ライフサイエンスコーパス: mol

1 fficiently under much milder conditions (1.0 mol % B(C6F5)3 at 25 degrees C).

2 Reactions, promoted by 2.0 mol % of a catalyst that is derived in situ from a readi

3 Transformations are catalyzed by </=6.0 mol % of a Ru catechothiolate complex and afford trisubs

4 highest molecular weight (Mw) with 147,000g/mol while it was 85,000g/mol for alginate from Cystoseir

5 from Cystoseira compressa (ACC) and 58,000g/mol for alginate from Dictyopteris membranaceae (ADM).

6 (Mw) with 147,000g/mol while it was 85,000g/mol for alginate from Cystoseira compressa (ACC) and 58,

7 zation with catalyst loadings as low as 0.01 mol%.

8 high absorption capacity for CO (up to 0.046 mol mol(-1) ) was achieved under ambient conditions, com

9 rformed in the presence of as little as 0.05 mol %, which is the lowest catalyst loading yet achieved

10 ng much lower catalyst-loading (down to 0.05 mol%).

11 , even with catalyst loadings as low as 0.05 mol%.

12 for the hydrogenation of esters down to 0.1 mol % catalyst loading, and gives up to 97 % ee in the h

13 s(-1) are achieved at 25 degrees C using 0.1 mol % of 1 or 2, respectively, in the presence of 20 equ

14 uce the catalyst loading to as little as 0.1 mol %, the lowest one described for this kind of reactio

15 mber (TON) (1 mol% of 1, 12 h, TON = 62; 0.1 mol% of 1, 7 days, TON = 620) reported to date.

16 tion of the extracting aqueous solution (0.1 mol.L(-1) nitric acid) on the sample.

17 oyl-sn-glycero-3-phospho-L-serine (POPS) 3:1 mol/mole and at neutral pH, the peptide adopts transmemb

18 roarenes to sp(2) C-Al bonds (19 examples, 1 mol % Pd loading).

19 methodology developed here operates at low 1 mol % catalyst and photosensitizer loadings.

20 ivities by employing a very low loading of 1 mol % of a bifunctional squaramide organocatalyst.

21 es with the highest turnover number (TON) (1 mol% of 1, 12 h, TON = 62; 0.1 mol% of 1, 7 days, TON =

22 reaction employs a Pd(OAc)2 catalyst at 5-10 mol % loading and silver(I) oxide as a halide-removal ag

23 Singly H-bonded species are dominant at 10 mol %, due to strong DMSO-water interactions.

24 achieved using B(C6F5)3 as the catalyst (10 mol %, 100 degrees C).

25 2.5 mol%) and a bulky ligand (JackiePhos, 10 mol%) controlling the beta-elimination pathway.

26 at low fractions of oDMSi-BTA sergeants (<10 mol%), the polymerization process is cooperative and the

27 ceive (1) autologous CD34+ cells (minimum 10 mol/L+/-20% cells; N=78) or (2) diluent alone (N=83), vi

28 ation of Sm(3+) in NYS phosphor was about 10%mol, and the corresponding concentration quenching mecha

29 obed using a (99m)Tc(VII) tracer at <10(-10) mol L(-1) and gamma camera imaging showed full retention

30 to lower concentrations (4.6(+/-1.3)x10(-10)mol/L perchlorate), a column packed with 70mg of sodium

31 rbium (Er(3+)) concentrations as high as 100 mol% in NaY(Er)F4/NaLuF4 core/shell nanocrystals enhance

32 ite detached was equivalent to 6.5 x 10(-11) mol m(-2) s(-1), which is over an order of magnitude gre

33 driven binding process (DeltaH(o)cal=29.11kJ.mol(-1)).

34 howed lower gs (less than approximately 0.12 mol m(-2) s(-1) ), higher relative Slim (>30%) and decre

35 Docking (binding energy -8.124kcal/mol) and simulation studies confirmed the binding patter

36 of magnitude for pH 7.9 (km = 4.8 x 10(-13) mol cm(-2) s(-1)) and pH 3.4 (km = 3.2 x 10(-13) mol cm(

37 cm(-2) s(-1)) and pH 3.4 (km = 3.2 x 10(-13) mol cm(-2) s(-1)).

