ライフサイエンスコーパス: orbital

1 S 3p character mixed into the Fe 3d valence orbitals).

2 NO pi* orbital or electron hole in an Fe dpi orbital.

3 inner is that of the underlying closed-shell orbital.

4 tron density into the C-H bond's antibonding orbital.

5 ground state and does not generate a hybrid orbital.

6 etween orbital and spin angular momenta in f orbitals.

7 oor spatial overlap between metal and ligand orbitals.

8 tal and spin angular momenta in lanthanide f orbitals.

9 ry involving two degenerate Sc-N2-Sc bonding orbitals.

10 of the sulfur 3p orbital with the Fe-heme d orbitals.

11 ange interactions between electrons in these orbitals.

12 ce s-orbitals when forming the bonding sigma-orbitals.

13 of correlations of occupations of localised orbitals.

14 anion, most notably the absence of valence p orbitals.

15 ure, others the electron density or electron orbitals.

16 pi donor orbital and the S-H sigma* acceptor orbital (a pi --> sigma* interaction).

17 the LUMO comprised by Fe(dxz,yz)N(px,y) pi*-orbitals, a splitting that is manifested in the electron

18 torial tetracarbene pushes the Fe-dx(2)-y(2) orbital above dz(2), 1 features a dramatically large qui

19 Ligand/metal orbital alignment is modulated by auxiliary phosphine do

20 localized molecular orbital and natural bond orbital analyses.

21 withN moiety was assessed through molecular orbital analysis, which suggests electrophilic character

22 heory of atoms in molecules and natural bond orbital analysis.

23 mispheric hydrologic seesaw is apparent over orbital and glacial-interglacial timescales, but its exi

24 h energy of their highest occupied molecular orbital and low energy of their lowest unoccupied molecu

25 lth of exotic phenomena ranging from charge, orbital and magnetic order to nontrivial topological pha

26 demonstrated lower WM volume bilaterally in orbital and medial prefrontal cortex, and greater GM vol

27 determined using natural localized molecular orbital and natural bond orbital analyses.

28 nteger numbers corresponding to the discrete orbital and radial momentum components of the light fiel

29 tional entropy arising from coupling between orbital and spin angular momenta in f orbitals.

30 ional entropy, arising from coupling between orbital and spin angular momenta in lanthanide f orbital

31 unctions, including frontostriatal circuits, orbital and temporal polar cortex, and the brainstem.

32 alation of the relatively high-lying pi(B=B) orbital and the low-lying pi* orbital of the anthryl moi

33 l interactions, between an aromatic pi donor orbital and the S-H sigma* acceptor orbital (a pi --> si

34 ted alkanes through analysis of natural bond orbitals and classical electrostatics.

35 er-shell s(0)/p(0) orbital mixing with d(10) orbitals and symmetry reduction upon cupriphication of c

36 the strong coupling between the chalcogen p orbitals and the intermetal t2g-bonding orbitals within

37 excitation of electrons into the bonding a1g orbital, and is then stabilized by a lattice distortion

38 ity, electron localization function, Wannier orbitals, and bond indices forms the evidence for covale

39 band structures that arise from local atomic orbitals, and show which are topologically non-trivial.

40 his unidirectional effect produces different orbital angular momenta in opposite directions upon exci

41 Electron waves that carry orbital angular momentum (OAM) are characterized by a qu

42 These elements-SAM-to-orbital angular momentum (OAM) converters-are based on t

43 Exact eigen modes with orbital angular momentum (OAM) in the complex media of u

44 ical filters can be realized using synthetic orbital angular momentum (OAM) lattices in degenerate ca

45 oding/decoding off-axis points with discrete orbital angular momentum (OAM) modes is investigated.

46 -throughput communication approach using the orbital angular momentum (OAM) of acoustic vortex beams

47 Optical vortices, which carry orbital angular momentum (OAM), can be flexibly produced

48 These light beams, which carry orbital angular momentum (OAM), have been successfully u

49 d quarter-wave plate devices empower spin to orbital angular momentum conversion and vector polarizat

50 ally, we investigate the conservation of the orbital angular momentum in necklace and elliptical rota

51 xploring a plethora of applications based on orbital angular momentum or vector polarization, such as

52 emonstrate entanglement swapping of multiple orbital angular momentum states of light.

53 Orbital angular momentum transfer is also shown to rotat

54 even exhibit elliptical orbits with nonzero orbital angular momentum.

55 from the beam diffraction and from the beam orbital angular momentum.

