ライフサイエンスコーパス: nitroxide

1 ium salts and trace amounts of corresponding nitroxide.

2 he modified Taft steric constant E(s) of the nitroxide.

3 uires a paramagnetic spin catalyst such as a nitroxide.

4 ent for the neutral and charged forms of the nitroxide.

5 n reacted with an iodomethyl derivative of a nitroxide.

6 adical to the oxoammonium ion to re-form the nitroxide.

7 a peroxyl radical to eventually re-form the nitroxide.

8 n alkyl bromide and a hydroxy-functionalized nitroxide.

9 radical that is spin-trapped in situ by the nitroxide.

10 ed reversible redox behavior for all studied nitroxides.

11 toolset for the predictive design of pyridyl nitroxides.

12 ompared to corresponding 2,2,5,5-tetramethyl nitroxides.

13 es were much more reactive than the backbone nitroxides.

14 ning of both the 15N-labeled and 14N-labeled nitroxides.

15 res efficient site-specific incorporation of nitroxides.

16 eased in the manner usually observed for bis-nitroxides.

17 ino nitroxide as the ratio [AS](0)/[nitronyl nitroxide](0) is increased.

18 hydrophilic tetracarboxylate ester pyrroline nitroxides 1 and 2, which serve as models in the search

19 Reduction of nitronyl nitroxide 3 in system NaNO2-AcOH yielded corresponding i

20 tetrafluoroborate (5), and its corresponding nitroxide (4) are reported.

21 of the probe methyl resonances to the stable nitroxide, 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxy

22 These nitroxides, like nitroxide 5, exhibited narrow linewidths-consistent with

23 Nitroxide 8 (4-carboxymethylidene-2,2,6,6-tetramethyl-1-

24 r a variety of structural diversity, such as nitroxide 9,that can, for instance, target tissue compar

25 hyperfine coupling constant of the released nitroxide a(N,SG1), meaning that the stabilization of th

26 raction between the 15N-labeled incarcerated nitroxide and a 14N-labeled free nitroxide in the extern

27 s verified with spectroscopically orthogonal nitroxide and Gd(III)-based labels.

28 (*) radical is connected to the PDI with the nitroxide and imide nitrogen atoms either para (1) or me

29 amine and is eventually converted into imino nitroxide and imino hydroxylamine.

30 X-ray diffraction analysis of both nitronyl nitroxide and iminonitroxide revealed a complete match o

31 and shifts the equilibrium in the mixture of nitroxide and reference hydroxylamine (3-carboxy-1-hydro

32 larity of both the incarcerated paramagnetic nitroxide and the nitroxides in the external bulk aqueou

33 e obtained for the reaction of imidozalidine nitroxide and the phenethyl radical.

34 imply that bulky substituents can stabilize nitroxide and/or destabilize hydroxylamine.

35 In the spectra of all ten compounds (nitroxides and corresponding oxoammonium salts), the car

36 ing to the formation of the respective imino nitroxides and hydroxylamines via a complex mechanism.

37 charged guest@host complex (incarcerated 15N nitroxide) and charged molecules in the aqueous phase.

38 f FA, we examined the potential of tempol, a nitroxide antioxidant and a superoxide dismutase mimetic

39 However, for membrane proteins, the nitroxide appears to have more interactions with the pro

40 Nitroxide diradicals, in which nitroxides are annelated to m-phenylene forming tricycli

41 Two nitroxides are attached to phosphorothioates that are ch

42 The nitroxides are designed to have the methyl groups furthe

43 denoting that the oxidant properties of the nitroxides are determined by steric and electronic effec

44 lamine increases at the expense of the imino nitroxide as the ratio [AS](0)/[nitronyl nitroxide](0) i

45 rm- d 1 were investigated in the presence of nitroxides as paramagnetic catalysts.

46 probe, occurring approximately about the NO nitroxide axis.

