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1 t by using DMSO as the solvent as well as an oxidant.
2 ith anilines in the presence of periodate as oxidant.
3 c hetero-ene reaction with a chalcogen-based oxidant.
4 roxycarbamate dehydrogenation using a common oxidant.
5 dioxygen (O2 ), to access a high-valent Mn2 oxidant.
6 ons using either H2 O2 or O2 as the terminal oxidant.
7 alytic strategy for generating an iron-bound oxidant.
8 tive activations that use I2 as the terminal oxidant.
9 ion zeroth order in reactants as well as the oxidant.
10 aerial molecular oxygen as a stoichiometric oxidant.
11 generated in the presence of an iodine(III) oxidant.
12 mands strategies to harness O2 as a terminal oxidant.
13 ater in the presense of a hypervalent iodine oxidant.
14 er dependence on the concentration of Cu(II) oxidant.
15 the reduction potential (E degrees ) of the oxidant.
16 ling-CDC) has been developed under air as an oxidant.
17 atalytic benzoisothiazolone/O2 in air as the oxidant.
18 oacetylacetone in the presence of an organic oxidant.
19 oxidant in the presence of O2 as an external oxidant.
20 es, respectively, using nitrosobenzene as an oxidant.
21 t-butyl hydroperoxide (TBHP) as the terminal oxidant.
22 tional 3-chloroperbenzoic acid as a terminal oxidant.
23 d generally considered to be an outer-sphere oxidant.
24 (CH3CN)2] as catalyst and benzoquinone as an oxidant.
25 need for a photocatalyst, light, or a strong oxidant.
26 at 723 K using O2 as an abundantly available oxidant.
27 e and react with proton donors and even mild oxidants.
28 rd reactivity of the indole unit to standard oxidants.
29 icate Laponite, without the use of cytotoxic oxidants.
30 thout the aid of metallic reagents and toxic oxidants.
31 nts such as ascorbic acid, or accelerated by oxidants.
32 m through formation of microbicidal reactive oxidants.
33 es no exogenous photosensitizers or external oxidants.
34 nts and organic electron donors that consume oxidants.
35 high-potential visible-light-absorbing photo-oxidants.
36 method for the quantification of DA-derived oxidants.
37 ts when reacted with different electrophiles/oxidants.
38 rophic SRB partners using soluble artificial oxidants.
39 ounteracts reactive oxygen species and other oxidants.
40 loss processes using newly available marine oxidants.
41 ing survival of S. aureus in the presence of oxidants.
42 ith the aim to create environmentally benign oxidants.
46 stems] as well as for the observation of pro-oxidant activities, with the measurements registering in
49 ed chloride, bromide, and iodide with strong oxidant additives (e.g., hypochlorite, persulfate, hydro
50 radical, whereas reaction with the stronger oxidant AgBF4 formed the metal-free radical dication L(.
54 s at the less steric side using O2 as a sole oxidant and a plausible reaction pathway for the reactio
55 The enzyme uses dioxygen as the terminal oxidant and achieves selectivity for anti-Markovnikov ox
56 ter and pH observed during the 2013 Southern Oxidant and Aerosol Study (SOAS) emphasizes the importan
57 Samples were collected during the Southern Oxidant and Aerosol Study (SOAS) in June-July 2013 near
58 to the continental U.S. during the Southern Oxidant and Aerosol Study (SOAS) to compare the potentia
65 conditions are relatively mild requiring no oxidant and no excess toxic heavy metal and the reagent
71 olar bone loss (ABL) and serum levels of pro-oxidants and antioxidant enzymes in rats with experiment
72 , the present protocol is free from external oxidants and conducting salts, thereby generating nitrog
75 mplications for the response of tropospheric oxidants and stratospheric thermal and mass balance.
76 hydroxyl radical is an important atmospheric oxidant, and a significant source of its production occu
77 reached after excessive exposure to cellular oxidants, and accumulate across different disease states
78 ions, including those promoted by biological oxidants, and its dysfunction has been associated with s
81 phenol found in natural foods, displays anti-oxidant, anti-inflammatory and anti-proliferative proper
83 onal benefits for human health, such as anti-oxidant, antiviral, and liver-protective properties.