38 lmitoyl-2-oleoyl-phosphatidylglycerol (</=15 mol %) in C1P source vesicles depressed C1P intermembran

39 nerates 10:0 resulted in TAGs with nearly 15 mol % of 10:0.

40 es to be quantified at 3.5 +/- 0.2 x 10(-15) mol cell(-1) for the first time.

41 limits of 9.3 nM or 190 amol (1.9 x 10(-16) mol).

42 e to be sigmaH = 10(2.12)S/m.CH2O.exp(-187kJ/mol/(RT)).

43 and as few as 310 zeptomoles (3.1 x 10(-19) mol) were detectable in single droplets (8.8 nL).

44 Here, we report that (i) citric acid (0.2 mol/L) pH-dependently induced a scratching response in m

45 water column, resulting in a flux of 0.01-2 mol m(-2) yr(-1) depending on population density and wat

46 and enantiocontrol, under mild conditions (2 mol % catalyst loading and as low as 50 degrees C).

47 ed the impeding effect, but only up to 10-20 mol %.

48 The addition of gramicidin D at a 1:20 mol ratio with DMPC results in the formation of protein-

49 more, a catalytic amount of 2-norbornene (20 mol %) to mediate this meta-C-H activation process is de

50 investigated the impacts of CerC16 (up to 20 mol %) on the lipid polymorphism of 1-palmitoyl-2-oleoyl

51 For example, copolymers containing 0.23 mol % silane can be generated at 60 degrees C, 600 psig

52 ve for product formation with as low as 0.25 mol% catalyst loading.

53 and DMPC/Cholesterol samples with 13 and 25 mol% cholesterol is a linear function of the heat capaci

54 higher fractions of oDMSi-BTA sergeant (>25 mol%), the isodesmic assembly of the increasing amounts

55 Doping of ClBDPPV with 25 mol% TBAF boosts electrical conductivity to up to 0.62 S

56 average molar mass of Mw=350kg/mol, Mn=255kg/mol.

57 .93kJ/mol, 2.50+/-0.66kJ/mol, 22.50+/-7.26kJ/mol and 15.22+/-2.75kJ/mol, respectively.

58 we describe that low catalyst loadings (0.27 mol %) of Rh2( S-BHTL)4 provide the BCN precursor with 7

59 verage molar mass of Mw=47kg/mol and Mn=28kg/mol and is composed of d-Galp-, d-Glcp- and d-Manp resid

60 ing para-substituted phenoxypyrimidine and 3 mol equiv of the diazo ester.

61 ue to the band convergence of the alloyed 3% mol.

62 n a commonly used IL [Bmim][Tf2 N] (2x10(-3) mol mol(-1) ).

63 with McGowan volumes greater than 1.7 (cm(3) mol(-1))/100.

64 concentration range of 6.3x10(-7)-1.0x10(-3)mol/L perchlorate.

65 tuent between approximately 30 and 232 cm(3)/mol volume with potency increased by halogen polarizeabi

66 demonstrated using iodine as a catalyst (30 mol %) and dimethyl sulfoxide as an oxidant under metal-

67 ovel transformation has been optimized to 30 mol% p-toluenesulfonic acid (p-TSA) in toluene using Dea

68 measured in the pure COH system by up to 30 mol%, as a consequence of a decrease in water activity p

69 hieved through a sequence of Rh2(OAc)4 (0.33 mol %)-catalyzed cyclopropanation, followed by ester hyd

70 e gel-phase domains contain approximately 35 mol % CerC16.

71 -bonded DMSO near the eutectic point (ca. 35 mol %) which also correlates with several abnormalities

72 possesses an average molar mass of Mw=350kg/mol, Mn=255kg/mol.

73 mospheric CO2 concentrations from 270 to 400 mol mol(-1) .

