ライフサイエンスコーパス: organometallic

1 d precautions that are commonplace for other organometallics.

2 Two organometallic 1D infinite coordination polymers and two

3 s solution, a critical feature for achieving organometallic ACS activity, and binds CO and -CH3 group

4 e Michael donors without the requirement for organometallic activation or propagation.

5 ergo different kinds of reactions, including organometallics addition, metal catalyzed vinylation and

6 transformations rely on chelation-controlled organometallic additions and a Petasis multicomponent re

7 three decades, are contextualized from both organometallic and coordination chemistry points of view

8 s led to the development of a broad range of organometallic and coordination compounds featuring prop

9 ver, Ag(111) and Ag(110) on the formation of organometallic and covalent structures for Ullmann-type

10 ivation and cleavage usually associated with organometallic and reductive approaches particularly dif

11 tional cross-coupling strategies that employ organometallics and halides (or pseudohalides) in order

12 ch as coordination complexes and frameworks, organometallics and organic molecules.

13 ilyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles.

14 In principle, these organometallic APNCs should not require harsh pretreatme

15 SO4 thus gave methylated Fc, contrary to non-organometallic aromatics giving mixtures of HO and MeO d

16 Here we demonstrate that ordered organometallic arrays can be formed spontaneously by rea

17 tion and characterization of benchtop-stable organometallic aryl-Co(III) compounds (NMR, HRMS, XAS, a

18 hts obtained from the application of our new organometallic aryl-Co(III) compounds in alkyne annulati

19 , we provide crystallographic evidence of an organometallic aryl-Co(III) intermediate proposed in 8-a

20 dies indicates that a mechanism involving an organometallic aryl-Co(III)-alkynyl intermediate species

21 sed to the 1e(-) transfer process typical of organometallic-based and conventional organic multicompo

22 Organic and organometallic-based electroactive materials are green a

23 nging perspectives which target the goals of organometallic bond activation.

24 metal catalysis or stoichiometric amounts of organometallic building blocks.

25 ber of synthetic steps and the production of organometallic byproducts.

26 ith other families of molecules that present organometallic C-Au bonds, we conclude that the conducta

27 ction have revolved around high temperature, organometallic C-H activation by noble metal catalysts t

28 s aimed at understanding the course of these organometallic cascade reactions it was later discovered

29 widely used in two main domains: ligands in organometallic catalysis and organocatalysis.

30 The viability of excited-state organometallic catalysis via direct photoexcitation has

31 Here, we demonstrate excited-state organometallic catalysis via such an activation pathway:

32 f second coordination sphere interactions in organometallic catalysis.

33 gated the application of sol-gel immobilized organometallic catalyst for regioselective hydroaminomet

34 A novel variant of an iridium-based organometallic catalyst was synthesized and used to enha

35 nyl groups were probed as substituents in an organometallic catalyst.

36 Furthermore, detection of organometallic catalysts (including air-sensitive [Rh-Me

37 rization of ubiquitous isopropyl moieties by organometallic catalysts has remained an unanswered chal

38 itization mechanisms to access excited-state organometallic catalysts have lagged far behind.

39 In contrast, organometallic catalysts most often rely on isopropanol

40 tly transformed into novel single-site solid organometallic catalysts without homogeneous analogs for

41 ntial for the generation of both organic and organometallic catalysts.

42 e spectroscopies reveals that it contains an organometallic center in which the 5' carbon of a SAM-de

43 In sharp contrast, organometallic cerium(iv) compounds are still exceedingl

44 gen-bonded 2D networks, which transform into organometallic chains and rings after debromination.

45 t the molecular level using advanced surface organometallic chemistry (SOMC) characterization techniq

46 xylated silica (silica700) using the surface organometallic chemistry approach.

47 rved, which shows that fundamental neptunium organometallic chemistry can provide new insights into t

48 Medicinal organometallic chemistry can provide us with an antimala

49 anoparticles (ca. 2 nm) prepared via surface organometallic chemistry from a mesityl complex [Cu5Mes5

50 e (NHC) compounds in organic, inorganic, and organometallic chemistry has been extended to another di

51 d its application to problems in organic and organometallic chemistry illustrate the power of the ASM

52 increasingly important because bioorthogonal organometallic chemistry involves palladium catalysis.

