ライフサイエンスコーパス: microporous

1 ne core, the resultant pore sizes range from microporous (10 A) to mesoporous (37 A), with surface ar

2 K, 1 bar) of any porous material, including microporous 13X zeolite (9 mol kg(1)), Amberlyst 15 (11

3 Microporous 3D polymers were created using 3D printing o

4 the QDs is chemically accessible within the microporous, about 15-mum-wide tube wall.

5 ctroscopy is used to investigate a series of microporous activated carbons derived from a poly(ether

6 s adsorbed chemical warfare agents (CWAs) on microporous activated carbons used in protective garment

7 we report a versatile and strong wet-contact microporous adhesive resulting from polyelectrolyte comp

8 For mixture separations with microporous adsorbents, uphill diffusion can cause supra

9 d periods, a property that is matched by few microporous adsorbents.

10 Ion channel mimics based on both microporous alumina and Au nanotube membranes were inves

11 r deposition of carbon within the pores of a microporous alumina template.

12 Iron-containing zeolites (microporous aluminosilicate minerals) are noteworthy in

13 yst supports, we have applied the results to microporous aluminosilicates and aluminophosphates (zeol

14 Phosphorus and microporous aluminosilicates, better known as zeolites,

15 ries of fluorocarbon derivatives on a set of microporous and hierarchical mesoporous frameworks.

16 Such carbons show largely microporous and mesoporous domains and exhibit Brunaeur-

17 Aerogels were microporous and mesoporous materials, as characterized b

18 lending with NCC decreased the count of both microporous and mesoporous-classified pores at the sub-1

19 operties, may lead to the development of new microporous and open-framework materials with potential

20 These materials are microporous and possess surfaces that are far from flat.

21 amined NPs included anatase and rutile TiO2, microporous and spherical SiO2, and alpha-form and beta-

22 s, including self-healing after deformation, microporous architecture, and stability against dilution

23 The microporous B/C material with B content > 7% and surface

24 For in vivo technical validation, the microporous balloon catheter was placed in the CBD by me

25 into CBD walls of six cadaveric pigs using a microporous balloon catheter.

26 emcitabine and 5-FU was performed by using a microporous balloon with (eight pigs) or without (eight

27 we hypothesized that (i) cell sorting across microporous barriers is regulated by nuclear deformabili

28 cribe the design and synthesis of two new 3D microporous base-functionalized COFs, termed BF-COF-1 an

29 dsorption of the organic vapors mixture onto microporous beaded activated carbon (BAC) and regenerati

30 st solvent molecules, evidence of functional microporous behaviour is scarce.

31 Both racemic and chiral microporous binaphthol (BINOL) networks can be produced

32 Microporous biodegradable polymer tubes were created fro

33 r discusses a new synthesis route to prepare microporous boron substituted carbon (B/C) materials tha

34 h thick walls but instead on controlling the microporous bridging between the two sets of mesopores i

35 Cryptomelane has shown to be highly microporous, by using CO2 physisorption, and highly hydr

36 For the first time, uniform and pinhole-free microporous cage thin films are formed and demonstrated

37 ctrodes (SC-ISEs) have been fabricated using microporous carbon (muPC) as the ion-to-electron transdu

38 carbon (Co-NGC) and inner shells of N-doped microporous carbon (NC) by templating against core-shell

39 A polyethylene glycol-supported microporous carbon coating (MPC/PEG coating) on a Celgar

40 Microporous carbon compartments (MCCs) were developed vi

41 to produce site-specific nitrogen doping in microporous carbon fibers.

42 ies exclusively on the surface of commercial microporous carbon fibers.

43 The insertion of a microporous carbon interlayer decreases the internal cha

44 ere predicted to enhance CO(2) adsorption in microporous carbon materials in the absence of water vap

45 sy scalability, the resulting nitrogen-doped microporous carbon monoliths are promising candidates fo

46 one-step synthesis method of nitrogen doped microporous carbon monoliths derived from biomass with h

47 With a bifunctional microporous carbon paper between the cathode and separat

48 nionic and cationic species within a working microporous carbon supercapacitor electrode.