74 omposed of sphingomyelin/cholesterol (55/45; mol/mol) (CPD100Li) and the other composed of sphingomye

75 te molecular weight ranging from 350 to 450g.mol(-1).

76 ction shows an average molar mass of Mw=47kg/mol and Mn=28kg/mol and is composed of d-Galp-, d-Glcp-

77 zing mild basic conditions and as low as 0.5 mol % catalyst loading, and achieving up to >99:1 dr sel

78 dye can be used as photosensitizers with 0.5 mol % loading.

79 The reaction conditions are mild (using 0.5 mol % Pd in general and KF as a base), and functional gr

80 ( 760,000) obtained in xNd: BaTiO3 (x = 0.5 mol%) ceramics derived from the counterpart nanoparticle

81 ts the dopant concentration to less than 1-5 mol% in lanthanide-doped materials, and this remains a m

82 the loading of the Pd can be lowered to 2.5 mol % by using the optimal ligand.

83 Transformations were performed with 0.5-2.5 mol % of a boron-based catalyst, generated in situ from

84 of catalytic conditions with Pd2(dba)3 (2.5 mol%) and a bulky ligand (JackiePhos, 10 mol%) controlli

85 B[8]-mediated non-covalent crosslinking (2.5 mol%), yields extremely stretchable and tough supramolec

86 2 cm/s at the near-saturating level of 62.5 mol % cholesterol and 10 +/- 2 cm/s in a 100% cholestero

87 Reactions are promoted by 5 mol % of Rh catalyst supported by a new chiral pincer ca

88 below room temperature in the presence of 5 mol % of a Pd catalyst bearing a PHOX ligand, generating

89 s (up to 98%) from alpha-diazoesters using 5 mol% of a simple copper(I) salt as catalyst.

90 alities (loadings up to approximately 10(-5) mol %).

91 d of sphingomyelin/cholesterol/PEG (55/40/5; mol/mol) (CPD100 PEGLi).

92 esterol added at concentrations of 25 and 50 mol% led to suppression of the main phase transition.

93 with all kinases, especially ABL1 (-8.5kcal/mol).

94 pheric pressure were 548.6kJ/mol and 324.5kJ/mol respectively for the stable and the labile fractions

95 tivity were 8.45+/-0.93kJ/mol, 2.50+/-0.66kJ/mol, 22.50+/-7.26kJ/mol and 15.22+/-2.75kJ/mol, respecti

96 standard enthalpy change (DeltaH(o)F=-8.67kJ.mol(-1)), while microcalorimetry showed an entropic driv

97 values at atmospheric pressure were 548.6kJ/mol and 324.5kJ/mol respectively for the stable and the

98 The x((30)Si) = 5.701 x 10(-7) mol mol(-1) estimate is close to the expected one and is

99 J/mol, 22.50+/-7.26kJ/mol and 15.22+/-2.75kJ/mol, respectively.

100 Eighteen (10 F, 8 mol/L) participants completed a placebo-controlled, 2-pe

101 drolysis of T and C could be achieved with 8 mol L(-1) of acid.

102 At 51 wt %/83 mol % H2 O, this segregation becomes unfavorable, and th

103 energy respectively lower by 1.3 and 1.8kcal/mol compared to the most activated allyl position.

104 ative weak to strong intensities (2.6-50.8kJ/mol).

105 with a standard uncertainty of 8.8 x 10(-9) mol mol(-1).

106 and antioxidant activity were 8.45+/-0.93kJ/mol, 2.50+/-0.66kJ/mol, 22.50+/-7.26kJ/mol and 15.22+/-2

107 in(-1)), and quantum yields (Phi) (0.03-0.95 mol einstein(-1)).

108 n is small but negative (DeltaS() = -3.0 cal mol(-1) K(-1)), while there is almost a 2-fold differenc

109 ), and DeltaS(double dagger) = -37 +/- 3 cal mol(-1) K(-1), measured over the range 70-90 degrees C.