47 behavior in a thermally unswitchable copper-nitroxide based molecular magnet Cu(hfac)2L(i-Pr) paves

48 We report a rare case of a copper-nitroxide based molecular magnet Cu(hfac)2L(i-Pr) that d

49 A new nitroxide-based biradical having a long electron spin-la

50 view of this finding, we synthesized two new nitroxides bearing an exocyclic double bond: 4-methoxyca

51 e, and paracetamol were impregnated with bis-nitroxide biradical (bis-cyclohexyl-TEMPO-bisketal, bCTb

52 A series of seven functionalized nitroxide biradicals (the bTbK biradical and six derivat

53 diradicals may be associated with the methyl nitroxide C-H- - -O contacts, including nonclassical hyd

54 to form (*)NO(2) and the corresponding imino nitroxide, C-PTI.

55 the corresponding imino nitroxide, nitronyl nitroxide can discriminate NO from HNO only when present

56 ance (EPR) of biomolecules spin-labeled with nitroxides can offer uniquely sensitive and selective in

57 Rotation of gem-dimethyls in commonly used nitroxides causes spin echo dephasing times (Tm) to be t

58 ablished cardioprotectant, dexrazoxane, or a nitroxide conjugated to a triphenylphosphonium cation, M

59 imidazol-3-oxide- 1-oxyl (3), a new nitronyl nitroxide containing a multifunctional framework of stro

60 The nitroxide-containing nucleoside Cm is reported as the fi

61 Nitroxide-containing organic radical polymers (ORPs) hav

62 curacy of pKa determination for pH-sensitive nitroxides could be achieved regardless of the frequency

63 the nitroxide-m-phenylene-CH(2)-m-phenylene-nitroxide coupling pathway, and through-space coupling i

64 lso explore alternative mechanisms for amine/nitroxide cycling for cases where the alkoxyamines do no

65 hat might, potentially, be involved in amine/nitroxide cycling, as well as several novel pathways pro

66 aspect of these studies is that both Cu(2+)/nitroxide DEER at cryogenic temperatures and T1 relaxati

67 Both of these profluorescent nitroxides demonstrated low cytotoxicity toward Chinese

68 Moreover, the new nitroxides demonstrated much higher stability toward red

69 nd evaluation of a series of furanyl-salicyl-nitroxide derivatives as effective chemical probes for s

70 cals has first been confirmed by using a new nitroxide-derived profluorescent radical trap.

71 the octamethyl derivative of benzobisoxazine nitroxide diradical, the conformationally constrained ni

72 Magnetic behavior of the nitroxide diradicals at low temperature is best fit to t

73 Nitroxide diradicals, in which nitroxides are annelated

74 ching were achieved for pyrazolines with the nitroxide directly fused to the chromophore.

75 Inter-nitroxide distances are measured using a four-pulse doub

76 esonance data yield Cu(2+)-Cu(2+) and Cu(2+)-nitroxide distances that are uniquely consistent with on

77 for the R1 relaxation rate, suggesting that nitroxide dynamics remain coupled to the backbone on mem

78 ine variants of N-PGK were labelled with the nitroxide electron spin-label MTSL [(1-oxyl-2,2,5,5-tetr

79 Here we describe the introduction of nitroxide EPR probes into calmodulin by means of site-di

80 id) (ABTS(+)) radical, as well as the stable nitroxide free radical 4-hydroxy-2,2,6,6-tetramethylpipe

81 ne-1,4,7,10-tetraacetic acid) containing two nitroxide free radical units was synthesized.

82 domimetics with two pendant, chiral nitronyl nitroxide free radical units.

83 The direct (13)C NMR and EPR spectra of the nitroxide free radicals and the oxoammonium salts, along

84 A range of varying chromophore nitroxide free radicals and their nonradical methoxyamin

85 t as 63 nanoseconds, in a frozen solution of nitroxide free-radicals at temperatures as high as 190 k

86 allowing the preparation of a library of the nitroxide functionalized pyrazolines and corresponding m

87 ajor contributions to the x-component of the nitroxide g-matrix: hydrogen-bond formation and local el

88 up bulky spirocyclic moieties adjacent to a nitroxide group and provides an important supplementatio

89 The nitroxide groups substantially shortened the T1 of the b

90 13C relaxivity in C60 induced by nitroxide has also been measured.