53 the historic and current development of the organometallic chemistry of cerium in its oxidation stat

54 cent progress in the preparative organic and organometallic chemistry of polypyridines has resulted i

55 These functions are connected by the organometallic chemistry of the MNR2BH3 group.

56 Unlike the organometallic chemistry of uranium, which has focused s

57 development of new single-molecule magnets: organometallic chemistry presents possibilities for usin

58 data therefore make an interesting case for organometallic chemistry that provides inherently better

59 for adjustable platforms for coordination or organometallic chemistry, anion binding, or mechanistic

60 They have also been prepared via surface organometallic chemistry.

61 rged as an important approach in organic and organometallic chemistry.

62 mechanistically using the familiar tools of organometallic chemistry.

63 mental change in the approach to macrocyclic organometallic chemistry.

64 ivated alkenes is a significant challenge in organometallic chemistry.

65 group for implementing in vivo bioorthogonal organometallic chemistry.

66 involving allene derivatives in organic and organometallic chemistry.

67 perhaps be employed in synthetic organic or organometallic chemistry.

68 ntal evidence for intermediates, although an organometallic Co(III) species is generally implicated.

69 lot and determined that the inclusion of the organometallic complex in the cavitand was endothermic a

70 ermine the three-dimensional structure of an organometallic complex on an amorphous silica surface us

71 COD was 5 kcal mol(-1) higher as an included organometallic complex than as free in solution.

72 l SAM-related [4Fe-4S](+) cluster forming an organometallic complex with an alkene, shedding addition

73 ion (CID) of [(phen)M(O2CCH3)](+) yields the organometallic complex, [(phen)M(CH3)](+), via decarboxy

74 ) acetate gave the corresponding silver(III) organometallic complex.

75 the first time by successively grafting two organometallic complexes [W(Me)6 (1) followed by ZrNp4 (

76 Organometallic complexes are effective hydrogenation cat

77 ive anchoring of 7-9, endorsing C-Au coupled organometallic complexes as excellent candidates for low

78 an also ionize ionic solid compounds such as organometallic complexes as well as a variety of neat ne

79 uctures and elementary reactions of discrete organometallic complexes bound to organic ligands.

80 on the development of well-defined platinum organometallic complexes covalently anchored to ordered

81 strate the potential to study a new genre of organometallic complexes for which the rates and outcome

82 tra and structurally significant spectra for organometallic complexes is a unique and potentially pow

83 Studies of transuranic organometallic complexes provide a particularly valuable

84 metal catalysis has traditionally relied on organometallic complexes that can cycle through a series

85 Organometallic complexes therefore have an extraordinary

86 cluding the data of recently prepared stable organometallic complexes with gold(I) and gold(III) cent

87 Organometallic complexes with metal-nitrogen/carbon (M-N

88 cer activity and maximize the selectivity of organometallic complexes with redox-based mechanisms of

89 biomedical and bioanalytical applications of organometallic complexes, that is, metal compounds with

90 This parallels the known trend for organometallic complexes, thus highlighting the local ch

91 Two compatible organometallic complexes, W(Me)6 (1) and TiNp4 (2), were

92 of such [Fe4S4]-containing proteins to form organometallic complexes.

93 ic and electronic structures of these Cu(II) organometallic complexes.

94 dE, HydF, and HydG-synthesize and insert the organometallic component of the [FeFe]-hydrogenase activ

95 ylcaffein-8-ylidene)2 ]BF4 is an exceptional organometallic compound of profound interest as a prospe

96 Iron(0) pentacarbonyl is an organometallic compound with a long history.

97 including the radiochemical synthesis of one organometallic compound), and the available anhydrous st

98 DNA biosensing approach based on exploiting organometallic compound, aminoferrocene (AFC), as electr

99 a low-temperature decomplexation of a stable organometallic compound, rather than high-temperature el

100 f the three single steps (preparation of the organometallic compound, sulfinate formation, and arylat

101 This review describes organometallic compounds and materials that are capable

102 m platform includes voltammetric analysis of organometallic compounds and quantitative analysis of as

103 6 cell line was determined for a total of 23 organometallic compounds and SAR's data analysis within

104 we report the synthesis of three new Np(III) organometallic compounds and the characterization of the

105 Examples of organometallic compounds as nucleoside analogues are rar

106 be used for the removal of toxic metals and organometallic compounds from aqueous systems.

