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1 planar, and 5/6-coordinate, square pyramidal/octahedral).
2 imately linear to distorted square planar to octahedral.
4 structure but also the less common distorted octahedral 1T-WS2 structure, which exhibits metallic beh
5 ansformation from trigonal prismatic (2H) to octahedral (1T) upon lithium or sodium intercalation has
7 r 5d metal) as well as a correction for d(6) octahedral acids (Cd6 = 6 for d(6) metal ion in the acid
8 state NMR spectra, consistent with the mixed octahedral Al/Zn chemical environment in typical Zn-Al L
9 ace-raised cubic, edge- and corner-truncated octahedral, all-corner-truncated rhombic dodecahedral, {
10 namely, the orthoclase (001) surface and the octahedral aluminum sheet of the kaolinite (001) surface
11 (+) (H-PNP = HN(CH2CH2P(t)Bu2)2) to generate octahedral ammine complexes that are kappa(2)-chelated b
12 ons at concentrations</=5 muM sorbed as both octahedral and tetrahedral complexes (Zn-O 1.98-2.03 A),
15 h alternating layers of transition metals in octahedral and trigonal prismatic coordination and is a
16 d cuboctahedral nanocrystals of Pt(3)Ni, and octahedral and truncated octahedral nanocrystals of PtNi
17 environments for Nb (trigonal prismatic and octahedral) and smaller crystallite size, which were con
20 nic noble metal NCs with tetrahedral, cubic, octahedral, and icosahedral geometries have been chemica
21 engths and polyhedral symmetry--tetrahedral, octahedral, and icosahedral--are the 5 Platonic polyhedr
22 c, truncated cubic, cuboctahedral, truncated octahedral, and octahedral structures have been employed
24 nity Ca(2+) sites with trigonal bipyramidal, octahedral, and pentagonal bipyramidal coordination geom
26 his class, formed by the occupation of small octahedral B-sites within an AO3 network defined by larg
27 train can be applied to characterize complex octahedral behaviours in other advanced oxide systems.
29 um ions in FTase are presented, and relevant octahedral binding motifs for Mg2+ in wild-type (WT) FTa
31 ons, beta and gamma phases, characterized by octahedral bonding with vdW gaps and tetrahedral bonding
32 he actinide is successively located first at octahedral brucite-like sites in the GR precursor, then
33 sorption sites around, and within, the small octahedral cage in the structure are favored over the ex
35 ients along a (011)-like direction, the PbI6 octahedral cage will distort and the bandgap will become
39 w that introduction of chemically mismatched octahedral cations into a cubic perovskite oxide parent
40 he existence of 6-coordinate hydrogen in the octahedral cavity of [HCo6(CO)15]- in 1979, and 5-coordi
41 of carbon- and nitrogen-centered radicals to octahedral centrochiral rhodium enolates has been invest
43 " pyrochlore, in which corner-connected NbO6 octahedral chains move smoothly apart to accommodate the
46 (EXAFS) analysis of a binary mixture of the octahedral Co(III) precatalyst and [Ru(bpy)3](2+) after
47 ix different molecular clusters based on the octahedral Co6E8 (E = Se or Te) and the expanded cubane
49 is9, His15 and Asp17 coordinate cobalt in an octahedral complex that includes a phosphate anion, whic
50 and an aspartate coordinate manganese in an octahedral complex that includes two waters and a phosph
52 ons between the sixth ligand of these pseudo-octahedral complexes and the pendant N atom of the ring
53 The observation of liquid crystallinity in octahedral complexes of this type is without precedent.
55 ex Fe(II) to form a series of diastereomeric octahedral complexes that are CD-active in both the UV a
57 F3(-) that mimic ground-state phosphates; 2) octahedral complexes, primarily based on AlF4(-) , which
58 , of a metal ion binding mode with a coupled-octahedral configuration at the active site, exhibiting
59 l structural change from a tetrahedral to an octahedral configuration is responsible for the observed
60 e active site contains a single Mn(2+) in an octahedral coordination complex with Asp187, His189, Asp
61 o Ni(II) ions bind to the NmtR dimer to form octahedral coordination complexes with the following ste
63 we designed a buried metal binding site with octahedral coordination geometry consisting of Bpy-Ala,
64 erves as the sixth ligand that completes the octahedral coordination geometry of the B metal ion.