56 of multiple electrons, which can also carry orbital angular momentum.

57 t possesses a helical wave front and carries orbital angular momentum.

58 ochemical course of photoreaction due to the orbital approaches required for photochemical reactivity

59 heory of atoms in molecules and natural bond orbital approaches support this conclusion and highlight

60 -dressed orbitals rather than the field-free orbitals are considered.

61 oefficients between Cu, aminoxyl, and halide orbitals are determined via these techniques with suppor

62 t it also diminishes significantly as the 4f orbitals are populated.

63 en the three sigma-bonds of the carbon sp(2) orbitals are roughly 120 degrees , 90 degrees , and 150

64 s between the 5fdelta/phi and 5fpi*/5fsigma* orbitals as a qualitative measure of overlap-driven acti

65 charge injection into diarylethene molecular orbitals, as a consequence of charge transfer at the dia

66 interactions among the high-energy, occupied orbitals associated with the lone-pair electrons on oxyg

67 steroid 2015 BZ509 is indeed a retrograde co-orbital asteroid of the planet Jupiter.

68 Retrograde co-orbital asteroids of Jupiter and other planets may be mo

69 triking if one considers that it has empty d-orbitals at its disposal and contains, at the same time,

70 ng how energy- and symmetry-matched impurity orbitals, at low concentrations, dramatically alter 1's

71 We evaluated the effects of orbital atherectomy on intraluminal paclitaxel delivery

72 fluctuations and provide connections both to orbital-based approaches to electron correlation, as wel

73 E(r) considers all virtual orbitals below the free electron limit and is determined

74 Orbital biopsy was then performed, but the results were

75 ity dependence show that these field-dressed orbitals can have strong Rydberg character for certain o

76 energy of their lowest unoccupied molecular orbital cause them to be reactive and unstable.

77 cuprates, including its [Formula: see text] orbital character, hole filling level, and strength of e

78 Single-crystal, molecular orbital computations, and optical/electrochemical data i

79 ints to dissociative OS-SET (SET to a sigma* orbital concerted with C-Cl breakage) in alkanes compare

80 al distribution of insolation due to Earth's orbital configuration, as well as climate change initiat

81 ms were created early in the comet's current orbital configuration.

82 The coldest orbital configurations are characterized by large axial

83 ich the atomic coefficients of heavy metal d orbitals contribute to the one-electron excitation confi

84 when it was proposed that covalency from 5f-orbitals contributed to the unique behavior of americium

85 damental understanding of the differences in orbital contributions and covalency in f-block metal-lig

86 nes reported herein exhibit enhanced metal d orbital contributions to HOMO and HOMO-1, which results

87 7s, 6d and 5f orbital contributions to the Th-As bonds are suggested b

88 f the retinal fovea, trichromatic vision and orbital convergence in ancestral primates may have helpe

89 rrelations were treated only in terms of two-orbital correlations, although the structure of multiorb

90 t is the recent discovery that strongly spin-orbital-coupled magnets, such as alpha-RuCl3, may displa

91 he Cu 3d(10) orbitals than for the Ag 4d(10) orbitals, Cu(I) atoms energetically favor 4-fold coordin

92 s deepen by approximately one centimetre per orbital cycle and grow only during periods of relatively

93 roximately 20-50% over the 100 kyr to 30 Myr orbital cycles during the early Mesozoic.

94 2 These findings highlight the importance of orbital cycles for the climate and carbon cycle during t

95 similar to those observed in remotely sensed orbital data from Mars.

96 ted using three systems biology approaches: "Orbital-deconvolution" elucidated upstream, regulatory p

97 the spin, valley isospin, and an accidental orbital degeneracy, leading to a complex phase diagram o

98 Charge and orbital degrees of freedom determine properties of many

99 he coupling between electronic, magnetic and orbital degrees of freedom with the crystal structure ac

100 couplings between charge, spin, lattice, or orbital degrees of freedom, giving rise to remarkable ph

101 interactions being dominated by n --> sigma* orbital delocalization between a lone pair (n) of a (thi

102 The alternative mechanism of n --> pi* orbital delocalization does not seem to play a significa

103 underline the importance of often-overlooked orbital delocalization effects in conformational control

104 ional theory with the gauge invariant atomic orbitals (DFT-GIAO).