88 s the terminal oxidant, or cheap sacrificial oxidants are used, providing a very practical approach f
90 drial bioenergetic capacity and produce more oxidants at birth suggest that the vascular endothelial
91 astas was evaluated by the novel Antioxidant/Oxidant Balance (AOB) parameter, calculated as Antioxida
92 is of alkenes, are considered as atmospheric oxidants besides OH and NO3 radicals as well as ozone.
93 , therapeutically targeting mitochondria and oxidant burden is an effective strategy to alleviate tis
95 The chlorine radical is a potent atmospheric oxidant, capable of perturbing tropospheric oxidative cy
97 without the need of pre-protection or added oxidant, catalyzed by a ruthenium pincer complex, is dev
98 ites on the oligonucleotide generated by two oxidants, catechol/Cu(2+)/NADPH and Fenton's reagent, we
99 ative stress is two sided: Whereas excessive oxidant challenge causes damage to biomolecules, mainten
101 les, maintenance of a physiological level of oxidant challenge, termed oxidative eustress, is essenti
103 lastoma (GBM) cells to ascorbate through pro-oxidant chemistry involving redox-active labile iron and
106 vs NHE], a strong and versatile ground-state oxidant commonly used in organic functional group transf
107 ure of vehicle exhaust that comprised of pro-oxidant constituents of exhaust, namely, carbon dioxide
108 s iron and sulfide in conjunction with rapid oxidant consumption suggested that the sediments harbore
110 wever, evidence has emerged that MPO-derived oxidants contribute to propagation of inflammatory disea
113 oxidative decarboxylations with H2O2 as the oxidant, coproheme III as substrate and cofactor, and he
114 al TEMPO by electron transfer to ferrocenium oxidants coupled to proton transfer to various pyridine
116 ion of DJ-1, which helps orchestrate nuclear oxidant defenses and Sirt3 in mice led to a clear age-re
120 f disturbed flow, inflammatory mediators and oxidants derived from cigarette smoke is known to promot
124 ses as a complementary co-catalyst to common oxidants, e.g., Cu(II) salts, in C-H bond activation and
126 hemolysis, but at high concentrations a pro-oxidant effect on erythrocyte morphology was observed.
128 with Cu((II))ATSM protected against the pro-oxidant effects of angiotensin II (Ang II) by attenuatin
130 cing sustained counter fluxes of sulfide and oxidants, elemental sulfur (S(0))-a key intermediate in
132 The inherently weak O-heteroatom bond in the oxidant enables the versatile reactivities of the initia
133 etic modulation, M2 macrophages and the anti-oxidant enzyme activity but reduced protein oxidation (c
136 ne) are transformed into the highly reactive oxidant [Fe(IV) (O)(TMCO)(OTf)](+) (1; TMCO=4,8,12-trime
139 ursors for dioxiranes, an important class of oxidants for the synthesis of value-added chemicals, and
140 o the mechanisms of the remarkably versatile oxidants formed by nature's most potent oxygenases.
141 xyamides to carboxylic acids, (3) metal- and oxidant-free benzocoumarin synthesis from ortho-aryl-N-m
144 rongly induced by diabetes and inhibits anti-oxidant function of thioredoxin, has been implicated in
145 s in mitochondrial bioenergetic function and oxidant generation in human umbilical vein endothelial c
148 or trend to sustainability, relying on green oxidants H2O2 and O2 as the ultimate oxygen source.
149 Transfer of a second electron to the same oxidant has a much lower thermodynamic driving force and
150 ment to simultaneously maintain Cu(I) and an oxidant has limited its practical utility, especially fo
151 The role of hypervalent iodine reagents as oxidants has been widely recognized for more than 20 yea
154 ies, including anti-cancer, anti-viral, anti-oxidant, hypoglycemic, hypo-lipidemic, and anti-inflamma
156 ectivity by holding the substrate and ferryl oxidant in a specific orientation through hydrogen bondi
157 ivity studies, 2 was shown to be a competent oxidant in an intermetal oxygen atom transfer, C-H bond
158 dation state (Mn(3+) ) is a newly identified oxidant in anoxic environments, whereas acetate is a nat
160 rnessite (delta-MnO2), a naturally occurring oxidant in soils, on the formation of bound residues.
