ライフサイエンスコーパス: monodentate

1 ron, reducing the chelates from bidentate to monodentate.

2 racting with the scissile DNA phosphate as a monodentate.

3 minal oxygen of the carboxylate, which stays monodentate.

4 TPA SAMs, in which 40% of the adsorbates are monodentate.

5 rate to gold ratios, while a monocarboxylate monodentate (1kappaO(1)) mode is favoured at high citrat

6 These V-shaped complexes contain either monodentate 4,4'-bipyridyl-derived ligands or related ch

7 aman features show that the Fe-O bond of the monodentate 4-hydroxybenzoate (4HB) inhibitor complex is

8 Monodentate acetate and aqua ligands lend the flexible e

9 At Zn concentrations>5 muM, tetrahedral monodentate adsorbates (Zn-O 1.98 A) dominated, transiti

10 2)2], where Am is a chelating diamine or two monodentate am(m)ine ligands and R(COO)2 is a chelating

11 nt of three classes of sterically demanding, monodentate amide ligands - the m-terphenyl anilides [N(

12 he search for extremely sterically demanding monodentate amide ligands to access main group complexes

13 magnitude higher than that with a comparable monodentate amine.

14 effect on the rate is also observed with the monodentate analogues: the rate of hydrogenation with th

15 es and that the energetic difference between monodentate and bidentate binding of a gold(I) ion are s

16 sible dimer-based transition structures with monodentate and bidentate coordination of TMEDA.

17 lus an Asp residue carboxylate shift between monodentate and bidentate coordination to the active sit

18 standard enthalpies of formation of adsorbed monodentate and bidentate formate on Pt(111) to be -354

19 resaturated (O-sat) Pt(111) to make adsorbed monodentate and bidentate formates using single-crystal

20 (99)Tc(V)O2-NHC complexes containing monodentate and bidentate N-heterocyclic carbenes (NHCs)

21 situ from iron chloride and a wide range of monodentate and bidentate phosphines and arsines have be

22 ace complexation model included inner-sphere monodentate and bidentate surface complexes and a ternar

23 Results suggest the formation of monodentate and bidentate surface complexes.

24 u-O2CCH3)2(eta1-O2CCH3)]+, which retains one monodentate and two bridging acetate groups, presumably

25 a(2) bound motifs or phosphonate ligand as a monodentate, as well as on tetrahedral Si sites as an ed

26 in retaining its [4Fe-4S](2+/+) cluster with monodentate aspartate ligation to one iron.

27 n of aryl halides and sulfonates utilizing a monodentate biaryl phosphine-Pd catalyst.

28 yses and NMR methods, and both chelating and monodentate binding modes characterised.

29 interaction with physiologic ligands is the monodentate binding of a ligand carboxylate to a Mg(2+)

30 6 octahedra being bridged by AsO4 bound in a monodentate binuclear (2)C complex (chain model).

31 ntate mononuclear (RAs-Fe = 2.88-2.94 A) and monodentate binuclear (RAs-Fe = 3.35-3.41 A) complexes w

32 In contrast, monodentate binuclear species of (-O)2-COHx=[0,1], are e

33 oth arsenate and arsenite exclusively formed monodentate-binuclear ("bridging") complexes (R(As-Fe) =

34 The most discussed ligands are bent, bis-monodentate bridges having their two donor sites pointin

35 results in a dramatically less tightly bound monodentate Ca(2+) coordination by aspartate.

36 carbon atom bound only to separate (that is, monodentate) carbon ligands.

37 Our results indicate that monodentate carboxylate oxygens of both conserved Asp re

38 (1)O2 and 2 undergoes ligand exchange of the monodentate CH3CN ligands with solvent when irradiated.

39 It was determined that monodentate complexes are dominant at low surface covera

40 Difference spectra revealed that monodentate complexes are particularly susceptible to io

41 complexes disproportionately suppressed over monodentate complexes at higher Al contents.

42 tor of 1.36 by the formation of inner-sphere monodentate complexes between sulfate and the aluminum s

43 s mostly bidentate corner-sharing, with some monodentate complexes.

44 Monodentate compounds featured the same trends as the co

45 es and the O binds to a surface Ti atom in a monodentate configuration, whereas the other OH group fo

46 tate-coordinated species, in contrast to the monodentate coordination in solid uranyl arsenate minera

47 in the side-chain band are mostly due to the monodentate coordination of aspartate to the cation.

48 The initial step involves monodentate coordination of the nitrocefin carboxylate g

49 ch converts bidentate Ca(2+) coordination to monodentate coordination.

50 ted in complexes much more stable than their monodentate counterparts.

51 has been developed that allows a variety of monodentate cyclic and acyclic ketones to successfully p

52 ands in (Asp49-Asp157)2 were replaced by the monodentate cysteine S-ligands.