107 on the aromaticity of a particular family of organometallic compounds known as metallabenzenes, which

108 New ruthenium(II) and iron(II) organometallic compounds of general formula [(eta(5)-C5H

109 Classically, late transition-metal organometallic compounds promote multielectron processes

110 s comprising singlet fluorophores or iridium organometallic compounds provided further improved detec

111 s, a deviation from traditional strong-field organometallic compounds that promote catalytic C-C bond

112 These results show that initial binding of organometallic compounds to MerB occurs at D99 followed,

113 nlike a direct H shift along the C-C bond in organometallic compounds with a single transition-metal

114 d isolate a myriad of fleeting species (i.e. organometallic compounds, cationic species, radical init

115 es, multiphase systems, slurries, gases, and organometallic compounds.

116 nce to attack by moist air than conventional organometallic compounds.

117 ic demonstration was then accomplished using organometallic condensation reactions under high dilutio

118 we report the synthesis of the mixed-valent organometallic copper APNC, [Cu20(CCPh)12(OAc)6)] (1), v

119 and benzhydryl bromides in competition with organometallic coupling (ipso) is shown.

120 ry alkylaluminum reagents can be utilized as organometallic coupling partners.

121 Over the past several decades, organometallic cross-coupling chemistry has developed in

122 Despite advances in organometallic cross-coupling of alkyl electrophiles, th

123 rcumvents prefunctionalization, isolation of organometallic cross-coupling partners, and/or stoichiom

124 nthetic schemes designed around conventional organometallic cross-coupling.

125 ds, thereby circumventing the preparation of organometallic derivatives and decreasing the overall pr

126 th palladium(II) acetate to give the related organometallic derivatives, but the thiabenziporphyrins

127 e gave excellent yields of the corresponding organometallic derivatives.

128 was converted into silver(III) and gold(III) organometallic derivatives.

129 rk function is substantially lowered with an organometallic donor monolayer, aligning the frontier le

130 ding conjugate bases) yield stronger surface organometallic electrophiles and for this reason have hi

131 identify the final HydG-bound species as an organometallic Fe(CO)2(CN) synthon that is ultimately tr

132 This arrangement includes the biomimetic and organometallic Fe-C sigma bond, which enables bidirectio

133 Cp2, of the {FeNO}(7) complex 1 leads to the organometallic {FeNO}(8) species 2.

134 The organometallic FLP 14 cleaves dihydrogen heterolytically

135 e diene and the five-coordinated 16-electron organometallic fragment 1 (generated from 1-OH2 by facil

136 lkanes bind in preference to the HFCs to the organometallic fragments employed in this study.

137 New organometallic gold(III) and platinum(II) complexes cont

138 of unmodified CDs' inclusion complexes with organometallic guests and update the research in this fi

139 K, the axial spinning motion of the included organometallic guests was slow on the (1)H NMR time scal

140 The organometallic H-cluster at the active site of [FeFe]-hy

141 The organometallic "half-sandwich" compound [Os(eta(6)-p-cym

142 Organometallic halide perovskite solar cells (PSCs) have

143 Two unique organometallic halide series (Ph3P)Au(4-Me-C6H4)(CF3)(X)

144 Highly reproducible organometallic-halide-perovskite-based devices are fabri

145 However, the precise mechanisms by which organometallic interactions are dynamically broken and r

146 Organometallic intermediate species were observed and ch

147 ctive protonation of the penultimate allylic organometallic intermediate.

148 borated through the characterization of both organometallic intermediates and electrophilically quenc

149 rising stability associated with the complex organometallic intermediates generated in the course of

150 HydG generates the first organometallic intermediates in this process, ultimately

151 ethyl group through a series of nickel-based organometallic intermediates.