161 n arylamine and then becoming a nucleophilic oxidant in the final oxidation of an aryl-nitroso interm
162 to be ambiphilic, acting as an electrophilic oxidant in the initial N-hydroxylation of an arylamine a
163 emo- and regioselectivity and the effects of oxidant in the intermolecular oxidative C-H/C-H coupling
164 using isotopically labeled oxygen (O2) as an oxidant in the presence of hydrogen peroxide (H2O2), we
165 ized as the nitro source as well as terminal oxidant in the presence of O2 as an external oxidant.
168 demonstrated the presence of a small pool of oxidants in the selected DOM isolates and whole water sa
169 whereas radical cations produced by chemical oxidants in various DNA systems are known to deprotonate
170 hypothesized that prolonged exposure to pro-oxidants in vehicle emissions result in behavioral and c
171 We observed that prolonged exposure to pro-oxidants in vehicle exhaust increased anxiety-and depres
174 MnSOD(K68) SIRT3 enforced expression reduced oxidant-induced AEC OGG1(K338/341) acetylation, mtDNA da
178 cyanate by heme peroxidases to antimicrobial oxidants is an important cornerstone in the innate immun
180 requires only persulfate as a stoichiometric oxidant, making the procedure suitable for the late-stag
181 increased fetal lung expression of the anti-oxidant marker CAT and decreased expression of the pro-o
183 the degree to which processes that influence oxidants may change with climate and owing to a lack of
186 thelial senescence was prevented by the anti-oxidant N-acetyl cysteine, as well as by plumericin and
189 methylate (CM), but not CM, and with an anti-oxidant N-acetylcystein significantly improved pulmonary
192 The reaction proceeds at rt without external oxidants, nitrene stabilizing groups, or directing funct
193 in a PCAP at night with lower NOx and higher oxidants (O3) and oxidized reactive nitrogen (N2O5) alof
194 chemistry of the most important atmospheric oxidants, O3, NO3, and OH, plays a central role in regul
196 questions, we directly tested the individual oxidants on the virulent Pseudomonas aeruginosa strain P
197 monly proposed that this additive acts as an oxidant or as a halide scavenger promoting Pd-catalyst t
200 typically it involves expensive or corrosive oxidants or reaction media that are not amenable to comm
205 many synthetic Mn(IV) -oxo species are mild oxidants, other members of this class can attack strong
206 ng nanostructured semiconductors in which an oxidant (Ox1 ) is used as a catalytic agent to facilitat
207 eaction between a semiconductor and a second oxidant (Ox2 ) that would be unreactive in the primary r
208 oxidation by other environmentally relevant oxidants (ozone, chlorine dioxide, and phosphate and car
210 electrokinetic (EK)-assisted delivery of an oxidant, persulfate (PS), and low temperature electrical
213 ing pathway, indicating that the form of the oxidant plays a key role in the reaction mechanism.
214 OA formed, and an indicator of which of four oxidant precursors was used to initiate reactions (NOx p
216 and in vitro redox assay systems, including oxidant production by transition metals, photodynamic th
217 ualization and measurement of hepatocellular oxidant production during liver ischemia-reperfusion.