105 The crystal field stabilization of the dxy orbital due to c-axis contraction is shown to be essenti

106 highlights the controlling role of frontier orbital effects underpinning the catalytic performance o

107 Superposition of orbital eigenstates is crucial to quantum technology uti

108 We show for the first time that the frontier orbital energetics (conduction band minimum (CBM) and va

109 ational free energies and computed molecular orbital energies was consistent with the chalcogen-bondi

110 mponents, dipole moment, polarizability, and orbital energies, can help shed light on the energetic,

111 omplex are largely ionic, the decrease in 5f orbital energy across the series manifests in orbital-mi

112 Frontier molecular orbital energy differences indicate a switch from normal

113 e shows a higher lowest unoccupied molecular orbital energy level (IOIC2: -3.78 eV vs IHIC2: -3.86 eV

114 perimental estimations of frontier molecular orbital energy levels, which are reported and discussed.

115 l overlap and mixing of the frontier valence orbital energy levels.

116 The higher lowest unoccupied molecular orbital energy of PhF2,5 increases the barrier to electr

117 of the cases studied, we report the dominant orbital excitations contributing to the optically active

118 ers the energy of the pi*(M identical withC) orbital, explaining the more deshielded chemical shift v

119 OI: idiopathic dacryoadenitis and idiopathic orbital fat inflammation (2 nonmyositic IOIs), and idiop

120 spinels, consolidating the role of electron orbital filling in metal oxide catalysis.

121 eration of many degrees of freedom including orbitals, fluctuating local moments, magnetism, and the

122 two key redox-active dpi* frontier molecular orbitals (FMOs).

123 es compared to stepwise OS-SET (SET to a pi* orbital followed by C-Cl cleavage) in ethenes.

124 y degeneracy with the dipicolinate molecular orbitals for Bk and Cf relative to Am and Cm.

125 opical cyclone development compared with the orbital forcing alone.

126 Cu(+):CdSe NCs localize primarily in Cu(3d) orbitals, formally oxidizing Cu(+) to Cu(2+), in Ag(+):C

127 raumatic brain injury, followed by facial or orbital fracture, long bone fracture, and chest injury.

128 TEMENT Altered functional interactions among orbital frontal cortex (OFC), medial frontal cortex (MFC

129 , dorsomedial prefrontal cortex, and lateral orbital frontal cortex predicted treatment response.

130 res of GMV in the anterior cingulate cortex, orbital frontal cortex, temporal pole, and insula, which

131 olecular orbital-lowest unoccupied molecular orbital gaps for local chromophores.

132 one electron exited to a normally unoccupied orbital have been obtained.

133 s slightly higher highest occupied molecular orbital (HOMO) (-5.43 eV) and lowest unoccupied molecula

134 ocation of indole highest occupied molecular orbital (HOMO) charge density toward the cation with a s

135 xhibits upshifted highest occupied molecular orbital (HOMO) energy level mainly due to the additional

136 currents via the highest occupied molecular orbital (HOMO) with a rectification ratio R = 99, but ju

137 oth 5f- and 6d-orbital mixing with the Cl-3p orbitals; however, contributions from the 6d-orbitals we

138 ce of the net magnetization of BFO to strong orbital hybridization between Fe and Mn across the inter

139 uN-H red-shifted band, as the electron donor orbital in the above hyperconjugative interaction does n

140 -orbit coupling lifts the degeneracy of t 2g orbitals in 5d transition-metal systems, leaving a Krame

141 by a sub-100 fs splitting of the Fe 3p core orbitals in the Fe M2,3 edge.

142 tween the metal d and the low-energy azo pi* orbitals in the intermediary redox state and additional

143 energies of {Co9(P2W15)3} frontier molecular orbitals in the surface-bound state were found to direct

144 ction of the calculated unoccupied molecular orbitals, in conjunction with experimentally measured N

145 By specifying criteria, diagnosis of orbital inflammation will be improved.

146 Examination of the orbital innervation in mice lacking Mafb has established

147 Strong spin orbital interaction (SOI) can induce unique quantum phen

148 thermodynamics are bolstered by a secondary orbital interaction in the transition state of the forma

149 alculations (density functional theory), and orbital interaction studies rationalize the selectivity

150 of the (11)B NMR signals, suggesting greater orbital interactions between the boron and transition me

151 ne bridges reveals remarkable sensitivity to orbital interactions between the spacer and the metal, r

152 The various orbital interactions of the propargylic and homopropargy

153 Computations reveal donor-acceptor orbital interactions that confirm the counterintuitive L

154 driven significantly by favorable molecular orbital interactions, between an aromatic pi donor orbit

155 in the strength of the primary and secondary orbital interactions.

