ライフサイエンスコーパス: oxidative addition

1 ies, with only one metal catalyst undergoing oxidative addition.

2 n, reductive elimination, and intramolecular oxidative addition.

3 -O2CR), the net product of methoxy group C-O oxidative addition.

4 ces the heterocycles based on chemoselective oxidative addition.

5 d an ionic S(N)1-like mechanism accounts for oxidative addition.

6 n inner-sphere electron-transfer pathway for oxidative addition.

7 is mainly determined by the relative ease of oxidative addition.

8 all criteria of a single-metal two-electron oxidative addition.

9 tive monoligated Pd(0) complex necessary for oxidative addition.

10 oved from each chelate, not the iron) during oxidative addition.

11 ene complexes are intermediates that precede oxidative addition.

12 Br) bonds react with Pd(PPh3)4 to yield net oxidative addition.

13 X, in contradiction to widely held views on oxidative addition.

14 reagents from the surface of the zinc after oxidative addition.

15 r the reluctance of alkyl halides to undergo oxidative addition.

16 ess Ni2(vinylidenoid) intermediates via C-Cl oxidative addition.

17 ement to a eta(2)-PhI intermediate, and Ph-I oxidative addition.

18 ing-opening/closing pathway over a concerted oxidative addition.

19 rs to generate a three-coordinate product of oxidative addition, a metallacyclic version of which has

20 Isolation of the oxidative addition adduct, with structural elucidation b

21 The oxidative-addition adducts, formed using nickel catalysi

22 eoretentive pathway stemming from a directed oxidative addition and a stereoinvertive pathway that is

23 on was devoted to the base effect in the C-O oxidative addition and C-H activation steps as well as t

24 esting state that is the product of N-H bond oxidative addition and coordination of the amide.

25 ng an electron-deficient olefin that directs oxidative addition and facilitates reductive elimination

26 uence of 4-BPin, which slows the rate of C-H oxidative addition and hence overall catalytic turnover.

27 ich compounds and the investigation of their oxidative addition and insertion behavior are reported.

28 Mechanistic considerations argue against oxidative addition and outer-sphere electron transfer pa

29 these compounds was studied with respect to oxidative addition and photoelimination of bromine, whic

30 s system appears to accelerate rate-limiting oxidative addition and promotes the cycle which proceeds

31 a double role in the arylation, facilitating oxidative addition and promoting the subsequent dissocia

32 ral key properties of nickel, such as facile oxidative addition and ready access to multiple oxidatio

33 Reversible single-metal two-electron oxidative addition and reductive elimination are common

34 ent silicon compounds, the interplay between oxidative addition and reductive elimination is key for

35 tal center, which affects the feasibility of oxidative addition and reductive elimination steps that

36 s of the classical organometallic processes, oxidative addition and reductive elimination.

37 this transformation, implicating facile C-H oxidative addition and slow reductive elimination steps.

38 ture of resting states that undergo O-H bond oxidative addition and subsequent olefin insertion to fo

39 nd transfers to a coordinated alkene without oxidative addition and support the conclusion from exper

40 ination number of the species that undergoes oxidative addition and to determine whether the type of

41 Combined with simultaneous control of oxidative addition and transmetalation, this enables che

42 sented, and observable transmetalation, C-Br oxidative addition, and C-C reductive elimination in a m

43 tivity patterns are identified: proton loss, oxidative addition, and dissociation, each of which ofte

44 (enabled by polarity matching), alkyl halide oxidative addition, and reductive elimination to enable

45 his reaction, they are created by reversible oxidative addition, and the high selectivity of this oxi

46 ing of the Ni(0) catalyst and intramolecular oxidative addition are facile in these intermediates.

47 revealed that the transition states for C-H oxidative addition are very late, resembling the aryl ir

48 rate constants of studies on stoichiometric oxidative addition, are consistent with a catalytic proc

49 loidal Ni(0) occurs concomitantly with Ni(0) oxidative addition as an unproductive process.

