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1 hydrolysis of the resulting phosphoramidate monoester.
2 a lower DeltaG(++) for the phosphorothioate monoester.
3 pids to yield diacylglycerol and a phosphate monoester.
4 but not tryptamine adenosine phosphoramidate monoester.
5 synthesis of aromatic and aliphatic sulfate monoesters.
6 ting sulfate for the biosynthesis of sulfate monoesters.
7 high-yielding synthesis of protected sulfate monoesters.
8 talyzed hydrolysis of phosphate diesters and monoesters.
9 and wax synthase led to the synthesis of wax monoesters.
10 to values previously reported for phosphate monoesters.
11 ate for AP-catalyzed hydrolysis of phosphate monoesters.
12 corresponding diols and hydrolyzes phosphate monoesters.
13 s along with some acyclic chloro-substituted monoesters.
14 of the preferential hydrolysis of phosphate monoesters.
15 proximately 10(2)-fold slower than phosphate monoesters.
16 for the nonenzymatic hydrolysis of phosphate monoesters.
17 inorganic phosphate and decreased phosphate monoesters.
18 lyze the hydrolysis of various organosulfate monoesters.
19 x 10(26)-fold for the hydrolysis of sulfate monoesters.
20 ovided first the originally assigned sulfate monoester 1 and then the reassigned and renamed phosphat
21 Selected deblocked derivatives, i.e., two monoesters (13 and 14), four phosphonic acids (15-18), a
23 nd then the reassigned and renamed phosphate monoester 2, relied on diagnostic (1)H NMR spectroscopic
25 triester 1-CO(2)()Et > diester 2-CO(2)()Et > monoester 3-CO(2)()Et) and may lead to substitution reac
26 ed antiviral activity of AZT phosphoramidate monoesters 3a and 4a in PBMCs and CEM cells, the mechani
30 cruzi, and Leishmania donovani in vitro.Only monoesters 7-9 with a log P value of >2.7 were active in
31 transformation of 8:2 fluorotelomer stearate monoester (8:2 FTS) in aerobic soils was conducted by mo
32 n number), and the fraction of hydrocarbons, monoesters, acids and alcohols have been determined in 9
35 l antagonist, and certain 12-deoxyphorbol 13-monoesters also function as partial antagonists but with
37 zymatic transition states for aryl phosphate monoester and aryl methylphosphonate hydrolysis reaction
38 ext, we addressed the preferential phosphate monoester and diester catalysis of PafA and NPP, respect
41 l catalytic proficiency for the most similar monoester and diester substrates in the two enzymes.
42 ect ((15)k) in the nitro group, and (for the monoester and diester) the secondary oxygen-18 isotope e
43 negatively charged N3'-->P5' phosphoramidate monoester and positively charged phosphoramidate diester
44 owing EH showed significant decreases in the monoester and pyrophosphate regions, with a correspondin
45 he second ester bond from the 8-5-benzofuran monoester and therefore, ferulic acid esterase A does no
47 te contain high amounts of organic P such as monoesters and diesters, compared to the other two sites
50 lates into the corresponding carboxylic acid monoesters and mixed esters (including tert-butyl esters
53 bait substrates, new hydrolases for sulfate monoesters and phosphotriesters were identified, mostly
54 l reassignment as a phosphate versus sulfate monoester, and the assignment of its relative and absolu
55 , two cis-astaxanthin isomers, 5 astaxanthin monoesters, and 10 astaxanthin diesters (7+/-1mg astaxan
58 nd their corresponding alcohols and glycerol monoesters are attractive candidates for the components
59 he hydrolytic rates of phosphate and sulfate monoesters are compared directly, and the misleading imp
60 lar metabolism of nucleoside phosphoramidate monoesters are distinct from that of phosphoramidate die
61 , or triester-like, because phosphorothioate monoesters are hydrolyzed by AP approximately 10(2)-fold
63 dging bond orders to phosphorus in phosphate monoesters are not significantly altered by differences
66 oth enzymes, despite the fact that phosphate monoesters are the cognate substrates for AP but promisc
67 ferulic acid esterase A was able to release monoesters as products of reactions with all three forms
69 PTPases catalyze the hydrolysis of phosphate monoesters by a two-step mechanism that proceeds through
73 of 1b that is similar to that of a phosphate monoester complex with the same leaving group, rather th
74 s were better inhibitors of T.b. brucei than monoester compounds, and some displayed high activity ag
75 activity of a series of AZT phosphoramidate monoesters containing amino acid methyl ester (3a-11a) a
76 use of H-phosphonate and H-phosphonothioate monoesters containing the base labile 9-fluorenemethyl p
77 for the reaction of p-nitrophenyl phosphate monoester coordinated to a dinuclear Co(III) complex.
