ライフサイエンスコーパス: olefin

1 recursor such as an alkene (also known as an olefin).

2 of a stereochemically defined disubstituted olefin.

3 erstand the stereoselectivity of the product olefin.

4 for stereochemical control over the forming olefin.

5 The Cl atom product was trapped with an olefin.

6 of H2 cleavage and hydrogen transfer to the olefin.

7 ctional groups several carbons away from the olefin.

8 erated by a trans to cis isomerization of an olefin.

9 om source (PhSiH3 ) or an electron-deficient olefin.

10 ons according to the photochemically excited olefin.

11 l,N'-tosyl diamine derivatives directly from olefin.

12 product, and a polymer precursor from simple olefins.

13 ariety of electron-rich and electron-neutral olefins.

14 itiation rates of these catalysts with trans olefins.

15 or the selective generation of both E- and Z-olefins.

16 tronically-differentiated donor and acceptor olefins.

17 e nascent polyketide intermediate to provide olefins.

18 reoselective cyclopropanation of unactivated olefins.

19 atalysts for the hydrosilylation of terminal olefins.

20 roperties, resulting in great selectivity to olefins.

21 lecular three-component amino oxygenation of olefins.

22 f facile geometric isomerization of nonrigid olefins.

23 e clusters during the hydrogenation of light olefins.

24 f functionalized as well as unfunctionalized olefins.

25 l hypothesis for singlet carbene addition to olefins.

26 xide, from the oxidation of a broad range of olefins.

27 operationally simple conditions (1 equiv of olefin, 1 atm O2 or air) with reduced Pd(II)/bis-sulfoxi

28 Starting from a chiral furanone, the nitrone-olefin [3 + 2] cycloaddition can be used to obtain bicyc

29 ectively, with the exception of imidacloprid-olefin (5 and 10microgkg(-1)).

30 selectively, but also kinetically produce E-olefins, a previously unmet challenge in olefin metathes

31 We prepare more than 60 olefins across a range of substrate classes, and the abi

32 lation via C-H activation and alkylation via olefin activation.

33 Arrays of nucleophiles including olefins, alkynes, heterocycles, and epoxides are compete

34 thetically useful transformations, including olefin amination and directed carbon-hydrogen (C-H) bond

35 rt a new catalytic method for intermolecular olefin aminofluorination using earth-abundant iron catal

36 id, an aldehyde, an allylic alcohol, an aryl olefin, an alpha substituent, or amino acid residues was

37 as a surrogate of functional groups such as olefin and amide as well.

38 lly endergonic relative to their constituent olefin and amine starting materials and thus are not acc

39 Reinstallation of the trans-olefin and gem-dimethyl group present in bryostatin 1 in

40 n oxidant that can add the nitrido ligand to olefin and sulfide sites as well as oxidize cyclohexadie

41 lefins and naphthenes via protonation of the olefin and the transfer of the hydride to the carbenium

42 ross-dehydrogenative coupling between simple olefins and alkylnitriles bears advantages over the conv

43 ated substrates beyond 1,3-dienes to include olefins and alkynes; this provides a new synthetic route

44 flexible linear carboxylic acids, alcohols, olefins and amines in both monomer and peptide settings.

45 transfer dehydrogenation of hydrocarbons to olefins and discuss a complete cycle based on a combined

46 g halide and (thio)ether substituents, while olefins and ester groups are not compatible with the rea

47 selective for epoxidations of electron-rich olefins and explain why Ti-based catalysts have been ide

48 rlongumine (PL), which contains two reactive olefins and inhibits proliferation in cancer cells but n

49 f methanol, hydrogen transfer occurs between olefins and naphthenes via protonation of the olefin and

50 aerobic oxidations of C1-C4 alkanes to form olefins and oxygenates.

51 ross-metathesis reactions between Z-internal olefins and Z-1,2-dichloroethylene or Z-(CF3)CH horizont

52 ive transformation with insertion of olefin, olefin, and carbon monoxide.

53 ) was conjugated to glutathione at the C7-C8 olefin, and this complex was bound to the active site of

54 on reactions, the reduction of electron-poor olefins, and the reductive coupling of benzyl bromide vi

55 e cocatalyst are active for ethylene + amino olefin [AO; H2 C=CH(CH2 )n NR2 ] copolymerizations in th

56 regioselective Wacker oxidation of internal olefin are the highlights of this disclosure.