50 exhibits poor nucleophilicity, but undergoes oxidative addition at ambient temperature of diverse O-H

51 The sigma-SnSn bond of 1 readily undergoes oxidative addition at both gold and copper, giving bis(s

52 ylation of aryl C-H bonds is known to be C-H oxidative addition, but the turnover-limiting step of th

53 ammonia (and water, albeit more slowly), E-H oxidative addition can be shown to be followed by reduct

54 successful implementation of palladium-aryl oxidative addition complexes as stoichiometric reagents

55 The binding of an amine to oxidative addition complexes composed of 1 and 2 is more

56 Lastly, oxidative addition complexes of BrettPhos are included,

57 e binding of a variety amines to monoligated oxidative addition complexes of the type L1Pd(Ar)Cl, whe

58 ternal reducing agent, the in-situ-generated oxidative addition complexes rapidly undergo beta-hydrid

59 amine binding to favorable conformations of oxidative addition complexes.

60 eaction process, which is consistent with an oxidative addition cross-coupling pathway.

61 kinetically reversible reductive-elimination/oxidative-addition exchange of N2 and H2, with an implie

62 to NFBS with inversion of configuration via oxidative addition followed by dissociation of the benze

63 lower C-S coupling and slower carbon-halogen oxidative addition for ortho-substituted aryls.

64 this catalytic reaction (transmetalation --> oxidative addition --> reductive elimination), resulting

65 ntene rearrangement that involves a mutistep oxidative addition/haptotropic shift/reductive eliminati

66 tionalization of the metal alkyl products of oxidative addition has not been fully explored.

67 nce: Pd(0) chemistry comprises discussion on oxidative addition in traditional Pd(0)/Pd(II) cross-cou

68 We therefore propose a catalytic cycle for oxidative addition in which PBut3.HBr reacts with the Pd

69 The isolation and structural analysis of oxidative addition intermediates indicate that the confi

70 d structural studies of neutral and cationic oxidative addition intermediates support a dynamic kinet

71 ta that supports a catalytic cycle involving oxidative addition into the aldehyde C-H bond is also pr

72 ns provide support for a mechanism involving oxidative addition into the carbamoyl chloride bond to g

73 n promotes a Rh(III) intermediate to undergo oxidative addition into the O-N bond to form a Rh(V) nit

74 On bare surfaces, C-H bonds cleave via oxidative addition, involving Pd atom insertion into the

75 ddition step and, most importantly, that the oxidative addition is accelerated by ethylene glycol, mo

76 reaction, for which the site selectivity of oxidative addition is highly dependent on the nature of

77 The two-electron oxidative addition is promising for catalyzing energy st

78 At elevated temperatures, the oxidative addition is shown to be reversible for volatil

79 Preliminary mechanistic studies suggest that oxidative addition is the rate-determining step for this

80 irst structural characterization of MOLP and oxidative addition isomers of the same compound.

81 act as both nucleophile and electrophile in oxidative additions, ligands (e.g., O* on surfaces) abst

82 dition of methyl iodide, indicating that the oxidative addition mechanisms for these two electrophile

83 ene complex with CO or reagents that undergo oxidative addition (MeI and PhOH) lead to release of the

84 acyloxy migration of propargylic esters with oxidative addition, migratory insertion, and reductive e

85 he EC iodination barrier and reduces the I-I oxidative addition (OA) barrier.

86 175 K, E4(2H)* reverts to E4(4H) through the oxidative addition (oa) of the H2.

87 rm equilibria in solution between their In-X oxidative addition (OA) products (Pt(II) indyl complexes

88 ormal d0 zirconium(IV) metal center, halogen oxidative addition occurred to form [N2O2(ox)]ZrCl2(THF)

89 fore isomerization to 1-[eta(2)-NCNMe(2)] no oxidative addition occurs at low temperatures.