49 anding of the CO(2) adsorption properties in microporous carbon-based materials.

50 emperature sodium-sulfur battery that uses a microporous carbon-sulfur composite cathode, and a liqui

51 energy barriers in the disordered network of microporous carbon.

52 Hierarchical zeolites are a class of microporous catalysts and adsorbents that also contain m

53 amily of periodic hybrid polymers containing microporous cavities provided by covalently bound organi

54 oporosity arising from two distinct types of microporous chambers in the structure.

55 cularly challenging for an emerging class of microporous complex hydride materials, such as gamma-pha

56 ch involves immobilizing apoenzymes within a microporous composite.

57 or a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge

58 Microporous coordination polymers (MCPs) are demonstrate

59 Five non-interpenetrated microporous coordination polymers (MCPs) are derived by

60 Microporous coordination polymers (MCPs) can achieve a h

61 A series of four isostructural microporous coordination polymers (MCPs) differing in me

62 The utility of microporous coordination polymers (MCPs) for the adsorpt

63 in and are responsible for destabilizing the microporous crystalline structure, for converting the re

64 ctors controlling the formation of nanosized microporous crystals are first revised.

65 and unconventional applications of nanosized microporous crystals including framework (zeolites) and

66 e organic cage molecules that precipitate as microporous crystals when solutions of opposite chiralit

67 The presence of small, highly crystalline, microporous crystals with narrow particle size distribut

68 of amorphous precursors in a wide variety of microporous crystals, insight of the SSZ-13 growth mecha

69 evelopment of an hierarchical variant of the microporous cubic Cu(3)(BTC)(2) (BTC = 1,3,5-benzenetric

70 Chemotaxis was determined using microporous-culture well inserts.

71 As an example, microporous dendrimers are prepared.

72 e new bone formation (19.7%) than the HA-TCP microporous disk (8.5%) or HA-TCP granule (6.9%) groups.

73 ment groups: HA-TCP macroporous disk, HA-TCP microporous disk, HA-TCP granules, and demineralized fre

74 A sintered near-surface microporous dust-ice layer with a porosity of 30 to 65%

75 harge through the electrosorption of ions on microporous electrodes.

76 Here, we report the development of tunable microporous enantiopure mixed-metal-organic framework (M

77 Compound 1 is also microporous, exhibiting a BET surface area of 2130 m2/g.

78 Specific capacitance of these microporous films was determined to be 59 +/- 6 F/cm3.

79 s, and for the formation of new zeolites and microporous films.

80 microstructure and optical properties of the microporous films.

81 oteins present in AH that were retained by a microporous filter was also performed using western blot

82 Myocilin is retained by microporous filters and may be involved in the obstructi

83 nti-gp60 Ab and secondary Ab) in EC grown on microporous filters increased transendothelial (125)I-al

84 was one of the proteins that was retained on microporous filters that were obstructed by AH.

85 g-lifetime pyrene core-affords a permanently microporous fluorescent metal-organic framework, [In(2)(

86 owed unambiguous imaging of light atoms in a microporous framework as well as determining the cationi

87 ther layered silicates with multidimensional microporous framework layers.

88 ot been seen in mixed octahedral/tetrahedral microporous framework materials, a newer and rapidly exp

89 atic hydroxyl groups, which leads to an open microporous framework with tunable permanent mesoporosit

90 e influence of heterovalent substitutions in microporous frameworks on material properties.

91 The microporous frameworks show a saturation uptake capacity

92 uminosilicate nuclei during self-assembly of microporous frameworks.

93 vented through an injectable, interconnected microporous gel scaffold assembled from annealed microge

94 ith enthalpies of sorption characteristic of microporous, glassy macromolecules.