152 m involving Lewis acid promoted insertion of organometallics into the O-O bond.

153 Organometallic ions were generated by spiking ligands in

154 Organometallic iridium complexes bearing oxidatively sta

155 of H2 by using, in its active site, a unique organometallic iron-guanylylpyridinol (FeGP) cofactor an

156 We developed ATP competitive organometallic kinase inhibitors, EM5 and FL772, which a

157 Organometallic lanthanide compounds first gave a tantali

158 de reduction, which includes metals, alloys, organometallics, layered materials and carbon nanostruct

159 etic hydride acceptor in combination with an organometallic Lewis base, may provide new inspiration f

160 Monocarbaporphyrinoids are superior organometallic ligands and form stable complexes with co

161 ng how covalently bonding, soft, carbocyclic organometallic ligands provide an excellent platform for

162 ly precise nanoclusters (APNCs) protected by organometallic ligands, such as acetylides and hydrides,

163 , Ir) form proteins containing Rh or Ir with organometallic ligands.

164 diversity and potential in e.g. coordination/organometallic main group and transition metal chemistry

165 ared in fair to good yields by a Zn-mediated organometallic Mannich reaction, followed by an intramol

166 suggests that these are of heavy organic or organometallic material.

167 trategy to 'switch on' important yet elusive organometallic mechanisms via oxidation state modulation

168 Organometallic medicinal chemistry is a relatively young

169 From a mechanistic standpoint, an archetypal organometallic mode of reactivity, carbonyl extrusion, h

170 ation of peptides to such medicinally active organometallic moieties started only about 20 years ago,

171 ne (either N- or C-terminally, or both) with organometallic moieties will be described, including the

172 inhibited by cellular debris, embedding the organometallic moiety within a host protein led to promi

173 is challenge was addressed by introducing an organometallic molecular compound, ferrocene, as a new p

174 o study the influence of the anchor group on organometallic molecular transport junctions to achieve

175 Binuclear organometallic molecules are model systems for investiga

176 amin, 1) is one of a few naturally occurring organometallic molecules.

177 ic 1D infinite coordination polymers and two organometallic monometallic complexes of thorium diazide

178 ty years have passed since the foundation of organometallic neptunium chemistry, and yet only a handf

179 ytic systems proposed to involve high-valent organometallic Ni intermediates.

180 evidence for the involvement of high-valent organometallic Ni species, possibly both Ni(III) and Ni(

181 eophyl) allows for the synthesis of isolable organometallic Ni(II), Ni(III), and Ni(IV) complexes.

182 characterization, and reactivity studies of organometallic Ni(III) complexes of general structure Tp

183 port the synthesis and reactivity of several organometallic Ni(III) complexes stabilized by a modifie

184 For example, organometallic Ni(III) intermediates with aryl and/or al

185 trong evidence for the direct involvement of organometallic Ni(III) species in cross-coupling reactio

186 nthesis, and characterization of a series of organometallic Ni(IV) complexes, accessed by the reactio

187 ar from Lactobacillus plantarum possesses an organometallic nickel-containing prosthetic group.

188 thout requiring the previous formation of an organometallic nucleophile.

189 used to form sp(3)-sp(3) bonds that utilize organometallic nucleophiles and alkyl electrophiles.

190 This method demonstrates that chiral organometallic nucleophiles can be successfully used in

191 intermediates that result react in situ with organometallic nucleophiles in a single pot, affording n

192 lkyl-Pd(II) intermediates are intercepted by organometallic nucleophiles or alcohols, under carbonyla

193 lic N-based component and employs "standard" organometallic nucleophiles to introduce the new carbon-

194 trahedral intermediates upon the addition of organometallic nucleophiles.

195 rature and precludes the need to pregenerate organometallic nucleophiles.

196 regiospecific ring-opening at C6 position by organometallic nucleophiles.

197 ic alkoxyl ("RO+") from organic peroxides to organometallics offers a complement to traditional metho

198 es have been altered by their conjugation to organometallic (OM) moieties.

199 mage protection schemes of photobiology, and organometallic opto-electronic materials.