156 atic components mask the role of stabilizing orbital interactions.

157 p showed no evidence of systemic lymphoma or orbital involvement.

158 different MS instruments (1 single TOF, 1 Q/orbital ion trap, and 7 QTOF instruments).

159 nifested through the same acceptor molecular orbital irrespective of whether a direct chalcogen...cha

160 oxygen and adjacent unfilled CC antibonding orbital is demonstrated by NBO second-order delocalizati

161 , the hybridization among out-of-plane boron orbitals is crucial for determining the relative stabili

162 a linkage of O-H-O involving O 2p and H 1 s orbitals is formed between two carbonate ions.

163 As the magnetism of the Fe d-orbitals is intertwined with the superconducting pairing

164 ents designed to concurrently probe spin and orbital/lattice degrees of freedom of Ba2NaOsO6 provide

165 ayer inserts into the sclera, and the outer, orbital layer inserts into the connective tissue pulley.

166 otoneuron pools, we injected tracer into the orbital layer of the cat lateral rectus muscle.

167 sing lower LUMO (lowest unoccupied molecular orbital), less than -4.2 eV) can open new opportunities

168 t almost the same highest occupied molecular orbital level, yet exhibit very efficient charge creatio

169 discernible activity trends at the frontier orbital level: (1) increasing the number of fluorine ato

170 low-lying LUMO (lowest unoccupied molecular orbital) level, while the 3D structured spirobifluorene

171 The valence Cs 6s orbital lies too high to be involved in bonding, and con

172 ted partial charges by measuring the size of orbital lobes that best overlap with the wavefunction ar

173 to unveil a two-step process mediated by an orbital localized on the core of the cluster in which ch

174 tial reduction in pi overlap (as these two p-orbitals loose coplanar state) resulting in a very weak

175 fer energies, and highest occupied molecular orbital-lowest unoccupied molecular orbital gaps for loc

176 ) (-5.43 eV) and lowest unoccupied molecular orbital (LUMO) (-3.80 eV) energy levels relative to ITIC

177 and downshifted lowest unoccupied molecular orbital (LUMO) energy level due to the fluorination of A

178 uted to the high lowest unoccupied molecular orbital (LUMO) level of EH-IDTBR.

179 BODIPY low-lying lowest unoccupied molecular orbital (LUMO) over the oligothienyl moieties, as confir

180 usion criteria were intraocular involvement, orbital lymphoma, or other systemic lymphoma.

181 material properties such as atomic spin and orbital magnetic moments and local magnetocrystalline an

182 high d-electron count would fill antibonding orbitals, making these species high in energy.

183 how these naturally arise within a single p-orbital manifold as a general consequence of a trigonal

184 rmation of planetary systems suggesting that orbital migration of giant planets ejects a large fracti

185 Given the importance of orbital mixing combined with the difficultly in measurin

186 rary to the expectations based on the simple orbital mixing model, the lone pairs in a pair of neutra

187 Outer-shell s(0)/p(0) orbital mixing with d(10) orbitals and symmetry reductio

188 We observed both 5f- and 6d-orbital mixing with the Cl-3p orbitals; however, contrib

189 rbital energy across the series manifests in orbital-mixing and, hence, covalency driven by energy de

190 r-model approaches, such as Gouterman's four-orbital model and Michl's perimeter model, to analyze tr

191 A simplified version of the frontier orbital model for a noncovalent dimer is used to derive

192 e coordinated atom follow the Gouterman four-orbital model.

193 ge enough defects on surfaces, forcing BV in orbital motion around these defects.

194 mmation (2 nonmyositic IOIs), and idiopathic orbital myositis (myositic IOI).

195 we pair these simulations with natural bond orbital (NBO) analysis to gain key insights into the rol

196 e, we show for the representative example of orbital-nematic ordering of a non-Kramers doublet that a

197 that the conventional representation of the orbital occupancies is incorrect in that the states have

198 electrons are injected into the anti-bonding orbital of a critical intermediate, while carbon monoxid

199 als, one from Fe dz(2) and the other a pi*op orbital of a unique bent axial NO ligand, which is respo

200 (thio)amide donor and the antibonding sigma* orbital of an acceptor thiophene or selenophene.

201 nd from the higher electron density in the d orbital of copper are central to its higher oxidase acti

202 al ligand field, these electrons populate an orbital of dxy parentage, an electronic configuration th

203 stal structure analysis revealed that the 2p orbital of N atom and the 2p orbital of the adjacent rin

204 correct orientation of the hydride receiving orbital of N5.