95 on and diagenesis produce in carbonate rocks microporous grains and a wide range of pore sizes, resul

96 rray working electrode format augmented with microporous graphitized carbon (MGC) that was electrodep

97 Microporous H-ZSM-5 containing one Bronsted acid site pe

98 izes ranging from mainly microporous to half microporous-half mesoporous to mainly mesoporous, were i

99 Here we report Y-shp-MOF-5, a hybrid microporous highly connected rare-earth-based metal-orga

100 l phase outperforms the structurally related microporous HKUST-1 as well as silicate-based hierarchic

101 umidity, and correlations were difficult for microporous HKUST-1 due to its relative instability towa

102 of mesoporous dimensions, in addition to the microporous host cavities.

103 is to allow enhanced access of guests to the microporous hosts.

104 Here, we 3D print microporous hydrogel scaffolds to test how varying pore

105 A homochiral microporous hydrogen-bonded organic framework (HOF-2) ba

106 onal groups leads to a unique rod-packing 3D microporous hydrogen-bonded organic framework (HOF-3).

107 The first microporous hydrogen-bonded organic framework with perma

108 low-grade heat to drive water vapor across a microporous hydrophobic membrane.

109 Several microporous hydrophobic zeolite imidazolate frameworks (

110 We report a microporous hydroxyl-decorated material, MFM-300(In) (MF

111 rescence labels and a flowing chamber with a microporous immunofilter.

112 d) in DMSO or DMSO-ethanol mixtures produces microporous inorganic-organic hybrids.

113 ature interaction of NH(3) and dioxygen with microporous layers of Co-porphyrins.

114 f AMH-3, a silicate with three-dimensionally microporous layers, obtained in high purity and crystall

115 of a successful balloon angioplasty using a microporous local delivery infusion balloon.

116 chieved suggest the potential application of microporous M'MOFs for practical adsorption-based separa

117 xolene ligands to support the formation of a microporous magnet and provide the first example of a st

118 hest ordering temperature yet observed for a microporous magnet.

119 tetraoxolene radical bridging ligands into a microporous magnetic solid is demonstrated.

120 Cr(CN)(6)](2) x 10 H(2)O (2) affords two new microporous magnets: CsNi[Cr(CN)(6)] (1d) and Cr(3)[Cr(C

121 d mesoporous material (COF) or an amorphous, microporous material (COP).

122 Exposure of the related microporous material Ni(2)(4,4'-bipyridine)(3)(NO(3))(4)

123 lass of porous materials called hybrid ultra-microporous materials (HUMs) affords new benchmark selec

124 e future needs and perspectives of nanosized microporous materials (zeolites and clays) are addressed

125 p the complex site population present inside microporous materials are critically discussed.

126 Similar to the parent compound, the new microporous materials are stable to desolvation and exhi

127 tection, absolute quantification of water in microporous materials becomes possible.

128 The synthesis of crystalline microporous materials containing large pores is in high

129 Zeolites are microporous materials driving industrial scale adsorptio

130 ption technologies may allow separation, but microporous materials exhibiting highly selective adsorp

131 Interest in microporous materials has risen in recent years, as they

132 hat (83)Kr NMR spectroscopy of nanoporous or microporous materials is feasible and straightforward de

133 The novel ordered microporous materials reported herein are promising as a

134 ed intrusion studies of water in hydrophobic microporous materials such as zeolites and MOFs, a field

135 s long been known that some highly adsorbing microporous materials suddenly become inaccessible to gu

136 ed here is the homochiral crystallization of microporous materials through the chirality induction ef

137 Adding mesopore networks in microporous materials using the principles of hierarchic

138 Microporous materials were obtained in all four combinat

139 ties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1

140 ees C/N(2) with loss of I(2) to form robust, microporous materials with BET surface areas of 500-700

141 They are integrated with zeolites (microporous materials) and based on surfactant inorganic

142 ar nuclei in the fields of energy materials, microporous materials, Earth sciences, and biomaterials.

143 thesis of the first member of a new class of microporous materials.

144 organic cages can assemble into crystalline microporous materials.