110 a factor of 2.3, and the energy efficiency (mol product/joule of incident photons) of the reaction b

111 netic behavior, with chiTIP = 6 x 10(-4) emu mol(-1), but its charge transport behavior, with sigmaRT

112 mass range of only a few thousand to 50000 g mol(-1) have been studied in detail via viscometry and s

113 erage molecular weights (Mn) 1770 to 10000 g/mol and semi crystalline with crystallinity below 1%) we

114 1.9), whereas in summer, smaller (225-330 g/mol) and more polar (logP approximately 0.55) molecules

115 ith a molar mass of approximately 1-2.10(5)g/mol, a hydrodynamic radius of approximately 6-10nm and a

116 e obtained for the largest molecules (>520 g/mol) with low polarity (logP approximately 1.9), whereas

117 rtitioning coefficient (logP) from 160-900 g/mol and 0.2-3.3, respectively.

118 for CO2 adsorption (Deltasads = -204 +/- 4 J/mol.K) positioning the step in the optimal range for car

119 C, DeltaH(double dagger) = 13.8 +/- 1.0 kcal mol(-1), and DeltaS(double dagger) = -37 +/- 3 cal mol(-

120 +/-0.39)x10(5) m(-1) (DeltaG=-6.9+/-0.1 kcal mol(-1) ).

121 of DeltaG(double dagger) = 27.1 +/- 0.1 kcal mol(-1) at 90 degrees C, DeltaH(double dagger) = 13.8 +/

122 tide chain of 120 residues is 5.8 +/- 1 kcal mol(-1).

123 n species can break the strong (105-111 kcal mol(-1) ) C-H bonds of pyridine substrates are unknown.

124 actions of cyclic 1-azadienes are 10-14 kcal mol(-1) higher than those of cyclic 2-azadienes, and the

125 potential with energy barriers of 0.185 kcal mol(-1) These results were confirmed with (2)H solid-sta

126 ne (with DeltaE for ring expansion=-6.2 kcal mol(-1) ).

127 equal) ) for beta-H elimination is 13.2 kcal mol(-1) .

128 within the membrane are approximately 2 kcal mol(-1).

129 nd the reaction free energies are 17-20 kcal mol(-1) more endergonic.

130 samarium aquo ion is estimated to be 26 kcal mol(-1), which is among the weakest known X-H bonds of s

131 bly hydrated trans tautomer by some 8.3 kcal mol(-1) .

132 his cost is predicted to remain above 3 kcal mol(-1) for denatured proteins as large as 900 residues.

133 s, DeltaH(double dagger) = 10.0 +/- 0.3 kcal mol(-1)).

134 free energy (BDFE) of approximately 32 kcal mol(-1).

135 ree oxidation states spans more than 37 kcal mol(-1).

136 alline nicotinic acid is only 7.7+/-0.5 kcal mol(-1) , suggesting that not all LBHBs are particularly

137 th a much lower rotation barrier of 6.5 kcal mol(-1) at 298 K in spite of the bulkier aryl groups.

138 anical calculations (4.6, 1.0, and 14.5 kcal mol(-1), respectively).

139 the rotation barriers are 11.3 and 9.5 kcal mol(-1), respectively, at 298 K.

140 an estimated activation barrier of 7.5 kcal mol(-1).

141 kcal mol(-1)) than 4b (DeltaH() = 0.54 kcal mol(-1)).

142 only needs to surmount a barrier of 1.6 kcal mol(-1) to rearrange into cyclopentyne (with DeltaE for

143 ion energy to rotation from 8.5 to 10.6 kcal mol(-1).

144 an activation energy Ea of 16.4 +/- 0.7 kcal mol(-1).

145 pite an experimental barrier of Ea =4.8 kcal mol(-1) and with only a shallow temperature dependence,

146 h (DeltaH(double dagger) = 17.9 +/- 0.8 kcal mol(-1)), which is 3 orders of magnitude longer than tha

147 (II)-OH2 complex was estimated to be 84 kcal mol(-1).