65 , Mg2 recruits a water molecule to retain an octahedral coordination geometry suggesting the strong b
66 tion metal dications having a preference for octahedral coordination geometry to afford {M 8L 12} (16
71 cluding W-W reconstruction and W-S distorted octahedral coordination, results in distinctive electric
77 core-shell structure containing a truncated octahedral core with bulk face-centered cubic-like arran
78 d a molecular model in which cobalt is in an octahedral CoS2-like state where the cobalt center is pr
79 the SL period is larger than the interfacial octahedral coupling length scale, whereas a single magne
81 0 uc of BTO, both associated with local MnO6 octahedral distortions of the (001) LSMO within the firs
82 square pyramidal versus a vanadium(IV) in an octahedral environment featuring the same coordinating l
83 ine) features a highly rhombically distorted octahedral environment that is responsible for the stron
84 ost common cases being three below two in an octahedral environment, two below three in tetrahedral c
85 sence of framework Sn(IV)-active sites in an octahedral environment, which probably correspond to so-
86 crystal field (CF) model were applied to the octahedral f(1) complexes to determine the covalency and
88 reinforced by a strong Ir-Ir bond across the octahedral faces, and the Ir-Ir Coulombic repulsion acro
91 for As(II,III) incorporation into pyrite at octahedral Fe(II) sites and for As(-I) at tetrahedral S(
92 compound 2 constitutes the first case of an octahedral Fe(V)(N) species prepared within a neutral li
94 e and shell was presented with the truncated octahedral Fe3O4 nanoparticle as the core over a layer o
97 e-bound active site with the hydroxide-bound octahedral form shows a shifting of residue Tyr34 toward
104 derivatives containing mixed tetrahedral and octahedral geometry could open up new horizons in the de
105 and the strong preference for a cis-divacant octahedral geometry in four-coordinate intermediates.
106 oligonucleotides with tetrahedral or pseudo-octahedral geometry is described that involves the coupl
108 as six neighboring oxygen atoms likely in an octahedral geometry with average bond lengths of 1.98 A.
109 L)2 Fe8 (PMe2 Ph)2 ] (1) displays a bicapped octahedral geometry with FeFe distances ranging from 2.4
110 ylpyrazol-1-yl)borate], exhibits a distorted octahedral geometry with Mo horizontal lineO and Mo=/--S
112 yme bind their respective metals with pseudo-octahedral geometry, and both may lose a histidine ligan
113 nickel sites can be described as preferring octahedral geometry, utilizing one to three protein liga
114 Ad = 1-adamantyl) confined to a cis-divacant octahedral geometry, was prepared by reduction of N3Ad b
115 decahedral, octahedral, and corner-truncated octahedral gold nanocrystals with sizes of tens of nanom
119 preferentially from the stereoisomer of the octahedral intermediate, kappa(3)-Ph(CH3)(Cl)Si(ONO(Q)),
121 ent with substantial deuteron density in the octahedral, interstitial voids of the oxygen lattice.
123 uced substitutionally labile chiral-at-metal octahedral iridium(III) complex exclusively bears achira
124 resent in the 12-coordinate site between the octahedral iron layers, and Ca is largely present in 10-
125 nditions as a photochemical precursor for an octahedral iron nitride containing the metal at the rema
134 tes, C4N2H14PbBr4, in which the edge sharing octahedral lead bromide chains [PbBr4 (2-)]infinity are
135 kward electron transfers is stabilized by an octahedral ligand field, whereas in the solution phase a
136 ggests that the dopants reside in the vacant octahedral locations within the alumina lattice, where c
137 n Fe(II) centers of the framework convert to octahedral, low-spin Fe(II) centers upon CO coordination
144 n state of the ATP alpha phosphate; a second octahedral Mg(2+) coordination complex bridges the beta
145 opic signal for this site consistent with an octahedral Mn(II) coordination sphere with simulated zer
147 tes, (ii) single crystalline manganese based octahedral molecular sieve (OMS) nanowires on silicon su
148 tudy examines the effects of manganese oxide octahedral molecular sieve chitosan microspheres (Fe3O4@
149 -2, a well-known one-dimensional microporous octahedral molecular sieve with manganese oxide framewor
151 Zn is present during struvite precipitation, octahedral monodentate sorbates detected at 1 muM (Zn-O
152 that is nearly identical to MOF-5 but has an octahedral morphology and a number of defect sites that
153 es as building blocks and possess a distinct octahedral morphology with eight {111} equivalent crysta
154 d in the common presence of titanium-centred octahedral motifs in both amorphous and crystalline Ti0.