145 (BDT(2)(-)) to generate a series of robust, microporous materials.

146 esis of other organic-functionalized ordered microporous materials.

147 and guests that are physically excluded from microporous materials.

148 micelles produced highly iridescent periodic microporous materials.

149 damage of beam-sensitive materials, such as microporous materials.

150 with H2, N2, Ar and CH4 on three classes of microporous materials: trapdoor zeolites, supramolecular

151 features which differentiate them from other microporous materials?

152 Synthetic microporous matrices can concentrate organics by thermop

153 A composite three dimensional microporous matrix containing multiwalled carbon nanotub

154 We conclude that mineral growth in a microporous media can be estimated based on free surface

155 e progenitors are separated from stroma by a microporous membrane and LTC-IC can proliferate if the c

156 hrough a cartridge enclosing a gas-permeable microporous membrane contactor.

157 tric cylinders, a priming volume of 45 ml, a microporous membrane for plasma separation, and an outer

158 layers were grown to confluency on 3 microns microporous membrane inserts and placed in 6-well tissue

159 nding antibodies and then passed through the microporous membrane where they attached to the membrane

160 Microporous membrane-mediated loading is a novel and eff

161 l cell (lower chamber) layers separated by a microporous membrane.

162 hich the two populations were separated by a microporous membrane.

163 Current microporous membranes [pore size < 1 nanometer (nm)], ho

164 tors that determine surface omniphobicity of microporous membranes and evaluated the potential applic

165 Microporous membranes fabricated from hydrophobic polyme

166 f using dye-encapsulating immunoliposomes in microporous membranes for the rapid detection of molecul

167 s and techniques, it is difficult to prepare microporous membranes thinner than 20 nm without introdu

168 ssure-induced passage of plant cells through microporous membranes.

169 rane applications, for synthesis of combined microporous-mesoporous materials, and for the formation

170 A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of

171 Here we report a microporous metal-organic framework in which the suitabl

172 cyanotrimethylsilane in the presence of the microporous metal-organic framework Mn3[(Mn4Cl)3BTT8(CH3

173 A luminescent microporous metal-organic framework Tb(BTC)G has been de

174 A breathing 2-fold interpenetrated microporous metal-organic framework was synthesized with

175 nzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (p

176 Reaction of the microporous metal-organic framework Zn4O(BDC)3 (BDC2- =

177 A highly luminescent three-dimensional microporous metal-organic framework, [Zn(2)(oba)(2)(bpy)

178 A microporous metal-organic framework, PCN-14, based on an

179 10.5 kJ/mol, the highest yet observed for a microporous metal-organic framework.

180 ntroduction of functionalized mesopores into microporous metal-organic frameworks (MOFs) can endow th

181 Six prototype microporous metal-organic frameworks (MOFs) HKUST-1, MOF

182 Microporous metal-organic frameworks are a class of mate

183 tratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP ca

184 in solutions containing Cu(II) cations, the microporous metal-organic material P11 ([Cd4(BPT)4].[Cd(

185 ape and functional group of the sorbate by a microporous metalloporphyrin solid in analogy to zeolite

186 Here we report a new microporous MOF (designated SBMOF-2) that is selective t

187 under solvothermal conditions afforded a new microporous MOF (NU-601).

188 we discuss the latest developments in ultra-microporous MOF adsorbents and their use as separating a

189 report a general synthetic approach to coat microporous MOFs and their derivatives with an enforcing

190 re currently few methods capable of yielding microporous MOFs containing accessible free-base porphyr

191 anic frameworks (DEMOFs) derived from parent microporous MOFs was obtained by systematic doping with

192 Microporous MOFs with robust metal nodes and pro-labile

193 applications requiring conformal coatings of microporous MOFs, such as gas separation membranes and e

194 ore aperture sizes below 5-7 A, namely ultra-microporous MOFs, which in contrast to conventional zeol

195 he BET theory for obtaining surface areas of microporous MOFs.

196 bar, respectively) as compared to benchmark microporous MOFs.