90 The preference for syn versus anti oxidative addition of 3-chloro-cyclopentene to Pd(0)L(n)

91 Intermolecular oxidative addition of a benzene C-H bond was directly ob

92 is transformation initially proceeds via the oxidative addition of a C(sp(3) )-H bond and can be reve

93 Me)(2)C(5)H(3)N; R = Me, (i)Pr), resulted in oxidative addition of a C-C bond at ambient temperature

94 Initial mechanistic studies revealed that oxidative addition of a heteroarene C-H bond to a neutra

95 eriments point to a stereoinvertive SN2-like oxidative addition of a nickel complex to the electrophi

96 Specifically, oxidative addition of a Pd(0)-catalyst into the N-O bond

97 is complex upon the third reduction, via the oxidative addition of a proton from the bound water to t

98 Biotin synthase catalyzes the oxidative addition of a sulfur atom to dethiobiotin (DTB

99 Biotin synthase (BS) catalyzes the oxidative addition of a sulfur atom to dethiobiotin (DTB

100 Oxidative addition of alkyl bromide to the Pd(II) center

101 rocess, involving two nickel centers for the oxidative addition of alkyl halide.

102 i* orbital is the key interaction leading to oxidative addition of allyl acetate to M(II).

103 of ancillary ligand energetic effects to the oxidative addition of ammonia to three-coordinate Ir(I)

104 The reaction is triggered by oxidative addition of an activated amide C-N bond to a N

105 step (RLS) in the catalytic cycle is not the oxidative addition of an arene C-H bond; rather, it appe

106 vation step in catalysis ostensibly involves oxidative addition of an aromatic C-H bond to the three-

107 m that appears to involve an unusual initial oxidative addition of an N-O bond to a Pd(0) species.

108 inetic isotope effects show that cleavage by oxidative addition of an O-H bond in H2O is the rate-det

109 d suggest that the catalytic cycle comprises oxidative addition of aniline to form a bis-anilide hydr

110 o(IV) sites after desorption of acetone, and oxidative addition of another propene molecule yielding

111 n reaction is likely to be controlled by the oxidative addition of ArCl to Pd(0).

112 s and the feasibility of Pd(IV) formation by oxidative addition of aryl halides.

113 sign, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered.

114 The facile oxidative addition of Au(I) species additionally demonst

115 The reaction involves the oxidative addition of B2pin2 to 1 to give RhCl(Bpin)2{xa

116 ns, including Suzuki-Miyaura cross coupling, oxidative addition of benzylamine, selective oxidation o

117 II) oxidation state and enables the C-C bond oxidative addition of biphenylene to the corresponding c

118 Parallels may be drawn with the oxidative addition of boron-hydrogen and silicon-hydroge

119 The oxidative addition of Br(2) to tellurophene compounds 1

120 Oxidative addition of BrCN to the metal complexes in sol

121 The oxidative addition of bromine to the isoselenazolone giv

122 We report that oxidative addition of bromobenzene to Pd(PtBu3)2 occurs

123 Oxidative addition of bulky primary, secondary, and tert

124 6H3-2,6-[CH2P(t-Bu)2]2), is found to undergo oxidative addition of C(sp(3))-O bonds of methyl esters

125 a metal centre, transformations that feature oxidative addition of C-C bonds are rare.

126 dies indicate that the reactions proceed via oxidative addition of C-H bonds followed by oxygenate mi

127 But while there are many examples for the oxidative addition of C-H bonds to a metal centre, trans

128 Herein we report the mechanism of oxidative addition of CF3I to Au(I), and remarkably fast

129 of phosphine chelation, direct evidence for oxidative addition of Csp(2)-X bonds (X = I, Br) to a si

130 t undergoes reversible, nearly thermoneutral oxidative addition of dihydrogen to give a borohydrido-h

131 Oxidative addition of E-H bonds (E = H, B, Si, C) was st

132 The oxidative addition of element-hydrogen bonds, for exampl

133 a(6)-C(6)-AcrH)Mo(PMe(3))(3), indicates that oxidative addition of H(2) is promoted by incorporation

134 3), indicates that ring fusion also promotes oxidative addition of H(2).