148 of the reactions vary over more than 90 kcal mol(-1) , but the rates are more dependent on the type o

149 aving a higher barrier (DeltaH() = 0.95 kcal mol(-1)) than 4b (DeltaH() = 0.54 kcal mol(-1)).

150 C-borirane was estimated to be about 95 kcal mol(-1).

151 nthalpy-driven (entropy changes below 2 kcal.mol(-1) at all stages of the reaction).

152 ), and for the second stage, it was 7.2 kcal.mol(-1), in excellent agreement with the experimental ba

153 ng free energy of the consensus-HD is 5 kcal.mol(-1) higher than that of the naturally occurring engr

154 th calculated barriers of 10.6 and 13.5 kcal.mol(-1), respectively.

155 a free-energy difference, DeltaG, of 6 kcal.mol(-1) between the two local conformations around a sin

156 ent with the experimental barrier (17.6 kcal.mol(-1)).

157 ion energy for the first stage was 18.7 kcal.mol(-1), and for the second stage, it was 7.2 kcal.mol(-

158 tative model in which approximately 1.0 kcal/mol of scrunching free energy is generated per transloca

159 ding of O2 to [Pd(IPr)2] (-14.5 +/- 1.0 kcal/mol) that is approximately one-half that of [Pd(IMes)2]

160 f FO is stabilized by 5.2, 7.2, and 9.0 kcal/mol, respectively, by 1.0 M phosphite dianion, d-glycero

161 n binding ability up to approximately 1 kcal/mol in acetone-d6 correlated with a theoretical increase

162 ands, yielded coupling energies of >/=1 kcal/mol, indicating a close, physical interaction between th

163 barriers, with a difference of only 0.1 kcal/mol.

164 lity of the analog (DeltaGU 5.0(+/-0.1) kcal/mol at 25 degrees C) was greater than that of WT insulin

165 er than that of WT insulin (3.3(+/-0.1) kcal/mol).

166 s only 4.4 kcal/mol, which is nearly 10 kcal/mol lower than that reported for the CH2OO case.

167 ith a singlet-triplet gap of +7 and +10 kcal/mol, respectively.

168 those of saturated cyclopropanes by >10 kcal/mol.

169 anilides can be varied by as much as 10 kcal/mol.

170 n two hydroxyl radicals, amounts to 100 kcal/mol.

171 e Naph(+*)(Pyr) heterodimer gives 10-11 kcal/mol increments in binding enthalpy.

172 y driven with -22 kcal/mol, which is 12 kcal/mol more stable than the antagonist-GPCR complex.

173 A remarkable 16 kcal/mol increase in the binding energy between Naph(+*)(Pyr)

174 iers at the cyclization-dehydration (17 kcal/mol) and oxidation (21 kcal/mol) steps agree well with t

175 quintet-triplet gap of approximately 18 kcal/mol compared to approximately 2-3 kcal/mol computed for

176 domain opening and the approximately 2 kcal/mol energy difference between the closed and open states

177 on to protein's energy balance, up to 2 kcal/mol.

178 dration (17 kcal/mol) and oxidation (21 kcal/mol) steps agree well with the values derived from the k

179 ion predict a free energy barrier of 22 kcal/mol for the concerted Diels-Alder process and provide no

180 n rhodopsin is enthalpy driven with -22 kcal/mol, which is 12 kcal/mol more stable than the antagonis

181 are consistently predicted to be ca. 25 kcal/mol, whereas barriers for 1,5- and 1,6-shifts range from

182 e (DeltaG of reaction approximately +28 kcal/mol at 200 degrees C, equilibrium constant K approximate

183 1,5- and 1,6-shifts range from 6 to 28 kcal/mol.

184 was determined experimentally to be 29 kcal/mol and is supported by quantum mechanical calculations.

185 l-arene bond strength in 5 by roughly 3 kcal/mol compared to that in 3, allowing the large-scale synt

186 kcal/mol compared to approximately 2-3 kcal/mol computed for A.