53 On anatase terraces, monodentate ('D1') and bidentate ('D2') conformations ar

54 mation of a Cu-Cl species, which facilitates monodentate diketonate formation and lowers the barrier

55 identate intramolecular quadruplex form to a monodentate duplex structure, via addition of external O

56 ), and simulations of the binding of O2 in a monodentate end-on manner revealed that the bridging car

57 o determine the energetics of formation of a monodentate end-on-bound O2 to one iron in the binuclear

58 monomer in THF but as a disolvated dimer in monodentate, ethereal, non-THF solvents, whereas (E)-1 w

59 The nitrate counterions bind in a monodentate fashion in the equatorial plane to complete

60 reveals that PBC can bind to one lysine in a monodentate fashion or bind to two lysines via a bidenta

61 s that the axial Gln ligand coordinates in a monodentate fashion via its side-chain amide oxygen atom

62 isomer is less active and binds halides in a monodentate fashion.

63 plex, but on the water-FeS(111) interface, a monodentate Fe-O-Fe complex was found.

64 Eight P-chiral monodentate ferrocenyl phosphines (1a-h) were prepared i

65 ssociative adsorption of formic acid to make monodentate formate (HCOOmon,ad) plus the water-hydroxyl

66 N(epsilon), the thiazoline nitrogen, and the monodentate Glu-4 carboxylate to form a labile complex i

67 ial histidine ligands and axial cysteine and monodentate glutamate ligands.

68 al histidyl ligands and axial cysteinate and monodentate glutamate ligands.

69 arious phosphine ligands (both bidentate and monodentate) have been isolated, fully characterized, an

70 on geometry and a minor conformer (30%) with monodentate hydroxamate-Zn(2+) coordination geometry, re

71 osinase, formed through the self-assembly of monodentate imidazole ligands, Cu(I) and O(2) at -125 de

72 Synthetic monodentate imidazole-bonded Cu(II) 2 O2 species self-as

73 e and inexpensive CuCl, a readily accessible monodentate imidazolinium salt, and commercially availab

74 Toward this end, nearly 20 new chiral monodentate imidazolinium salts, most of which are non-C

75 An outer-sphere complex and a monodentate inner-sphere complex with the neutral MCPA m

76 etrahedral Zn bound to phosphate groups in a monodentate inner-sphere surface complex for all conditi

77 hat monothioarsenate binds to Fe oxides as a monodentate, inner-sphere complex.

78 N1 atom coordinates in a hitherto unreported monodentate interaction with the active site Fe(2+) ion,

79 that the catalytic DDE motif makes correct, monodentate interactions with the two active-site magnes

80 he tris(2-mercaptoethyl)amine (NS3)) and the monodentate isocyanide ligand (CN-peptide).

81 robust than Cr(0) complexes with carbonyl or monodentate isocyanides, manifesting in comparatively sl

82 e monomeric and dimeric Pd(II) species, with monodentate (kappa(1)), bidentate (kappa(2)), and bridgi

83 cies, irrespective of the starting isomer or monodentate ligand (such as hydride or Cl), reacts with

84 at forms via self-assembly from a simple bis-monodentate ligand and Pd(II) cations.

85 The predominant species 5 is a monodentate ligand complex analogue of the chelate 3a.

86 tion between the ruthenium(II) complex and a monodentate ligand linked covalently to the nanoparticle

87 s SnCl2 or Ti(O(i)Pr)4 in combination with a monodentate ligand such CYTOP 292 or P(p-anisyl)3 to enh

88 Homogentisate binds as a monodentate ligand to Fe(2+), and its interaction with T

89 yclic(alkyl)(amino)carbene] bearing a single monodentate ligand was prepared by addition of NaBH4 or

90 I)-terpyridine-phenylpyridine-X (X = anionic monodentate ligand) complexes were synthesized by select

91 In this work, azide (an exogenous monodentate ligand) was used to probe the role of copper

92 g a combination of Pd(2)dba(3).CHCl(3) and a monodentate ligand, tert-butyl X-Phos.

93 inal carboxylate of Ile839, which binds as a monodentate ligand.

94 he complexes of the porphyrin oligomers with monodentate ligands (pyridine or 4-benzyl pyridine) prin

95 ich two sites at each Cd(II) are occupied by monodentate ligands (solvent or counterions), was also c

96 The weak monodentate ligands (water) are replaced by a copper-sul

97 occurs in hemoproteins, is achieved so that monodentate ligands add preferentially to the axial bind

98 de data that suggest that the use of certain monodentate ligands can also prevent the formation of th

99 /mol) demonstrating that the presence of two monodentate ligands changes the mechanism from that of t

100 es, stereogenic-at-Mo complexes bearing only monodentate ligands have been designed.

101 2IrXL complexes (L = NH3 and CO; X = various monodentate ligands) to parametrize the relative sigma-

102 ligand types, being relatively large for the monodentate ligands, 1.32 eV for Cl and 0.78 eV for SPh

103 Through alteration of O-based monodentate ligands, catalysts have been identified that

104 tricationic complexes bound only by neutral monodentate ligands, which are a new class of gold reage

105 and trans isomers of a system employing two monodentate ligands.

106 nd the cations, affording both bidentate and monodentate ligands.

