM) on secretion in vivo, a compound chos
  
  
    93  vitro ATP-dependent reductive activation of methylamine:CoM methyl transfer from all three methylami
  
  
    96  layer-composed of a metal halide perovskite-methylamine complex-from a transparent state (68% visibl
  
    98 ny of the persisting organisms play roles in methylamine cycling, ultimately supporting methanogenesi
  
  
   101 tentials for the oxidized/reduced couples of methylamine dehydrogenase (MADH) and aromatic amine dehy
   102 pared with the complex of the TTQ-containing methylamine dehydrogenase (MADH) and the cupredoxin amic
   103 s for methylamine oxidation: the periplasmic methylamine dehydrogenase (MaDH) and the cytoplasmic N-m
   104 tryptophylquinone (TTQ) in substrate-reduced methylamine dehydrogenase (MADH) by amicyanin is known t
  
  
  
  
  
   110 factor tryptophan tryptophylquinone (TTQ) in methylamine dehydrogenase (MADH) involves the post-trans
  
  
  
   114 yptophan tryptophylquinone (TTQ) cofactor of methylamine dehydrogenase (MADH) is covalently modified 
  
  
  
   118 in that mediates electron transfer (ET) from methylamine dehydrogenase (MADH) to cytochrome c-551i.  
   119 he diheme enzyme MauG and different forms of methylamine dehydrogenase (MADH) were subjected to kinet
  
  
   122    Contrary to the TTQ-containing subunit of methylamine dehydrogenase (MADH), which is catalytically
  
  
  
  
  
   128 nal modification of the precursor protein of methylamine dehydrogenase (preMADH) to complete biosynth
   129 ional modification of a precursor protein of methylamine dehydrogenase (preMADH) to complete the bios
   130 ation of a biosynthetic precursor protein of methylamine dehydrogenase (PreMADH) with partially synth
   131 rent from those for the related quinoprotein methylamine dehydrogenase and its associated redox prote
   132 ee-dimensional structure of the quinoprotein methylamine dehydrogenase from Paracoccus denitrificans 
   133 ese data in which the reduction of Cu(2+) by methylamine dehydrogenase is a true ET reaction while th
   134 talyzes posttranslational modifications of a methylamine dehydrogenase precursor protein to generate 
   135 -studied aerobic methylotroph, a periplasmic methylamine dehydrogenase that catalyzes the primary oxi
  
   137 ectron transfer (ET) reactions from O-quinol methylamine dehydrogenase to oxidized native and mutant 
   138 tophylquinone (TTQ), the prosthetic group of methylamine dehydrogenase, is formed by post-translation
  
   140  related to M. extorquens AM1 but is lacking methylamine dehydrogenase, to dissect the genetics and p
  
  
  
  
   145 es, methylotrophy is enabled by methanol and methylamine dehydrogenases and their specific electron t
  
   147 n of Tmm and DMS oxidation in R. pomeroyi is methylamine-dependent and regulated at the post-transcri
   148 ergy barrier for the ET from copper to heme, methylamine-dependent reduction of heme by the three-pro
   149 try of IPA/NO, we prepared the corresponding methylamine derivative as a sodium salt that was highly 
  
   151 played positive chemotactic responses toward methylamine, dimethylamine, and trimethylamine but did n
  
   153 small numbers of water molecules to ammonia, methylamine, dimethylamine, and trimethylamine, and thei
   154 eration is found to increase the basicity of methylamine, dimethylamine, benzylamine, and N,N-dimethy
   155 eration is found to increase the basicity of methylamine, dimethylamine, benzylamine, N,N-dimethylani
   156  reports have shown that the organic cations methylamine, dimethylamine, ethylamine, and trimethylami
   157 tion of the omega-bromo groups with ammonia, methylamine, dimethylamine, or trimethylamine provided p
   158 tal structures have also been determined for methylamine-, dimethylamine-, and trimethylamine-borane,
   159  Whereas the poorly nucleophilic ammonia and methylamine do not react, hydroxylamine, methoxylamine, 
  
   161  (Arg), and several primary amines including methylamine, ethylamine, n-propylamine, n-butylamine, an
   162  from uric acid, glucose, ammonia, caffeine, methylamine, ethylenediamine, hydroxylamine, n-butylamin
   163 f homologous nucleophiles (e.g., ammonia and methylamine) facilitates recognition and identification 
   164 (13)C-labeled glucose by derivatization with methylamine followed by multiple reaction monitoring sca
   165 onothio-1,3-diketones with alpha-substituted methylamines, followed by their alpha-nitrosation with s
   166 ines as functional groups (e.g., secondary N-methylamines) formed chloropicrin at high yields, likely
  