187 ation and eliminate the approximately 3 kcal/mol energy barrier to TM domain opening and the approxim

188 radical was found to be approximately 3 kcal/mol less stable than the allyl radical, which was attrib

189 " clusters, which are approximately 5.3 kcal/mol less stable than the global minimum nonpolar cyclic

190 constant, which corresponds to only 0.3 kcal/mol stabilization compared to the noncovalent, tightly b

191 experimentally determined value of 34.3 kcal/mol.

192 is that they are unstable (DeltaG > 30 kcal/mol), precluding their formation under mild conditions.

193 ed kinetic parameters shows that the 31 kcal/mol stabilization of the transition state for decarboxyl

194 affinity difference ( approximately 36 kcal/mol), favoring proton transfer to formate, is offset by

195 rom 65 (Fe-C identical withNH) to </=37 kcal/mol (Fe-N horizontal lineNH), are determined.

196 ,3]-NO shift, calculated to be only 8.4 kcal/mol above 21.

197 indicated strain energies at least 5.4 kcal/mol higher than those of the six-membered monocyclic pho

198 The 4 kcal/mol is comparable with calculations of stabilization eff

199 l I*U pair or central Psi*A pair is 2.4 kcal/mol less stable or 1.7 kcal/mol more stable, respectivel

200 Helix stabilities are relatively low, 4 kcal/mol to 5 kcal/mol, consistent with flexibility and facil

201 r the cyclization of SiH2OO is only 4.4 kcal/mol, which is nearly 10 kcal/mol lower than that reporte

202 -functional calculations estimate 35-43 kcal/mol binding energy, akin to typical M-M single-bond ener

203 ble singlet-triplet gaps of -47 and -45 kcal/mol to the lowest-energy triplet state, respectively.

204 ct and shorter (i.e., approximately 0.5 kcal/mol at 0.26 nm).

205 ehydrates the ion pore, creating a 13.5 kcal/mol barrier to ion translocation.

206 indicate that 3-Pheq conformer lies 0.5 kcal/mol higher than the 3-Phaxo conformer.

207 eoisomers due to tiny differences (<0.5 kcal/mol) both in the energy of (Z)/(E)-isomeric ester enolat

208 half that of [Pd(IMes)2] (-27.9 +/- 1.5 kcal/mol).

209 ies are relatively low, 4 kcal/mol to 5 kcal/mol, consistent with flexibility and facile reversible u

210 ith a doublet-quartet splitting of 35.5 kcal/mol.

211 ng a free energy difference of only 0.5 kcal/mol.

212 ifference, DeltaH degrees = 3.0 +/- 0.6 kcal/mol (130 +/- 30 meV).

213 PDC represents the sum of 11.8 and 10.6 kcal/mol stabilization by the substrate phosphodianion and th

214 ribosyl ring, respectively, and an 8.6 kcal/mol stabilization from the orotate ring.

215 iodopindolol, which corresponds to a 6-kcal/mol higher dissociation free energy barrier.

216 th ligand efficiencies from 0.442-0.637 kcal/mol/heavy atom.

217 pair is 2.4 kcal/mol less stable or 1.7 kcal/mol more stable, respectively, than the corresponding du

218 he kinetics measurements (20.7 and 22.7 kcal/mol, respectively).

219 t accuracy (mean unsigned error of 1.76 kcal/mol and Pearson correlation of 0.48); however, the repar

220 Results indicate a loss of 1.78 kcal/mol, on average, when an internal P*U replaces A-U in an

221 t of the Naph(+*)(Naph) homodimer (17.8 kcal/mol).

222 experiment (mean unsigned error of 0.81 kcal/mol and Pearson correlation of 0.75).

223 BLYP/cc-pVDZ computed barriers of 74-82 kcal/mol, consistent with pyrolysis temperatures of 900 to 11

224 of the Naph(+*)(Pyr) heterodimer (20.9 kcal/mol) exceeds that of the Naph(+*)(Naph) homodimer (17.8

225 two hexafluoropropene molecules of 36.9 kcal/mol, which is in good agreement with the experimentally

226 region 298 to 397 with a DeltaG = -7.9 kcal/mol.