205 ufficient energy to populate the antibonding orbital of O2 as illustrated by in situ X-ray absorption

206 While the lowest unoccupied molecular orbital of Ru3Rh is localized on a bridging ligand, it i

207 nment of the Au Fermi level to the molecular orbital of silane that mediates charge transport would b

208 led that the 2p orbital of N atom and the 2p orbital of the adjacent ring C atom to which the o-NO2 i

209 -lying pi(B=B) orbital and the low-lying pi* orbital of the anthryl moiety with no significant conjug

210 The DFT-computed frontier orbital of the relevant protein segments suggests that t

211 action involving the four frontier molecular orbitals of benchmark porphyrins and associated construc

212 e find that energy mismatch between occupied orbitals of both the solutes NH3 and NH4(+) and the surr

213 en make antibonding possible with the 6p x/y orbitals of surrounding Bi atoms.

214 n energy by oxygen doping because the 2p x/y orbitals of the doped oxygen make antibonding possible w

215 Ag(+):CdSe NCs they localize primarily in 4p orbitals of the four neighboring Se(2-) ligands, and Ag(

216 ed preferentially on electrons from the d yz orbitals of the iron atoms.

217 materials makes them distort the degenerate orbitals of the Ln ions more efficiently than the symmet

218 fficient spin-dependent interaction with the orbitals of the molecule.

219 -M effect of the o-NO2 group, whereas the 2p orbitals of the N atom of the p-NO2 group and the adjace

220 Co surface can interact with the asymmetric orbital on an organometal halide perovskite surface, lea

221 onegative ligands, and no low-lying acceptor orbitals on the central atom.

222 tic coupling between two strictly orthogonal orbitals, one from Fe dz(2) and the other a pi*op orbita

223 al), with no localized electron in an NO pi* orbital or electron hole in an Fe dpi orbital.

224 erally given in terms of delocalized bonding orbitals, or, alternatively, in terms of correlations of

225 ns via interfacial coupling induces a charge/orbital order in the FeAs layers, without either static

226 ed 1:3 charge order of Mn(4+) and Mn(3+) and orbital order of Mn(3+) near room temperature, but both

227 al. report the measurement of the valley and orbital order, allowing them to directly reconstruct the

228 etween states of different valley, spin, and orbital order, including previously unobserved orbitally

229 ecreasing temperature, different charge- and orbital-order transitions take place accompanied by symm

230 Inspection of the frontier orbital ordering of 1 shows a relatively small HOMO/LUMO

231 uces a non-collinear spin state even without orbital orderings and may be responsible for macroscopic

232 ) near room temperature, but both charge and orbital orders collapse below about 115 K with the reent

233 mers was used as a proxy for the efficacy of orbital overlap and therefore ligand binding.

234 tation of the Ox group, driven by increasing orbital overlap of the nitrogen lone pair with the incip

235 evaluate the effect of the extent of atomic orbital overlap on their reactivity.

236 igand molecular orbitals rather than spatial orbital overlap.

237 erous/Permian boundary to changes in Earth's orbital parameters and in atmospheric CO2 using a couple

238 Orbital pathology, namely infection and trauma, was the

239 l was observed in rostral peri-insular areas orbital periallocortex, orbital proisocortex, and insula

240 o known as KELT-9), which reveal a close-in (orbital period of about 1.48 days) transiting giant plan

241 The co-existence at the same orbital period of novalike binaries and dwarf novae-whic

242 form a near-resonant chain, such that their orbital periods (1.51, 2.42, 4.04, 6.06, 9.1 and 12.35 d

243 d to the planet's as well as to the binary's orbital periods are present in a variety of climate indi

244 warfs are often found in binary systems with orbital periods ranging from tens of minutes to hours in

245 , orbit, periorbital, and facial structures (orbital-periorbital plexiform neurofibroma [OPPN]) can r

246 etal-to-metal channel involving the Ce(IV) f orbitals.Perovskite manganites exhibit intriguing but po

247 From a molecular orbital perspective, the bonding scheme is reminiscent o

248 sponse TDDFT calculation is used to generate orbitals perturbed by the excitonic state, and then a se

249 bscuration from the heaviest elements in the orbital plane and a direct view of any ultrarelativistic

250 hereas Cs2(C14H10) is diamagnetic because of orbital polarization, Cs(C14H10) is a Heisenberg antifer

251 l peri-insular areas orbital periallocortex, orbital proisocortex, and insular proisocortex following

252 We also applied a procedure involving retro-orbital puncture after enucleation and biopsied the fron

253 * toward the ring carbons and an aromatic pi orbital rather than toward the aromatic centroid.

