ライフサイエンスコーパス: organoborane

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1 f the polymerization is a tris-polymethylene organoborane.

2 are obtainable from the intermediate chiral organoboranes.

3 catalyst provided access to 16 novel chiral organoboranes.

4 We investigated the actions of the organoborane, 2-aminoethoxydiphenylborane (2APB), on Ca2

5 latoboryl nucleophile with the electrophilic organoboranes, 9-BBN and Ph3 B, provide facile B-B' sing

6 es or the transfer of special units from the organoboranes and represent a useful generalization of t

7 The bifunctional conjugated organoboranes Ar2B-bt-BAr2, which contain 2,2'-bithiophe

8 Even highly hindered organoboranes are quantitatively converted to their boro

9 The bonding in 1 and its reactivity with organoboranes are reminiscent of CO.

10 Organoboranes are some of the most synthetically valuabl

11 Trialkyl and aryl organoboranes catalyze the polymerization of dimethylsul

12 aring almost any alkyl group available using organoborane chemistry and incorporating all features of

13 The oxidation of these macrocyclic organoboranes generates a three-armed star polymethylene

14 n of 1-bromo and 1-chloroalkyl radicals from organoboranes has been investigated.

15 ctions of aryl-stabilized sulfur ylides with organoboranes has been studied under a variety of condit

16 Conjugated organoboranes have emerged as attractive hybrid material

17 These novel organoborane homoalanine anion equivalents are generated

18 tic potential of the expected functionalised organoboranes, however, many groups have recently focuse

19 ically encoded platform for producing chiral organoboranes in bacteria.

20 98:<2 site selectivity and furnish secondary organoborane isomers that complement those obtained thro

21 e homologation of phosphorus carbenoids with organoboranes leads to alpha-boranophosphorus compounds,

22 etermination of the isomeric distribution in organoborane mixtures resulting from common organoborane

23 Representative organoborane mixtures were quantitatively converted to t

24 educing agents employed include organozincs, organoboranes, organosilanes, and methanol.

25 mologation reaction to cyclic and polycyclic organoboranes permits the construction of unique oligome

26 organoborane mixtures resulting from common organoborane processes (e.g., hydroboration).

27 meric composition of a variety of asymmetric organoborane processes.

28 The organoborane products are among the most versatile synth

29 be tuned to provide either enantiomer of the organoborane products.

30 Through this simple KH treatment, complex organoborane reaction mixtures are converted to the corr

31 al and straightforward route to these chiral organoborane reagents in one-pot has been developed alon

32 yde and ketone substrates using these chiral organoborane reagents in subsequent coupling reactions.

33 typal Lewis acids such that common routes to organoboranes rely on the reactivity of boron as an elec

34 with pre-generated organozinc, Grignard and organoborane species has been used to furnish diverse mo

35 rtunity for the development of new routes to organoboranes, the synthesis of current candidates is ge

36 ickel-catalyzed reaction with organozincs or organoboranes to afford densely functionalized cyclohexe

37 demonstrated by converting the intermediate organoboranes to alcohols, amines, and alkenes.

38 type reaction of imines, acid chlorides, and organoboranes to form alpha-substituted amides is descri

39 Trialkyl and triaryl organoboranes undergo multiple, repetitive homologations

40 Representative organoboranes were examined by this new technique permit

41 thetic target of this method, polymeric star organoboranes with molecular weights of 1.5 million have

42 involves initial formation of a zwitterionic organoborane.ylide complex which breaks down in a rate-l

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