135 hly reacts with H2 and benzamide PhCONH2 via oxidative addition of H-H and H-N bonds, respectively.

136 sigma-donating boryl ancillary ligands, the oxidative addition of H2 to a single site Sn(II) system

137 nt(P(i)Pr2)2} (7) have also been obtained by oxidative addition of HBR2 to 1.

138 The oxidative addition of HCl to 2 selectively yields the ci

139 cal experiments demonstrate the viability of oxidative addition of I2 to Pd(II).

140 om the more commonly described S(N)2(')-type oxidative addition of low-valent transition metals to mo

141 cally, this process involves the challenging oxidative addition of LPd(0) into the Ar-NO2 bond.

142 re of a palladium complex resulting from the oxidative addition of Me3SiI using an analogous ligand t

143 terized via a rare example of a two-electron oxidative addition of MeI to Ni(I).

144 electron transfer from Nbeta to Ir prior to oxidative addition of MeI to the iridium center.

145 Computed energies of oxidative addition of methane to a series of three- and

146 The trend for oxidative addition of methane to four-coordinate Ir(I) w

147 ncreasing sigma-donation by X also disfavors oxidative addition of N-H bonds to trans-(PH3)2IrX.

148 employed to quantify the enthalpy of the N-H oxidative addition of n-propylamine to 1 ((n)PrNH2 + 1 -

149 well-defined nickelaoxetanes formed via the oxidative addition of nickel(0) with epoxides featuring

150 S-nitrosation is a posttranslational, oxidative addition of NO to cysteine residues of protein

151 his report, we describe a strain-induced C-C oxidative addition of norbornadiene.

152 ling studies rule out a direct four-electron oxidative addition of O2 to one chromium atom, which inv

153 d, in contrast to the extensive chemistry of oxidative addition of other substrates (e.g., H2, HX) to

154 Aza-Heck cyclizations initiated by oxidative addition of Pd(0) -catalysts into the N-O bond

155 th an allenyl-palladium species, formed from oxidative addition of Pd(0) to propargyl carbonates, to

156 The subsequent oxidative addition of Pd(0)L with aryl halide and C-N co

157 The irreversible step of the oxidative addition of PhBr occurred with a bisphosphine

158 The irreversible step of the oxidative addition of PhCl occurred with a monophosphine

159 Enthalpies of oxidative addition of PhE-EPh (E = S, Se, Te) to the M(0

160 The rate-limiting step of the oxidative addition of PhI occurred with L(2)Pd(0) in all

161 binding, eta(1) to eta(2) isomerization, and oxidative addition of PhSSPh has been assembled and give

162 The oxidative addition of PhSSPh to 1-[eta(1)-NCPh] is a rap

163 The oxidative addition of PhSSPh to 1-[eta(2)-NCNMe(2)] also

164 The oxidative addition of PhX (X = I, Br, Cl) to the complex

165 Further oxidative addition of pinacolborane to intermediate 2 le

166 tudies by (13)C-labeling experiments confirm oxidative addition of Pt(II) regioselectively to the lea

167 The reaction begins with oxidative addition of R2 N-OBz to a Pd(0) /PAr3 catalyst

168 e involvement of a Rh-H intermediate through oxidative addition of Rh(I) into the beta-C-H bonds.

169 of dethiobiotin (DTB) to biotin through the oxidative addition of sulfur between two saturated carbo

170 ally a decrease in the rate constant for the oxidative addition of superoxide to Mn2+MnSOD leading to

171 udies, a mechanism is proposed in which both oxidative addition of the aldehyde to give an acyl hydri

172 arbonate anion, which was generated from the oxidative addition of the allylic carbonate, likely acti

173 an allylpalladium(II) intermediate formed by oxidative addition of the allylic pivalate to the Pd(0)

174 priate Grignard reagent or more typically by oxidative addition of the appropriate alkyl bromide to t

175 echanistic features of this reaction are (1) oxidative addition of the aryl halide PhI to Pd(0)/PCy3,

176 ehavior is consistent with turnover-limiting oxidative addition of the aryl halide to Ni(0).