254 eneracy of 5f orbitals with ligand molecular orbitals rather than spatial orbital overlap.

255 an only be understood when the field-dressed orbitals rather than the field-free orbitals are conside

256 Cu-planes closest to the surface exhibit an orbital reconstruction similar to that observed at La1-x

257 Such orbital reconstruction would establish an upper temperat

258 No patient developed an orbital recurrence.

259 e Fe-NO pi-bonding and antibonding molecular orbitals relative to the exchange interactions between e

260 mbined to probe the electronic structure and orbitals responsible for the bonding interactions in the

261 orbital wall and the superior rectus and the orbital roof was assessed by masked review of computed t

262 le of approximately 30 degrees away from the orbital rotation axis, which avoids both obscuration fro

263 erical symmetry makes super atomic molecular orbital (SAMO) states optically active.

264 persistent groundwater hydro-refugia through orbital-scale climate cycles.

265 own to have strongly affected centennial- to orbital-scale climate variability during past glaciation

266 s been examined for more than a century, the orbital-scale paleoclimate forcings remain poorly unders

267 x gap configuration reveals the existence of orbital-selective Cooper pairing that, in FeSe, is based

268 report a striking result: the finding of an orbital-selective Mott transition in a pure p-band eleme

269 that Rydberg contributions to field-dressed orbitals should be routinely considered when studying po

270 lize more than one singly occupied molecular orbital (SOMO) to form multiple pancake-bonded dimers wi

271 ulse control of Si:P orbitals using multiple orbital state admixtures, observing beat patterns produc

272 ical clock transition between two electronic orbital states in (87)Sr atoms.

273 essible state, a single-unoccupied molecular orbital (SUMO), which turns rectification off and drops

274 ree formation of graphitic lattices, and the orbital symmetry conservation rules favour hole rather t

275 atively larger contribution of the cerium 5d orbital than the 4f orbital to the Ce horizontal lineN b

276 e much higher energy level for the Cu 3d(10) orbitals than for the Ag 4d(10) orbitals, Cu(I) atoms en

277 ate to the hybridization states of the boron orbitals that form the B-B bonds and to the strength of

278 etal center has to provide occupied or empty orbitals that strongly interact with the junction metal

279 ic and possess comparable frontier molecular orbitals, the borylimido ligand is both a better pi-dono

280 nough to include one of the cluster frontier orbitals, the current blockade is lifted and charge carr

281 analyses based on the quantitative molecular orbital theory and a canonical energy decomposition anal

282 h effective-medium theory, linear muffin-tin orbital theory, and the d-band model, we rationalize the

283 ive plasma cells per high-power field in the orbital tissue is compatible with the diagnosis of IOI.

284 ibution of the cerium 5d orbital than the 4f orbital to the Ce horizontal lineN bonds.

285 Cs uses outer core 5s and 5p orbitals to bind the oxygen atoms.

286 e (MALT) lymphoma (POAML) is the most common orbital tumor, there are large gaps in knowledge of its

287 nel electron-electron interaction (EEI), and orbital two-channel Kondo effect, leaving a three-dimens

288 ounding water prevents strong mixing between orbitals upon hydrogen bonding and, thus, inhibits subst

289 demonstrate THz laser pulse control of Si:P orbitals using multiple orbital state admixtures, observ

290 eridional shifts in the zonal mean rainbelt, orbital variations produce expansion/contractions in ter

291 issue between the lateral rectus and lateral orbital wall and the superior rectus and the orbital roo

292 orbitals; however, contributions from the 6d-orbitals were more substantial.

293 the enhanced transmission close to the HOMO orbital when the radical forms.

294 , due to the overlap of mainly the valence s-orbitals when forming the bonding sigma-orbitals.

295 e position of the highest occupied molecular orbital, which dwells in a region that is spatially sepa

296 bout 37, due to weak mixing of the sulfur 3p orbital with the Fe-heme d orbitals.

297 interactions stems from the degeneracy of 5f orbitals with ligand molecular orbitals rather than spat

298 which all carbon atoms possess sp(2) hybrid orbitals with some distortion, forming an extensive conj

299 ffering interaction strengths of the Si/S 3s orbitals with the cation levels, with the more core-like

300 en p orbitals and the intermetal t2g-bonding orbitals within the basic triangular pyramid structure u