155 hedra as templates, we obtained Pt cubic and octahedral nanocages enclosed by {100} and {111} facets,
159 core-shell NPs (nanorods and nanocubes) into octahedral nanorattles via room-temperature galvanic rep
160 tal structure is made up of a corner-sharing octahedral network of Ga and Ge atoms with Mn atoms at t
161 ormed through axial bridging of the in-plane octahedral Ni sites by the bidentate 1,2-bis(4-pyridyl)e
163 on the ligands used, they possess either an octahedral (Oh) or trigonal bipyramidal ligand sphere.
164 ile, Mo geometry evolves from tetrahedral to octahedral on the edge, and back to tetrahedral coordina
165 le tetrahedral Goldberg polyhedron, a single octahedral one, and a systematic, countable infinity of
170 and DFT calculations also indicate either an octahedral or trigonal-bipyramidal complex between Zn(2+
171 This structure exhibits an unprecedented bi-octahedral (or hexagonal close packing) Au9 kernel prote
173 of (100) facets at the vertices of truncated octahedral particles promote preferential delithiation,
174 l to cubic Pd seeds with different sizes and octahedral Pd seeds of one size to generate an array of
175 d tetrahedral Pd(II)4L8 assembly, whereas an octahedral Pd(II)6L12 cage was formed with a ligand of t
183 through their structural incorporation into octahedral positions of gamma-Fe2O3 (maghemite) nanopart
184 s generated by isoelectronic substitution in octahedral positions of Pb atoms by Fe within the struct
185 metric trimeric esterase into a well-defined octahedral protein cage by appending a C4-symmetric coil
186 alysts was about 50% higher than that of the octahedral Pt(3)Ni catalysts (1.26 mA/cm(2)(Pt)), even t
187 he preparation of carbon-supported truncated-octahedral Pt(3)Ni nanoparticle catalysts for the oxygen
190 ree, and cost-effective method for producing octahedral Pt-Ni alloy nanoparticles on carbon support.
193 orrelated to a substantially enhanced c axis octahedral rotation (a(-)a(-)c(-), alpha~3.8 degrees , g
194 ental evidence for the interrelation between octahedral rotation and magnetism at interface is scarce
196 present work demonstrates the importance of octahedral rotation and tilt in perovskites, for influen
198 be expected in Ca2IrO4 due to its increased octahedral rotation and tilting, which results in enhanc
200 to observe two Mn sites associated with the octahedral rotation in the bulk through the "chirality"
201 eory identifies how configurations of oxygen octahedral rotation patterns, ordered cation arrangement
204 ructure (space group Imcm) featuring minimal octahedral rotations (a(-)a(-)c(-), alpha~4.2 degrees ,
205 t, the presence of modulations of the MnO(6) octahedral rotations along the growth direction commensu
208 tensile in-plane strain which produced weak octahedral rotations in the out-of-plane direction, an o
209 bonding tendencies, thermally activated soft octahedral rotations, and the propensity for the Pb(2+)
210 e accommodated by lattice distortions and/or octahedral rotations, ferroelectric-ferromagnetic interf
211 e and probability of the short-range ordered octahedral rotations, which resembles the pre-transition
212 transfer, intermixing, epitaxial strain, and octahedral rotations/tilts as dominating mechanisms for
215 e ATP-binding sites by using bulky and rigid octahedral ruthenium complexes as structural scaffolds i
216 6-SBU is isostructural with the 12-connected octahedral SBUs of UiO-type MOFs, the M8-SBU is composed
219 crystals, which was previously used to form octahedral shapes of Cu(2)O crystals, effectively inhibi
220 thms (shear line analysis and calculation of octahedral shear strain [OSS]) to identify the degree of
222 I)-Al(III)-layered double hydroxides with an octahedral sheet structure similar to nikischerite (NaFe
223 f Jahn-Teller distorted Mn(III) sites in the octahedral sheet within 0.6 ps of photoexcitation; (ii)
224 in clay minerals and electron conduction in octahedral sheets of nontronite, however, raise the ques
225 occurred in variable amounts: (1) Zn in the octahedral sheets of phyllosilicates, (2) Zn sulfide min
226 duction of Fe(II) into predominantly-Fe(III) octahedral sheets or through the adsorption of Fe(II) on
