ライフサイエンスコーパス: o-xylene

1 in the C-H/C-H aerobic oxidative coupling of o-xylene.

2 wing exposure to a nonmetabolizable solvent, o-xylene.

3 reaction if the synthesis is carried out in o-xylene.

4 pe effects for the benzylic hydroxylation of o-xylene-alpha-(2)H(3), p-xylene-alpha-(2)H(3), 2-(2)H(3

5 to 86% yield of aromatic product, primarily o-xylene and secondarily ethylbenzene.

6 While toluene, o-xylene, and tetralin were not degraded in the B0 and B

7 y of the suitability of alpha,alpha'-dibromo-o-xylene as a reagent for cyclic o-xylylene protection o

8 the presence of CuI, PPh(3), and KO-t-Bu in o-xylene at 100 degrees C.

9 mpounds, benzene, toluene, ethylbenzene, and o-xylene (BTEX) and polar compounds, phenol, 4-chlorophe

10 ompounds benzene, toluene, ethylbenzene, and o-xylene (BTEX) are conveniently and rapidly preconcentr

11 (MTBE), benzene, toluene, ethylbenzene, and o-xylene (BTEX), and analysis of delta(13)C for chlorina

12 , toluene, ethylbenzene, p-xylene, m-xylene, o-xylene (BTEX), and total BTEX using measurement based

13 re, we investigate the oxidative coupling of o-xylene catalyzed by a PdX2/2-fluoropyridine catalyst (

14 diffraction structures were obtained for an o-xylene clathrate of 2 and for solvent-free crystals of

15 ion of mixtures containing benzene, toluene, o-xylene, cymene, tert-butylbenzene, carbon tetrachlorid

16 sole-d(8), fluorobenzene-d(5), toluene-d(8), o-xylene-d(10), m-xylene-d(10), p-xylene-d(10), or mesit

17 from the diphosphonium salt of alpha,alpha'-o-xylene dibromide, formaldehyde, and 5-tolyl-, 4-phenyl

18 Following o-xylene exposure, P. putida MW1200 exhibited a decrease

19 pendence from CoA and ATP) also apply to the o-xylene-fumarate addition reaction.

20 o-Xylene is not a growth substrate for strain T, and its

21 with respect to an alphabetagamma promoter), o-xylene (kcat approximately 0.8 s-1), m-xylene (kcat ap

22 parting) is benzene, fluorobenzene, toluene, o-xylene, m-xylene, or p-xylene and the incoming arene i

23 rmed to be a result of expression of toluene-o-xylene monooxygenase (ToMO) by P. stutzeri OX1, since

24 The four-component toluene/o-xylene monooxygenase (ToMO) from Pseudomonas stutzeri

25 Toluene/o-xylene monooxygenase (ToMO) is a non-heme diiron prote

26 e site, the hydroxylase component of toluene/o-xylene monooxygenase activates dioxygen for subsequent

27 of a Rieske protein, component C of toluene/o-xylene monooxygenase from Pseudomonas sp. OX1, with an

28 the reduced hydroxylase component of toluene/o-xylene monooxygenase from Pseudomonas sp. OX1.

29 mediate in the reaction of a reduced toluene/o-xylene monooxygenase hydroxylase (ToMOH(red)) T201S va

30 d T201 residue in the active site of toluene/o-xylene monooxygenase hydroxylase (ToMOH) revealed that

31 Toluene/o-xylene monooxygenase hydroxylase (ToMOH), a diiron-con

32 , which can hydroxylate methane, and toluene/o-xylene monooxygenase hydroxylase (ToMOH), which cannot

33 hat voids comprising the cavities in toluene/o-xylene monooxygenase hydroxylase are not artifacts of

34 Toluene/o-xylene monooxygenase hydroxylase is a dioxygen-activat

35 te formed in the reaction of reduced toluene/o-xylene monooxygenase hydroxylase with dioxygen.

36 Alpha-subunit position M180 of toluene-o-xylene monooxygenase influences the regiospecific oxid

37 ly occurring variants of the toluene/benzene/o-xylene monooxygenase subfamily.

38 mediate is the active oxidant in the toluene/o-xylene monooxygenase system and is a peroxodiiron(III)

39 toluene (T), p-xylene (p-X), m-xylene (m-X), o-xylene (o-X), styrene (S), o-cresol (o-C), phenol (PhA

40 phases demonstrated enhanced or comparable (o-xylene only) extraction efficiencies.

41 and slightly different regiospecificity for o-xylene oxidation.

42 hydrocarbon compounds consisting of toluene, o-xylene, p-xylene, and mesitylene.

43 unusually low frequencies of flavin ring I (o-xylene ring) relevant bands, which suggests a ring I m

44 e CPMAS (13)C NMR studies with a crystalline o-xylene solvate of biphenylene rotor 2 suggested a 2-fo

45 s of strain T also catalyzed the addition of o-xylene to fumarate to form (2-methylbenzyl)succinate.