ライフサイエンスコーパス: nonpolar solvent

1 (OA, polar surfactant) to 1-octadecene (OD, nonpolar solvent).

2 tergent, and resolubilizing the protein in a nonpolar solvent.

3 )(2)}(2) or 1.{3(PF(6))(2)}(2)) formation in nonpolar solvent.

4 cosities, and miscibilities with a polar and nonpolar solvent.

5 ich at low concentrations induce gelation in nonpolar solvent.

6 3 is not intermolecularly hydrogen bonded in nonpolar solvents.

7 n to rearrange via a syn beta-elimination in nonpolar solvents.

8 equally rapid, high-yield singlet fission in nonpolar solvents.

9 indeed have substantial lifetime in gas and nonpolar solvents.

10 sphonium and octylammonium chloride salts in nonpolar solvents.

11 oleoyl-sn-glycero-3-phosphocholine (DOPC) in nonpolar solvents.

12 hey have high fluorescence quantum yields in nonpolar solvents.

13 atively narrow fluorescence emission band in nonpolar solvents.

14 The longer rise component is absent in nonpolar solvents.

15 se after five cycles of heating in polar and nonpolar solvents.

16 ow ordering of superparamagnetic colloids in nonpolar solvents.

17 solvents, whereas C-C cleavage is favored in nonpolar solvents.

18 chanism is also implicated in both polar and nonpolar solvents.

19 reas the ortho isomer is oxidized fastest in nonpolar solvents.

20 but pyrene-like fluorescence is observed in nonpolar solvents.

21 t carbene ISC rates are generally fastest in nonpolar solvents.

22 to a hydrogen atom, and ISC is more rapid in nonpolar solvents.

23 ion of their conformations in both polar and nonpolar solvents.

24 in the presence of ligands in both polar and nonpolar solvents.

25 pair character, even in the gas phase or in nonpolar solvents.

26 functional even after prolonged exposure to nonpolar solvents (20 min).

27 kyllithium addition by cyclic chelation in a nonpolar solvent, (3) iodination of the naphthyridine at

28 onor and acceptor entities in both polar and nonpolar solvents, a feature that was not evident in don

29 ks(zero) of 1 A2 of the charged, polar, and nonpolar solvent-accessible protein surfaces.

30 have comparable thermodynamic stabilities in nonpolar solvents according to calculations at the DFT B

31 chiral anionic phase-transfer catalyst in a nonpolar solvent allows the enantioselective fluorinatio

32 t the assignment of a quinoidal structure in nonpolar solvents and a zwitterionic structure in high-p

33 d nonglass microchips, namely, resistance to nonpolar solvents and conservation of sample integrity.

34 d to adopt 12-helical secondary structure in nonpolar solvents and in the solid state.

35 This catalyst facilitates the use of common, nonpolar solvents and increased concentrations as compar

36 ificantly increases the solubility of C60 in nonpolar solvents and increases the reduction potentials

37 f the two C==O groups occurs at 1650 cm-1 in nonpolar solvents and shifts to 1638 cm-1 in H2O.

38 The nature of the polar/nonpolar solvents and their miscibility strongly influen

39 ible blocks lead to aggregation in polar and nonpolar solvents, and to complex surface morphologies d

40 is efficient at micromolar concentrations in nonpolar solvents, and under more competitive conditions

41 lectron transfer reactions of 1a(2+) even in nonpolar solvents, anion-pi interactions of 1a(2+) with

42 ponse to solution ion concentration, pH, and nonpolar solvents are consistent with this process being

43 ld by treatment with sulfuryl diimidazole in nonpolar solvents at elevated temperatures.

44 tramers or higher aggregates is favorable in nonpolar solvents, but in strongly coordinating solvents

45 magnetically tunable photonic properties in nonpolar solvents by establishing long-range electrostat

46 demonstrates that measurements conducted in nonpolar solvents can indeed provide insight into nanode

47 association between nucleic acid bases in a nonpolar solvent (CCl4) are described.

48 In the gas phase, and possibly in very nonpolar solvents, concerted addition-migration of H(2)O

49 H- groups is similar to that afforded by the nonpolar solvent cyclohexane (epsilon = 2).

50 nes could be directed toward 2 in the highly nonpolar solvent, cyclohexane, or toward 3 in the more p

51 kCR, was slower by 5 orders of magnitude in nonpolar solvents, cyclohexane and toluene, resulting in

52 order of these C22 stationary phases, while nonpolar solvents decrease conformational order.

53 and readily phase transfer between water and nonpolar solvents depending on the electronic and ionic

54 terminal Dbg in almost quantitative yield in nonpolar solvent (dichloroethane-DMF, 9:1).

55 In solid phase or in the nonpolar solvent (diethyl ether), only one of the three

56 a-elimination to a carbenoid intermediate in nonpolar solvents due to the unusual acidity of the alph

57 In nonpolar solvents (e.g., hexane/ethyl acetate or ethyl a

58 spectroscopy, we show that hexane, a common nonpolar solvent for quantum dots, has negligible influe

59 are capable of behaving as supergelators in nonpolar solvents, forming self-standing gels with very

60 of the protected 2-deoxysugar chloride in a nonpolar solvent give 2'-deoxynucleoside derivatives wit

61 states of appreciable lifetimes in polar and nonpolar solvents has been established from studies invo

62 nic liquids as aids for microwave heating of nonpolar solvents has been investigated.