78 fourfold increase in binding of phosphomanan monoester core complex (PPME), a natural mimic of an L-s
79 y different biological properties from their monoester counterparts, and they may be relevant to the
80 s a potent herbicide whereas its phosphonate monoester derivative, glyceryl glyphosate, is approximat
82 The nature of the hydrolysis of phosphate monoester dianions in solutions and in proteins is a pro
84 e energy relationships (LFERs) for phosphate monoester dianions with different leaving groups showed
87 PMDA in CH2Cl2/Et3N led to the formation of monoesters (e.g., 18) or diesters (11, 12), as needed, r
88 Addition of alpha,gamma-diesters and alpha-monoesters enhanced chemical stability and provided exce
89 and for the first time palmitate and oleate monoesters esterified with 1-octadecanol and 1-eicosanol
90 Glycerol monolaurate (GML), a fatty acid monoester found naturally in humans, has been reported t
92 ne derivatives which include combinations of monoesters, free acids, and amines, some of which are in
93 n cultured cells led to the formation of wax monoesters from straight chain saturated, unsaturated, a
96 ew member of this superfamily, a phosphonate monoester hydrolase/phosphodiesterase from Rhizobium leg
97 of this superfamily, namely the phosphonate monoester hydrolases from Burkholderia caryophylli and R
98 transition state for AP-catalyzed phosphate monoester hydrolysis and support previous models suggest
100 er catalytic proficiency by AP for phosphate monoester hydrolysis relative to sulfate monoester hydro
101 studies suggest that AP catalyzes phosphate monoester hydrolysis through a loose transition state, s
102 the PTPases appear to bring about phosphate monoester hydrolysis through a similar mechanism, there
103 inear free energy relationship for phosphate monoester hydrolysis to explore the effect of modulating
104 - and solvent-assisted pathways of phosphate monoester hydrolysis, and show that the solvent-assisted
105 AP is evolutionarily optimized for phosphate monoester hydrolysis, it is possible that the active sit
106 imental and theoretical studies on phosphate monoester hydrolysis, significant questions remain conce
112 beta-lactamases are inhibited by phosphonate monoesters in a reaction that involves phosphonylation o
114 rgy surfaces for the hydrolysis of phosphate monoesters in solution, establishing quantitatively that
115 ion of pyrophosphate to form a metaphosphate monoester intermediate or formation of a circular phosph
121 ch D-beta-hydroxybutyrate-(R)-1,3 butanediol monoester [ketone ester (KE)] replaced equicaloric amoun
122 (CALF-25), which contains a new phosphonate monoester ligand, was synthesized through a hydrothermal
123 ions, CYP4B1 covalently binds heme through a monoester link furnished, in part, by a conserved I-heli
124 We introduce a strategy to capture phospho-monoester lipids and improve the detection of long-chain
125 nambiguous structural identification of four monoesters (lutein 3'-O-linoleate, lutein 3-O-linoleate,
126 general, this work suggests that phosphonate monoesters may provide a novel molecular tool for determ
127 the presence of large amounts of circulating monoester metabolites, which pose significant developmen
128 iastereomerically pure phenylphosphonic acid monoester monoamide led to the formation of P-stereogeni
131 0-fold more inhibitory than similar monoacid-monoester, monoester-monoamide, or diester derivatives.