177 he annulation is believed to proceed via (1) oxidative addition of the aryl iodide to Pd(0), (2) syn-

178 r these correlations (1.2-1.7) indicate that oxidative addition of the bromoarene is not the turnover

179 consistent with a catalytic process in which oxidative addition of the bromoarene occurs to [Pd(BINAP

180 9-methyladenine react with [Pt(PPh3)4] under oxidative addition of the C(8)-halogen bond to the metal

181 Oxidative addition of the C(sp)-H bond of methyl propiol

182 Oxidative addition of the C(sp)-H bond of phenylacetylen

183 unanticipated radical chain pathway wherein oxidative addition of the C-Br bond occurs through a bim

184 of a sigma-complex intermediate, followed by oxidative addition of the C-H bond by the rhodium.

185 After oxidative addition of the C-H bond in this mechanism, re

186 m and suggest that the rate-limiting step is oxidative addition of the C-H bond to the metal center.

187 cal catalytic cycle consisting of an initial oxidative addition of the C-OMe bond to Ni(0) species co

188 the aryl ring, which is compatible with the oxidative addition of the copper ion being rate limiting

189 ds by a mechanism involving rate-determining oxidative addition of the diboron to Pd followed by tran

190 onal mechanistic studies revealed an initial oxidative addition of the distal carbon-carbon bond of a

191 s are initiated by loss of a ligand prior to oxidative addition of the hydrosilane or by a metathesis

192 er two products are likely formed by initial oxidative addition of the methyl C-H bond and the subseq

193 ,6-[CH(2)P(t-Bu)(2)](2)) is found to undergo oxidative addition of the methyl-oxygen bond of electron

194 The Pd(II) complex from oxidative addition of the N-X bond has been isolated for

195 for this transformation does not proceed via oxidative addition of the Ni(0) precatalyst into the C-O

196 ovnikov hydrocupration of the o-halostyrene, oxidative addition of the resulting Cu(I) complex into t

197 of platinum and palladium was induced by the oxidative addition of the transition metal into the sili

198 n alkene-mediated S(N)2-type stereoinvertive oxidative addition of unactivated primary and secondary

199 Oxidative addition of vinyl triflate 41 to Pd(0) and the

200 In oxidative additions of C-X bonds to the Pd(0) complexes,

201 Oxidative additions of the N-H bonds of benzophenone hyd

202 ons are performed and are consistent with an oxidative addition/olefin insertion/reductive eliminatio

203 ation occurs on a single metal center, by an oxidative addition on the quartet surface followed by cr

204 he subsequent reaction proceeds by either an oxidative addition or a concerted pathway.

205 anisms based on C-F activation via concerted oxidative addition or electron-transfer processes proved

206 amine and rule out alternative 3-center C-N oxidative addition or Hofmann elimination processes.

207 at the formation of configurationally labile oxidative addition palladacycles is the key for the succ

208 g of amide nucleophiles to a wide variety of oxidative addition partners using Pd-NHC catalysts.

209 ross-coupled product with aryl or heteroaryl oxidative-addition partners, none have shown reliable se

210 proceeds via a rarely precedented concerted oxidative addition pathway.

211 erium-labeling experiment indicates that the oxidative addition proceeds via SN2-type attack of palla

212 that reacts in the irreversible step of the oxidative addition process for complexes 1-4 depends mor

213 omeric alpha-chloroamides in an irreversible oxidative-addition process.

214 e acyl C-O bonds of methyl esters through an oxidative-addition process.

215 xes undergo reversible reductive elimination/oxidative addition processes in solution via thermal and

216 The S-H oxidative addition product (POCOP)Rh(H)(SPh) (16) has be

217 hermal decomposition of the three-coordinate oxidative addition product (PtBu3)Pd(Ar)(Br) during the

218 he azole C-H activation initiated by the C-O oxidative addition product Ni(dcype)(Naph)(PivO), 1B, pr

219 -) and their onward conversion to the formal oxidative addition product Sn(boryl)2(H)(NH2).