227 he following activation parameters: Ea (kcal/mol) 3: 12.1, 2: 9.2; 5: 11.5, 6: 7.1.

228 ent and high molecular weight (up to 92.5 kg mol(-1) ).

229 ve DeltaCPdouble dagger) was -1.2 +/- 0.1 kJ mol(-1) K(-1) .

230 ts, with Ng binding energies of 80 to 100 kJ mol(-1) , contain B-Ng bonds with a substantial degree o

231 py showed an enthalpy of activation of 19 kJ mol(-1) and a approximately 2.5-fold kinetic isotope eff

232 cceptors) changes by only approximately 2 kJ mol(-1) across the AnO2(2+) series, indicating that the

233 ctive enthalpy of vaporization of 117-237 kJ mol(-1).

234 observed at pH 2.5: DeltaDeltaGF >/=11.3 kJ mol(-1) .

235 energy of CO2 to benzyl thiolate of -66.3 kJ mol(-1), consistent with the experimental observation of

236 The heat of adsorption was below 32 kJ mol(-1) and the temperature of onset of intense thermal

237 difference in adsorption enthalpy of 2.5 kJ mol(-1) between D2 and H2 results in D2-over-H2 selectiv

238 mented DraE (DraE-sc) by approximately 50 kJ mol(-1) in an exclusively thermodynamic manner, i.e. by

239 lues for stearic acid show a spread of 68 kJ mol(-1).

240 1) and an activation energy (Ea ) of 18.8 kJ mol(-1) .

241 ansition-state recognition by up to -14.8 kJ mol(-1).

242 +/- 2.5 kJ/mol, ACO2 IRE-RNA 35.0 +/- 2.0 kJ/mol.

243 alpy of adsorption (Deltahads = -73 +/- 1 kJ/mol), with a larger than expected entropic penalty for C

244 stabilizes the domain by approximately 10 kJ/mol, promoting its unfolding.

245 istent with a high activation energy, 106 kJ/mol) that increases Mn(II) affinity.

246 tivation energies of the process span 135 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for nea

247 ss span 135 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for neat and recycled PE, respectivel

248 was suggested by DeltaDeltaGo values >4.2 kJ/mol obtained from double mutant cycle analysis.

249 ies of the process span 135 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for neat and recycled

250 /mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for neat and recycled PE, respectively, and the so-

251 formic acid (TOF = 1718 h(-1) and Ea = 31 kJ/mol) and one-pot reactions of formic acid, 2-nitrophenol

252 The activation energy (35 kJ/mol) for dimerization is almost identical to this enthal

253 ed pi-complex at Bronsted acid sites, -36 kJ/mol.

254 94 K and activation energy Ea = 64 +/- 37 kJ/mol.

255 a DeltaG(double dagger) of 45, 39, and 39 kJ/mol, respectively.

256 hat of MEA-PCC (60-72 kJ/mol versus 33-46 kJ/mol, respectively).

257 vation energies: FRT IRE-RNA 47.0 +/- 2.5 kJ/mol, ACO2 IRE-RNA 35.0 +/- 2.0 kJ/mol.

258 IrO2(110), and equal to a value of 28.5 kJ/mol.

259 gy difference to the TSA-like form is 8.5 kJ/mol.

260 spectrometry indicated that a loss of 4-5 kJ/mol/protomer in the N3 domain that is peripheral to the

261 ate enthalpic barrier of approximately 62 kJ/mol, to give H2 and an antiferromagnetically coupled [LN

262 lefin binding enthalpies, below 55 and 70 kJ/mol for ethylene and propylene, respectively, indicate t

263 is less than twice that of MEA-PCC (60-72 kJ/mol versus 33-46 kJ/mol, respectively).

264 nificantly higher (DeltaG() = 102.6-103.8 kJ/mol).

265 bond cleavage is 9.5 kilojoule per mole (kJ/mol) lower than the binding energy of the adsorbed precu

266 ciency, with a kcat /Km value of 6.1x10(6) L mol(-1) s(-1) .