  
   169 ssay conditions (pH and salt concentration), methylamines (glycerophosphocholine, betaine, and trimet
   170 terium extorquens AM1, MaDH is essential for methylamine growth, but the NMG pathway has no known phy
   171 ne > pyridine > triethylamine > ethylamine > methylamine > diethylamine > tert-butylamine > ammonia. 
  
   173 and N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine, has been proposed to attack C-H bonds by an
  
  
   176 ich prevents acidification of endosomes) and methylamine HCl (which neutralizes acidification of endo
   177 t (4-bromo-3,6-dimethoxybenzocyclobuten-1-yl)methylamine hydrobromide (TCB-2) enhanced C-fiber-evoked
  
   179 st 4-bromo-3,6-dimethoxybenzocyclobuten-1-yl)methylamine hydrobromide, binds less to the mGlu2 promot
   180 5,5-bis-(4-fluorophenyl)tetrahydrofuran-2-yl]methylamine hydrochloride, NCC1048) in a model of hypoxi
   181 respect to nucleophilic addition to ammonia, methylamine, hydroxylamine, methoxylamine, and hydrazine
  
   183 rom the dark reactions of methylglyoxal with methylamine in simulated evaporated cloud droplets.     
  
   185 C3), we coupled the free sulfhydryl group of methylamine-inactivated C3 to a thiolSepharose matrix.  
  
  
  
   189 ion in the adenine base to incorporate [(3)H]methylamine into the synthesis of [(3)H]MRS2279 to high 
  
  
  
   193 is(2-[2-(N',N'-4-dimethylamino)pyridyl]ethyl)methylamine) is described, to model aspects of the chemi
  
  
   196 The method employs neutron encoded (NeuCode) methylamine labels ((13)C or (15)N enriched) that are af
  
   198 -N-(2,2,2-trifluoroethylsulfonyl)-pyrid-3-yl methylamine (LY487379) is a selective positive allosteri
   199 id (OxA) on NPF from the reaction of MSA and methylamine (MA) at 1 atm and 294 K in the presence and 
  
  
   202 h trimethylamine (TMA), dimethylamine (DMA), methylamine (MA), and ammonia over the range of 21-28 de
   203  with the primary and secondary alkylamines: methylamine (MA), dimethylamine (DMA), and ethylamine (E
   204 th the radioactive analog of ammonium [(14)C]methylamine (MA), had an apparent EC(50) of 1.6 mm and a
  
   206 No measurable amounts of cadaverine (CAD) or methylamine (MEA) were found, showing no spoilage sympto
   207 (tfepma = (bis[bis(trifluoroethoxy)phosphino]methylamine, MeN(P[OCH2CF3]2)2), have been prepared by t
  
   209 lized and the effects of Etn, MeEtn, Me2Etn, methylamine (MeNH2), and dimethylamine (Me2NH) were stud
   210 hylated ethanolamines (MeEtn and Me2Etn) and methylamines (MeNH2, Me2NH) were used as Etn models that
   211 type of DeltappylT reveals the deficiency in methylamine metabolism expected of a Methanosarcina spec
   212 ysine derivative encoded by the UAG codon in methylamine methyltransferase genes of Methanosarcina ba
  
  
  
  
   217 have been characterized previously, a set of methylamine methyltransferases in which Pyl is assumed t
  
   219 codon in genes encoding proteins such as the methylamine methyltransferases present in some Archaea a
  
  
   222  were comparable with those determined using methylamine-modified alpha(2)M, suggesting that higher-o
   223 n the presence of excess substrate, the next methylamine molecule initiates a nucleophilic attack of 
   224 pe, the DeltappylT strain cannot grow on any methylamine, nor use monomethylamine as sole nitrogen so
   225 anomalous basicity effect of ammonia and the methylamines on going from the gas phase to aqueous solu
  
   227 atial arrangement, namely to the interior of methylamine or ammonia-treated alpha(2)M and to the exte
  
