ライフサイエンスコーパス: methylstyrene

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1 ism of para-disubstituted benzenes such as p-methylstyrene.

2 -dimethylstyrene, 4-tert-butylstyrene, and 3-methylstyrene.

3 III) salen-catalyzed epoxidation of cis-beta-methylstyrene.

4 ne monomers: styrene, 2,5-dimethylstyrene, 4-methylstyrene, 2,4-dimethylstyrene, 4-tert-butylstyrene,

5 mihydrogenate 1-phenyl-1-propyne to cis-beta-methylstyrene (20 bar H2, 40 degrees C) with turnover nu

6 The selective oxidation of trans-methylstyrene, a phenyl-substituted propene that contain

7 e compromised by polymerization of the alpha-methylstyrene, a process favored by tetrahydrofuran (THF

8 ino)naphthalenide (LDMAN), is added to alpha-methylstyrene, a tandem addition/cyclization to a phenyl

9 -mediated sulfonylation of substituted alpha-methylstyrenes and sodium sulfinates (RSO2Na) in MeCN wi

10 arable conditions alpha-methylstyrene, trans-methylstyrene, and allylbenzene behave very differently

11 )-dependent epoxidation of styrene, cis-beta-methylstyrene, and cis-stilbene with retention of stereo

12 engaging in a [3+2] cycloaddition with alpha-methylstyrene, and conversion into dienones.

13 rom the reaction of 1 with styrene and alpha-methylstyrene are formulated as [(PhNO)3Cu(eta(2)-alkene

14 end consisting of polystyrene and poly(alpha-methylstyrene), both polymers having similar molecular w

15 ms in THF due to polymerization of the alpha-methylstyrene, but moderate yields are attained in a sol

16 nchains 15.4% more styrene (B), 28.9% more 4-methylstyrene (C), 45.4% more 4-fluorostyrene (D), 41.2%

17 The epoxidation of beta-methylstyrene catalyzed by the Shi fructose-derived keto

18 mulations of an explicitly solvated cis-beta-methylstyrene/chloroperoxidase-Compound I complex are pe

19 d by hypercrosslinking from a generic poly(4-methylstyrene-co-vinylbenzyl chloride-co-divinylbenzene)

20 This is demonstrated for poly(alpha-methylstyrene), in which backbiting is obstructed due to

21 on of the dimethyl ether in vacuo, the alpha-methylstyrene is added and the solution is warmed to -30

22 3), CPO's enantiospecificity toward cis-beta-methylstyrene is likely to be caused by a specific group

23 to approximately 22 A in length (e.g., two p-methylstyrene molecules).

24 secutive chain transfer reaction, first to p-methylstyrene (or styrene) and then to hydrogen, during

25 Each PP chain formed contains a terminal p-methylstyrene (or styrene) unit.

26 ular mechanics calculations of 1S,2S-trans-2-methylstyrene oxide in the active site of murine epoxide

27 S(N)2 reaction of acetate with 1S,2S-trans-2-methylstyrene oxide to provide the corresponding diol ac

28 ersely proportional to the molar ratio of [p-methylstyrene]/[propylene] and [styrene]/[propylene] wit

29 ns from the reactions of trans- and cis-beta-methylstyrene reveal that the reaction proceeds, at leas

30 ve rates of oxidation of cis- and trans-beta-methylstyrenes together with the rho value of a series o

31 found that under comparable conditions alpha-methylstyrene, trans-methylstyrene, and allylbenzene beh

32 quential reaction was also completed where p-methylstyrene was oxidized to 4'-methyl-acetophenone by

33 ucts, except for the reactions of trans-beta-methylstyrene, which afford exo-chromans.

34 tic activity for the hydroarylation of alpha-methylstyrene with N,N-dimethylaniline, and the copper(I

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