218 ss, a state in which intra- or extracellular oxidant production outweighs the antioxidative capacity,
221 ctive enzyme with anti-inflammatory and anti-oxidant properties that is induced in response to multip
224 ng that the amino acid composition-dependent oxidant-quenching role of catalase is more important tha
226 lysis of intra- and extracellularly produced oxidants, respectively, using a single read-out paramete
227 ons but that cigarette smoke induces an anti-oxidant response that appears to reduce endothelial infl
229 2), the master transcription factor for anti-oxidant responses, has also been implicated in inflammas
230 abundance determine the climate response of oxidants, resulting in lower tropospheric O3 in cold cli
233 med without seed and at low concentration of oxidant showed a lower SOA yield than other seeded exper
235 as a novel directing group, Mn(OAc)2 as a co-oxidant (silver free reaction conditions), and absolute
236 constant pH values, due to using a buffered oxidant solution, did not support increased PFAA removal
237 r LPS concentrations and neutrophil reactive oxidant species (ROS) production were observed in PV vs
243 to correct adrenergic dysfunction, elevated oxidant stress and increased thromboxane A2 improve perf
244 enzyme myo-inositol oxygenase (MIOX) induces oxidant stress in vitro However, the relevance of MIOX t
246 logical cascade beginning with mitochondrial oxidant stress leading to oxidized dopamine accumulation
247 ing decreased aerobic respiration, increased oxidant stress, and mitochondrial DNA damage that, in tu
248 well as measures of injury, inflammation and oxidant stress, including production of reactive oxidati
249 circumstances such as chronic inflammation, oxidant stress, local constriction, and injury in trigem
250 glutamate uptake, and elevated mitochondrial oxidant stress, which was ameliorated by NMDA receptor a
252 was blunted in OZR vs. LZR due to increased oxidant stress-based loss of nitric oxide bioavailabilit
257 dary atmospheric aerosols and of atmospheric oxidants such as ozone and the hydroxyl radical, which c
259 ased the resistance of PA14 toward all three oxidants, suggesting that we have discovered a novel, ta
261 e macrophages, these protozoans contain anti-oxidant systems that include iron-dependent superoxide d
264 Widely abundant air acts as the terminal oxidant that avoids the use of a stoichiometric amount o
265 pound 2 proved to be a powerful two-electron oxidant that can add the nitrido ligand to olefin and su
267 potent antioxidant and can also act as a pro-oxidant that induces oxidative stress on the vascular en
269 yl chloride (ClNO2), a source of atmospheric oxidants that is poorly prescribed in atmospheric models
270 e dimetal cofactors with stable one-electron oxidants that serve to initiate the enzyme's free-radica
271 so obtained by reacting 1 with an artificial oxidant (that is, iodosylbenzene) and characterized by v
272 tive capacity of the troposphere directly as oxidants themselves and indirectly via their influence o
273 albumin oxidation, and albumin acts as a pro-oxidant; this promotes oxidative stress and inflammation
274 ical catalytic one, namely quenching harmful oxidants through its recyclable Met residues, resulting
275 s of the initial gold-promoted adduct of the oxidant to alkyne, including its fragmentation into a hi
277 enerated carbazole radical cation acts as an oxidant to return the photocatalyst into the original st
278 onversion of benzene, ethylene, and a Cu(II) oxidant to styrene using the Rh(I) catalyst ((Fl)DAB)Rh(
279 a PA14, antibiotics called phenazines act as oxidants to balance the intracellular redox state of cel
281 ymes tune redox-active cofactors and recruit oxidants to improve the specificity and efficiency of di
282 catalysts are used in the presence of strong oxidants to presumably generate phosphine Au(III) interm
283 hat the addition of peracetic acid, a strong oxidant, to mild dilute acid pretreatment reduces the te
287 H and Mn(IV)-oxo species by channeling these oxidants toward the synthesis of a functionally equivale
289 single-molecule conductance through an acid oxidant triggered phenothiazine (PTZ-) based radical jun
293 It was previously shown that the active oxidant used by CmlI to facilitate this chemistry is a p
294 catalytic amount of I2 and TBHP as the green oxidant via the C-H bond cleavage of the benzylic carbon
295 nd Cl(*)ads) and homogeneous (HOCl and HOBr) oxidants was evaluated on Ti-IrO2 and boron-doped diamon
296 ions using ambient pressure O2 or air as the oxidant while producing water as the only by-product.
297 e appears to exploit this H2O2 as a terminal oxidant while simultaneously defending the cell against
298 s exponentially upon depletion of the peroxo oxidant with a rate constant that is substrate independe
299 netics and products of the reaction of these oxidants with PDI remain incompletely characterized, we
300 catalysis, in which O2 serves as a chemical oxidant without necessitating incorporation of oxygen in
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