200 The binding of organometallic osmium carbonyl clusters onto the surface

201 Solution-processed organometallic perovskite solar cells have emerged as on

202 grow continuous, pinhole-free thin films of organometallic perovskites with millimeter-scale crystal

203 Organometallic perovskites, solution-processable materia

204 ctive alternatives to the predominantly used organometallic phosphors but are generally dimmer and ar

205 Robust, dense, redox active organometallic poly(ferrocenylsilane) (PFS) grafted film

206 operty relations of a novel, dual-responsive organometallic poly(ionic liquid) (PIL), consisting of a

207 thyltin glutarate) is presented as the first organometallic polymer, a high dielectric constant, and

208 is increased through blending with a second organometallic polymer.

209 as those inorganic polymers (more precisely organometallic polymers) appear to be hitherto the only

210 unanticipated chemical subspaces offered by organometallic polymers.

211 typical laboratory conditions from a simple organometallic precursor.

212 h the preferen-tial adsorption sites for the organometallic precursors prior to reaction.

213 Copper alkanethiolates are organometallic precursors that have been used to form Cu

214 nce studies on electron-induced reactions of organometallic precursors, cis-Pt(CO)2Cl2 (1) was design

215 ic bonds and the nucleation of clusters from organometallic precursors.

216 toward engineering biological catalysts for organometallic processes.

217 unified bonding scheme of carbometalates and organometallics proffered by earlier studies is realized

218 eparation and reactivity of these artificial organometallic proteins demonstrate the potential to stu

219 metal exchange because chelation anchors the organometallic proximal to the electrophilic, tetrasubst

220 anistic studies are consistent with a hybrid organometallic-radical process.

221 o promote cross-coupling reactions involving organometallic reaction intermediates and catalysis by L

222 A bioorthogonal organometallic reaction is a biocompatible transformatio

223 undamental mechanistic insights into complex organometallic reaction pathways.

224 omplexes for which the rates and outcomes of organometallic reactions can be controlled by genetic ma

225 eir rich and varied cycloaddition chemistry, organometallic reactions, and theoretical studies that s

226 ng of C-N, C-O and C-S bonds via fundamental organometallic reactions, i.e. oxidative addition, reduc

227 potential applications for a broad range of organometallic reactions.

228 to gain mechanistic insight into organic and organometallic reactions.

229 ations, cycloadditions, and several types of organometallic reactions.

230 ar Dynamics (AIMD) calculations in modelling organometallic reactivity in water.

231 ural and spectroscopic characterization, and organometallic reactivity of Ni(III) complexes containin

232 This organometallic reagent was shown to be effective in the

233 f sulfonamides through the combination of an organometallic reagent, a sulfur dioxide equivalent, and

234 ides without the need for preformation of an organometallic reagent.

235 e alkylations, only one of which requires an organometallic reagent.

236 etal-trapping strategies with lower polarity organometallic reagents (Mg(CH2 SiMe3 )2 and Al(TMP)iBu2

237 t chemoselectivity gives zinc- and magnesium-organometallic reagents a central position in modern org

238 is of sulfonimidamides from widely available organometallic reagents and amines.

239 classical carbonyl additions, stoichiometric organometallic reagents and discrete alcohol-to-carbonyl

240 pared from the reaction of the corresponding organometallic reagents and sulfur dioxide.

241 onditions that preclude the pregeneration of organometallic reagents and the regioselectivity issues

242 llic reagents, and Csp(2)-centered magnesium organometallic reagents are compatible with important fu

243 Organometallic reagents are generated in situ from alken

244 ve to the longstanding use of stoichiometric organometallic reagents in carbonyl addition.

245 ompatibility, requiring the use of preformed organometallic reagents in conjunction with a stoichiome

246 The range of effective organometallic reagents includes alkyl, allyl, alkynyl,

247 ar fashion through the in-line generation of organometallic reagents is also established.