267 trum of 1 (lambda = 610 nm, epsilon = 1375 L.mol(-1).cm(-1); lambda = 613 nm (calcd)).

268 5.5 +/- 1 nm, epsilon approximately 200000 L.mol(-1).cm(-1)).

269 siderably slower, with k = 9.29(4) x 10(3) L.mol(-1).s(-1).

270 and microcalorimetric, and 10(3) and 10(4)L.mol(-1) by surface plasmon resonance (steady-state equil

271 anging from 3.26+/-0.09 to 8.08+/-0.0610(4)L.mol(-1), at the warfarin binding site of BSA.

272 binding constant was of the order of 10(5)L.mol(-1) by fluorescence and microcalorimetric, and 10(3)

273 c between >/=7.7% and </=11.0% [>/=61.0 mmol/mol and </=97.0 mmol/mol]) and had been prescribed insul

274 BP precursors decreased from 6.8 to 3.0 mmol/mol-C at initial-exponential phase then increased to 4.2

275 </=11.0% [>/=61.0 mmol/mol and </=97.0 mmol/mol]) and had been prescribed insulin for at least 12 mo

276 CGM plus CSII group and 0.1% (0.4; 1.1 mmol/mol [4.4]) in the CGM plus MDI group (p=0.32).

277 -0.57% to -0.29%] or -4.7 [-6.3 to -3.1 mmol/mol]; P < .001).

278 exponential phase then increased to 4.2 mmol/mol-C at death phase.

279 eline to 28 weeks was 0.3% (SD 0.9; 3.3 mmol/mol [SD 9.8]) in the CGM plus CSII group and 0.1% (0.4;

280 c was 8.53% (70 mmol/mol; SD 0.67% [7.3 mmol/mol]).

281 ed hemoglobin decreased from 6.1 to 5.4 mmol/mol and 41.8% to 37.7%, respectively.

282 with prediabetes (HbA1c 5.7-6.4% [39-46 mmol/mol] or FPG 5.6-6.9 mmol/L) at baseline.

283 moglobin (HbA1c) of less than 6.5% (<48 mmol/mol) after at least 2 months off all antidiabetic medica

284 records, or baseline HbA1c of 6.5% (48 mmol/mol) or greater or fasting plasma glucose (FPG) of 7.0 m

285 an (SD) HbA1c level of 6.66 (0.73)% [49 mmol/mol].

286 globin A1c (HbA1c) of at least 7.5% (58 mmol/mol) treated with multiple daily insulin injections.

287 mia in adults with HbA1c below 7.5% (58 mmol/mol).

288 Mean HbA1c was 7.92% (63 mmol/mol) during continuous glucose monitoring use and 8.35%

289 us glucose monitoring use and 8.35% (68 mmol/mol) during conventional treatment (mean difference, -0.

290 were women, and mean HbA1c was 8.6% (70 mmol/mol).

291 Mean baseline HbA1c was 8.53% (70 mmol/mol; SD 0.67% [7.3 mmol/mol]).

292 etes who had HbA1c lower than 8.8% (<73 mmol/mol).

293 etes who had HbA1c lower than 9.7% (<83 mmol/mol) or in women with type 1 diabetes who had HbA1c lowe

294 thesis increased by 10%-50% with a 150 mumol mol(-1) increase in atmospheric CO2 across seasons.

295 d the mole fraction range of (378-420) mumol mol(-1) and were prepared and/or value assigned either b

296 ondrial P/O ratios (mol of ATP generated per mol of [O] consumed) are 2.73 for oxidation of pyruvate

297 median [interquartile range] 13 [7 to 25] pg/mol vs. 18 [9 to 36] pg/mol; p < 0.001; n = 340).

298 nge] 13 [7 to 25] pg/mol vs. 18 [9 to 36] pg/mol; p < 0.001; n = 340).

299 The effect of parameters such as pH, mol ratio of DES composition, volume of DES, volume of t

300 Mitochondrial P/O ratios (mol of ATP generated per mol of [O] consumed) are 2.73 f