91 yclic C(2)-symmetric chiral pyrrolidine-type nitroxide has been successfully synthesized starting fro

92 sion were observed, with the presence of the nitroxide having no significant impact on the cycloaddit

93 d attitude of the scalar interaction for the nitroxide hydrogen bonding at the methyl group in CH3CN

94 ed in an endofullerene based on a reversible nitroxide/hydroxylamine system.

95 ncarcerated nitroxide and a 14N-labeled free nitroxide in the external aqueous solution was observed

96 spiro dinitroxide biradicals that orient the nitroxides in a rigid, approximately orthogonal geometry

97 surements of local hydration dynamics around nitroxides in bulk water and on the surface of proteins

98 ed the oxidation potential of the respective nitroxides in comparison to electron-donating groups.

99 The positions of nitroxides in other helices at the cytoplasmic surface r

100 incarcerated paramagnetic nitroxide and the nitroxides in the external bulk aqueous phase.

101 escence is partially quenched by surrounding nitroxides in the native state; exposure to ascorbate or

102 he distribution of distances between the two nitroxides in the peptides when in solution and when bou

103 redox status." The preferential reduction of nitroxides in tumors compared with normal tissue was obs

104 Two nitroxides incorporating anthracene and fluorescein chro

105 y that for both systems triplet quenching by nitroxide induces spin polarization of the radical spin

106 It is concluded that nitronyl nitroxide is readily reduced by HNO to nitronyl hydroxyl

107 hered to streptavidin or the mobility of the nitroxides is altered.

108 paramagnetic resonance imaging (EPRI) using nitroxides is an emergent imaging method for studying in

109 -PTIO), which yields the corresponding imino nitroxides, is widely used for NO detection (mainly by e

110 e inner loop (residues 401-413), and the EPR nitroxide label revealed ligand-induced conformational d

111 , GroEL may come into close proximity to the nitroxide label.

112 EPR spectroscopy of nitroxide-labeled BASPs was used to probe differences be

113 Nitroxide-labeled paired-Cys replacements were construct

114 On the cytoplasmic side, each of six nitroxide-labeled pairs exhibits decreased interspin dis

115 ported here presents a new method for facile nitroxide labeling at the 5' terminus of nucleic acids o

116 Moreover, the nitroxide-labelled GDP binds inside the channel and seem

117 In addition, the EPR spectra from nitroxide labels attached to the extracellular loops in

118 ane that is characterized by the presence of nitroxide labels both at the wheel and at the dumbbell.

119 Reduction of the nitroxide labels by a polymeric reductant revealed locat

120 CC6803 (Cph1) by measuring distances between nitroxide labels introduced into the protein.

121 evealed location-dependent reactivity of the nitroxide labels: peripheral nitroxides were much more r

122 trates that HNO readily reacts with nitronyl nitroxides, leading to the formation of the respective i

123 Metal complexes of a tripodal nitroxide ligand [{(2-(t) BuNO)C6 H4 CH2 }3 N](3-) (TriN

124 These nitroxides, like nitroxide 5, exhibited narrow linewidth

125 to find a globally minimized arrangement of nitroxide locations that simultaneously satisfied the cr

126 jacent nitroxide radicals is mediated by the nitroxide-m-phenylene-CH(2)-m-phenylene-nitroxide coupli

127 n electrostatic potential through changes in nitroxide magnetic parameters and the degree of rotation

128 ate that this fully isotopically substituted nitroxide markedly improves signal-to-noise ratio and, t

129 n relaxation parameters demonstrate that new nitroxides may be suitable for PELDOR distance measureme

130 formation of alkoxyamines on the fate of the nitroxide-mediated polymerization (NMP) of styrene.