63 that self-assemble into reverse micelles in nonpolar solvents have been used by us in the context of

64 In nonpolar solvents, however, the substrate racemization i

65 In a solvent mixture consisting of mostly a nonpolar solvent (i.e., CCl(4)) and a polar solvent (i.e

66 g radical polymerizations (LRP) performed in nonpolar solvents, including atom-transfer radical polym

67 he consequent dipole-dipole interaction in a nonpolar solvent is believed to be the driving force for

68 The PL in nonpolar solvents is significantly influenced by added s

69 Although ESIPT-type emission in nonpolar solvents is weak, the Stokes shifts are very hi

70 ongly depend on the solvent polarity: (1) in nonpolar solvents, it is symmetric and quadrupolar; (2)

71 forms a highly stable molecular duplex in a nonpolar solvent (Kdim > 1.9 x 10(7) M(-1) in CDCl3).

72 Folding was also favored by smaller/acyclic nonpolar solvent molecules, probably because they could

73 hin the nanocavity better than larger/cyclic nonpolar solvent molecules.

74 s, which can be performed in the presence of nonpolar solvents or in the neat alkene substrate.

75 nated self-assembled monolayers in different nonpolar solvents or in two-component liquid mixtures co

76 in the absence of ligands in CHCl3 and other nonpolar solvents, OsO4 is unreactive toward H2 over a w

77 ilized bacteriorhodopsin is extracted into a nonpolar solvent phase by adding a chloroform/methanol/w

78 , indicate that the reorganization energy of nonpolar solvents plays a minimal role in the energy lan

79 imal yield and selectivity; proper choice of nonpolar solvent provided improved yield through suppres

80 Nonpolar solvents resist the formation of new charges.

81 On the other hand, dipolar-aprotic and nonpolar solvents resulted in larger concentrations ( ap

82 thylhexyl) sulfosuccinate (AOT) dissolved in nonpolar solvents spontaneously form an organogel when p

83 In the case of nonpolar solvents, subsequent ipso-protiodeauration of t

84 that folded chain conformations can occur in nonpolar solvents such as benzene and extended chain con

85 ies in solvent mixtures consisting of mostly nonpolar solvents such as carbon tetrachloride or ethyl

86 seen with each labeled polymer in polar and nonpolar solvents such as heptane and DMF or heptane and

87 Relatively nonpolar solvents such as toluene and THF favored the br

88 omote these complex redistribution pathways, nonpolar solvents such as toluene enable increased stabi

89 When heated in nonpolar solvents such as toluene, the number of solvent

90 increase the barrier to rotation compared to nonpolar solvents such as toluene.

91 The use of the industrially attractive nonpolar solvents, such as 2-methyl-tetrahydrofuran, is

92 nglet excited-state energy in both polar and nonpolar solvents suggested the possibility of electron

93 crossing rate on going from polar aprotic to nonpolar solvents, suggesting that a solvent-dependent e

94 ore acidic and significantly more soluble in nonpolar solvents than their oxosquaramide counterparts,

95 injected supercritical CO(2) (sc-CO(2)) is a nonpolar solvent that can potentially mobilize organic c

96 In nonpolar solvents the reaction with free radicals procee

97 In nonpolar solvents the relatively weakly electron-withdra

98 Upon further dilution with the nonpolar solvent, the intense Cotton effects are recover

99 In nonpolar solvents, the abundance of these minor products

100 In nonpolar solvents, the fluorescence lifetime and quantum

101 In nonpolar solvents, the molecules utilize the hydrophilic

102 In more nonpolar solvents, the solid-state assembly switches to

103 eight amino acid functionalised molecules in nonpolar solvents through 48 hydrogen bonds.

104 ity of the resulting polygonal structures in nonpolar solvents, thus forming hydrogen bonds with the

105 alyst for living radical polymerization in a nonpolar solvent to produce a polymer-iodide and was sub

106 The molecule turns its polar faces inward in nonpolar solvents to bind polar molecules such as sugar

107 strategy based on mercury cation exchange in nonpolar solvents to prepare bright and compact alloyed

108 ts an exponential distance dependence in the nonpolar solvent toluene with an attenuation factor (bet

109 Fluorescence quantum yield of each dyad in nonpolar solvent (toluene) is comparable with that obser

110 ygen as the sole stoichiometric oxidant in a nonpolar solvent (toluene).

111 but dependent on the chemical nature of the nonpolar solvent used.

112 imilar to bulk films, however, in relatively nonpolar solvents (varepsilon< approximately 3) they dem

113 ation of 8 and 9, respectively, in polar and nonpolar solvents was elucidated by the anisotropic upfi

114 Moreover, when we switched to a nonpolar solvent we observed the opposite behavior: The

115 trochemical properties of these flavins in a nonpolar solvent were determined.

116 s well as polar-protic, dipolar-aprotic, and nonpolar solvents were investigated.

117 -specifically pair into H-bonded duplexes in nonpolar solvents were modified with S-trityl groups, al

118 tions of poly(alkyl acrylamide) oligomers in nonpolar solvents were studied using molecular dynamics

119 r methyl esters and leaves them monomeric in nonpolar solvents, where their esters are dimeric.

120 that HAT may be the predominant mechanism in nonpolar solvents, while HAT and SPLET are competitive p

121 The N-in form is generally favored in nonpolar solvents, while the N-out form is favored in po

122 ion; namely, R-I and N3(-) generated R(*) in nonpolar solvents, while the substitution product R-N3 w

123 ing its solubility in a variety of polar and nonpolar solvents without changing the anion structure a