107 ve a stereogenic metal centre and carry only monodentate ligands; the molybdenum-based complexes are

108 The monodentated ligands arranged as SAMs on the MC surface

109 ygens of Gly52 and Asn262 from one chain and monodentate ligation by one of the epsilon-oxygens of Gl

110 e absence of l-Arg resulted in predominantly monodentate metal coordination, distinct from the typica

111 meric materials via incorporation of dynamic monodentate metal-ligand crosslinks.

112 inal portion of the metal-binding loops with monodentate Mg(2+) ligation by the conserved Glu at posi

113 Two of these ligands display a monodentate mode of coordination to the active site Zn(2

114 onicotinate is always adsorbed in a bridging monodentate mode, four different adsorption modes of cat

115 A small amount (<3%) of monodentate mononuclear inner-sphere surface complexes w

116 indications leaning toward a predominance of monodentate mononuclear species, -O-CO2Hx=[0,1].

117 efin metathesis catalysts containing chiral, monodentate N-heterocyclic carbenes and their applicatio

118 rmations are promoted by 5 mol % of a chiral monodentate NHC-Cu complex, derived from a readily avail

119 While complexes with monodentate NHCs only are hydrolytically unstable, compl

120 ion to a considerably lesser extent than the monodentate nitrogen donors do.

121 omocitrate ligand of the cofactor can become monodentate on reduction, allowing N(2) to bind at Mo.

122 that the denticity of the carbonate linkage, monodentate or bidendate, to the divalent cation is a us

123 ation with a palladium catalyst ligated by a monodentate phosphine allows the coupling of aryl and al

124 oth solvent classes hold for both a hindered monodentate phosphine and the labile bidentate ligand BI

125 Palladium(II) in combination with a monodentate phosphine ligand enables the unprecedented d

126 s, and when combined with the use of a bulky monodentate phosphine ligand, interrupts the catalytic c

127 However, when monodentate phosphine ligands are used, a vacant coordin

128 Many experiments have shown that nickel with monodentate phosphine ligands favors the C(aryl)-O activ

129 )X(2)(+) has a chiral C(2) geometry, whereas monodentate phosphine ligands lead to a C(1) structure.

130 potential can be increased by introducing a monodentate phosphine to the Re(I)(NN)(CO)(3)(+) framewo

131 paper describes a high-yielding and general monodentate phosphine-ligated palladium catalyst for bia

132 e presence of palladium catalysts with bulky monodentate phosphines (SPhos and Cy-CarPhos) and aryl b

133 n stark contrast, often-used ligands such as monodentate phosphines and N-heterocyclic carbenes are t

134 Addition of various monodentate phosphines to 1 results in the formation of

135 ing the instability of ketene complexes with monodentate phosphines.

136 e, we show that a perfectly ordered layer of monodentate phosphonic acid molecules is chemically graf

137 The monodentate phosphoramidite ligand exhibits superb react

138 Monodentate phosphoramidite ligands have been developed

139 s are promoted by a readily available chiral monodentate phosphoramidite-copper complex in the presen

140 NMR study shows that M, a 1:1 mixture of the monodentates, PMePh 2 and methyl monophosphonite L 1a (b

141 igand, k(2) = 12,000 M(-1) s(-1), versus the monodentate pyrazinyl ligand, k(2) = 1500 M(-1) s(-1)) t

142 e self-assembly of dibenzosuberone-based bis-monodentate pyridyl ligands L(1) with Pd(II) cations lea

143 Moreover, PCA binds as a monodentate rather than a bidentate ligand, and Tyr447 f

144 greater stereoselectivity than do those with monodentate side chains.

145 iated with two groups of sites, one from the monodentate sites and another one from the bidentate and

146 nt during struvite precipitation, octahedral monodentate sorbates detected at 1 muM (Zn-O 2.08-2.10 A

147 erate C-H activation of otherwise unreactive monodentate substrates is crucial for outcompeting the b

148 Platinum(IV) complexes containing monodentate sulfonamide ligands, fac-(dppbz)PtMe(3)(NHSO

149 version of physically adsorbed arsenate into monodentate surface complexes had Gibbs free energies of

150 The conversion of monodentate surface complexes to bidentate, binuclear co

151 In the presence of a chiral monodentate taddol-derived phosphoramidite ligand, these

152 were achieved through the design of a novel monodentate TADDOL-like phosphonite ligand.

153 ric unit, sulfate is coordinated to Mn2 in a monodentate, terminal fashion, and the two Mn(II) ions a

154 bstitution of one bidentate carboxylate by a monodentate terphenyl forms a M-C sigma bond and creates

155 ctivity, as do catalysts formed in situ with monodentate trialkyl and triaryl phosphite ligands.

156 tivation than complexes of the corresponding monodentate triarylphosphines.

157 Mechanistic investigations reveal a monodentate, two-electron oxidative fragmentation proces

158 h NHC-based complexes from the corresponding monodentate variants.

159 nding of the substrate to the iron, but both monodentate (via the phosphonate) and chelated (via the

160 Substitution of bidentate with monodentate X-type ligands led to a severe attenuation o

161 These structures reveal that an unusual monodentate Zn(2+) coordination mode is exploited by ste