131 through temporal regulation of initiation in nitroxide-mediated polymerization reactions.

132 A nitroxide-mediated polymerization strategy allows one-st

133 iphenylphosphino)styrene was synthesized via nitroxide-mediated polymerization.

134 or use in, for example, organic synthesis or nitroxide-mediated polymerization.

135 Species 6b induces the controlled nitroxide-mediated radical polymerization (NMP) of styre

136 a of the resulting K1 mutants reflect higher nitroxide mobilities than the spectra of analogous mutan

137 diradical, the conformationally constrained nitroxide moieties are coplanar with the m-phenylene, le

138 exchange interaction between the trityl and nitroxide moieties determines the magnetic field at whic

139 e are sterically shielded, distortion of the nitroxide moieties from coplanarity is moderate, such th

140 Reduction of paramagnetic nitroxide moieties to a diamagnetic species resulted in

141 201) leading to a rigid complex with remote nitroxide moieties.

142 ing that increasing the distance between the nitroxide moiety and methyl groups is effective in lengt

143 ants for collisional quenching of Trp by the nitroxide moiety are approximately 1 / 5 x 10(12) M(-1)

144 In site-directed spin labeling (SDSL), a nitroxide moiety containing a stable, unpaired electron

145 Tethering the nitroxide moiety directly to the lipid polar headgroup d

146 es (ROS) was measured using a profluorescent nitroxide molecular probe 9-(1,1,3,3-tetramethylisoindol

147 ork has established that stable paramagnetic nitroxide molecules are excellent probes of intermolecul

148 X-band EPR spectroscopy was used to monitor nitroxide motions in the 0.1-50 ns regime.

149 itroxide yields only the corresponding imino nitroxide, nitronyl nitroxide can discriminate NO from H

150 on an adamantane core bearing six equivalent nitroxide-nitroxide distances is also reported.

151 The synthesis of four nitronyl nitroxide (NN) biradicals is described which are conjuga

152 ly blue-colored Ullman imidazolinyl nitronyl nitroxide (NN) mono-radicals have found various applicat

153 In a nitroxide (NO)-labeled sample, distance distributions ob

154 The nitroxides of 7-azadispiro[5.1.5.2]pentadecane and 7-aza

155 ascorbate than spirocyclohexane-substituted nitroxides of piperidine series and showed 1.3-3.14 time

156 ly manipulate the oxidizing power of surface nitroxide/oxoammonium redox couple, hence showing the pr

157 he gramicidin segment was used to target the nitroxide payload to mitochondria because antibiotics of

158 310-helical conformation with both nitronyl nitroxide pendants positioned on the same side of the he

159 ,SG1), meaning that the stabilization of the nitroxide played an important role in C-ON bond homolysi

160 th microwaves in the presence of typical bis-nitroxide polarizing agents is utilized for steady-state

161 gh power battery electrodes by hybridizing a nitroxide-polymer redox supercapacitor (PTMA) with a Li-

162 atives were synthesized, each containing the nitroxide probe 2,2,6,6-tetramethyl-piperidine-1-oxyl-4-

163 -RE, measured using a nucleotide-independent nitroxide probe and double-electron-electron-resonance s

164 irected spin labeling, a covalently attached nitroxide probe containing a chemically inert unpaired e

165 nanometer distances in nucleic acids using a nitroxide probe that can be attached to any nucleotide w

166 es SDSL distance measurements in RNA using a nitroxide probe, designated as R5, which is attached in

167 These profluorescent nitroxide probes are potentially powerful tools for imag

168 ctural and dynamic features using a class of nitroxide probes that are linked to chemically substitut

169 Sensitivity of the nitroxide probes to H(2)O(2)-induced damage was also dem

170 tor demonstrated good cellular uptake of the nitroxide probes.