57 alpha-Olefins are the most abundant petrochemical feedstock be

58 oor, and internal styrenes, as well as alpha-olefins, are functionalized with alpha-halocarbonyls and

59 e abundance of alkanes as well as the use of olefins as building blocks in the chemical community.

60 hyde alkylation reaction that employs simple olefins as coupling partners.

61 he scarce examples of halocyclizations using olefins as nucleophilic counterparts and allows the synt

62 A range of mono-, di-, and trisubstituted olefins as well as alkyl- and arylthioamides with variat

63 uble bond permutations containing conjugated olefins as well as both cis- and trans-olefins, providin

64 N-group transfer reagent to cyclic internal olefins as well as styrene.

65 oduce long-chain n-aldehydes, 1-alcohols and olefins, as well as n-paraffins over potassium-promoted

66 ] photocycloaddition with electron-deficient olefins at lambda = 419 nm.

67 ntion of the stereochemistry of the starting olefins at low conversion.

68 on of mono-, di-, tri-, and tetrasubstituted olefins at the alpha-carbon of amino acid derivatives.

69 es used in the syntheses of tetrasubstituted olefin-based anticancer agents are described.

70 reover, this reactivity was extended into an olefin-based Minisci reaction to functionalize heterocyc

71 inhibited by use of substrates in which the olefin bears a beta-methyl group.

72 Moderate olefin binding enthalpies, below 55 and 70 kJ/mol for et

73 sm that makes an electrophilic attack on the olefin bond possible as the attack on the aldehyde carbo

74 s, in addition to propenes, are base.HCl and olefin-bound, cyclometalated dimers [RuCl(kappa(2)-H2IMe

75 mately found not to be active with diterpene olefins but converted the recently discovered, unstable

76 Two carbenoids combine to generate an olefin by a mechanism involving formation of an ate comp

77 bly, reduction of the nucleophilicity of the olefin by the second, inductively electron-withdrawing h

78 The formation of olefins by the eliminative dimerization and eliminative

79 m of reaction of N-(3-pyridyl)aldimines with olefins can be explained by an asynchronous [4+2] cycloa

80 horizontal lineO bond formation in terminal olefins can be initiated by a combination of the Pd(II)

81 f carbenoids offers a connective approach to olefins capable of precisely targeting a given isomer re

82 ity under relevant conditions, together with olefin capacities exceeding 7 mmol/g.

83 excellent olefin/paraffin selectivity, high olefin capacity, rapid adsorption kinetics, and low raw

84 mputational studies suggest that a disulfide-olefin charge-transfer complex is possibly responsible f

85 Olefin chemistry, through pericyclic reactions, polymeri

86 Iridium-(P,olefin) complex-catalyzed enantio- and diastereoselectiv

87 as Cu(I) and Ni(0), with ethylene and other olefins, complexation of d(10) Zn(II) to simple olefins

88 The method has considerable scope, as olefins containing an alcohol, an aldehyde, an epoxide,

89 typical mono- and multi-substituted aromatic olefins could be converted into ketones and aldehydes at

90 on of alkyl groups to give the corresponding olefins could open almost unlimited avenues to functiona

91 ad range of electronically diverse amide and olefin coupling partners is amenable to this transformat

92 of a more efficient second-generation set of olefin cross-coupling conditions.

93 re of the synthesis is the utilization of an olefin cross-metathesis strategy, which provides for an

94 visible light photoredox-catalyzed aldehyde olefin cyclization is reported.

95 carbenes have been inert, or shown to favor olefin cyclopropanation and heteroatom-hydrogen insertio

96 yclopropanes by means of myoglobin-catalyzed olefin cyclopropanation reactions in the presence of 2-d

97 ize donor-type diazo reagents for asymmetric olefin cyclopropanation.

98 is active in non-natural carbenoid-mediated olefin cyclopropanation.

99 ctive couplings of unactivated and activated olefin-derived nucleophiles with carbonyl partners.

100 n is a new iron-catalyzed diastereoselective olefin diazidation reaction which occurs at room tempera

101 ization of alkenes is a classical method for olefin difunctionalization.

102 sistent with a catalytic mechanism involving olefin-dione oxidative coupling to form an oxa-osmacyclo

103 rylboron reagents to ketones results in aryl olefins directly.