248 Polyfunctional zinc and magnesium organometallic reagents occupy a central position in org

249 The reactivity of glyconitriles toward organometallic reagents such as organomagnesium or organ

250 Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpe

251 Addition of Grignard or other organometallic reagents to 2-halocyclohex-2-en-1-ones be

252 ng agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boroni

253 anic functional groups are tolerated by zinc organometallic reagents, and Csp(2)-centered magnesium o

254 of which are currently made with pre-formed organometallic reagents, and lead to the discovery of ne

255 al entities not readily accessed using other organometallic reagents, and most recently, the developm

256 amide bond N-C cross-coupling reactions with organometallic reagents, are intrinsically twisted aroun

257 Efficient and general preparations of these organometallic reagents, as well as their most practical

258 =Cl, Br, I) stand out amongst salt-supported organometallic reagents, because apart from their effect

259 ophiles, for instance, alcohols, amines, and organometallic reagents, to provide a broad range of N-f

260 typically predicated on the use of reactive organometallic reagents.

261 al alternative to conventional "organic" or "organometallic" realms.

262 o acids complexed in situ with a nonspecific organometallic receptor.

263 A ferraquinone-ferrahydroquinone organometallic redox couple was prepared and characteriz

264 nd system, was synthesized and coupled to an organometallic rhodium complex designed for photocatalyt

265 Using an organometallic route, the clusters interconvert rapidly

266 A series of organometallic ruthenium(II) complexes containing iminop

267 sumanene (C21 H12 ) affords a novel type of organometallic sandwich [Cs(C21 H11(-) )2 ](-) , which c

268 rate a new synthesis route for the growth of organometallic sandwich molecular nanowires, taking the

269 (V) was the major species where as in juices organometallic Sb species were also present.

270 cesium source for the construction of cesium organometallic scaffolds.

271 l stoichiometric reactions of the artificial organometallic site of this protein, including reactions

272 ls and interfaces explain high efficiency in organometallic solution-processed perovskite films which

273 scope while obviating the need for sensitive organometallic species and by an unprecedented regiosele

274 stoichiometric reactions between heteroaryl organometallic species and silicon electrophiles or dire

275 Cross-couplings of alkyl halides and organometallic species based on single electron transfer

276 The organometallic species involved are derived from nonacti

277 sulfonamides from sulfamoyl inner salts and organometallic species is presented.

278 rboxylic acids with both aryl and heteroaryl organometallic species.

279 differences can be extended to more complex, organometallic species.

280 ntion is given to the seminal stoichiometric organometallic studies which led to the corresponding ca

281 was limited by the tools available for both organometallic synthesis and protein engineering.

282 uting one metal for another in inorganic and organometallic systems is a proven strategy for synthesi

283 One strategy for the creation of new organometallic systems is to exploit the intricate and h

284 ing for on-surface polymerizations and novel organometallic systems preparations.

285 largely unexplored class of one-dimensional organometallic systems with potential for exciting elect

286 Inspired by certain organometallic systems, where ligand-localized phosphore

287 ted to oxidation conditions or exchange with organometallics that are prepared from aryl halides.

288 oaryl, and aryl derivatives) as bench-stable organometallics that can be readily utilized as carbanio

289 We identify Stannin, a peptide involved in organometallic toxicity, as the Hemotin functional homol

290 tes a long-sought opportunity to trap unique organometallic transformations which include instances o

291 n(CO)5 ] is widely recognized as an unstable organometallic transient and is known to dimerize rapidl

292 Here, we describe an alternative to the organometallic transmetallation step that is common in m

293 TMT, LiTMP performs the metalation, while an organometallic trap intercepts the emergent carbanion.

294 Organometallic trihalide perovskites are promising mater

295 l years has witnessed a surge of interest in organometallic trihalide perovskites, which are at the h

296 y of charged domain walls in n- and p- doped organometallic uniaxial ferroelectric semiconductor pero

297 re picture has been derived for these unique organometallic variants of the key bioinorganic {FeNO}(x

298 Organometallics with N-heterocyclic carbene (NHC) ligand

299 on of C-I bonds followed by the formation of organometallic zigzag structures, consisting of molecule

300 l12](6-) nodes in ZrCl2-BTC, and then to the organometallic [Zr6(mu3-O)4(mu3-OLi)4R12](6-) nodes in Z