171 ved alkyl radical with a diarylamine-derived nitroxide-proceeds by different mechanisms depending on

172 The nitroxides proved to be hundreds of times more effective

173 hed to the cytoplasmic domain of CLS and the nitroxide quencher attached to the lipid bilayer, we sho

174 nthesized two series of compounds in which a nitroxide radical and a fullerene C(60) moiety were kept

175 ements larger than 10 were obtained with bis-nitroxide radical at 14.1 T and low temperature ( approx

176 e examine a family of polythiophenes bearing nitroxide radical groups, showing that while both specie

177 ected spin labeling (SDSL) utilizes a stable nitroxide radical to obtain structural and dynamic infor

178 A stable nitroxide radical, 1-oxyl-4-bromo-2,2,5,5-tetramethylpyr

179 ad portion of XJB-5-131 consists of a stable nitroxide radical, which has been extensively investigat

180 These nitroxide radical-based nanostructures have longitudinal

181 arization of solvent molecules that approach nitroxide radical-based spin labels within <5-10 A.

182 l state and hence the electroactivity of the nitroxide radical.

183 ds to its corresponding catalytically active nitroxide-radical.

184 We attach nitroxide radicals (i.e., spin labels) to multiple phosp

185 The ORCA is based on spirocyclohexyl nitroxide radicals and poly(ethylene glycol) chains conj

186 Nitroxide radicals are introduced into the reverse micel

187 Nitroxide radicals are paramagnetic contrast agents, use

188 space coupling is found between the diagonal nitroxide radicals at the conformationally constrained N

189 recent reports that the coupling factor for nitroxide radicals cannot be quantified due to the diffi

190 TEMPO oxoammonium salts and three homologous nitroxide radicals have been prepared and characterized.

191 Through-bond coupling between the adjacent nitroxide radicals is mediated by the nitroxide-m-phenyl

192 cleotide-independent labeling scheme, stable nitroxide radicals were attached to eight specific pRNA

193 pening metathesis polymerization (ROMP), and nitroxide radicals were incorporated at three different

194 Nitroxide radicals were introduced at selected positions

195 e-coupled clusters of copper(II) with stable nitroxide radicals.

196 ganic solvents in the presence of paramagnet nitroxide radicals.

197 es cysteine residues and sulfhydryl-reactive nitroxide reagents, can be challenging for proteins that

198 ascorbate or ascorbate/glutathione leads to nitroxide reduction and a concomitant 2- to 3.5-fold inc

199 Electrochemical analysis and chemical nitroxide reduction experiments show that the dipole mom

200 We find that most of the literature nitroxide regeneration cycles should be discarded on eit

201 The attached nitroxides reported duplex formation as well as tertiary

202 t the very beginning of the irradiation; the nitroxide resulting from the trapping of propargyl radic

203 tereomers (R(p) or S(p)) were separated, and nitroxide rotational motions were monitored using electr

204 tic resonance (EPR) spectra, which report on nitroxide rotational motions, were found to vary dependi

205 The synthesized chiral nitroxide showed a very high stability to reduction with

206 The new isotopically substituted nitroxide shows increased sensitivity to changes in O(2)

207 d with a hydroxylamine reagent to generate a nitroxide side chain (K1).

208 With a commonly used nitroxide side chain (R1) and Cu(2+), it has been found

209 A disulfide-linked nitroxide side chain (R1) is the most widely used spin l

210 investigate the structure of the tetramer, a nitroxide side chain (R1) was introduced at 18 different

211 Here, we introduce a highly constrained nitroxide side chain designated RX as an alternative to

212 electron paramagnetic resonance spectra of a nitroxide side chain placed at position 85 or 409 of the

213 directed spin labeling of Ser(155)Cys with a nitroxide side chain, we detected a change in conformati

214 distance data, and the known rotamers of the nitroxide side chain.