104 eport a catalytic, vicinal difluorination of olefins displaying broad functional group tolerance, usi

105 athesis approach for accessing macrocyclic E-olefins entails selective removal of the Z-component of

106 results allowed earlier work of de Visser on olefin epoxidation by diiron complexes and QM-cluster st

107 work-substituted zeolites have been used for olefin epoxidation reactions for decades, yet the underl

108 xygen atom transfer, C-H bond activation and olefin epoxidation reactions.

109 y increase the reactivity and selectivity of olefin epoxidation.

110 Methane was converted to light olefins (ethene and propene) or higher hydrocarbons in a

111 n of ethylene, beta-hydride elimination, and olefin exchange at gold(III).

112 Unactivated olefins, featuring a wide range of functional groups, ar

113 ition of a carbon-centered radical across an olefin followed by oxidation to form a 5-membered oxocar

114 disubstituted alkynes that were reduced to Z-olefins followed by borepin formation either through an

115 ce-selective oxidation of their Delta(12,13) olefins followed by bromoallene installation allowed acc

116 d Ti-mediated alkyne reduction, leading to Z-olefins, followed by direct lithiation and borepin forma

117 as alkylating agents, the use of unactivated olefins for alkylations has become attractive from both

118 tivation at Ir(I) here is in contrast to the olefin-free catalysis with state-of-the-art Ir complexes

119 were evaluated as adsorbents for separating olefins from paraffins.

120 The formation of internal olefins from the gold(III) n-butyl complex 3b shows that

121 ic hydrogenation of largely unfunctionalized olefins, from the first reports to the advent of chiral

122 alized and unfunctionalized tetrasubstituted olefins, from the reports of Zhou and Buchwald for funct

123 etrochemical feedstocks while preserving the olefin functionality as a handle for further chemical el

124 Several examples of site-selective olefin functionalizations and C-C bond formations are al

125 Transfer of the H* onto an olefin gives a radical that can either (1) transfer an H

126 N'')3 ] were treated with the N-heterocyclic olefin H2 C=C(NMeCH)2 , which constitutes a new, general

127 hesis of tetrasubstituted acyclic all-carbon olefins has been developed via a stereoselective enoliza

128 rene diazonium salts with electron deficient olefins has been exploited for the synthesis of phenylpr

129 te/borane-system -catalyzed isomerization of olefins has been uncovered.

130 The olefins have the double role of radical trap and electro

131 bles a highly branch-selective (Markovnikov) olefin hydroarylation.

132 nds arising from oxidative alkenylation with olefins, hydroarylation with alkynes, and iodination wit

133 Furthermore, the catalytic olefin hydrogenation activity of the Co(I) species was s

134 Treatment of TsNBr2 with olefin in MeCN at room temperature produced imidazoline

135 h arises from participation of the C12-alpha-olefin in the transformation.

136 a strategy that difunctionalizes unactivated olefins in 1,2-positions with two carbon-based entities.

137 actions of a series of water-insoluble nitro-olefins in an aqueous medium.

138 and initiates the biosynthesis of long chain olefins in bacteria.

139 interactions essential for the formation of olefins in polyketide natural products.

140 for Ni-catalyzed dicarbofunctionalization of olefins in styrenes by intercepting Heck C(sp(3))-NiX in

141 on of stereochemistry followed by reversible olefin insertion to form a (cyclopropylcarbinyl)nickel c

142 nd are consistent with an oxidative addition/olefin insertion/reductive elimination mechanism for eac

143 nt in selectivity arises from enhanced metal-olefin interactions induced by increased charge density

144 We have developed a strategy to transform olefins into homoallylic nitriles through a mechanism th

145 enantioselective hydrogenation of prochiral olefins is a key reaction in asymmetric synthesis.

146 Stereoselective phosphinidene transfer to olefins is consistent with singlet phosphinidene reactiv

147 eospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic a

148 allylic C-H amination of trans-disubstituted olefins is reported.

149 ionalization of sterically hindered terminal olefins is reported.

150 ated annulation of N-sulfonylallylamines and olefins is reported.

151 fins, complexation of d(10) Zn(II) to simple olefins is too weak to form isolable complexes due to th

152 Although the addition of acid halides across olefins is well-studied, limitations remain with a numbe

153 s were formed with moderate to excellent (E)-olefin isomer selectivity (74:25 to 97:3) and with excel

154 y useful quantities of a kinetically favored olefin isomer.

