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1 o-(Pyrrolidinylmethyl)phenylboronic acid (4) and its com
3 re length (1.9-2.2 mum) and external [Ca(2+)]o (1-2.5 mM), which produce an increase of TP, do not af
4 l/mg protein), and inhibited by guanosine-5'-o-(3-thiotriphosphate) (GTPgammaS) suggesting that these
5 pyranopyridines can be prepared by allowing o-(1-alkynyl)arenecarboxaldehydes and ketones to react w
6 Heck cyclization of butenalide 22 having an o-(N-acetyl-N-benzylamino)phenyl substituent at C2 provi
7 nactive, as were aromatic species lacking an o- or m-nitrogen atom in the ring, or possessing multipl
8 to the more tractable trifluoride analogue ((o-(Ph2P)C6H4)2SbF3)AuCl (3-Cl) by treatment with a fluor
10 including pyrazolyl-substituted anilines and o-, m-, and p-phenylenediamine as pi-conjugated spacers.
12 [((o-(Ph2P)C6H4)2SbCl)Au](+) ([1](+)) and [((o-(Ph2P)C6H4)2SbF3)Au](+) ([3](+)), which have been isol
13 -1H-indenes (from beta-alkyl-beta-alkyl/aryl-o-(alkynyl)styrenes) and 3-iodobenzofulvenes (from beta,
14 orescence, thiazole orange (TO)-PNA and [bis-o-(aminoethoxy)phenyl]pyrrolocytosine (BoPhpC)-PNA, we e
20 s increased without increasing average [Ca2+]o (by increasing sarcomere length), [NADH]m fell similar
21 H]m (since [NADH]m rapidly fell) or by [Ca2+]o (since work could also be increased at constant [Ca2+]
22 y were applied: cation concentrations ([Ca2+]o = 2 mM, [Mg2+]o = 1.7 mM, [K+]o = 3 mM) and recording
23 The present study found that elevated [Ca2+]o (2.5 mmol/L) enhanced proliferation of skeletal metast
25 al amplification, while an increase in [Ca2+]o (from 2 to 8 mM) generated this behaviour in neurones
27 A synthesis by increasing [Ca2+]i; low [Ca2+]o (0.3 mM) blocked this effect, while treatment with Ca2
28 r in Ringer's solution containing 1 mM [Ca2+]o + 50 microM verapamil (tg = 49.3 +/- 3.8 minutes).
30 (in millimoles per liter per second) at [Cl-]o = 75 mmol/L (newborns; 0.15 +/- 0.04; weanlings; 0.2 +
32 e corresponding trichlorostiborane complex ((o-(Ph2P)C6H4)2SbCl3)AuCl (2-Cl), which can be converted
33 he tetravalent platinum stiboranyl complex [(o-(Ph2P)C6H4)2(o-C6Cl4O2)Sb]PtCl2Ph (2) has been synthes
34 ford the dicationic chlorostibine complex [((o-(Ph2P)C6H4)2SbCl)PtCNCy](2+) ([3](2+)) as a bis-trifla
36 nthetic agonists Ace-Trp-Lys[NH(epsilon)CONH-o-(MePh)]-Asp-MePhe-NH(2) (GI5269) and the C1 N-isopropy
42 malous mole fraction effects observed for Cs+o + K+o mixtures, suggest that DR channels select for K+
47 d 3-iodobenzofulvenes (from beta,beta-diaryl-o-(alkynyl)styrenes) in good yields under mild reaction
48 hoxy-6-methyl-5,6,7,8-tetrahydro[1,3]-dioxol o-[4,5-g]isoquinolin-5-yl)isobenzo-furan-1(3H)-one (nosc
49 tom of the tridentate diphosphinobismuthine (o-(Ph(2)P)C(6)H(4))(2) BiCl behaves as a Z rather than L
50 III)Pt(I)Cl(o-dppp)(2)](+) ([1](+), o-dppp = o-(Ph(2)P)C(6)H(4)) by reaction of the new bis(phosphino
51 ed Cl2Sb(IV)Pt(III)Cl3(o-dppp)2 (2, o-dppp = o-(Ph2P)C6H4)), a complex featuring a highly oxidized [P
52 sized [Cl3Sb(V)Pd(II)Cl2(o-dppp)2] (o-dppp = o-(Ph2P)C6H4), a palladium dichloride complex featuring