215 of helices rather than rearrangement of the nitroxide side chains are responsible for observed dista

216 tances and distance changes between pairs of nitroxide side chains introduced in helices at the cytop

217 al structure but EPR spectroscopy studies of nitroxide side chains placed at selected sites on annexi

218 In the present study, nitroxide side chains were introduced at sites within th

219 nce quantum yield between the profluorescent nitroxide species and their nonradical adducts provides

220 First, the fraction of hydrogen-bonded nitroxide species for each n-doxyl-PtdCho was calculated

221 ed to hydrogen-bonded and nonhydrogen-bonded nitroxide species.

222 er of which was modified with a paramagnetic nitroxide spin label (MTSL).

223 A nitroxide spin label (R5a) was covalently attached to a

224 eta42) to an alternative sequence in which a nitroxide spin label attached to cysteine has been intro

225 f spin-lattice relaxation rate (T1(-1)) of a nitroxide spin label by a paramagnetic metal.

226 lectron paramagnetic resonance spectrum of a nitroxide spin label can be obtained from the Fourier tr

227 xcited porphyrin triplet state (S = 1) and a nitroxide spin label chemically incorporated into a smal

228 a measurement of 140 amol of the most common nitroxide spin label in a approximately 593 fL liquid ce

229 detected by EPR as a change in mobility of a nitroxide spin label positioned near the maltose-binding

230 The paramagnetic nitroxide spin label was attached to Cys residues that w

231 ectroscopy shows that rotational motion of a nitroxide spin label, placed at the N-terminal end of th

232 An R5a nitroxide spin label, which was covalently attached at a

233 A pargyline based nitroxide spin labeled irreversible inhibitor (ParSL) wa

234 li, has been carried out using site directed nitroxide spin labeling (SDSL) of cysteine residues.

235 Nitroxide spin labels are used for double electron-elect

236 ling technology has enabled the insertion of nitroxide spin labels at positions on the surface of the

237 vative of nonaribonucleotide pUUCGUAAAA with nitroxide spin labels attached to the 5'-phosphate and t

238 magnetic resonance detection and imaging of nitroxide spin labels in an individual macromolecule to

239 ements are the instabilities of the standard nitroxide spin labels in the cell environment and the li

240 d by the short lifetime of the commonly used nitroxide spin labels in the reducing milieu inside a ce

241 osition and sample temperature indicate that nitroxide spin labels on the exterior surface of BtuB, w

242 ibrium distribution of distances between two nitroxide spin labels rigidly attached to the helices of

243 oscopy was used to measure distances between nitroxide spin labels strategically placed in dimeric An

244 placed, site-specifically attached pairs of nitroxide spin labels to monitor changes in the mini TAR

245 Nitroxide spin labels were incorporated into selected si

246 e-helical collagen V mimic (synthesized with nitroxide spin labels) in the active site of the catalyt

247 Nitroxide spin labels, introduced specifically at three

248 proximately 7 nm between introduced pairs of nitroxide spin labels, we show that distances are close

249 those observed previously in the presence of nitroxide spin labels, while this phenomenon is signific

250 ipolar coupling to paramagnetic probes, here nitroxide spin labels.

251 ule that could be individually modified with nitroxide spin labels.

252 electron spin resonance from a T (1) = 1 ms nitroxide spin probe in a thin film at 4.2 K and 0.6 T.

253 at 236.6 and 9.5 GHz probed the tumbling of nitroxide spin probes in the lower stem, in the upper lo

254 anorods (GNRs) on paramagnetic properties of nitroxide spin probes.

255 he spin-spin and spin-lattice relaxations of nitroxide spin probes.

256 om representation of the covalently attached Nitroxide spin-label and virtual "solvent" particles cor

257 A first thiol-specific pH-sensitive nitroxide spin-label of the imidazolidine series, methan

258 d spin labeling by resolving rotamers of the nitroxide spin-label side chain in a variety of alpha-he

259 s in the proximity of a strategically placed nitroxide spin-label up to 8 A away.