155 ination of [Pd(OAc)2]3-boronate-PCy3-enabled olefin isomerization at 80 degrees C has been investigat

156 ich is chiral and racemic, by base-catalyzed olefin isomerization followed by kinetic resolution of 2

157 Mechanistic probes indicate that the olefin isomerization occurs via an intermediate, possibl

158 the gold(III) n-butyl complex 3b shows that olefin isomerization takes place after beta-hydride elim

159 Post-heterocycle-formation olefin isomerization was employed as a key strategy.

160 Olefin isomerization was observed during the Suzuki-Miya

161 ed ring indene skeleton is also prepared via olefin isomerization, 1,2-addition followed by cyclizati

162 Use of ethylene can also cause adventitious olefin isomerization-a particularly serious problem when

163 ghly enantioselective hydrogenation for both olefin isomers in the case of alpha,beta-dialkylvinyl es

164 ese studies are the first to report a set of olefin isomers that synergistically inhibit GGDPS, thus

165 we determined the activity of the individual olefin isomers.

166 s, including carbamate NH, halogen, nitrile, olefin, ketone, and ester moieties.

167 that nucleophilic attack on PL at the C2-C3 olefin led to PL hydrolysis.

168 lic substitution enabled by (phosphoramidite,olefin) ligands are reported.

169 the overhand knot end groups by ring-closing olefin metathesis affords a single enantiomer of the tre

170 Ruthenium-based olefin metathesis catalysts are used in laboratory-scale

171 Ruthenium-based olefin metathesis catalysts bearing dithiolate ligands h

172 A library of 29 homologous Ru-based olefin metathesis catalysts has been tested for ethenoly

173 nium benzylidene complexes are well-known as olefin metathesis catalysts.

174 ve species of industrial supported MoO3/SiO2 olefin metathesis catalysts.

175 scope of catalyst-controlled stereoselective olefin metathesis considerably.

176 Lately, stereoretentive olefin metathesis has garnered much attention as a metho

177 Recent studies in olefin metathesis have focused on the synthesis of catal

178 Olefin metathesis is an incredibly valuable transformati

179 pment of catalyst-controlled stereoselective olefin metathesis processes has been a pivotal recent ad

180 While the corresponding carbonyl-olefin metathesis reaction can also be used to construct

181 Specifically, the catalytic olefin metathesis reaction has led to profound developme

182 The olefin metathesis reaction of two unsaturated substrates

183 gn principle of iron(III)-catalyzed carbonyl-olefin metathesis reactions.

184 Advancements in stereoretentive olefin metathesis using tungsten, ruthenium, and molybde

185 and through applications in stereoselective olefin metathesis where Z-alkene substrates are required

186 nsive computational study of stereoretentive olefin metathesis with Ru-dithiolate catalysts has been

187 However, while the mechanism of olefin metathesis with ruthenium benzylidenes has been w

188 A major shortcoming in olefin metathesis, a chemical process that is central to

189 a notable effect on broadening the scope of olefin metathesis, as the stability of methylidene compl

190 eta-H elimination) occurs on Ti, followed by olefin metathesis, which occurs on W.

191 the precursors of the most active sites for olefin metathesis.

192 reas that have historically been enhanced by olefin metathesis.

193 e E-olefins, a previously unmet challenge in olefin metathesis.

194 A tandem olefin metathesis/oxidative cyclization has been develop

195 ddition/nitrogen extrusion, and a remarkable olefin migration through a vinylcyclopropane retro-ene/e

196 ase that acts on CPP to produce the abietane olefin miltiradiene, but also their subcellular localiza

197 rminal oxo complexes of Re(III) supported by olefin moieties of substituted cyclopentadienes.

198 essible diene starting materials bearing a Z-olefin moiety.

199 route in catalytic conversion of methanol to olefins (MTO) for the formation of nonolefinic byproduct

200 erocyclic carbenes (NHCs) and N-heterocyclic olefins (NHOs) as well as phosphazene bases.

201 zes the addition of a phenol to the terminal olefin of a reverse prenyl group to give a dihydrobenzof

202 at the C7-C8 olefin of PL, whereas the C2-C3 olefin of PL was postulated to react with GSH.