53 ndoergic charge separation products (Delta E o = -0.6 V) remain after several minutes, which points t
54 sence of a tetraheme, low-redox-potential (E'o = -233 mV), cytochrome c-type cytochrome with a molecu
55 em representing one of these families, i.e., o- and p-xylene as aromatics, 1-octene as an alkene, and
56 lide or benzamide bonds were prepared (i.e., o-, m-, p-poly-1 and poly-2 series) and characterized bo
57 ime for the protein, phi p, of 4.7 ns; r(eff)o = 0.214 and phi p = 4.2 ns for the FKBP12/FK506 comple
58 .1 nmol/min/ mg of protein were obtained for o-, m-, and p-cresol oxidation by wild-type T4MO, which
59 the level of MMFF, theory predicts that for o- or m-oligophenylene ethynylenes, helix formation is e
61 effect on cross-linking in progressing from o- to p-PDM was on the alphagammagamma trimer, which is
63 ucleus (DRN), feedback activation by Galphai/o -coupled 5-HT1A autoreceptors reduces the excitability
67 d (in COS-7 cells) with several different Gi/o- or Gs-coupled receptors, and ligand-induced increases
68 by designer drugs) receptors, we enhanced Gi/o- or Gs-protein-mediated signaling selectively in direc
69 extracellular proton concentrations ([H(+) ]o ) on mouse TMEM16A expressed in HEK-293 cells using wh
71 d by distinct classes of receptor (G(alpha)i/o- and G(alpha)q-coupled), providing dynamic regulation
72 biologically and pharmaceutically important o-(dimethylamino)aryl ketones, acridones, acridinium sal
73 lethanol, alpha-ionone, 3-methyl-1-indanone, o-(chloromethyl)phenyl sulfoxide, o-(bromomethyl)phenyl
74 tion of (o-(Ph2P)C6H4)3SbNi(PPh3) (1) into [(o-(Ph2P)C6H4)3ClSb]NiCl (2) is accompanied by a conversi
77 -80 mV), via equilibration with 145 mm [K(+)]o (depolarization to approximately -5 mV), or during int
80 from neonatal rat hippocampus (20-22 C; [K+]o = 2.5 mM) revealed two previously recorded non-inactiv
84 bellum, cultured in physiological levels [K+]o (5 mM) for 14 days, loose the majority of granule cell
88 tions ([Ca2+]o = 2 mM, [Mg2+]o = 1.7 mM, [K+]o = 3 mM) and recording temperature (30-32 degrees C) we
94 mologs of the barley mildew resistance locus o (MLO) protein biochemically shown to have a seven-tran
95 ]o (from 2 to 1 mM) and an increase in [Mg2+]o (from 2 to 10 mM), or the addition of Ni2+ (2-3 mM), a
96 cation concentrations ([Ca2+]o = 2 mM, [Mg2+]o = 1.7 mM, [K+]o = 3 mM) and recording temperature (30-
97 This allows the generation of 3 x (m + n + o + p) different peptide topologies because the fourth c
99 hanediyl bismethanethiosulfonate (3 A), N,N'-o- phenylenedimaleimide (6 A) and N,N'-p-phenylenedimale
100 he catalyst under mildly basic conditions, N-o-(trifluoromethane)benzenesulfonyl aziridine was effici
101 ted by a 10-fold molar excess over PDM of N-(o- and p-tolyl)succinimide, which are chemically inert s
104 ry conductance was 31 pS at -67 mV with [Na+]o = 140 mM, [Cs+]o = 5 mM, [Na+]i = 88 mM, and [Cs+]i =
105 two approaches: first, introduce a nitrogen o- or p- to the 3-OH group in the phenyl ring; second, r
109 r than solvent, giving only trace amounts of o-/p-chloro adducts upon addition of chloride trap.