220 dynamically favored to produce the mu-oxo or oxidative addition product, Fe(II)-O-Fe(II); nevertheles

221 This compound reacts with H2 to afford the oxidative addition product, in which the hydride ligands

222 e, and evidence for the intermediacy of such oxidative addition products in the catalytic reaction ha

223 ination of L(Cl)Si with Me(3)SnF resulted in oxidative addition products.

224 We proposed a reductive elimination/oxidative addition (re/oa) mechanism for reduction of N2

225 The oxidative addition reaction mechanism was studied using

226 In the latter method, the formal oxidative addition reaction produced ((iPr)PDI)FeBr (1-B

227 hiols were attached at the 6-position via an oxidative addition reaction using I2.

228 nveniently attached at the 5-position via an oxidative addition reaction using iodine.

229 Alternatively, 2 can be prepared by an oxidative-addition reaction of Mes(2)Si(H)OTf (Tf = CF(3

230 -isocyanide Pd(CNAr(Dipp2))(2) is active for oxidative addition reactions and readily reacts with ben

231 lly elucidate the first irreversible step in oxidative addition reactions of a zerovalent nickel cata

232 This silylene species undergoes facile oxidative addition reactions with dihydrogen (at sub-amb

233 a fundamental organometallic reactions, i.e. oxidative addition, reductive elimination, insertion and

234 The oxidative addition-reductive elimination mechanism via a

235 t that the current transformation follows an oxidative addition-reductive elimination pathway.

236 alkylation mechanism for all species is via oxidative addition/reductive elimination (OA/RE).

237 In such cases, the reaction proceeds via an oxidative addition/reductive elimination mechanism invol

238 (f)Cu] is generated from [PhCu] by either an oxidative addition/reductive elimination mechanism or nu

239 Mechanisms involving either oxidative addition/reductive elimination or sigma-bond m

240 ramolecular proton transfer as opposed to an oxidative addition/reductive elimination pathway.

241 nt mechanisms: (i) S(N)2; (ii) S(N)2'; (iii) oxidative-addition/reductive elimination (OA/RE) via an

242 h-energy dissociation of one ligand prior to oxidative addition, rendering the system unreactive.

243 lly a six-electron reductive elimination and oxidative addition, respectively, this represents the fi

244 group that plays a dual role of intercepting oxidative addition species derived from aryl halides and

245 or arms were synthesized via C-X (X = H, Br) oxidative addition, starting from the corresponding [EC(

246 hat the arylation is turnover-limited by the oxidative addition step and, most importantly, that the

247 for the highly nucleophilic character of the oxidative addition step in contrast to the concerted mec

248 clusters, C-H bond activation occurs via an oxidative addition step that involves a three-center (H3

249 e addition, and the high selectivity of this oxidative addition step to form the more stable diastere

250 r served a critical role in facilitating the oxidative addition step.

251 be explained by competitive pathways for the oxidative addition step.

252 step and a subsequent Lewis basic palladium oxidative-addition step.

253 rably destabilized, resulting in more facile oxidative addition; the electron transfer from dz(2) to

254 Like the C-O bond oxidative additions, these reactions also proceed via in

255 thiophene derivatives undergo intramolecular oxidative addition through irreversible pi-complexation.

256 e equally low for the reverse reactions [C-C oxidative addition to ( (H)PCP)Ir].

257 organopalladium(II) intermediate, such that oxidative addition to a carbon electrophile outcompetes

258 lar bond ever observed to undergo reversible oxidative addition to a metal complex.

259 re found to undergo rapid intermolecular N-H oxidative addition to a planar mononuclear sigma(3)-phos

260 demonstrate the first direct observation of oxidative addition to a quinolinium salt.