   229  prepared from nitrophenyl carbamate 14a and methylamine or directly from 5-aminoimidazole-4-carboxam
   230  Aminolyses of these isoquinolinediones with methylamine or ethanolamine produced the isoquinolinedio
   231 he compound 3 reacts at normal pressure with methylamine or ethylamine, forming N-alkylpyridinium sal
  
  
  
  
   236 lly or chemically in solutions of hydrazine, methylamine, or pyridine to produce electronically coupl
  
  
  
   240 mutation had no effect on the parameters for methylamine oxidation by MADH, but significantly affecte
   241 ection of proteins for the N-methylglutamate methylamine oxidation pathway that appears to be auxilia
   242 omparable, while profiles of Y305A-catalyzed methylamine oxidation suggest the pH-dependent build-up 
   243 ination of the steady state species of D319E methylamine oxidation, in combination with the kinetic d
  
  
  
   247 cterium extorquens AM1 encode two routes for methylamine oxidation: the periplasmic methylamine dehyd
  
  
  
   251 led that aniline and aliphatic amines (e.g., methylamine) prefer to attack C8 of intermediate 4a, aff
  
  
   254 shown that an mtdB mutant is able to grow on methylamine, providing a system to study the role of Mtd
  
  
  
  
  
   260 hyltransferase activity, including MtbA, the methylamine-specific CoM methylase and the pyl operon re
  
  
   263 ion of Km of wild-type enzyme by urea and/or methylamines that is partially additive, whereas at the 
   264 omotropic weak bases (NH4Cl, chloroquine, or methylamine) that increased lysosomal pH and sensitized 
  
   266 es in aquatic habitats on the utilization of methylamine, the simplest methylated amine, have mainly 
   267 pid immobility in and the slow permeation of methylamine through the inner membrane of dormant spores
   268 sintegration, either by serum treatment with methylamine to block C4 and C3 split product binding or 
  
  
   271 cterium extorquens AM1 oxidizes methanol and methylamine to formaldehyde and subsequently to formate,
   272 nase that catalyzes the primary oxidation of methylamine to formaldehyde has been examined in great d
   273 ylamine demonstrated that ozonation converts methylamine to nitromethane at approximately 100% yield.
   274 ion and (b) S(N)2 substitution reaction with methylamine to provide diamine 14 with inversion of conf
   275 laterally separated by 120 A, whereas in the methylamine-transformed alpha2M, the epitopes are at the
  
  
  
   279 tory and assimilatory modules suggested that methylamine use via the N-methylglutamate pathway requir
   280 B-like and sox-like genes play a key role in methylamine utilization and encode N-methylglutamate syn
   281 ded by the amber codon in genes required for methylamine utilization by members of the Methanosarcina
   282 rrectly assembled MADH, eight genes from the methylamine utilization gene cluster of P. denitrificans
   283 lete genome of a model obligate methanol and methylamine utilizer, Methylobacillus flagellatus (strai
  
   285 teomics facilitated identification of active methylamine-utilizing Alpha- and Gammaproteobacteria.   
   286 re firstly exposed to atmospheres containing methylamine vapours with concentrations over the range 2
   287 ibition of ANR activity by hydroxylamine and methylamine was due to formation of the glutamine analog
  
   289 yano-induced cleavage of cysteinyl proteins, methylamine was found to be superior to ammonia for cyan
  
   291 participating in coenzyme M methylation with methylamines, was not inhibited by dimethylsulfide and d
   292 he improved NPF descriptions for ammonia and methylamines, we placed special focus on the potential t
   293 series of N-substituted (2-phenylcyclopropyl)methylamines were designed and synthesized, with the aim
   294 l reacted (presumably on chamber walls) with methylamine with a rate constant k = (9 +/- 2) x 10(-17)
   295  Both forms are rapidly reduced by substrate methylamine with a rate constant of 199 s(-1) but behave
   296 mann-type coupling reactions of methanol and methylamine with iodobenzene by beta-diketone- and 1,10-
   297 uctive amination of an epoxy aldehyde with N-methylamine with subsequent intramolecular oxirane ring 
   298 ethanosarcina spp. begin methanogenesis from methylamines with methyltransferases made via the transl
   299 ion showed highest reporter gene activity on methylamines with much lower expression on CO or methano
   300 f lysK or lysS grew normally on methanol and methylamines with wild-type levels of monomethylamine me
   301 mational change upon thiol ester cleavage by methylamine, with the presence of crosslinks correlating
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