227 ally, we assessed how Fe(II) residing in the octahedral sheets, or Fe(II) adsorbed at the edge sites
228 rmine the structure of apoferritin, a smooth octahedral shell of alpha-helical subunits that is parti
229 ia an associative pathway involving neutral, octahedral silicon complex 22 with only one molecule of
230 selectivities arising from different chiral octahedral silicon complexes provide guidelines for the
233 f electrons between Ni(2+) and Ni(3+) in the octahedral site and result in an enhanced electrochemica
234 ) cations distribution and concentrations in octahedral site Fe vacancies of gamma-Fe2 O3 instead of
237 the eg occupancy of the active cation in the octahedral site is the activity descriptor for the ORR/O
238 (x)O(5), taking into account the tetrahedral/octahedral site preferences for the various M(3+) ions,
239 thermodynamic preference for Cr to occupy an octahedral site within a II-VI semiconductor lattice wit
244 ysis reveals that Tc(IV) replaces Fe(III) in octahedral sites and illustrates how the resulting charg
245 diffraction data, it is determined that the octahedral sites contain a mixture of divalent Co and tr
246 occupying edge-sharing tetragonal distorted octahedral sites generated by formation of three Zn ion
248 Li sites and through intervening unoccupied octahedral sites that share faces with the LiO(4) tetrah
249 eals that Fe(3+) in Ni(1-x)Fe(x)OOH occupies octahedral sites with unusually short Fe-O bond distance
250 ual cationic sub-lattice arrangement wherein octahedral sites, which serve as bridges for cation migr
256 ETAE) occurred between edge-bound Fe(II) and octahedral (structural) Fe(III) within the clay lattice,
257 er of TMDCs, Mo doped ReSe2 (Mo:ReSe2) is an octahedral structure semiconductor being optically biaxi
259 ic, cuboctahedral, truncated octahedral, and octahedral structures have been employed to form microme
263 eversible annihilation/reconstruction of the octahedral superlattice correlated with the delithiation
265 als can be systematically engineered via the octahedral superstructures leading to a modulated magnet
267 gn a 24-subunit, 13-nm diameter complex with octahedral symmetry and a 12-subunit, 11-nm diameter com
268 ediate its self-assembly to form hexamers of octahedral symmetry in the solid state, in solution, and
269 hat this initial excited state preserves the octahedral symmetry of the electronic ground state by de
273 II), Ir(I), Rh(I), and Co(I)) and eight d(6)-octahedral systems (M = Ir(III), Rh(III), Co(III), Fe(II
274 nd tilt pattern of the corner-connected NiO6 octahedral--the structural signatures of perovskites--ow
277 omic-level imaging condition to measure TiO6 octahedral tilt angles, unit-cell-by-unit-cell, in perov
278 btain a direct real-space correlation of the octahedral tilt modulation with the superstructure geome
279 re we demonstrate a violation of established octahedral tilt rules in the double perovskite analogue
280 lead, show the opposite trend: they show no octahedral tilting upon Cs-substitution but only a contr
282 % less), prevents monoclinic tilt and oxygen octahedral tilts, and increases the ferroelectric polari
286 s retained but becomes rate-limited when the octahedral-to-tetrahedral structural change bottlenecks
288 show that Zn(II) adsorbs as tetrahedral and octahedral triple-corner-sharing complexes at layer vaca
289 haped supercrystals at room temperature, but octahedral, truncated triangular pyramidal, and square p
291 Li(N horizontal lineC(t)BuPh), generates the octahedral U(V) ketimide complex [Li][U(N horizontal lin
292 occupied at different X sites in each Re-X6 octahedral unit cell with perfect matching between their
293 u8S12]16- clusters that behave like a pseudo-octahedral unit in the bonding pattern and are linked th
294 20 and 35 GPa and up to 800 K, features MgO6 octahedral units arranged in the anatase-TiO2 structure.
296 e-corner-sharing inner-sphere complexes over octahedral vacancies in the Mn oxide sheet structure.
299 )(+) have structures slightly distorted from octahedral, while Nb(CO)(7)(+) and Ta(CO)(7)(+) have C(3
300 ous materials whose structure is composed of octahedral Zn4O(-COO)6 and triangular 1,3,5-benzenetribe
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