261 g the E-H bonds in both substrates by formal oxidative addition to afford the corresponding phosphoru

262 a change in turnover limiting step from C-H oxidative addition to C-B reductive elimination.

263 -X bond formation steps may occur via either oxidative addition to form a Ni(IV) intermediate or radi

264 complexes to 4 atm of H2 resulted in facile oxidative addition to furnish the corresponding zirconoc

265 5a), Pd (5b)) with allyl acetate proceed via oxidative addition to give M(IV) species [(CH2CO2-C,O)M(

266 C-H activation routes change from oxidative addition to H-abstraction and then to sigma-bo

267 -BINAP]Ni(eta(2)-NC-Ph) (4), which undergoes oxidative addition to haloarenes at room temperature.

268 (DFT) suggests that the AN path involves C-H oxidative addition to Ir(III) to give Ir(V) with little

269 ally a Ni(III)F430 hydride complex formed by oxidative addition to Ni(I).

270 No base effect in the C(aryl)-O oxidative addition to Ni-dcype was found, but the nature

271 chlorides and bromides that usually undergo oxidative addition to palladium complexes bearing phosph

272 N-Sulfonyl aziridines undergo oxidative addition to palladium(0) complexes generated i

273 oupling of PhI and PHMe(Is) (1) initiated by oxidative addition to Pd(0) yielding Pd((R,R)-Me-Duphos)

274 The oxime N-O bond undergoes oxidative addition to Pd(0)(PCy3)2, and the product of t

275 includes oxidation of Pd(0) to Pd(I) dimers, oxidative addition to Pd(I) dimers, oxidation of Pd(II)

276 ) inserts into the alkyl halide bond through oxidative addition to produce an organonickel species.

277 CF3I undergoes a fast, formal oxidative addition to R3PAuR' (R = Cy, R' = 3,5-F2-C6H4,

278 Oxidative addition to the bis-pyridine Au(I) cation, [Au

279 sulfur substrate that enable the challenging oxidative addition to the C(sp(3))-S bond.

280 eveals a nonradical mechanism involving Ar-X oxidative addition to the Cu(I) center as the rate deter

281 ycle, which is converted into an indoline by oxidative addition to the diaziridinone and two subseque

282 ation, Pd(II) was selectively coordinated by oxidative addition to the surface-bound aryl halide.

283 Alhough vinyl and aryl C-F bonds can undergo oxidative addition to transition metal complexes, this r

284 ins why the few documented examples of H-NH2 oxidative addition to transition metals involve complexe

285 ps that constitute the catalytic cycle, i.e. oxidative addition, transmetalation and reductive elimin

286 ng proceeds through the generic three-stage 'oxidative addition, transmetalation, reductive eliminati

287 Mechanistic studies suggest an oxidative addition/transmetallation pathway.

288 This ranges from facilitating oxidative additions upon d(0) metals or cross coupling r

289 acycles, under conditions-dependent radical (oxidative addition) versus anionic (S(N)Ar) benzannulati

290 ional calculations indicate that a concerted oxidative addition via a classical three-center transiti

291 The kinetics of n-propylamine N-H oxidative addition were monitored by in situ UV absorpti

292 nal studies demonstrate an unprecedented C-H oxidative addition, which is initiated by a triplet exci

293 h(I) center that can efficiently promote the oxidative addition with a low barrier.

294 w the corresponding Ni(II) species undergoes oxidative addition with alkyl halides, as well as rapid

295 alated Pt(II) complexes are known to undergo oxidative addition with appropriate electrophiles (princ

296 The oxidative addition with carbamates or sulfamates occurs

297 e allylic substitution was shown to occur by oxidative addition with inversion of configuration, foll

298 hanism involving nickel(0)-mediated benzylic oxidative addition with inversion of stereochemistry fol

299 lization of a Pd(IV) tris-alkyl moiety after oxidative addition with MeI.

300 e disrupted by excess cyanide, including ArX oxidative addition, X/CN exchange, and ArCN reductive el