203 rough covalent adduct formation at the C7-C8 olefin of PL, whereas the C2-C3 olefin of PL was postula

204 d oxidative transformation with insertion of olefin, olefin, and carbon monoxide.

205 mbly of molecules traditionally generated by olefin-olefin metathesis or olefination.

206 ically replace it with an organozinc-derived olefin on a molar scale.

207 electron density of both the nucleophile and olefin on the reactivity, site selectivity, and enantios

208 oordinated H2O2 followed by reaction with an olefin or H2O2.

209 n of C-H bonds across olefins) using regular olefins or 1,3-dienes up to May 2016.

210 Either cis olefins or cyclobutenes were obtained from 4,4-disubstit

211 back to the metal, generating an isomerized olefin, or (2) add intramolecularly to a double bond, ge

212 eworks all exhibit an increased affinity for olefins over paraffins relative to their corresponding s

213 ate that has not been previously observed in olefin oxidation reactions.

214 The excellent olefin/paraffin selectivity, high olefin capacity, rapid

215 The chemical industry is dependent on the olefin/paraffin separation, which is mainly accomplished

216 works the materials of choice for adsorptive olefin/paraffin separations.

217 terials for carbon capture and separation of olefin/paraffin, acetylene/ethylene, linear/branched alk

218 sed pi-backbonding at the stage of the metal-olefin pi-complex plays a critical role in facilitating

219 n AS18 latex-coated surface-sulfonated cyclo-olefin polymer (COP) capillary column with an inner diam

220 different materials (polystyrene (PS), cyclo-olefin polymer (COP), and PDMS).

221 y unique properties such as high activity in olefin polymerization and alkane dehydrogenation (M = Cr

222 ic complexes, which are key intermediates in olefin polymerization and oligomerization, are presented

223 n synthesized that serve as single-component olefin polymerization catalysts.

224 o establish a general platform for selective olefin polymerization in a high surface area solid promi

225 actions and to highlight its applications in olefin polymerization, alkane hydrogenolysis, depolymeri

226 imination/transfer events in metal-catalyzed olefin polymerization, which provide the well-studied ex

227 pacts our lives daily through reactions like olefin polymerization.

228 nd analogous late-transition-metal-catalyzed olefin polymerizations, and a number of carbonylative me

229 g that miltiradiene is the relevant abietane olefin precursor.

230 ls in a stereocontrolled fashion from simple olefin precursors.

231 atalyzed allylic C-H oxidation from terminal olefin precursors.

232 the critical deactivation in the methanol to olefin process.

233 T calculations show strong adsorption of the olefin produced, leading to further unwanted reactions.

234 able functional groups which appear in alpha-olefins produced by the chemical industry, and they appe

235 e manipulation of the system for large scale olefin production with hydrocarbon chains lengths equiva

236 rate high yield and stereoselectivity of the olefin products.

237 and theoretical studies, we propose that the olefin promotes a Rh(III) intermediate to undergo oxidat

238 asymmetric hydrogenation of tetrasubstituted olefins provides direct access to very useful biological

239 the inherent thermodynamic preference of an olefin, providing synthetically useful quantities of a k

240 gated olefins as well as both cis- and trans-olefins, providing an unrivaled model system for polyket

241 Olefins react with TsNBr2 in moist THF to form delta-ami

242 m-based functionalities, providing a unified olefin reactivity.

243 obutanes by controlled heterodimerization of olefins remains a substantial challenge, particularly in

244 The produced olefin resulting from a beta-H elimination undergoes eas

245 rwent BF3.Et2O-mediated Et3SiH reduction and olefin ring-closing metathesis (RCM) using Ru(II) cataly

246 tive intermediates in the catalytic carbonyl-olefin ring-closing metathesis has been obtained.

247 Here we demonstrate a catalytic carbonyl-olefin ring-closing metathesis reaction that uses iron,

248 Iron(III)-catalyzed carbonyl-olefin ring-closing metathesis represents a new approach

249 An Eyring plot for beta-hydride elimination-olefin rotation-reinsertion is constructed from variable

250 retentive catalysts that not only generate Z-olefins selectively, but also kinetically produce E-olef

251 he first time in only 18 steps from a simple olefin starting material.

252 In turn, HCHO reacts with olefins stepwise to aromatic molecules on Bronsted acid

253 This olefin stereochemistry then controls the THF diol stereo

254 nd their activity can be highly sensitive to olefin stereochemistry.