260 NMR titrations with three nitroxide spin-labeled analogues of collagenous peptide,

261 The unliganded form of nitroxide spin-labeled HIV-1 protease and three differen

262 Here we report the synthesis of a nitroxide spin-labeled lipid A, characterize its localiz

263 n two unpaired electron spins (site-directed nitroxide spin-labels) is measured.

264 The paramagnetic nitroxides (spin-adducts) formed as a result of reaction

265 nvestigate more carefully the effects of the nitroxide structure on the re-formation rate constant k(

266 The conjugated phenyl nitroxide substituted HBC with five alkyl chains exhibit

267 The unique reaction of NO with nitronyl nitroxides such as 2-(4-carboxyphenyl)-4,4,5,5-tetrameth

268 nt supplementation to traditional methods of nitroxide synthesis.

269 Good agreement was found between nitroxide T (1) 's measured mechanically and inductively

270 IMTSL-PTE) containing a reversibly ionizable nitroxide tag attached to the lipids' polar headgroup.

271 e been spin-labeled at both ends with stable nitroxide TEMPO radicals.

272 a paramagnetic catalyst (dissolved O2 or the nitroxide Tempo) a slow back conversion into oH2@C60 was

273 agents referred to as TEMTriPols, in which a nitroxide (TEMPO) and a trityl radical are chemically te

274 (-/-) mice a diet supplemented with a stable nitroxide, Tempol, and showed that the progression of ne

275 xchange-coupled biradicals, e.g., the trityl-nitroxides (TNs), possess particular magnetic properties

276 We reasoned that targeting a redox cycling nitroxide to mitochondria could prevent reactive oxygen

277 (*)NO(2) oxidizes the nitronyl and imino nitroxides to their respective oxoammonium cations, whic

278 enols and the carboxylic acid functionalized nitroxide TPC.

279 mmon families of persistent organic radicals-nitroxide, triphenylmethyl, verdazyl, phenalenyl, and di

280 The manganese-nitronyl-nitroxide two-dimensional coordination polymer {[Mn2(NIT

281 echanically blocked on a thread containing a nitroxide unit by a Cu(I) catalyzed azide-alkyne cycload

282 pling between the two mechanically connected nitroxide units and were analyzed by a model assuming th

283 avenue for the preparation of profluorescent nitroxides via nitrile imine-mediated tetrazole-ene cycl

284 bility of obtaining multifunctional nitronyl nitroxides via the interaction of paramagnetic lithium d

285 A 15N-labeled nitroxide was incarcerated into an octa acid nanocapsule

286 ckbone dynamics could be mapped with SDSL, a nitroxide was introduced at 55 independent sites in a mo

287 loping a framework for designing narrow-line nitroxides, we sought to understand the unexpectedly nar

288 5,5-tetraalkyl imidazoline and imidazolidine nitroxides were investigated.

289 activity of the nitroxide labels: peripheral nitroxides were much more reactive than the backbone nit

290 Importantly, the pyrazoline profluorescent nitroxides were shown to efficiently act as sensors for

291 -350) revealed greater immobilization of the nitroxide when compared to that of the N-terminally modi

292 m involving the acid-catalyzed reaction of a nitroxide with a peroxyl radical to yield an oxoammonium

293 c cycle involving the rapid combination of a nitroxide with an alkyl radical to yield an alkoxyamine

294 d by switching the position of fullerene and nitroxide with respect to the peptide nitrogen and carbo

295 d utilizing the reaction of a profluorescent nitroxide with the B-n-butylcatecholboronate ester forme

296 ed by electron interchange reactions between nitroxides with an N-acetyl substituent and oxoammonium

297 Nitroxides with narrow linewidths are essential for low-

298 (c) values of the cross-coupling reaction of nitroxides with tert-butoxylcarbonyl-2-prop-2-yl radical

299 Since the reaction of NO with nitronyl nitroxide yields only the corresponding imino nitroxide,

300 suring dipolar interactions between pairs of nitroxides yields internitroxide distances, from which q