197 -4) S/cm, which is also among the highest in microporous MOFs.

198 xygen at relatively high pressures among all microporous MOFs.

199 Microporous molecular sieve catalysts and adsorbents dis

200 ents under consideration are shape-selective microporous molecular sieves with hierarchical pore morp

201 is also applicable to other cage-containing microporous molecular sieves, where some of the most ind

202 This process enables the syntheses of microporous nanocrystalline silicon micro-assemblies wit

203 nanostructured silica micro-assemblies into microporous nanocrystalline silicon replicas.

204 carbon hybrids with a morphology containing microporous nanometer-sized particles were obtained.

205 hical zeolite made of orthogonally connected microporous nanosheets.

206 ive analysis of the emerging applications of microporous nanosized crystals in the field of semicondu

207 Owing to their microporous nature nanosized zeolites and clays exhibit

208 ead of on a chip-by-chip basis, and (ii) the microporous network eliminates the diffusion limitations

209 r building blocks with metal ions generating microporous network solids has been the focus of intense

210 which molecular building blocks form robust microporous networks, are usually synthesized as insolub

211 ased on variation of synthesis parameters of microporous networks, such as, for example, zeolites or

212 ption of OMS-2, a well-known one-dimensional microporous octahedral molecular sieve with manganese ox

213 mple method for the bottom-up fabrication of microporous organic particles with surface areas in the

214 Microporous organic polymers have attracted significant

215 ndance (13)C and (15)N CP MAS NMR spectra of microporous organic polymers with excellent signal-to-no

216 Here, we prepare a series of amorphous, microporous organic polymers with exquisite synthetic co

217 Use of synthetic zeolites and other microporous oxides since 1950 has improved insulated win

218 ynthesis of zeolites and related crystalline microporous oxides usually end up entrapped inside the v

219 Zeolites and related crystalline microporous oxides-tetrahedrally coordinated atoms coval

220 ation, the displacement reaction occurs in a microporous packed column of silica beads prefunctionali

221 based electrochemical WBC counting device on microporous paper with patterned gold microelectrodes.

222 eks after coronary ligation, a 6-mm diameter microporous PEUU patch was implanted directly on the inf

223 The mechanical response and morphology of microporous physically-crosslinked cryogels are compared

224 Here, microporous poly(epsilon-caprolactone) scaffolds were de

225 -2-methyl-1-propanesulfonic acid (AMPS) onto microporous poly(ether sulfone) (PES) substrates and suc

226 d also as a 1-2 mum thin layer anchored on a microporous poly(ether sulfone) by surface grafting.

227 e we show that HLOs required a bioartificial microporous poly(lactide-co-glycolide) (PLG) scaffold ni

228 anode and a Ag/AgCl cathode housed behind a microporous poly(tetrafluoroethylene) (PTFE; Gore-tex) g

229 n, induces reactive ozone that collapses the microporous polymer framework.

230 st switching over 10(4) cycles, and flexible microporous polymer membranes incorporating microcrystal

231 edox-active organics (RAOs) were paired with microporous polymer membranes, the rate of active-materi

232 Here, we show using the microporous polymer PIM-1 as a model system that its Qst

233 Microporous polymer scaffolds fabricated from copolymers

234 Microporous polymer scaffolds that allow vascular ingrow

235 gical structure of channels and pores within microporous polymers and their molecular sieving propert

236 Microporous polymers are covalently bound, entirely orga

237 d cationic groups, based on the formation of microporous polymers containing the V-shape rigid Troger

238 inear optical chromophores, liquid crystals, microporous polymers for energy storage and nano and mic

239 ategy of shape-directed packing of chains of microporous polymers may be applied to other rigid polym

240 Microporous polymers of extreme rigidity are required fo

241 article starts with the question, what makes microporous polymers special and are there certain featu

242 We focus here on microporous polymers which are solution-processable, can

243 Emerging applications for these microporous polymers which make explicit use of these un

244 structural and functional features found in microporous polymers which make them really unique and m