115 cycles, we derived heats of hydrogenation of o-, m-, and p-benzoquinone (Delta(hyd)H degrees (1o, 1m,
116 he CYP4B1-mediated benzylic hydroxylation of o- and p-xylenes were fully expressed (k(H)/k(D) = 9.7 a
117 Mannich reaction performed on Boc-imines of o-(azidomethyl)benzaldehydes, followed by a one-pot Stau
118 n established sequence of iodocyclization of o-(buta-1,3-diynyl)thioanisoles followed by Sonogashira
119 res is varied systematically using a pair of o-, m-, or p-xylylene (o-, m-, or p-Xy) covalent linkers
120 chieved by stereoselective quaternization of o-(pinacolato)boronatophenylphosphine with beta- or gamm
122 mild reaction conditions by the reaction of o-(1-alkynyl)benzoates and (Z)-2-alken-4-ynoates with IC
123 ed on the 5-endo iodocyclization reaction of o-(alkynyl)styrenes, represents one of the scarce exampl
125 ailed analysis for this reaction a series of o-(2'-imidazolyl)naphthyl (4-nitrophenyl) phosphate isom
128 data, it is shown that PhICl2 oxidation of (o-(Ph2P)C6H4)3SbNi(PPh3) (1) into [(o-(Ph2P)C6H4)3ClSb]N
129 Cl (2), which was obtained by treatment of ((o-(Ph2P)C6H4)2SbCl2)PtCl (1) with 2 equiv of AgOTf, is s
131 xyl isocyanide results in the formation of [(o-(Ph2P)C6H4)3(o-O2C6H4Sb)]Ni(CNCy) (4), a complex featu
133 of future chemosensing technologies based on o-(N,N-dialkylaminomethyl)arylboronate scaffolds that ar
135 hydroxy-4-(4'-phenoxy)-1butenyl)-7-oxabicycl o-[2.2.1]heptan-2-yl]-5-heptanoic acid, an agonist, with
136 day 1 = 59.0 6 27.0 vs. day 5 = 4.0 6 5.5, p o .05) as well as in comparison to the untreated control
138 substituents (isopropyl, cyclohexyl, phenyl, o- or p-nitrophenyl) in beta anomeric configuration exhi
140 of this precursor show rearranged protonated o-/p-aminophenols and solvent water adducts (catechol, h
142 lipid content = 40% (surface potential, psi o =-30 mV), conditions for which the protein has high ac
143 ) and KRT13 (PAML = 1.67 x 10 (-) (4); PSKAT-o = 1.07 x 10 (-) (5)), reaffirming variant-level analys
144 uded ACTBL2 (PAML = 3.23 x 10 (-) (5); PSKAT-o = 9.23 x 10 (-) (4)) and KRT13 (PAML = 1.67 x 10 (-) (
147 mplex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone and (S)- or (R)-
150 electron-donating amino groups onto a simple o-(phenylazo)aniline platform dramatically accelerates i
151 d the corresponding cationic gold species [((o-(Ph2P)C6H4)2SbCl)Au](+) ([1](+)) and [((o-(Ph2P)C6H4)2
153 ins bearing three heterocyclic substituents (o-, m-, p-pyridyl) or four alkyl groups (ethyl, propyl,
154 e Pd-catalyzed cross-coupling of substituted o-(pseudo)halobenzoates and hydrazines with isocyanide i
155 -indanone, o-(chloromethyl)phenyl sulfoxide, o-(bromomethyl)phenyl sulfoxide, and ethyl p-tolylsulfon
156 c, vanillic, caffeic, chlorogenic, syringic, o- and p-coumaric, ferulic, rosmarinic, and tr-cinnamic
158 cal mol(-)(1), respectively, indicating that o- and p-benzoquinone should be excellent radical traps.
161 A novel 1,4-palladium migration between the o- and o'-positions of biaryls has been observed in orga
164 arynes generated by the treatment of various o-(trimethylsilyl)aryl triflates with CsF results in [4
166 ddition of a variety of diazo compounds with o-(trimethylsilyl)aryl triflates in the presence of CsF
167 ) complex of the Schiff base of glycine with o-[N-alpha-picolylamino]acetophenone, as a nucleophilic
168 )-complex of the Schiff base of glycine with o-[N-alpha-pycolylamino]acetophenone and (S)- or (R)-3-(
169 couplings of o-, m-, and p-halophenols with o-, m-, and p-phenol boronic acids were investigated for
170 cally using a pair of o-, m-, or p-xylylene (o-, m-, or p-Xy) covalent linkers to produce o-ExBox(4+)
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