132 le in six steps from 2-bromovanillin and the monoester of methyl 6-hydroxycyclohexene-1-carboxylate.
133 nephosphonic acids replace the two phosphate monoesters of 1, 3-BPG and lead to several stable, tight
136 cle glycogen contained covalent phosphate as monoesters of C2, C3, and C6 carbons of glucose residues
137 f intramolecular condensation of a series of monoesters of dicarboxylic acids have been shown to be h
139 often pictured as polyoxyethylated sorbitan monoesters of saturated and/or unsaturated fatty acids.
140 lectivity for hydrolysis of either phosphate monoesters or diesters, we have measured a promiscuous s
143 s were also measured for the reaction of the monoester p-nitrophenyl phosphate by Ce(IV) bis-Tris pro
145 tivation for the hydrolysis reactions of the monoesters, p-nitrophenyl phosphate and p-nitrophenyl ph
146 atidylinositol 4-phosphate, which contains a monoester phosphate attached to its myo-inositol headgro
147 VII and protein C bind preferentially to the monoester phosphate of PA because of its accessibility a
148 tor VII and protein C bind preferentially to monoester phosphates, which may have implications for th
149 cleavage have previously been reported to be monoester phospholipids, which would result from substra
151 first step for the hydrolysis of a phosphate monoester (pNPP(2-)) in enzymes of the alkaline phosphat
152 in the transition state of reactions of the monoester pNPPT is more advanced than for its phosphate
154 ved for mezerein, for the 12-deoxyphorbol 13-monoesters prostratin or 12-deoxyphorbol 13-phenylacetat
155 ability of GpdQ to hydrolyze the phosphonate monoesters provides an alternative selection strategy in
159 t/Km)S conditions, the methylene phosphonate monoester substrate dCCCUCUT(mp)TA4 (where mp indicates
160 of DiFMU approximately 4.7) in the phosphate monoester substrate makes the assay highly sensitive.
161 h the nonbridging oxygen(s) of the phosphate monoester substrate provides a substantial amount of the
163 The enzymatic hydrolysis of a series of aryl monoester substrates yields a Bronsted beta(lg) of -0.32
164 69) and similar to the beta(lg) measured for monoester substrates, indicative of similar transition s
171 ation of the alkylphosphonic acids and their monoesters, the influence of pH on these separation syst
172 enzyme catalyzes the hydrolysis of phosphate monoesters through a loose, dissociative transition stat
173 mixture of myristoleic acid and its glycerol monoester to construct vesicles that were Mg(2+)-toleran
174 rees C for hydrolysis of a series of sulfate monoesters to a pK(a)(LG) value of 16.1, typical of an a
176 oducts and a higher proportion of carotenoid monoesters to diesters compared to ripe fruits were obse
181 etween these two, the less complex palmitate monoester was chosen to demonstrate that dog plasma nalm
182 metal complex of the p-nitrophenyl phosphate monoester was found to hydrolyze by a single-step concer
183 e and a series of substituted aryl phosphate monoesters, we demonstrate that the preferred mechanism
184 ffects of desolvation of dianionic phosphate monoesters were carried out, and the possible effect of
185 ofin, palmitate, oleate and hydroxypalmitate monoesters were detected, and for the first time palmita
186 cholesterol, C31 diene/triene, and three wax monoesters were detected, representing some of the large
188 rms of diesters, only the 5-5- and the 8-O-4-monoesters were substrates for the enzyme, forming the c
189 P itself, preferentially hydrolyze phosphate monoesters, whereas others, such as nucleotide pyrophosp
191 or the hydrolysis of a series of phosphonate monoesters which are the hydrolysis products of the high
192 is was mimicked by incubating cells with GSH monoester, which increased intracellular GSH similarly t
194 ide derivatives 7 of their (R)-mandelic acid monoesters, which provided access to the individual dias
195 ze a variety of chemically diverse phosphate monoesters while making contacts solely to the transferr
196 ur substitution accelerates the rates of the monoesters while slowing the rates of diesters and of tr
198 s the synthesis of a series of oligofructose monoesters with fatty acids of different chain length (C
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