255 2C6F5)12 in the presence of a less activated olefin such as isobutylene results in the production of

256 Smaller olefins such as ethylene or 1-hexene were more advantage

257 in the gas phase, and its reactivity against olefins, sulfides, and substrates with weak C-H bonds st

258 resolved in the design of iron catalysts for olefin syn-dihydroxylation with potential utility in org

259 Despite its importance, olefin synthesis still relies largely on chemistry intro

260 tilizes alkyl/arylzinc reagents derived from olefin-tethered alkyl/aryl halides that undergo radical

261 It is carried out on an olefin that is accessed in three steps from commercially

262 Cross-metathesis with olefins that contain a carboxylic acid, an aldehyde, an

263 CuH)-catalyzed hydroamination of unactivated olefins, the substantially enhanced reactivity of copper

264 cular aldehyde alpha-methylene coupling with olefins to construct both cyclic and acyclic products, r

265 [2+2] dimerization reaction of these acyclic olefins to construct cyclobutanes in a highly regio- and

266 ep oxidations in the conversion of diterpene olefins to DRAs.

267 terically hindered tri- and tetrasubstituted olefins to give products containing quaternary centers.

268 process directly converts readily available olefins to internal vicinal fluoro carbamates with high

269 addition of Br-CX3 (X=Cl or Br) to terminal olefins to introduce a trihalomethyl group and generate

270 elopment of the iron-catalyzed conversion of olefins to radicals and their subsequent use in the cons

271 ytic C-C bond-forming reactions that convert olefins to value-added products remains an important obj

272 oaddition of nitrileimines and electron-poor olefins, to detect fumarate via fluorescent pyrazoline c

273 ts has been tested for ethenolysis of cyclic olefins toward the goal of selectively forming alpha,ome

274 tion with the judicious choice of subsequent olefin-type difunctionalization reactions, permits rapid

275 f aryl ketones with a wide range of aromatic olefins under ambient air in good yields.

276 lectively converting linear alkanes to alpha-olefins under mild conditions is a highly desirable tran

277 s with chain lengths of C4 to C8 to terminal olefins under mild conditions.

278 tty-acid-derived fatty alcohols, alkanes and olefins up to 700%.

279 hydrogen bonds (addition of C-H bonds across olefins) using regular olefins or 1,3-dienes up to May 2

280 methylenecyclopropanation reaction of simple olefins, utilizing 1,1-dichloroalkenes as vinylidene pre

281 ronic acids to react with electron-deficient olefins via radical addition to efficiently form C-C cou

282 A vinyl sulfone acceptor olefin was developed, which allowed for the efficient sy

283 A bicyclic olefin was discovered as a cocatalyst in a Cp*Rh(III)-ca

284 When the olefin was treated with 2.4 mol equiv of TsNBr2 in the p

285 rmation of aminobromine was observed when an olefin was treated with the reagent in dry CH2Cl2 at roo

286 Although the substitution on the donor olefins was initially limited to alkyl and aryl groups,

287 A number of cyclic olefins were prepared and evaluated for the asymmetric h

288 A series of olefins were reacted under mild reaction conditions at 6

289 of stoichiometric quantities of sacrificial olefin, which is hydrogenated to consume the H2 equivale

290 ighly hindered trisubstituted alpha-branched olefins, which when coupled with a cationic azaspirocycl

291 yclization yields a highly strained bicyclic olefin whose surface chemistry was hitherto unknown.

292 artner provides access to either the E- or Z-olefin with excellent yield and stereochemical fidelity.

293 precatalyst for homogeneous hydrogenation of olefins with a wide substrate scope under 1 bar H2 press

294 ere we describe a simple method of accessing olefins with any substitution pattern or geometry from o

295 ng for a variety of terminal monosubstituted olefins with aryl electrophiles using Pd and CuH catalys

296 ondary alkyl amines to a wide range of alkyl olefins with complete anti-Markovnikov regioselectivity.

297 ands have been recently employed to generate olefins with high E-selectivity (>99% E) but have been l

298 an catalyze the cyclopropanation of styrenyl olefins with high efficiency and selectivity, interest i

299 of the vicinal difluoride moiety from simple olefins without a prefunctionalization step remains cons

300 te that Co2(m-dobdc) can produce high purity olefins without a temperature swing, an important test o