245 Removal of the axial ligand afforded a microporous POP that is catalytically active in the meth

246 The catalysts are microporous (pore diameter 7.3 A) aluminophosphates in w

247 N)(6)](3-/4-) complexes for the synthesis of microporous Prussian blue type solids with adjustable po

248 Extracellular matrix proteins adsorbed to microporous scaffolds can enhance the function of transp

249 ctionalized inverted colloidal crystal (ICC) microporous scaffolds were fabricated and their influenc

250 This is because the symmetric microporous shells combine with the hollow space to prom

251 possess the functions of nanoparticle cores, microporous shells, and a cavity in between, which offer

252 ition to the fact that aqueous solutions and microporous silica materials are environmental friendly,

253 ing of a core of metal clusters and an outer microporous silica shell.

254 o-dimensional silica surface, bulk amorphous microporous silica, and bulk amorphous mesoporous silica

255 a time-dependency of barite growth rates in microporous silica.

256 be transformed via calcination into ordered microporous silicas with pore diameters tailorable from

257 d on the internal surface of micropores of a microporous silicate exhibit high selectivity and activi

258 lomeration occurred at low pH or high IS for microporous SiO2, while marked heteroagglomeration only

259 n that methanol to olefin (MTO) catalysis on microporous solid acids proceeds through a hydrocarbon p

260 Crystalline microporous solids are an important class of inorganic m

261 tations open opportunities for the design of microporous solids by the rational positioning of acid s

262 cropore incorporation into mesoporous and/or microporous solids in order to enhance their catalytic p

263 ed zeolite catalysts, a class of crystalline microporous solids that has been revolutionized by the e

264 chemistries made possible by the ability of microporous solids to select reactants, transition state

265 opical applications to inorganic, especially microporous solids, and to molecular crystals; we also l

266 appears to be unprecedented in catalysis by microporous solids, which typically select reactions by

267 nd understanding of the behavior of flexible microporous solids.

268 Microporous SpectraCarb carbon cloth was treated using n

269 Synergetic effects of its high surface area, microporous structure and high nitrogen content, especia

270 ectron microscopy reveals the interconnected microporous structure of both types of hydrogels.

271 owed higher sorbed concentrations due to its microporous structure.

272 the in situ formed LiCl byproduct created a microporous structure.

273 l vanadium silicates with open-framework and microporous structures has been synthesized under mild h

274 als were formed unlike that of our classical microporous structures involving reagent induced-macromo

275 olites are crystalline inorganic solids with microporous structures, having widespread applications i

276 odified glass slides or on three-dimensional microporous substrates.

277 isting of a thin silicone layer on a tubular microporous support, for removing CO(2) in suppressed io

278 lial cells were first grown to confluence on microporous supports and then cultured under low pressur

279 gement of one-dimensional chains that form a microporous supramolecular network with large channels (

280 mmonia which diffused across the hydrophobic microporous Teflon membrane of the device into an adjace

281 Phase separations and microporous textures that are the result of these rearra

282 Microporous thin films (approximately equal to 50 to 400

283 Microporous titania replicas were made from the MOF temp

284 In the present work, ETS-10 microporous titanosilicate has been synthesized and its

285 upports, with pore sizes ranging from mainly microporous to half microporous-half mesoporous to mainl

286 If in the case of microporous UiO-66, CO(2) uptake remained similar whatev

287 ive 5 nm wide mesopores separated by uniform microporous walls in a single crystal structure.

288 orption measurements at 77 K show them to be microporous with BET surface areas of 360 and 400 m(2)/g

289 edicting rate constants for reactions within microporous zeolite catalysts with chemical accuracy has

290 The self-pillared, meso- and microporous zeolite is an active and selective catalyst

291 dedicated to integrating mesopores with the microporous zeolite structures by using templating and/o

292 The microporous ZIF-8 shell provides excellent molecular-siz

293 Microporous zincophosphate sodalite crystal growth has b